High-resolution optical dating of Late Holocene storm surge deposits – a showcase from Schokland (Noordoostpolder,the Netherlands)

Storm surges have a major impact on land use and human habitation in coastal regions. Our knowledge of this impact can be improved by correlating long-term historical storm records with sedimentary evidence of storm surges, but so far few studies have applied such an approach. Here we apply, for the first time, state-of-the-art optically stimulating luminescence (OSL) methods to obtain high-resolution age information on a sequence of Late Holocene storm surge deposits. By combining this chronological framework of storm surges with other reconstruction methods, we investigate the storm surge impact on the former island Schokland, located in a former inlet of the North Sea (central Netherlands).During the Late Holocene, Schokland transformed from a peat area that gradually inundated (~800 CE) via an island in a marginal marine environment (~1600 CE) to a land-locked island in the reclaimed Province of Flevoland (1942 CE). These transitions are recorded in the sediment archive of the island, consisting of silty clay with sandy intervals deposited during storm surges. A series of ten quartz OSL ages, obtained using best-practice methods to deal with incomplete resetting of the OSL signal and dose rate heterogeneity, reveal two periods of storm surge deposition, around 1600 CE and between 1742 and 1822 CE. Historical sources indicate that major storm surges hit Schokland during these periods. Laboratory analyses (thermogravimetry, grain-size, foraminifera, bivalves and ostracods) corroborates the existence of the two sets of storm surge deposits within the clay sequence. Our study sets a benchmark for obtaining robust depositional age constraints from storm surge sediments, and demonstrates the great potential of modern OSL methods to contribute to improved assessment of storm surge risk. © 2018 John Wiley & Sons, Ltd.     

A study of transient variations in the Earth’s electromagnetic field at equatorial electrojet latitudes in western Africa (Mali and the Ivory Coast)

In the framework of the French-Ivorian participation to the IEEY, a network of 10 electromagnetic stations were installed at African longitudes. The aim of this experiment was twofold: firstly, to study the magnetic signature of the equatorial electrojet on the one hand, and secondly, to characterize the induced electric field variations on the other hand. The first results of the magnetic field investigations were presented by Doumouya and coworkers. Those of the electric field experiment will be discussed in this study. The electromagnetic experiment will be described. The analysis of the electromagnetic transient variations was conducted in accordance with the classical distinction between quiet and disturbed magnetic situations. A morphological analysis of the recordings is given, taking into consideration successively quiet and disturbed magnetic situations, with the results interpreted in terms of the characterization of external and internal sources. Particular attention was paid to the effects of the source characteristics on the induced field of internal origin, and to the bias they may consequently cause to the results of electromagnetic probing of the Earth; the source effect in electromagnetic induction studies. During quiet magnetic situations, our results demonstrated the existence of two different sources. One of these, the S_R^E source, was responsible for most of the magnetic diurnal variation and corresponded to the well-known magnetic signature of the equatorial electrojet. The other source (the S_R*^E source) was responsible for most of the electric diurnal variation, and was also likely to be an ionospheric source. Electric and magnetic diurnal variations are therefore related to different ionospheric sources, and interpreting the electric diurnal variation as induced by the magnetic field diurnal variation is not relevant. Furthermore, the magnetotelluric probing of the upper mantle at dip equator latitudes with the electromagnetic diurnal variation is consequently impossible to perform. In the case of irregular variations, the source effect related to the equatorial electrojet is also discussed. A Gaussian model of equatorial electrojet was considered, and apparent resistivities were computed for two models of stratified Earth corresponding to the average resistive structure of the two tectonic provinces crossed by the profile: a sedimentary basin and a cratonic shield. The apparent resistivity curves were found to depend significantly on both the model used and the distance to the center of the electrojet. These numerical results confirm the existence of a daytime source effect related to the equatorial electrojet. Furthermore, we show that the results account for the observed differences between daytime and night-time apparent resistivity curves. In particular, it was shown that electromagnetic probing of the Earth using the classical Cagniard-Tikhonov magnetotelluric method is impossible with daytime recordings made at dip latitude stations.     

