The Origin and Evolution of the Atmospheres of Venus, Earth and Mars

The chemical compositions of the primordial atmospheres of Venus, Earth and Mars have long been a topic of debate between the experts. Some believe that the original atmospheres were a product of outgassed volatiles from the newly accreted terrestrial planets and that these atmospheres consisted primarily of carbon dioxide, nitrogen, water vapor and residual hydrogen and helium (e.g., Lewis and Prinn, <it>Planets and their Atmospheres,</it> Academic Press, Orlando, FL, 1984, pp. 62–63, 81–84, 228–231, 383). Still others think the earliest atmospheres were composed of the gas components of the solar nebula from which the solar system formed (i.e., hydrogen, helium, methane, ammonia and water). I consider the latter to be the correct scenario. Presented herein is a proposed mechanism by which the original atmospheres of Venus, Earth and Mars were transformed to atmospheres rich in carbon dioxide and nitrogen. An explanation is proposed for why water is so common on the surface of Earth and so scarce on the surfaces of Venus and Mars. Also presented are the effects the “great impact” (single cataclysmic event that was responsible for producing the Earth–Moon system) had upon the early atmosphere of Earth. The origin, structure and composition of the impacting object are determined through deductive analyses.     

Studies of Planetary Atmospheres by Stellar Occultations: Application to Mars and Venus

We consider the application of the stellar occultation method to the studies of planetary atmospheres and its history and briefly describe the instruments designed for such measurements (SPICAM/Mars-96, GOMOS/ENVISAT). In comparison with solar occultations, this method allows the profiles to be measured almost at any time of the day and at any location of the planet, irrespective of the orbit of the spacecraft from which observations are carried out. Based on the measuring characteristics of the SPICAM-Light UV spectrometer for the spectral range 118–320 nm with a resolution of 0.9 nm (for the ESA Mars Express Mission; launched in June 2003), we simulate the capabilities of the method to study the Martian atmosphere. In stellar occultation measurements, the stellar spectrum changes because of the absorption by CO₂ and O₃, other gases, and aerosols. The profiles of the CO₂ and O₃ density (and, hence, the temperature) and the aerosol content can be restored by solving the inverse problem. Observations of bright stars (no fewer than 30) three to five times in a turn allow us to measure the atmospheric density at altitudes 10–150 km with an accuracy of about 2% and the temperature at altitudes 20–130 km with an accuracy of 3 K. Ozone is measured with an accuracy of several percent at altitudes 25–40 km or lower, depending on the conditions. Optically thin clouds and hazes, particularly on the nightside where no measurements are possible in reflected light, can be studied. The SPICAV experiment, which is similar to SPICAM-Light, is part of the Venus Express (to be launched in 2005) scientific payload. On Venus, stellar occultations can be used to measure the atmospheric temperature and density above clouds at altitudes up to 130–150 km and to study the SO₂ profile. The results of our simulations can be easily extended to instruments with different measuring characteristics.     

Comparative analysis of Venus and Mars magnetotails

We have an unique opportunity to compare the magnetospheres of two non-magnetic planets as Mars and Venus with identical instrument sets Aspera-3 and Aspera-4 on board of the Mars Express and Venus Express missions. We have performed both statistical and case studies of properties of the magnetosheath ion flows and the flows of planetary ions behind both planets. We have shown that the general morphology of both magnetotails is generally identical. In both cases the energy of the light (H⁺) and the heavy (O⁺, etc.) ions decreases from the tail periphery (several keV) down to few eV in the tail center. At the same time the wake center of both planets is occupied by plasma sheet coincident with the current sheet of the tail. Both plasma sheets are filled by accelerated (500-1000 eV) heavy planetary ions. We report also the discovery of a new feature never observed before in the tails of non-magnetic planets: the plasma sheet is enveloped by consecutive layers of He⁺ and H⁺ with decreasing energies.     

