n-Alkan-2-one distributions in a northeastern China peat core spanning the last 16 kyr

Most research on long chain methyl ketones has focused on their origins and distributions. Their application in paleoclimate studies is less common than that of other n-alkyl lipids. The goal of this research was to explore this potential by studying n-alkan-2-ones from the Hani peat sequence in northeastern China. They were identified using gas chromatography-mass spectrometry (GC-MS) and showed a distribution ranging from C₁₉ to C₃₁ with a strong odd/even predominance. This type of distribution is considered to derive from Sphagum and microbial oxidation of n-alkanes. Comparison with climate sensitive indicators and macrofossil analysis shows that microbial oxidation of n-alkanes derived from higher plants was enhanced during the warm early Holocene period. This led us to develop three n-alkan-2-one proxies - C₂₇/ΣC_23-31 (C₂₇/HMW-KET), carbon preference index (CPI_H-KET) and average chain length (ACL_(27-31)-KET) - as possible indicators of paleoclimate in the peat-forming environment. These proxies, in combination with C₂₇n-alkane δD values and peat cellulose δ¹⁸O records, might allow examination of paleo-ecosystem behavior during climatic evolution in northeastern China over the past 16,000 yr.     

Organic carbon accumulation over the last 16 kyr off Vancouver Island,Canada: evidence for increased marine productivity during the deglacial

The organic carbon content of marine sediments is commonly used as a proxy for export production. However, in continental margin sediments a large fraction of the organic matter may be of terrestrial origin, and it is necessary to correct the total organic carbon data accordingly. Radiocarbon dating of bulk organic carbon, organic geochemistry and isotope data (δ¹³C and δ¹⁵N) are used here to characterize the type of organic matter present in Core JT96-09 collected at a water depth of 920 m on the slope off Western Canada. The quantities of marine and terrestrial organic carbon are then estimated using the δ¹³C data. The 16 kyr record obtained from Core JT96-09 suggests that accumulation of total organic carbon was highest during the late glacial and deglacial, but geochemical data indicate that as much as 70% of this carbon is terrestrial in origin. When the palaeo-record is corrected for this terrigenous input it is observed that accumulation of marine organic matter, and presumably marine export production, increased at the end of the last glacial contemporaneous with the Bølling, and that it peaked during the Allerød. Data from other palaeoproductivity proxies (i.e., bio-barium, opal and alkenones) also indicate relatively high productivity during the deglacial. These results indicate a return to modern upwelling conditions and high marine export production at ∼14.3 calendar kyr BP and a period of enhanced upwelling, relative to the present, during the Allerød.     

The response of NW Iberian vegetation to North Atlantic climate oscillations during the last 65 kyr

Pollen and oceanographic data from deep ocean core MD95-2039 provide a centennial to millennial scale record of conditions offshore and of the vegetation of north-west Iberia for the period 10–65 ka. The planktonic oxygen isotope record of this core, reflecting predominantly sea surface temperature (SST), shows a pattern of millennial-scale oscillations that is very similar to climatic changes recorded by the Greenland ice core records over the same interval. In turn, tree populations show a pattern of rapid expansions and contractions that follow the pronounced and abrupt isotopic shifts recorded offshore. Through Marine Isotope Stage (MIS) 3, this millennial-scale pattern of vegetation change, alternating between steppe and open woodland, is superimposed on a longer-term pattern of shrinking ericaceous heathland and decreasing size of successive interstadial tree populations. Trees persisted during the Last Glacial Maximum (LGM), at greater abundance than during many of the coldest episodes of MIS 3. This agrees with the marine data which indicate that LGM sea surface temperatures here were significantly warmer than the minima recorded in MIS 3. Our combined marine-terrestrial record, together with data from nearby sequences, provides a stepping stone between terrestrial sequences and the Greenland ice core and North Atlantic marine records. This will permit a better understanding of the behaviour of vegetation across different regions at several scales of climatic forcing.     