A case study of spatial heterogeneity of soil moisture in the Loess Plateau, western China： A geostatistical approach

Soil moisture distribution shows highly variation both spatially and temporally. This study assesses the spatial heterogeneity of soil moisture on a hill-slope scale in the Loess Plateau in West China by using a geostatistical approach. Soil moisture was measured by time-domain reflectometry （TDR） in 313 samples. Two kinds of sampling scales were used （2 × 2 m and 20 ×20 m） at two soil layers （0-30 cm and 30-60 cm）. The general characteristics of soil moisture were analyzed by a classical statistics method, and the spatial heterogeneity of soil moisture was analyzed using a geostatistical approach. The results showed that the spherical model is the best-fit model to simulate soil moisture on the experimental hill-slope. The parameters of this model indicated that the spatial dependence of soil moisture in the selected hill-slope was moderate. Even the 2 × 2 m sampling scale was too coarse to show the detailed spatial variances of soil moisture in this area. The dependent distance increased from 27.4 m to 494.16 m as the sampling scale became coarse （from 2× 2 m to 20 ×20 m）. A map of soil moisture was generated by using original soil moisture data and interpolated values determined by the Kriging method. The average soil moisture （area weighted） in the different layers of soil was calculated on the basis of this map （10.94% for the 0-30 cm soil layer, 11.88% for the 30-60 cm soil layer）. This average soil moisture is lower than the corresponding average effective soil moisture, which suggests that the soil moisture is not sufficient to support vegetation in this area.     

New findings on the tectono-metamorphic history of the western Rhenish Massif (Germany) by K–Ar dating of metasedimentary illite

Metapelites, clay-rich sandstones and volcanics from Cambrian, Ordovician and Lower Devonian strata of the western Rhenish Massif underwent a complex regional Variscan tectono-thermal evolution, as shown by mineralogical and K–Ar isotopic analyses of the illite to mica components from three NW-SE transects. The metamorphic degree extended from an anchimetamorphic to an epimetamorphic intensity during two major episodes of illite crystallization at 328 ± 6 and 282 ± 12 Ma. A further late orogenic or post-orogenic extensional activity could also be detected, but not precisely, around 270 Ma, probably recorded by the precipitation of illite in new or reactivated extensional faults with upward moving heat flows.     

Holocene Earth’s magnetic field variations recorded in marine sediments of the NW African continental margin

Holocene records documenting variations in direction and intensity of the geomagnetic field during the last about seven and a half millennia are presented for Northwest Africa. High resolution paleomagnetic analyses of two marine sediment sequences recovered from around 900 meter water depth on the upper continental slope off Cape Ghir (30°51′N, 10°16′W) were supplemented by magnetic measurements characterizing composition, concentration, grain size and coercivity of the magnetic mineral assemblage. Age control for the high sedimentation rate deposits (∼60 cm/kyr) was established by AMS radiocarbon dates. The natural remanent magnetization (NRM) is very predominantly carried by a fine grained, mostly single domain (titano-)magnetite fraction allowing the reliable definition of stable NRM inclinations and declinations from alternating field demagnetization and principal component analysis. Predictions of the Korte and Constable (2005) geomagnetic field model CALS7K.2 for the study area are in fair agreement with the Holocene directional records for the most parts, yet noticeable differences exist in some intervals. The magnetic mineral inventory of the sediments reveals various climate controlled variations, specifically in concentration and grain size. A very strong impact had the mid-Holocene environmental change from humid to arid conditions on the African continent which also clearly affects relative paleointensity (RPI) estimates based on different remanence normalizers. To overcome this problem the pseudo-Thellier RPI technique has been applied. The results represent the first Holocene record of Earth’s magnetic field intensity variations in the NW Africa region. It displays long term trends similar to those of model predictions, but also conspicuous millennium scale differences.     