A sensitive search for nitric oxide in the lower atmospheres of Venus and Mars: Detection on Venus and upper limit for Mars

High-resolution spectra of Venus and Mars at the NO fundamental band at 5.3 μm with resolving power ν/δν=76,000 were acquired using the TEXES spectrograph at NASA IRTF on Mauna Kea, Hawaii. The observed spectrum of Venus covered three NO lines of the P-branch. One of the lines is strongly contaminated, and the other two lines reveal NO in the lower atmosphere at a detection level of 9 sigma. A simple photochemical model for NO and N at 50-112 km was coupled with a radiative transfer code to simulate the observed equivalent widths of the NO and some CO₂ lines. The derived NO mixing ratio is 5.5±1.5 ppb below 60 km and its flux is . Predissociation of NO at the (0-0) 191 nm and (1-0) 183 nm bands of the δ-system and the reaction with N are the only important loss processes for NO in the lower atmosphere of Venus. The photochemical impact of the measured NO abundance is significant and should be taken into account in photochemical modeling of the Venus atmosphere. Lightning is the only known source of NO in the lower atmosphere of Venus, and the detection of NO is a convincing and independent proof of lightning on Venus. The required flux of NO is corrected for the production of NO and N by the cosmic ray ionization and corresponds to the lightning energy deposition of . For a flash energy on Venus similar to that on the Earth (∼¹⁰⁹ J), the global flashing rate is ∼90 s⁻¹ and ∼6 km⁻² y⁻¹ which is in reasonable agreement with the existing optical observations. The observed spectrum of Mars covered three NO lines of the R-branch. Two of these lines are contaminated by CO₂ lines, and the line at 1900.076 cm⁻¹ is clean and shows some excess over the continuum. Some photochemical reactions may result in a significant excitation of NO (v=1) in the lowest 20 km on Mars. However, quenching of NO (v=1) by CO₂ is very effective below 40 km. Excitation of NO (v=1) in the collisions with atomic oxygen is weak because of the low temperature in the martian atmosphere, and we do not see any explanation of a possible emission of NO at 5.3 μm. Therefore the data are treated as the lack of absorption with a 2 sigma upper limit of 1.7 ppb to the NO abundance in the lower atmosphere of Mars. This limit is above the predictions of photochemical models by a factor of 3.     

Atmospheric ion wakes of Venus and Mars in the solar wind

A model has been developed for the currents induced in the ionospheres of Venus and Mars by the flowing magnetized solar wind in a previous paper (Cloutier and Daniell, 1973). The altitudes of the ionopauses on both planets, determined from the electrodynamical models of the previous paper, are used here to calculate the total rates of atmospheric mass loss to the solar wind for Venus and Mars. These loss rates are compared to the rates calculated by Michel (1971) based upon the limit of mass loading of the solar wind flow determined from hydrodynamic constraints. The distributions of planetary ions in the downstream wakes of Venus and Mars are calculated, and the interpretation of ion spectrometer measurements from close planetary encounters is discussed.     

Temperature effect on the photodissociation rates in the atmospheres of Mars and Venus

The available solar flux at a given altitude in the atmospheres of Mars and Venus is attenuated mainly by CO₂ (molecular absorption and Rayleigh scattering) with an extra contribution due to SO₂ on Venus. The dissociation cross section of CO₂ depends on temperature. At temperatures appropriate for these atmospheres (～250°K), the cross sections are about 15% lower than those at room conditions (Y.L. Yung and W.B. De More, 1982, Icarus, 51, 199). It is shown that this temperature effect cannot be neglected in the evaluation of photolysis rates. Calculations of the photodissociation coefficients of CO₂, SO₂, HCl, and H₂O are presented. For example, at the surface of Mars, the coefficient of H₂O is nearly multiplied by a factor of 10!     

