Airborne spectroscopy and spacecraft radiometry of Venus in the far infrared

In March 1979, the spectrum of Venus was recorded in the far infrared from the G.P. Kuiper Airborne Observatory when the planet subtended a phase angle of 62°. The brightness temperature was observed to be 275°K near 110 cm^?1, dropping to 230°K near 270 cm^?1. Radiance calculations, using temperature and cloud structure formation from the Pioneer Venus mission and including gaseous absorption by the collision-induced dipole of CO₂, yield results consistently brighter than the observations. Supplementing the spectral data, Pioneer Venus OIR data at similar phase angles provide the constraint that any additional infrared opacity must be contained in the upper cloud, H₂SO₄ to the Pioneer-measured upper cloud structure serves to reconcile the model spectrum and the observations, but cloud microphysics strongly indicates that such a high particle density haze $\text{(N ? 1.6 × 10}{}^7\text{cm}{}^{\mathrm{?3}}\text{)}$ is implausible. The atmospheric environment is reviewed with regard to the far infrared opacity and possible particle distribution modifications are discussed. We conclude that the most likely possibility for supplementing the far-infrared opacity is a population of large particles $\text{(}\text{r}\text{? 1 μm)}$ in the upper cloud with number densities less than 1 particle cm^?3 which has remained undetected by in situ measurements.     

On the thermal structure of Uranus

Uranus has an effective temperature close to the solar equilibrium value and undoubtedly a thermal inversion of at least 140 K at a pressure of ～3 dyncm^?2. With the inversion and the thermal opacity provided by a HeH₂ mixture in a ratio close to solar abundance, acceptable agreement can be achieved with the available infrared observations. The cause of the inversion is, however, uncertain. The use of the HeH₂ opacity for Uranus is justified by the excellent agreement of the frequency variation of that opacity with the thermal spectrum of Jupiter.     

Radiative equilibrium model of Titan's atmosphere

A simple global radiative equilibrium model is developed for Titan. It is restricted to the two-stream approximation, is vertically homogeneous in its scattering properties, and is spectrally divided into one thermal and two solar channels. A partially absorbing “violet” channel is responsible for heating in the stratosphere, while a conservatively scattering “red” channel permits heating at the surface. The optical thickness of the atmosphere in the red is 1 < τ₁^r < 3. Between 13 and 33% of the total incident solar radiation is absorbed at the planetary surface. The ratio of violet to thermal infrared absorption cross sections is between 30 and 60 in the stratosphere, leading to the large temperature inversion observed there. The observed and theoretically computed tropopause temperatures are 72 and 69°K, respectively, while their corresponding thermal optical depths are, respectively, ～0.1 and ～0.07. The spectrally integrated mass absorption coefficient at thermal wavelengths is approximately constant throughout the stratosphere and roughly linear with pressure in the troposphere. This in turn implies the presence of a uniformly mixed aerosol in the stratosphere, and suggests pressure-induced absorption by gaseous N₂CH₄H₂ in the troposphere. In addition there appear to be two regions of enhanced opacity near 30 and 500 mbar which may be due to C₂H₂C₂H₆C₃H₈ and CH₄ condensation clouds, respectively.     

The spectra of Uranus and Neptune at 8–14 and 17–23 μm

An array spectrometer was used on the nights of 1985 May 30–June 1 to observe the disks of Uranus and Neptune in the spectral regions 7–14 and 17–23 μm with effective resolution elements ranging from 0.23 to 0.87 μm. In the long-wavelength region, the spectra are relatively smooth with the broad S(1) H₂ collision-induced rotation line showing strong emission for Neptune. In the short-wavelength spectrum of Uranus, an emission feature attributable to C₂H₂ with a maximum stratospheric mixing ratio of 9 × 10⁻⁹ is apparent. An upper limit of 2 × 10⁻⁸ is placed on the maximum stratospheric mixing ratio of C₂H₆. The spectrum of Uranus is otherwise smooth and quantitatively consistent with the opacity provided by H₂ collision-induced absorption and spectrally continuous stratospheric emission, as would be produced by aerosols. Upper limits to detecting the planet near 8 μm indicate a CH₄ stratospheric mixing ratio of 1 × 10⁻⁵ or less, below a value consistent with saturation equilibrium at the temperature minimum. In the short-wavelength spectrum of Neptune, strong emission features of CH₄ and C₂H₆ are evident and are consistent with local saturation equilibrium with maximum stratospheric mixing ratios of 0.02 and 6 × 10⁻⁶, respectively. Emission at 8–10 μm is most consistent with a [CH₃D]/[CH₄] volume abundance ratio of 5 × 10⁻⁵. The spectrum of Neptune near 13.5 μm is consistent with emission by stratospheric C₂H₂ in local saturation equilibrium and a maximum mixing ratio of 9 × 10⁻⁷. Radiance detected near 10.5 μm could be attributed to stratospheric C₂H₄ emission for a maximum mixing ratio of approximately 3 × 10⁻⁹. Quantitative results are considered preliminary, as some absolute radiance differences are noted with respect to earlier observations with discrete filters.     