Luminescence properties and optically (post-IR blue-light) stimulated luminescence dating of limnic sediments from northern Lake Malawi – Chances and limitations

Affected by the shifting Intertropical Convergence Zone, Lake Malawi holds an outstanding limnic sediment archive storing palaeo-environmental information of a climatically highly responsive landscape in the East African Rift Valley. Reliable chronological data are essential to interpret the lake-bottom sediments and optically stimulated luminescence (OSL) dating is an important method to build up the chronology. We report on material-property studies and OSL-dating results for polymineral fine grains extracted from piston cores obtained from the northern basin of Lake Malawi during the 1998 campaign of the International Decade of the East African Lakes (IDEAL). OSL-dating is based on a post-IR blue (pIRB) light stimulation single aliquot regeneration (SAR) protocol. Our results support earlier publications demonstrating the general applicability of OSL-dating on Lake Malawi sediments of Holocene and late Pleistocene age. However, the study also shows that dose rate estimations imply major challenges which need to be investigated in more detail to improve future OSL-dating results.     

Preliminary study of mollusk fossils in the Qinan Miocene loess-soil sequence in western Chinese Loess Plateau

The Qinan Miocene loess-soil sequence (~22―6.2 Ma)[1] discovered from the Gansu Group[2] several years ago extends the well-known Quaternary loess-soil sequence and the late Tertiary Red Clay se-quence of the Loess Plateau to early Miocene epoch. Most recently, the Dongwan late Miocene–Pliocene loess-soil sequence (~7.1―3.5 Ma)[3] further extends the upper limit of the reported Qinan Miocene loess-soil sequence into the Pliocene. These extensions have great potentials for the study o…     

Spatial distribution of phosphorus forms in sediments in the Gulf of Gdańsk (southern Baltic Sea)

The paper analyses the concentrations of total phosphorus and its forms in sediments from the Gulf of Gdańsk on the basis of studies conducted at 25 sampling sites in 2001–05. The phosphorus speciation analysis was performed by sequential extraction. The extensive spatial variability of P_tot concentrations and speciation was found to be dependent on the physicochemical properties of the sediments, the oxygen conditions in the water and sediments, and the depth of the water column above the sediment surface. In the coastal zone, the sedimentation of riverine suspended matter and the sorption and chemisorption processes exert a considerable influence on P speciation. Over 70% of variation of total phosphorus concentration in sediments in the Gulf of Gdańsk could be explained by changes of proportion of fine fraction of sediments (grain size <0.0625 mm). Maximum P_tot concentrations were recorded in clays and silts in the deep water, stratified part of the Gulf of Gdańsk. In the coastal zone, where sandy sediments are dominant, phosphorus concentrations were much lower; this was due to the considerable dynamics of the bottom water and intensive sea floor transport. P_tot concentrations in the Gulf of Gdańsk sediments ranged from 1.75 to 957.17 μmol g⁻¹ d.w. Of all the forms of phosphorus, the highest concentrations were found for organic phosphorus (Org-P). Of its inorganic forms, the highest concentrations were of phosphorus bound to clay minerals and aluminium oxides (NaOH-P), the lowest ones were of loosely bound phosphorus (NaCl-P). On the basis of determinations of total phosphorus concentrations in sediments of a given type and the available data on the seabed areas covered by particular sediment types in the Gulf of Gdańsk, the mass of total phosphorus in the surficial sediment layer (0–2 cm) was estimated at ca. 15.6×10³ tonnes.     

Source characterization and spatio–temporal evolution of the metal pollution in the sediments of the Basque estuaries (Bay of Biscay)

According to Water Framework Directive requirements, Member States must identify and analyze effects derived from human pressures in aquatic systems. As different kind of pressures can impact water bodies at different scales, analyses of spatio-temporal evolution of water bodies becomes essential in order to understand ecosystem responses. In this investigation, an analysis of spatio-temporal evolution of sedimentary metal pollution (Cd, Cr, Cu, Hg, Ni, Pb, Zn) in 12 Basque estuaries (Bay of Biscay) is presented. Data collected in extensive sampling surveys is the basis for the GIS-based statistical approach used. The implementation of pollution abatement measures is reflected in a long-term decontamination process, mostly evident in estuaries with highest historical sediment pollution levels. Spatial evolution is determined by either naturally occurring or human driven processes. Such spatial processes are more obviously being reflected in estuaries with lower historical sediment pollution levels.     