Spectroscopy and photometry of Mars Trojans

Mars is the only terrestrial planet known to have co-orbiting “Trojan” asteroids. We have obtained visible and near-IR reflectance spectra of three of these objects: 5261 Eureka and 1998 VF31 in the L5 region and 1999 UJ7 in the L4 region. We also obtained JHK spectrophotometry and a visible lightcurve for 5261 Eureka. The asteroid 5261 Eureka has a visible spectrum that is classified as Sr in the Bus taxonomy, and has infrared colors consistent with the A-class asteroids. The data for 1998 VF31 have a restricted wavelength range, but are most consistent with the Sr or Sa class, though we note a marginal consistency with the D class. We can rule out a C-class classification. 1999 UJ7 has an X-class or T-class spectrum, which is unlike that of the other two Mars Trojans. The photometric data for Eureka are limited, but we can constrain the period to longer than 5 hours (likely 5.5-6 hours) and lightcurve amplitude of at least 0.15 magnitude at this viewing geometry. The spectral differences among the Mars Trojans suggests that either they did not all form at their present solar distances or that they have not always been at their present sizes.     

Far-infrared spectral observations of Venus,Mars, and Jupiter

Spectra of Venus, Mars, and Jupiter between 45 and 115 μm have been obtained at a resolving power of ～10, observing from the NASA Lear Jet at an altitude of 13.7 km. The results are calibrated with lunar observations, and show Mars and Venus to have relatively constant brightness temperatures over this wavelength region, with Venus appearing somewhat warmer at longer wavelengths. The brightness temperature of Jupiter decreases slightly toward longer wavelengths.     

Helium on Mars and Venus: EUVE observations and modeling

Long-exposure spectroscopy of Mars and Venus with the Extreme Ultraviolet Explorer (EUVE) has revealed emissions of He 584 Å on both planets and He 537 Å/O⁺ 539 Å and He⁺ 304 Å on Venus. Our knowledge of the solar emission at 584 Å, eddy diffusion in Mars' upper atmosphere, electron energy distributions above Mars' ionopause, and hot oxygen densities in Mars' exosphere has been significantly improved since our analysis of the first EUVE observation of Mars [Krasnopolsky, Gladstone, 1996, Helium on Mars: EUVE and Phobos data and implications for Mars' evolution, J. Geophys. Res. 101, 15,765-15,772]. These new results and a more recent EUVE observation of Mars are the motivation for us to revisit the problem in this paper. We find that the abundance of helium in the upper atmosphere, where the main loss processes occur, is similar to that in the previous paper, though the mixing ratio in the lower and middle atmosphere is now better estimated at 10±6 ppm. Our estimate of the total loss of helium is almost unchanged at 8×¹⁰²³ s⁻¹, because a significant decrease in the loss by electron impact ionization above the ionopause is compensated by a higher loss in collisions with hot oxygen. We neglect the outgassing of helium produced by radioactive decay of U and Th because of the absence of current volcanism and a very low upper limit to the seepage of volcanic gases. The capture of solar wind α-particles is currently the only substantial source of helium on Mars, and its efficiency remains at 0.3. A similar analysis of EUV emissions from Venus results in a helium abundance in the upper atmosphere which is equal to the mean of the abundances measured previously with two optical and two mass spectrometers, and a derived helium mixing ratio in the middle and lower atmosphere of 9±6 ppm. Helium escape by ionization and sweeping out of helium ions by the solar wind above the ionopause is smaller than that calculated by Prather and McElroy [1983, Helium on Venus: implications for uranium and thorium, Science 220, 410-411] by a factor of 3. However, charge exchange of He⁺ ions with CO₂ and N₂ between the exobase and ionopause and collisions with hot oxygen ignored previously add to the total loss which appears to be at the level of 10⁶ cm⁻² s⁻¹ predicted by Prather and McElroy [1983, Science 220, 410-411]. The loss of helium is compensated by outgassing of helium produced by radioactive decay of U and Th and by the capture of the solar wind α-particles with an efficiency of 0.1. We also compare our derived α-particle capture efficiencies for Mars and Venus with observed X-ray emissions resulting from the charge exchange of solar wind heavy ions with the extended atmospheres on both planets [Dennerl et al., 2002, Discovery of X-rays from Venus with Chandra, Astron. Astrophys. 386, 319-330; Dennerl, 2002, Discovery of X-rays from Mars with Chandra, Astron. Astrophys. 394, 1119-1128]. The emissions from both disk and halo on Mars agree with our calculated values; however, we do not see a reasonable explanation for the X-ray halo emission on Venus. The ratio of the charge exchange efficiencies derived from the disk X-ray emissions of Mars and Venus is similar to the ratio of the capture efficiencies for these planets. The surprisingly bright emission of He⁺ at 304 Å observed by EUVE and Venera 11 and 12 suggests that charge exchange in the flow of the solar wind α-particles around the ionopause is much stronger than in the flow of α-particles into the ionosphere.     