Variations of Indian monsoon precipitation during the last 32 kyr reflected in the surface hydrography of the Western Bay of Bengal

Hydrography of the Bay of Bengal is highly influenced by the river runoff and rainfall during the southwest monsoon. We have reconstructed δ¹⁸Osw, sea surface salinity and sea surface temperature (SST) changes in the Bay of Bengal by using paired measurements of δ¹⁸O and Mg/Ca in a planktonic foraminifera species Globigerinoides ruber from core SK218/1 in the western Bay of Bengal in order to understand the rainfall variability associated with southwest monsoon over the past 32 kyr. Our SST reconstructions reveal that Bay of Bengal was ～3.2 °C cooler during the LGM as compared to present day temperature and a ～3.5 °C rise in SST is documented from 17 to 10 ka. Both SST and δ¹⁸Osw exhibit greater amplitude fluctuations during MIS 2 which is attributable to the variability of NE monsoon rainfall and associated river discharge into the Bay of Bengal in association with strong seasonal temperature contrast. On set of strengthening phase of SW monsoon was started during Bølling/Allerød as evidenced by the low δ¹⁸Osw values ～14.7 ka. δ¹⁸Osw show consistently lower values during Holocene (with an exception around 5 ka), which suggests that the freshening of Bay of Bengal due to heavy precipitation and river discharge caused by strong SW monsoon. Results of this study signify that the maximum fluctuations of the NE monsoon rainfall during MIS 2 appear to be controlled by the strong seasonality and boundary conditions.     

Storminess variation during the last 6500 years as reconstructed from an ombrotrophic peat bog in Halland,southwest Sweden

Cores taken from an ombrotrophic peat bog in the coastal zone of Halland, southwest Sweden, were examined for wind transported mineral grains, pollen and humidity indicators. The core covers the period from 6500 cal. yr BP to present. Ombrotrophic conditions existed from ca. 4200 cal. yr BP onwards. Bog surface wetness fluctuated strongly until ca. 3700 cal. yr BP, with an apparent dominance of dry summer conditions from 4800–4500 cal. yr BP. Local wet shifts occurred around 4300, 2800, 2400 and 1500 cal. yr BP, whereas the most recent 600 years of the record show increasingly dry conditions. Mineral grain content, interpreted as aeolian sand influx (ASI), was used as a proxy for (winter) storm frequency and intensity until ca. 1500 cal. yr BP, after which increasing human impact, as reconstructed by pollen analysis, became a second important potential cause for increased sand drift. Strongly increased storminess occurred at 4800, 4200, 2800–2200, 1500, 1100 and 400–50 cal. yr BP, indicating a dominance of cold and stormy winters during these periods. Many of these storm periods apparently coincide with storm events in other sites in southwestern Scandinavia, suggesting that our ASI record reflects a regional scale climatic signal. Furthermore these stormy periods correlate to well‐known cold phases in the North Atlantic region, suggesting a link to large‐scale fluctuations in atmospheric circulation patterns. Copyright © 2006 John Wiley & Sons, Ltd.     

Millennial-scale variations in hydrography and biogeochemistry in the Eastern Equatorial Pacific over the last 100 kyr

In this study, we use records of nitrogen isotope ratios (δ¹⁵N), UK’37 temperature estimates, organic carbon and opal percentages from high-resolution sediment cores located in the eastern equatorial Pacific (EEP) to explore the mechanisms linking millennial-scale changes in low-latitude sea surface temperature, water column denitrification and surface productivity to the timing of northern or southern polar climate during the last 100,000 yr. Our results support a hypothesis that the Southern Hemisphere, and its connection to the low latitudes via shallow subsurface ocean circulation, has a primary influence on the biogeochemistry of the EEP. In addition, our results suggest that, during the last glacial stage, denitrification rates fluctuated on millennial timescales in response to water-column ventilation rather than upstream oxidant demand in intermediate-depth waters.However, due to the poor age constraints available for Marine Isotopic Stage (MIS) 3, the EEP sedimentary data presented here could support two conflicting mechanisms, one driven by enhanced intermediate overturning circulation in the Southern Ocean during Heinrich Events/Antarctic Warm Events, implying that subsurface flow rates control thermocline ventilation, and a second one consistent with more sluggish intermediate circulation during Antarctic Warm Events and giving a central role to the temperature control on oxygen solubility in Southern Ocean surface waters.     