Magnetic record of El Niño Southern Oscillation in Late Pleistocene sediments from Mucubají lake (western Venezuela)

El Niño Southern Oscillation (ENSO) is an internal forcing of the climate system. This event has an actual frequency of 2 to 8 years. Evidence from a paleoclimate proxy database of gray scale (GS), in samples from Pallcacocha lake in Ecuador, indicates that the ENSO had a frequency of 35 to 75 years during the Late Pleistocene. In this work we explored the possible relationship between the ENSO proxies (GS) from Pallcacocha and magnetic parameters from sediments sampled at the Mucubají lake in Mérida, Venezuela (i.e. mass-specific magnetic susceptibility, magnetic remanence S ratio and susceptibilitynormalized saturation isothermal remanent magnetization). After applying a Lanczos bandpass filter to the rock magnetic and the GS data, in order to remove, as much as possible, frequencies associated to any periodic event other than ENSO, we found significant correlations between GS and magnetic parameters for the period between 12450 and 10560 cal. yrs BP. These relationships were obtained using an Adaptive Neuro Fuzzy Inference System (ANFIS), a hybrid algorithm that combines fuzzy logic with neural networks. The results show that the magnetic parameters obtained in Mucubají are able to explain 50.5% of the total variance of the ENSO proxy in a range of 35 to 75 years in Pallcacocha, which is roughly the same percentage of the total variance of the temperature in the Venezuelan Andes, explained by the ENSO at present times. In this way we have inferred a possible influence of the ENSO in the Venezuelan Andes during the Late Pleistocene.     

Potential of establishing a ‘global standardised growth curve’ (gSGC) for optical dating of quartz from sediments

We report investigations of the optically stimulated luminescence (OSL) signals of sedimentary quartz from different regions of Asia, Africa, Europe and North America using a single-aliquot regenerative-dose (SAR) procedure. We show that variations in the shape of dose response curves (DRCs), or growth curves, of the test dose sensitivity-corrected OSL signals among single aliquots composed of multiple grains can be greatly reduced by normalising the DRCs using one of the regenerative dose OSL signals. We refer to this regenerative-dose normalisation procedure as ‘re-normalisation’. We find a common re-normalised DRC extends to doses of ∼250 Gy for samples that differ significantly in terms of geological provenance, sedimentary context and depositional age. This feature permits the development of a ‘global standardised growth curve’ (gSGC) for OSL signals from single aliquots of quartz. The equivalent dose (D_e) of an aliquot can be estimated from the natural signal, one regenerative dose signal and their corresponding test dose signals. For the variety of samples investigated, we find that D_e estimates obtained from the gSGC are consistent with those obtained using full SAR procedures for doses of up to ∼250 Gy. Use of the gSGC for single aliquots would greatly reduce the time required to estimate the D_e values of older samples and for a large number of aliquots.     

Re-Os (ICP-MS) dating of the massive sulfide ores from the Jinchuan Ni-Cu-PGE deposit

The Jinchuan Ni-Cu-PGE deposit is the largest nickel sulfide deposit in China and the third largest in the world[1]. It is also the largest platinum deposit in China and contains about 60% platinum reserve of China[2]. The Jinchuan intrusion covers only an area of 1.34 km2, but 47.8% of its volume is the orebody. That makes Jinchuan a typical “large ore deposit in a small intrusion”. A number of research works has been car-ried out towards the Jinchuan deposit. Different ore-forming mo…     

A study of the role of ion–molecule chemistry in the formation of sporadic sodium layers