Airborne spectroscopy of Jupiter in the 100- to 300-cm−1 region: Global properties of ammonia gas and ice haze

A spectrum of the disk of Jupiter was obtained in January 1978 from the Kuiper Airborne Observatory, covering the 100- to 300-cm^?1 spectral range at a resolution corresponding to 1.65 cm^?1. Although taken more than a year before the Voyager 1 Jupiter encounter, this spectrum serves to extend the Voyager IRIS experiment coverage down from its lower limit of 200 cm^?1. Analysis of the spectrum provides information on global mean properties of ammonia gas and an ammonia ice haze. A vertical distribution indistinguishable from saturation equilibrium, with a sharp depletion near the temperature minimum, matches the observed shape of the rotational line absorption best. Constraints on the total optical thickness of the ammonia ice haze can be made, but other properties, such as particle size or vertical scale height, cannot be distinguished clearly from our data in this spectral region. Nevertheless, all models of the haze produce a “continuum” thermal emission between the NH₃ line manifolds which is much lower than that produced by the H₂ collision-induced dipole opacity.     

Cosmic ray synthesis of organic molecules in Titan's atmosphere

We have studied the possible synthesis of organic molecules by the absorption of galactic cosmic rays in an N₂CH₄H₂ Titan model atmosphere. The cosmic-ray-induced ionization results in peak electron densities of 2 × 10³ cm^?3, with NH₄⁺, C₃H₉⁺, and C₄H₉⁺ being among the important positive ions. Details of the ion and neutral chemistry relevant to the production of organic molecules are discussed. The potential importance of $\text{N}\text{(}{}^2\text{D)}$ reactions with CH₄ and H₂ is also demonstrated. Although the integrated production rate of organic matter due to the absorption of the cosmic ray cascade is much less than that by solar ultraviolet radiation, the production of nitrogen-bearing organic molecules by cosmic rays may be greater.     

The structure of cometary atmospheres

The temperature distributions in cometary atmospheres at various heliocentric distances for comets of Bennett and Encke types have been calculated by taking into account heating due to the absorption of solar ultraviolet radiation, cooling by H₂O far infrared emission, and various dynamical processes (expansion, advection, and thermal conduction). The agreement of the results with the observations is in general satisfactory. The conversion of CH₄ and NH₃ to CO and N₂ through thermochemical reaction with H₂O is concluded to be impossible, since the temperature is too low at a heliocentric distance 1.5 AU where CO⁺ ions begin to be observable.     

A study of the 3ν3CH4 region in a high-resolution spectrum of Jupiter recorded by Fourier transform spectroscopy

A spectrum of Jupiter between 6000 and 12 000 cm^? at high resolution (0.05 cm^?) was recorded with a Michelson interferometer at Palomar Mountain in October 1974. An analysis of the R branch of the 3ν₃CH₄ band with the reflecting-layer model, taking into account the H₂ absorption which occurs in the same spectral range, leads to a Lorentzian half-width of 0.09 ± 0.02 cm^?1, a rotational temperature of 175 ± 10° K, and a CH₄ abundance of order 52m atm. Five lines of the ¹³CH₄3ν₃ band have been identified; a comparison with new laboratory spectra indicates that the ¹³CH₄/¹²CH₄ ratio in the Jupiter atmosphere is close to the terrestrial ratio.     

Photochemistry of nitrogen in the Martian atmosphere

Models are developed for the photochemistry of a CO₂H₂ON₂ atmosphere on Mars and estimates are given for the concentrations of N, NO, NO₂, NO₃, N₂O₅, HNO₂, HNO₃, and N₂O as a function of altitude. Nitric oxide is the most abundant form of odd nitrogen, present with a mixing ratio relative to CO₂ of order 10^?8. Deposition rates for nitrite and nitrate minerals could be as large as 3× 10⁵ N equivalent atoms cm^?2 sec^?1 under present conditions and may have been higher in the past.     