Biomarker records of phytoplankton productivity and community structure changes in the Japan Sea over the last 166 kyr

Glacial-interglacial sea level changes have caused drastic variations in the surface hydrography, ventilation and ecosystem structure in the Japan Sea. Previous reconstructions using microfossils and geochemical proxies suggested decreased productivity and a more calcareous plankton community during glacial periods. However, the inferred community structure change is not consistent with significantly lower salinity in the Japan Sea during the glacials, which would have had a deleterious effect on calcareous plankton growth. Here, biomarker records of ODP Site 797 are generated to further evaluate phytoplankton productivity and community structure changes in the Japan Sea over the last 166 kyr. Although the contents of the phytoplankton biomarkers changed by two to three orders of magnitude, there were no clear glacial-interglacial patterns as sediment biomarker contents reflected the combined effect of production and water column degradation. The collective assessments of our biomarker records and published records support previous conclusions of decreased productivity in the Japan Sea during the glacials. However, a community structure proxy based on the alkenone/brassicasterol ratio reveals a shift from a diatom-dominated community during the glacials to a coccolithophorid-dominated community during the interglacials, mainly as a result of surface salinity variations in the Japan Sea controlled by sea-level changes. Previous community structure reconstruction using biogenic carbonate/silica ratio could have been complicated by the different environmental factors governing silica and CaCO₃ dissolution in the Japan Sea.     

Millennial‐scale stratigraphy of a tide‐dominated incised valley during the last 14 kyr: Spatial and quantitative reconstruction in the Tokyo Lowland,central Japan

Spatial and quantitative analysis of infilling processes of the tide‐dominated incised valleys beneath the Tokyo Lowland during the last 14 kyr was undertaken by using data from 18 sediment cores, 467 radiocarbon dates and 6100 borehole logs. The post‐Last Glacial Maximum valley fills consist of braided river, meandering river, estuary, spit and delta systems in ascending order. The boundary between the estuary and delta systems is regarded as the maximum flooding surface. The maximum flooding surface beneath the Tokyo Lowland is dated at 8 ka in the Arakawa Valley and 7 ka in the Nakagawa Valley. This age difference is due to the migration of the Tone River from the Arakawa Valley to the Nakagawa Valley at 5 ka, and suggests that the widely held view that the global initiation of deltas coincided with the abrupt rise of sea‐level at 9 to 8 ka is true only where there has been steady sediment supply from major rivers. The meandering river system is dominated by sheet‐like sands that were deposited during lateral migration of channels during the Younger Dryas and isolated vertical sands within muds that reflect vertical aggradation of channels before and after the Younger Dryas. The transition between these channel geometries is controlled by a threshold sea‐level rise of 4 to 7 mm yr^?1. Before migration of the Tone River at 5 ka, the tide‐dominated bay in the Nakagawa Valley was filled by upward‐fining laterally accreting muds. The muds accreted from the margin to the axis of the bay. Such lateral accretion of suspended particles derived from outside the bay has been documented in other tide‐dominated coastal environments and is probably common in other similar settings. After the migration of the Tone River, the bay was filled by upward‐coarsening deltaic sediments.     

Chronology of major terrace forming events in the Andaman islands during the last 40 kyr

Major earthquakes that trigger tsunamis are great natural hazards. The devastations caused by the December 26, 2004 Sumatran earthquake, and the March 11, 2011 Japan earthquake, and associated tsunamis will remain in our memories for a long time. Such events reaffirm the need for studying the cause and effects of large earthquakes of the past and to prepare the world better for the future. In such an effort, to understand the pattern of earthquakes and their effects on the geomorphic evolution, we have studied deformation history in the Andaman and Nicobar Islands, located in one of the most active convergent margins of the world. Focusing on tectonically formed coastal terraces and determining the timing of their formation from the exposed dead corals, we have been able to reconstruct the history of major earthquakes in these islands for the last 40 kyr. Our results in conjunction with the existing radiocarbon age data from coastal terraces of these islands appear to suggest that the frequency of major earthquakes (M > 7) in the region has increased during the last 9 kyr. In confirmation with some earlier work, we find evidences for a major earthquake and a tsunami between 500-600 cal yr BP and possibly 4 others during 6–9 cal kyr BP. Our results also indicate that there has been a continuous subsidence of the south Andaman Islands.     