Origin and evolution of the atmospheres of early Venus,Earth and Mars

We review the origin and evolution of the atmospheres of Earth, Venus and Mars from the time when their accreting bodies were released from the protoplanetary disk a few million years after the origin of the Sun. If the accreting planetary cores reached masses \(\ge 0.5 M_\mathrm{Earth}\) before the gas in the disk disappeared, primordial atmospheres consisting mainly of H\(_2\) form around the young planetary body, contrary to late-stage planet formation, where terrestrial planets accrete material after the nebula phase of the disk. The differences between these two scenarios are explored by investigating non-radiogenic atmospheric noble gas isotope anomalies observed on the three terrestrial planets. The role of the young Sun’s more efficient EUV radiation and of the plasma environment into the escape of early atmospheres is also addressed. We discuss the catastrophic outgassing of volatiles and the formation and cooling of steam atmospheres after the solidification of magma oceans and we describe the geochemical evidence for additional delivery of volatile-rich chondritic materials during the main stages of terrestrial planet formation. The evolution scenario of early Earth is then compared with the atmospheric evolution of planets where no active plate tectonics emerged like on Venus and Mars. We look at the diversity between early Earth, Venus and Mars, which is found to be related to their differing geochemical, geodynamical and geophysical conditions, including plate tectonics, crust and mantle oxidation processes and their involvement in degassing processes of secondary \(\hbox {N}_2\) atmospheres. The buildup of atmospheric \(\hbox {N}_2\), \(\hbox {O}_2\), and the role of greenhouse gases such as \(\hbox {CO}_2\) and \(\hbox {CH}_4\) to counter the Faint Young Sun Paradox (FYSP), when the earliest life forms on Earth originated until the Great Oxidation Event \(\approx \) 2.3 Gyr ago, are addressed. This review concludes with a discussion on the implications of understanding Earth’s geophysical and related atmospheric evolution in relation to the discovery of potential habitable terrestrial exoplanets.     

Comments about the direct perturbations of Venus and Mars on the Moon's motion

In a previous paper (Standaert, 1980) we have described an algorithm to compute the direct perturbation of the planets on the Moon's motion. A short summary of this algorithm is presented in Section 2 of this paper. Our first results permit us to present some complements and comments about these computations.The algorithm is based upon the Lie transform method and is implemented using Chapront's ELP as solution of the main problem with the partial derivatives of Henrard's Semi-Analytical Lunar Ephemeris (SALE), and Bretagnon's mean Keplerian orbit.An analysis of truncation errors in intermediate results is presented including the resonance effects. The final accuracy of the solution is intended to be about 0.0005 for terms of period up to 2000 yr in the case of Venus and up to 5000 yr in the case of Mars.The effects of second-order terms in the masses are investigated. Only those depending upon the second derivatives of the mean motions are found to be significant to the given accuracy and are included.Proceedings of the Conference on Analytical Methods and Ephemerides: Theory and Observations of the Moon and Planets. Facultés universitaires Notre Dame de la Paix, Namur, Belgium, 28–31 July, 1980.     