Titan: Far-infrared and microwave remote sensing of methane clouds and organic haze

It is shown that Titan's surface and plausible atmospheric thermal opacity sources—gaseous N₂, CH₄, and H₂, CH₄ cloud, and organic haze—are sufficient to match available Earth-based and Voyager observations of Titan's thermal emission spectrum. Dominant sources of thermal emission are the surface for wavelenghts λ ? 1 cm, atmospheric N₂ for 1 cm ? λ ? 200 μm,, condensed and gaseous CH₄ for 200 μm ? λ ? 20 μm, and molecular bands and organic haze for λ ? 20 μm. Matching computed spectra to the observed Voyager IRIS spectra at 7.3 and 52.7° emission angles yields the following abundances and locations of opacity sources: CH₄ clouds: 0.1 g cm^? at a planetocentric radius of 2610–2625 km, 0.3 g cm^?2 at 2590–2610 km, total 0.4 ± 0.1 g cm^–2 above 2590 km; organic haze: $\text{4 ± 2 × 10}{}^{\mathrm{?6}}\text{,}\text{g cm}\text{,}{}^{\mathrm{?2}}$ above 2750 km; tropospheric H₂: 0.3 ± 0.1 mol%. This is the first quantitative estimate of the column density of condensed methane (or CH₄/C₂H₆) on Titan. Maximum transparency in the middle to far IR occurs at 19 μm where the atmospheric vertical absorption optical depth is $\text{?0.6}$ A particle radius $\text{r}\text{? 2 μ}\text{m}$ in the upper portion of the CH₄ cloud is indicated by the apparent absence of scattering effects.     

Local burst model of CMB temperature fluctuations: scattering in primordial hydrogen lines

The propagation of an instantaneous burst of isotropic radiation from the time of its onset at some redshift z ₀ to the time of its detection at the present epoch (at z = 0) is considered within the framework of a flat Universe. Thomson scattering by free electrons and scattering in primordial hydrogen lines (Hα, Hβ, Pα, and Pβ) are believed to be the sources of opacity, with the single-scattering albedo in the lines being calculated by taking into account the deexcitation of the upper levels of the transitions being considered under the action of background blackbody radiation. The profiles of these lines in the burst spectrum at the present epoch have been constructed for various z0 at various distances from the burst center. To a first approximation, these profiles do not depend on the burst radiation spectrum and intensity. It is shown that the lines are purely absorption ones at a sufficiently large distance, but an emission component can appear with decreasing distance, which strengthens as the distance decreases, while the absorption component weakens. The absorption depth in the combined profile can reach 2 ×10^?4 for the Hα and Hβ lines and 7 × 10^?6 for the Pα and Pβ lines. In this case, the relative amplitude of the temperature fluctuations lies within the range 10^?7?10^?9. The calculations have been performed for bursts with different characteristic initial sizes. At the same z ₀, the hydrogen line profiles essentially coincide for sizes smaller than some value, and the contrast of the lines decreases with increasing burst size for greater ones.

     

The microwave absorption of SO2 in the Venus atmosphere

Sulfur dioxide has a strong and complex rotational spectrum in the microwave and far infrared regions. The microwave absorption due to SO₂ in a CO₂ mixture is calculated for conditions applicable to the Venus atmosphere. It is shown that at the concentrations detected by Pioneer-Venus in situ measurements, SO₂ may be expected to contribute significantly to the microwave opacity of the Venus atmosphere. In particular, SO₂ might provide the major source of opacity in the atmospheric region immediately below the main sulfuric acid cloud deck. The spectrum is largely nonresonant at the pressures where SO₂ is expected to occur, however.     

The continuous absorption coefficient of a stellar atmosphere

It is pointed out that, when calculating the continuous absorption coefficient in a stellar atmosphere, it is advantageous to use the coefficient per particle of the most abundant element instead of the usual coefficient per gram of matter. The sources of continuous opacity considered are 1) absorption by H^-, HI, H₂^-, H ₂⁺, HeI, HeII, CI, CII, CIII, NI, NII, OI, OII, NaI, MgI, MgII, AlI, AlII, SiI, SiII, ClI, KI, CaII; and 2) Rayleigh scattering by HI, HeI, CI, NI, OI, H₂, and 3) Thomson scattering of free electrons. The calculations are illustrated by the results for a solar-type photosphere.     

The binary collision-induced second overtone band of gaseous hydrogen: modelling and laboratory measurements

Collision-induced absorption (CIA) is the major source of the infrared opacity of dense planetary atmospheres which are composed of nonpolar molecules. Knowledge of CIA absorption spectra of H₂–H₂ pairs is important for modelling the atmospheres of planets and cold stars that are mainly composed of hydrogen. The spectra of hydrogen in the region of the second overtone at 0.8 μm have been recorded at temperatures of 298 and 77.5 K for gas densities ranging from 100 to 800 amagats. By extrapolation to zero density of the absorption coefficient measured every 10 cm⁻¹ in the spectral range from 11,100 to 13,800 cm⁻¹, we have determined the binary absorption coefficient. These extrapolated measurements are compared with calculations based on a model that was obtained by using simple computer codes and lineshape profiles. In view of the very weak absorption of the second overtone band, we find the agreement between results of the model and experiment to be reasonable.     