Lignin and fatty acid records in Lake Baikal sediments over the last 130 kyr: A comparison with pollen records

A 10 m sediment core from Academician Ridge in Lake Baikal was analyzed for its molecular composition using on-line TMAH (tetramethylammomium hydroxide) thermochemolysis. Major products are lignin phenols, n-C₁₄ to C₃₀ fatty acids (alkanoic acids), cutin acids, hydroxy acids and aliphatic dicarboxylic acids. Lignin phenols are abundant in warmer periods (the interglacial: marine isotope stage (MIS) 5e and MIS 1), but extremely low in the other (colder) periods. This result coincides well with pollen records reported for a core near the present site, where an expansion of coniferous forests in sub-stage 5e and MIS 1 was implied. Normal C₂₄–C₃₀ alkanoic acids, important components of plant wax esters, are abundant in 5e and MIS 1 and are present in significant amounts in the other (colder) periods, unlike the lignin phenols. A high abundance of n-C₂₄ to C₃₀ alkanoic acids relative to lignin phenols in the Bølling–Allerød warm period suggests an enhanced development of herbs.It is implied from comparison of the sedimentary lignin phenol record with fossil pollen records and lignin phenol analysis of modern pollen that the ratio of cinnamyl phenols to vanillyl phenols may serve as an indicator of pollen contribution to sedimentary organic matter.     

Identification of Icelandic tephras from the last two millennia in the White Sea region (Vodoprovodnoe peat bog,northwestern Russia)

The generation of reliable age models for palaeoenvironmental and archaeological records in the Eurasian Arctic is often problematic when using conventional dating techniques. Tephrochronology can potentially improve the chronologies of such records and synchronise disparate sedimentary archives. However, to date, systematic tephra studies are lacking for this region. This paper presents the first cryptotephra data from the White Sea region (northwestern Russia) based on a peat core spanning the past ~1800 years. We identify seven geochemical glass populations that derive from six Icelandic volcanoes and correlate four of them to north European tephra isochrons; these include Askja ad 1875, the basaltic component of the ad 877 Landnám tephra, and tephras BTD-15 (c. ad 1750–1650) and SL-2/SB-2 (ad 803–767) from unknown eruptions of Katla and Snæfellsjökull, respectively. The remaining three populations originate from Grímsvötn, Hekla and Katla; however, their attribution to individual eruptions remains ambiguous. These findings highlight the potential to extend the Late Holocene tephrochronological framework of northern Europe to the west Eurasian Arctic. The detection of at least three basaltic tephras in the core suggests that basaltic shards can be transported over larger distances than previously known and that peatlands are well suited to preserve such components.     

Environmental changes in southeastern Amazonia during the last 25,000 yr revealed from a paleoecological record

New pollen, micro-charcoal, sediment and mineral analyses of a radiocarbon-dated sediment core from the Serra Sul dos Carajás (southeast Amazonia) indicate changes between drier and wetter climatic conditions during the past 25,000 yr, reflected by fire events, expansion of savanna vegetation and no-analog Amazonian forest communities. A cool and dry last glacial maximum (LGM) and late glacial were followed by a wet phase in the early Holocene lasting for ca. 1200 yr, when tropical forest occurred under stable humid conditions. Subsequently, an increasingly warm, seasonal climate established. The onset of seasonality falls within the early Holocene warm period, with possibly longer dry seasons from 10,200 to 3400 cal yr BP, and an explicitly drier phase from 9000 to 3700 cal yr BP. Modern conditions with shorter dry seasons became established after 3400 cal yr BP. Taken together with paleoenvironmental evidence from elsewhere in the Amazon Basin, the observed changes in late Pleistocene and Holocene vegetation in the Serra Sul dos Carajás likely reflect large-scale shifts in precipitation patterns driven by the latitudinal displacement of the Inter-Tropical Convergence Zone and changes in sea-surface temperatures in the tropical Atlantic.     

A pollen record of the last 450 years from a lowland peat bog on Tristan da Cunha,South Atlantic,implying early anthropogenic influence

A pollen diagram from a small peat bog on the island of Tristan da Cunha in the central South Atlantic (37°05'S,12°17'W) is presented. The pollen diagram contains data from both introduced and native plant taxa. The earliest pollen grains from introduced Plantago lanceolata are dated to around AD 1570, and probably represent unintentional introductions of weeds by the earliest Portuguese explorers visiting the islands. After AD 1600, a greater abundance of pollen from introduced plants and declining tree pollen values indicate opening of the lowland vegetation and more intense land use, probably attributable to the effect of seasonal seal and whale hunters. After AD 1800, evidence of increased erosion and more intense land use are inferred from the pollen diagram, reflecting permanent settlement. Copyright © 2011 John Wiley & Sons, Ltd.     