Over two campaigns in 1998 and 1999, multiple sporadic sodium events were observed by the Arecibo Observatory sodium density lidar while simultaneously monitoring the plasma density using the incoherent scatter radar. In this paper, we test the theoretical explanation proposed by Cox and Plane (1998) where Na⁺ in a plasma layer is neutralized via an ion–molecule mechanism to form a sporadic sodium layer. A particular challenge is to interpret observations made in a Eulerian frame of observation where the spatial and temporal characteristics of events cannot easily be separated. The reaction scheme in the original mechanism is modified to include the reactions NaO⁺+N₂→Na⁺·N₂+O and NaO⁺+O₂→Na⁺+O₃, following the results of theoretical quantum calculations. Six unique case studies of sporadic sodium layers are presented here, and excellent agreement between simulation and observations was obtained for five of them.     

Rivers as a source of marine litter – A study from the SE Pacific

Composition and abundance of persistent buoyant litter (plastics, polystyrene and manufactured wood) were investigated at riversides and on adjacent coastal beaches of four rivers flowing into the SE Pacific Ocean. Persistent buoyant litter made up the main share of litter at riversides (36–82%) and on coastal beaches near the river mouths (67–86%). The characteristic litter composition of each river is attributable to human influences along its course. Riverine litter items were deposited to both sides of the river mouths on coastal beaches, and their abundance generally declined with distance from the river mouth. However, maximum litter accumulations were often found on beaches north of the river mouth, suggesting a long-term influence of the prevailing equatorward low-level jet along the Chilean coast. The results confirm that riverine transport has an important impact on litter abundances on coastal beaches.     

Trace element contamination in the estuarine sediments along Tuticorin coast – Gulf of Mannar,southeast coast of India

Sediment samples were collected from Kallar, Korampallam creek and Punnakayal estuaries of Tuticorin coast for assessing the level of contamination by trace elements in these estuarine sediments. The trace element concentration, calcium carbonate, organic carbon and mercury level were analyzed by Inductively Coupled Plasma Atomic Emission Spectrophotometer, Titrimetric method and SnCl₂ reduction method. The results reveals that the enrichment factor, metal pollution index and geo-accumulation index of these estuarine sediments were predominantly polluted by Cd, As, Zn, Hg and Pb. The factor analysis revealed the source of trace element accumulation in the estuarine sediments particularly Mn and Fe are from riverine inputs and As and Hg from untreated industrial effluents. Among the selected estuaries, Korampallam creek was found to be highly contaminated by trace elements due to the discharge of effluents from thermal power plant, Tuticorin alkali chemicals, copper smelting, Petrochemical industries and shipping activities.     

Can we improve the spatial predictions of seabed sediments? A case study of spatial interpolation of mud content across the southwest Australian margin

Spatially continuous data of environmental variables is often required for marine conservation and management. However, information for environmental variables is usually collected by point sampling, particularly for the marine region. Thus, methods generating such spatially continuous data by using point samples to estimate values for unknown locations become essential tools. Such methods are, however, often data- or even variable-specific and it is difficult to select an appropriate method for any given dataset. In this study, 14 methods (37 sub-methods) are compared using samples of mud content with five levels of sample density across the southwest Australian margin. Bathymetry, distance-to-coast, slope and geomorphic province were used as secondary variables. Ten-fold cross validation with relative mean absolute error (RMAE) and visual examination were used to assess the performance of these methods. A total of 1850 prediction datasets are produced and used to assess the performance of the methods and the effects of other factors considered. Considering both the accuracy and the visual examination, we found that a combined method (i.e., random forest and ordinary kriging: RKrf) is the most robust method. This method is novel, with a RMAE up to 17% less than that of the control. No threshold in sample density was detected in relation to prediction accuracy. No consistent patterns are observed between the performance of the methods and data variation. The RMAE of three most accurate methods is about 30% lower than that of the best methods in previous publications, highlighting the robustness of the methods selected in this study. The implications and limitations of this study are discussed and a number of suggestions are provided for further studies.     