Far-infrared opacity sources in Titan’s troposphere reconsidered

We use Cassini far-infrared limb and nadir spectra, together with recent Huygens results, to shed new light on the controversial far-infrared opacity sources in Titan’s troposphere. Although a global cloud of large CH₄ ice particles around an altitude of 30 km, together with an increase in tropospheric haze opacity with respect to the stratosphere, can fit nadir and limb spectra well, this cloud does not seem consistent with shortwave measurements of Titan. Instead, the N₂-CH₄ collision-induced absorption coefficients are probably underestimated by at least 50% for low temperatures.     

Absorption and photodissociation in the Schumann-Runge bands of molecular oxygen in the terrestrial atmosphere

The penetration in the terrestrial atmosphere of solar radiation corresponding to the spectral range of the Schumann-Runge bands of molecular oxygen is analyzed between 1750 and 2050 Å. The variation of the absorption cross section with temperature is taken into account and it is shown that average O₂ absorption cross sections cannot lead to correct photodissociation coefficients. Reduction factors are defined in order to simplify the computation of the molecular oxygen photodissociation and to permit a simple determination of the photodissociation coefficients of any minor constituent with smoothly varying absorption cross section. Examples are given for O₂, H₂O, CO₂, N₂O, HNO₃ and H₂O₂. Numerical approximations are developed for three types of spectral subdivisions: Schumann-Runge band intervals, 500 cm^?1 and 10 Å intervals. The approximations are valid from the lower thermosphere down to the stratosphere and they can be applied for a wide range of atmospheric models and solar zenith distances.     

Venus cloud properties: Infrared opacity and mass mixing ratio

By using the Mariner 5 temperature profile and a homogeneous cloud model, and assuming that CO₂ and cloud particles are the only opacity sources, the wavelength dependence of the Venus cloud opacity is infrared from the infrared spectrum of the planet between 450 and 1250 cm^?1. Justification for applying the homogeneous cloud model is found in the fact that numerous polarization and infrared data are mutually consistent within the framework of such a model; on the other hand, dense cloud models are not satisfactory.Volume extinction coefficients varying from 0.5 × 10^?5 to 1.5 × 10^?5 cm^?1, depending on the wavelength, are determined at the tropopause level of 6110 km. By using all available data, a cloud mass mixing ratio of approximately 5 × 10^?6 and a particle concentration of about 900 particles cm^?3 at this level are also inferred. The derived cloud opacity compares favorably with that expected for a haze of droplets of a 75% aqueous solution of sulfuric acid.     

Can the ion H3 + account for missing opacity in the solar ultraviolet?

Limb darkening and specific intensity data imply more continuous opacity in the solar photosphere between 2000 Å and 3500 Å than has been predicted theoretically. The temperature dependence and wavelength dependence of this missing opacity are in qualitative agreement with those deduced for the ion H₃ ⁺, but it is unlikely that H₃ ⁺ is sufficiently abundant to account for this opacity.     

Venus: Preliminary prediction of the mineral composition of surface rocks

A thermodynamical analysis of the multicomponent system SiTiAlFeMnMgCaNaKPCHO open with respect to CO₂, CO, H₂O was carried out. Hydration and carbonatization processes are proposed to be geochemical consequences of the hypothesis of quasi-equilibrium conditions between the troposphere and crustal surface rocks. The probable rock-forming hydrated mineral phases are represented by epidote, glaucophane, tremolite, phlogopite, and annite; the carbonatization results in existence of calcite and dolomite as rock-forming minerals of weathered alkaline lavas. The surface rocks are assumed to have high ferric/ferrous iron ratios. The wollastonite equilibrium is rejected as a buffering chemical reaction. Hydrated minerals could be stable at least up to 5-km depths and contribute about 0.1 × 10²⁴ g of H₂O whereas about (0.7–0.8) × 10²⁴ g of H₂O would be consumed in ferrous iron oxidation with concomitant hydrogen dissipation. The distribution of H₂O in the outer planetary shells is possibly a function of their temperatures.     

Models of the cometary coma in which abundances are calculated for various heliocentric distances

One-dimensional radial models of the chemistry in cometary comae have been constructed for heliocentric distances ranging from 2 to 0.125 AU. The coma's opacity to solar radiation is included and photolytic reaction rates are calculated. A parent volatile mixture similar to that found in interstellar molecular clouds is assumed. Profiles through the coma of number density and column density are presented for H₂O, OH, O, CN, C₂, C₃, CH, and NH₂. Whole-coma abundances are presented for NH₂, CH, C₂, C₃, CN, OH, CO⁺, H₂O⁺, CH⁺, N₂⁺, and CO₂⁺.