Distributions and hydrogen isotopic compositions of plant leaf wax from Orinus kokonorica along a general aridity gradient around Lake Qinghai,China

To quantitatively analyze the response of distributions and hydrogen isotopic compositions （SD） of plant leaf wax to moisture, and to better understand their implications for paleoclimatic reconstruction, we measured av- erage chain length （ACL） and 8D values of n-alkanes and n-fatty acids （n-FAs） from Orinus kokonorica, a typical and representative plant in Lake Qinghai area, along a distance transect extending from lakeshore to wetland to dry- land in the arid ecosystem. The results showed that the ACL values of n-alkanes and n-FAs were negatively corre- lated with soil water content （SWC） with R2~0.593 and R2=0.924, respectively. This is as a result of plant＇s response to water loss with more abundance in long-chain n-alkyl lipids under increasing aridity by analyzing relationships between the molecular ratios of long-chain n-alkyl lipids （n-alkanes and n-FAs） from O. kokonorica and SWC. The 8D values of C29 n-alkane and C28 n-FA were also negatively correlated with SWC with R2-0.778 and R2-0.760, respectively, which may due to enhanced D-enrichment in leaf water by evapotranspiration （soil water evaporation and leaf water transpiration） with increasing aridity. Our results demonstrated that moisture exerts a significant con- trol on the ACL and 8D values from O. kokonorica in an arid ecosystem. This preliminary study on a modern single plant （O. kokonorica） sets a foundation for comprehending these values as quantitative proxies for paleo-humidity reconstruction.     

Surface ocean temperatures in the north-east Atlantic during the last 500 000 years: evidence from foraminiferal census data

Abstract Changes in North Atlantic sea surface temperature (SST) are regarded as a key element of the climate during the Quaternary. However, there are relatively few long-term records providing quantitative SST estimates from this region. Using planktic foraminiferal-derived SSTs together with changes on species level and iceberg-rafted debris, the last 500 ka were studied. Pronounced SST changes, as determined from the last glacial–interglacial cycle, characterize most colder periods. Peak interglacial temperatures were found for marine isotope stages (MIS) 1, 5e and 11, the latter two being the warmest. The warm substages within MIS 7 and 9 are marked by enhanced dissimilarity coefficients, indicating that SSTs obtained for these times appear to be overestimated. This is corroborated by differences within the species assemblage, which show enhanced cold water components. It is therefore concluded that detailed analysis down to species level is a crucial prerequisite to better reconstructions of SST.     

Paleoceanographic changes of surface and deep water based on oxygen and carbon isotope records during the last 130 kyr identified in MD179 cores,off Joetsu,Japan Sea

We reconstructed the paleoenvironmental history of surface and deep water over the last 130 kyr from oxygen and carbon isotope ratios of planktonic and benthic foraminifera in two cores (MD179-3312 and MD179-3304) from the Joetsu Basin, eastern margin of the Japan Sea. Our data showed that paleoceanographic changes such as influx of surface currents and vertical circulation were associated with global glacial–interglacial sea level change. Surface water conditions were influenced by the influx of Tsushima Current, East China Sea coastal or off-shore waters through the Tsushima Strait during interglacial or interstadial stages, and strongly affected by freshwater input during the glacial maximum. During interglacial maximums such as Marine Isotope Stages 1 and 5e, development of well-oxygenated bottom water was indicated. A density-stratified ocean with weak ventilation was inferred from the isotopic records of benthic foraminifera during the Last Glacial Maximum. Local negative excursions in carbon isotopes during deglacial or interglacial periods may suggest the dissolution of gas hydrates or methane seep activities.     