Quantifying the actual sediment load flux into Lake Baikal: A case study of the main tributary – The Selenga River (Russia)

The significant reduction of sediment load flux into Lake Baikal from its main tributary – the Selenga River began in the mid-1970s, and can be explained by climate change and socio-economic activities. Integrated analysis was done of changes in hydro-meteorological parameters (water discharge, sediment load, air temperature, and precipitation) and their tendencies over periods of 1946–1975 (baseline) and 1976–2017 (warming). Changes in natural processes and human activity were negligible during the baseline period. In the warming period, against the background of an increase in temperature, the water discharge had a slight decreasing trend (?13%) whereas the sediment load has significantly decreased (?53%) these are consist with the precipitation change (?9.4%). Analysis of hydro-climatic data using statistical methods showed that in the warming period the greatest reduction in river sediment runoff occurred in the interval 1996–2017. In this period the sediment load was 768 × 10³ t/yr, which is less than the average value during the warming period – 1048 × 10³ t/yr. Considering sedimentation in the Selenga River delta, the actual sediment load flux from the Selenga River into Lake Baikal amounted to 515 × 10³ t/yr, which is three times less than the average multiyear value 1535 × 10³ t/yr for observation period (1946–2017).     

Plastic litter in sediments from the Croatian marine protected area of the natural park of Telaščica bay (Adriatic Sea)

This paper reports baseline levels of litter (macro, meso and microplastics) in sediments collected from different areas of the Croatian MPA of the Natural Park of Tela??ica bay (Adriatic Sea, GSA n. 17). The distribution of total abundance according to size, for all analysed locations evidences that microplastics are the dominant fraction concerning item's numbers. In all analysed samples no macroplastics were found, while microplastics are 88.71% and mesoplastics are 11.29% of the total.     

Interbasinal marker intervals—A case study from the Jurassic basins of Kachchh and Jaisalmer,western India

The Kachchh Basin and the Jaisalmer Basin are two neighboring Mesozoic sedimentary basins at the western margin of the Indian craton. The Jurassic succession of the Kachchh Basin is more complete and more fossiliferous than that of the Jaisalmer Basin. Consequently, intrabasinal correlation of the sedimentary units has been possible in the Kachchh Basin, but not in the Jaisalmer Basin. However, some marker beds existing in the Kachchh Basin can be recognized also in the Jaisalmer Basin. Ammonite evidence shows that they are time-equivalent. The following four units form marker intervals in both basins: (1) the pebbly rudstone unit with Isastrea bernardiana and Leptosphinctes of the Kaladongar Formation (Kachchh Basin) and the Isastrea bernardiana-bearing rudstone of the Jaisalmer Formation (Jaisalmer Basin) both represent transgressive systems tract deposits dated as Late Bajocian; (2) bioturbated micrites with anomalodesmatan bivalves within the Goradongar Yellow Flagstone Member (Kachchh Basin) and bioturbated units in the Fort Member (Jaisalmer Basin) represent maximum flooding zone deposits of the Middle to Late Bathonian; (3) trough-crossbedded, sandy pack- to grainstones of the Raimalro Limestone Member (Kachchh Basin) and the basal limestone-sandstone unit of the Kuldhar section of the Jaisalmer Formation (Jaisalmer Basin) correspond to Late Bathonain transgressive systems tract deposits; and (4) ferruginous ooid-bearing carbonates with hardgrounds of the Dhosa Oolite member (Kachchh Basin) and the middle part of the Jajiya Member (Jaisalmer Basin) are Oxfordian transgressive systems tract deposits. The fact that in both basins similar biofacies prevailed during certain time intervals demonstrates a common control of their depositional history. As the two basins represent different tectonic settings, the most likely controlling factors were the relative sea-level changes produced by eustatic processes, a common subsidence history of the northwestern margin of the Indian craton, and the paleoclimate.