Planetary ENA Imaging: Venus and a comparison with Mars

We present simulated images of energetic neutral atoms (ENAs) produced in charge exchange collisions between solar wind protons and neutral atoms in the exosphere of Venus, and make a comparison with earlier results for Mars. The images are found to be dominated by two local maxima. One produced by charge exchange collisions in the solar wind, upstream of the bow shock, and the other close to the dayside ionopause. The simulated ENA fluxes at Venus are lower than those obtained in similar simulations of ENA images at Mars at solar minimum conditions, and close to the fluxes at Mars at solar maximum. Our numerical study shows that the ENA flux decreases with an increasing ionopause altitude. The influence of the Venus nighttime hydrogen bulge on the ENA emission is small.     

Atmospheric acoustics of Titan, Mars, Venus, and Earth

Planetary atmospheres are complex dynamical systems whose structure, composition, and dynamics intimately affect the propagation of sound. Thus, acoustic waves, being coupled directly to the medium, can effectively probe planetary environments. Here we show how the acoustic absorption and speed of sound in the atmospheres of Venus, Mars, Titan, and Earth (as predicted by a recent molecular acoustics model) mirror the different environments. Starting at the surface, where the sound speed ranges from ∼200 m/s for Titan to ∼410 m/s for Venus, the vertical sound speed profiles reveal differences in the atmospheres' thermal layering and composition. The absorption profiles are relatively smooth for Mars, Titan, and Earth while Venus stands out with a noticeable attenuation dip occurring between 40 and 100 km. We also simulate a descent module sampling the sound field produced by a low-frequency “event” near the surface noting the occurrence of acoustic quiet zones.     

Comparison study of magnetic flux ropes in the ionospheres of Venus, Mars and Titan

Magnetic flux ropes are created in the ionosphere of Venus and Mars during the interaction of the solar wind with their ionospheres and also at Titan during the interaction of the Saturnian magnetospheric plasma flow with Titan’s ionosphere. The flux ropes at Venus and Mars were extensively studied from Pioneer Venus Orbiter and Mars Global Surveyor observations respectively during solar maximum. Based on the statistical properties of the observed flux ropes at Venus and Mars, the formation of a flux rope in the ionosphere is thought first to arise near the boundary between the magnetic barrier and the ionosphere and later to sink into the lower ionosphere. Venus flux ropes are also observed during solar minimum by Venus Express and the observations of developing and mature flux ropes are consistent with the proposed mechanism. With the knowledge of flux rope structure in the Venus ionosphere, the twisted fields in the lower ionosphere of Titan from Cassini observations are studied and are found to resemble the Venus flux ropes.     

Spectroscopy of stars in ground-based ultraviolet. II: Atmospheres

Some of the tasks of spectroscopic studies of stellar atmospheres in the ground-based ultraviolet are reviewed in historical perspective. Examples used include fragments of spectra that we obtained with the 6-m telescope of the Special Astrophysical Observatory of the Russian Academy of Sciences     

Exospheric density and escape fluxes of atomic isotopes on Venus and Mars

Energetic neutrals in dissociative recombinations near or above the exobase provide an important component of exospheric density and escape fluxes. Plasma thermal velocities provide the main contribution to the velocity spread and an exact integral for the escape flux applicable in marginal cases is found for a simple atmosphere and collisional cut-off. Atomic fragments from recombination of diatomic oxygen and nitrogen ions in the Venus and Mars atmospheres are examined and density integrals derived. The oxygen escape flux on Mars is half that previously estimated and there is very little isotope preference supplementing diffusive separation. However, escape of the heavier ¹⁵N isotope is low by a factor two. Reinterpretation of its 75% enrichment as detected by Viking leads to a range 0.4–1.4 mbar for the primeval nitrogen content on Mars.     