Vegetation dynamics in southern France during the last 30 ky BP in the light of marine palynology

The composition of the glacial vegetation of southern French plains has been a matter of debate for several decades. Vegetation is considered as steppic according to French and Spanish lacustrine pollen records whereas cave deposits suggest the presence of mesothermophilous trees through the Last Glacial Maximum. In our paper, we display new palynological records from marine sediments of the Gulf of Lions. They indicate the presence of Abies, Picea and deciduous Quercus in the Gulf of Lions, certainly located in the drainage basins of the Pyreneo-Languedocian rivers. These populations that were sensitive to short climatic events during Marine Isotopic Stage 2 could have been linked to northeastern Spanish and southeastern French relicts already evidenced by phylogenetic data. These trees were absent from the Rhone drainage basin during the deglaciation and certainly also disappeared from the Pyreneo-Languedocian drainage basins from ca 17 to 15 ky cal BP. Finally, the Last Glacial Maximum does not appear as stable, cold and dry as previously thought.     

A detailed pollen record of vegetation and climate changes in Central China during the past 16 000 years

Zhu, C., Ma, C., Yu, S.-Y., Tang, L., Zhang, W. & Lu, X. 2009: A detailed pollen record of vegetation and climate changes in Central China during the past 16 000 years. Boreas , 10.1111/j.1502-3885.2009.00098.x. ISSN 0300-9483.
Detailed pollen analyses, along with magnetic and loss-on-ignition (LOI) measurements, were conducted on a 3 m long peat sequence recovered from the Dajiuhu Basin, the Shennongjia Mountains in Central China. Ten AMS ¹⁴C dates provide a firm age control on this pollen record in terms of vegetation changes governed essentially by the rise and fall of the Asian summer monsoon during the past 16 000 years. Between 16 000 and 12 700 cal. yr BP, pollen assemblages were dominated by coniferous and broad-leaved trees, indicating a mixed forest landscape corresponding to the initial establishment of the monsoonal climate after the Last Glaciation. The progressive increases in percentages of evergreen tree pollen after 12 700 cal. yr BP point to a steady enhancement of the summer monsoon, which was episodically weakened during the Younger Dryas stadial. From 11 000 to 6000 cal. yr BP, values of coniferous and deciduous tree pollen decreased, while evergreen broad-leaved tree pollen increased substantially, implying a stronger than normal monsoonal climate condition corresponding to the Holocene Hypsithermal Interval. A great reduction in the values of evergreen tree pollen at about 4000 cal. yr BP indicates a sudden retreat of the summer monsoon from this area.     

Paleoceanographic conditions in the western Bering Sea as a response to global sea level changes and remote climatic signals during the last 180 kyr

We present results from the sediment core SO201-2-85KL retrieved from the western Bering Sea that recovered the past 180 000 years. For the first time, the intense dissolution of calcareous microfossils has been established when the Bering Strait was open during the glacioeustatic sea level rise. Possible mechanisms of climatic teleconnections between remote regions are considered.     

Paleoclimatic changes during the last 2.5 myr recorded in the Kathmandu Basin,Central Nepal Himalayas

Palynological and sedimentological studies of a series of slimes collected from a 284 m-long drill-well from the Kathmandu Basin reveal paleoclimatic records and environmental changes within the Kathmandu Valley during the last 2.5 myr. The slimes are composed of fluvio-deltaic and lacustrine sediments comprising sand beds of 66.3 m and mud beds of 218 m in length. Pollen analyses show Quercus and Cyclobalanopsis are predominant, with frequencies exceeding 70%. Pinus, Alnus and Gramineae are the next dominant taxa. Three fossil pollen zones were discriminated; each zone reflects major climatic change: Zone I, the oldest stage, indicates a cool and rather wet climate during 400 kyr from ca. 2.5 to 2.1 Ma; Zone II, the middle stage, reflects a warm and relatively dry climate without remarkable fluctuation; Zone III is characterized by seven cycles of warm-and-wet and cold-and-dry climate, which reflect the alternation of glacial and interglacial periods. The last cold maximum, 11 m deep, corresponds to the last glacial age around 20 kyr bp, judging from the ¹⁴C dating of the uppermost part of the lacustrine sediments.The Paleo-Kathmandu Lake is likely to have been initiated at around 2.1 Ma and to have been filled with black organic mud, the Kalimati Clay. The top of the Kalimati Clay is eroded and was overlain by fluvial sand after the last glacial age. The abrupt appearance of a 4 m-thick fossiliferous sand bed at the top of the middle member suggests a lowering of water level at around 1 Ma.