Comparative planetology, climatology and biology of Venus, Earth and Mars

Spacecraft studies of the three terrestrial planets with atmospheres have made it possible to make meaningful comparisons that shed light on their common origin and divergent evolutionary paths. Early in their histories, all three apparently had oceans and extensive volcanism; Mars and Earth, at least, had magnetic fields, and Earth, at least, had life. All three currently have climates determined by energy balance relationships involving carbon dioxide, water and aerosols, regulated by solar energy deposition, atmospheric and ocean circulation, composition, and cloud physics and chemistry.This paper addresses the extent to which current knowledge allows us to explain the observed state of each planet, its planetology, climatology and biology, within a common framework. Areas of ignorance and mysteries are explored, and prospects for advances in resolving these with missions within the present planning horizon of the space agencies are considered and assessed.     

Ionospheric photoelectrons: Comparing Venus, Earth, Mars and Titan

The sunlit portion of planetary ionospheres is sustained by photoionization. This was first confirmed using measurements and modelling at Earth, but recently the Mars Express, Venus Express and Cassini-Huygens missions have revealed the importance of this process at Mars, Venus and Titan, respectively. The primary neutral atmospheric constituents involved (O and CO₂ in the case of Venus and Mars, O and N₂ in the case of Earth and N₂ in the case of Titan) are ionized at each object by EUV solar photons. This process produces photoelectrons with particular spectral characteristics. The electron spectrometers on Venus Express and Mars Express (part of ASPERA-3 and 4, respectively) were designed with excellent energy resolution (ΔE/E=8%) specifically in order to examine the photoelectron spectrum. In addition, the Cassini CAPS electron spectrometer at Saturn also has adequate resolution (ΔE/E=16.7%) to study this population at Titan. At Earth, photoelectrons are well established by in situ measurements, and are even seen in the magnetosphere at up to 7R_E. At Mars, photoelectrons are seen in situ in the ionosphere, but also in the tail at distances out to the Mars Express apoapsis (∼3R_M). At both Venus and Titan, photoelectrons are seen in situ in the ionosphere and in the tail (at up to 1.45R_V and 6.8R_T, respectively). Here, we compare photoelectron measurements at Earth, Venus, Mars and Titan, and in particular show examples of their observation at remote locations from their production point in the dayside ionosphere. This process is found to be common between magnetized and unmagnetized objects. We discuss the role of photoelectrons as tracers of the magnetic connection to the dayside ionosphere, and their possible role in enhancing ion escape.     

Comparative study of ion cyclotron waves at Mars, Venus and Earth

Ion cyclotron waves are generated in the solar wind when it picks up freshly ionized planetary exospheric ions. These waves grow from the free energy of the highly anisotropic distribution of fresh pickup ions, and are observed in the spacecraft frame with left-handed polarization and a wave frequency near the ion’s gyrofrequency. At Mars and Venus and in the Earth’s polar cusp, the solar wind directly interacts with the planetary exospheres. Ion cyclotron waves with many similar properties are observed in these diverse plasma environments. The ion cyclotron waves at Mars indicate its hydrogen exosphere to be extensive and asymmetric in the direction of the interplanetary electric field. The production of fast neutrals plays an important role in forming an extended exosphere in the shape and size observed. At Venus, the region of exospheric proton cyclotron wave production may be restricted to the magnetosheath. The waves observed in the solar wind at Venus appear to be largely produced by the solar-wind-Venus interaction, with some waves at higher frequencies formed near the Sun and carried outward by the solar wind to Venus. These waves have some similarity to the expected properties of exospherically produced proton pickup waves but are characterized by magnetic connection to the bow shock or by a lack of correlation with local solar wind properties respectively. Any confusion of solar derived waves with exospherically derived ion pickup waves is not an issue at Mars because the solar-produced waves are generally at much higher frequencies than the local pickup waves and the solar waves should be mostly absorbed when convected to Mars distance as the proton cyclotron frequency in the plasma frame approaches the frequency of the solar-produced waves. In the Earth’s polar cusp, the wave properties of ion cyclotron waves are quite variable. Spatial gradients in the magnetic field may cause this variation as the background field changes between the regions in which the fast neutrals are produced and where they are re-ionized and picked up. While these waves were discovered early in the magnetospheric exploration, their generation was not understood until after we had observed similar waves in the exospheres of Mars and Venus.