Methane in the water and bottom sediments of the mouth area of the Severnaya Dvina River (White Sea)

The mouth area of the Severnaya Dvina River is characterized by a high level of methane in the water (from 1.0 to 165.4 μl/l) and in the bottom sediments (from 14 to 65000 μl/kg), being quite comparable to the productive mouth areas of the rivers in the temperate zone. The maximum methane concentrations in the water and sediments were registered in the delta in the segments of channels and branches with low rates of tidal and runoff currents to which domestic and industrial wastewaters are supplied. In the riverine and marine water mixing zone with its upper boundary situated far into the delta and displaced depending on the phase of the tidal cycle, a decrease of the methane amount with the salinity increase was observed. The prevailing role in the formation of the methane content level in the water of the mouth area pertains to the bottom sediments, which is testified to by the close correlation between the gas concentrations in these two media. The existence of periodicity in the variations of the methane content level in the water of the river downstream caused by the tidal effects was found.     

Early diagenesis in recent bottom sediments of the Dvina Bay (White Sea)

Investigations in the water column and bottom sediments including entrapped water were carried out on expeditions of the P.P. Shirshov Institute of Oceanology in the Dvina Bay, the White Sea. We studied the transformation of particulate organic matter at the biogeochemical barrier between the water and bottom and in the underlying Holocene sediments. Low rates of the early diagenesis of sediments caused by low values of primary production in the conditions of high fluxes of terrigenous organic matter were established. The low temperatures of microorganisms habitat play the secondary role.     

Methane in the water and bottom sediments of the mouth area of the Severnaya Dvina River during the winter time

The spatial distribution of methane in the water and bottom sediments of the mouth area of the Severnaya Dvina River shows quite a similar character during the ice-cover and summer periods. It is characterized by the increase of the gas content from the head of the mouth area towards the delta with maximum values at the sites subjected to permanent anthropogenous impact. The difference consists in the higher level of the methane content in the bottom sediments during the winter period. At the same time, the excess of the winter to summer concentrations in the water was registered only at the stations within the impact area of the sources of anthropogenous contamination. As in the summer, the bottom sediments have a prevailing role in the formation of the level of the methane content in the water of the mouth area. The linear dependence between the concentrations of the total hydrogen sulfide and methane in the surface layer of the riverine sediments is probably caused by the parallel and nonconcurrent proceeding of the generation of these gases, which are controlled by the bacterial communities being not inhibitory to each other.     

Mineral composition of the modern bottom sediments of the White Sea

The mineral composition of the modern bottom sediments were studied in the White Sea. The single terrigenous-mineralogical province is defined; it is characterized by the mineral association of amphibole, epidote, garnet, and pyroxene. Five regions are assigned in the White Sea in accordance with the mineral composition of the surface bottom sediments. We argue that the granite-metamorphic rock complexes of the Baltic Shield are the main source of the modern sediments in the White Sea, while the East European Craton (Russian Platform) plays a secondary role.     

Composition of the suspended particulate matter at the Severnaya Dvina River mouth (White Sea) during the spring flood period

The grain-size and mineral composition of the suspended particulate matter (SPM) of the Severnaya Dvina River mouth is studied, as well as the content of several lithogenic elements in the SPM during the spring flood in May 2004. The data published on the composition of the riverine SPM in the White Sea basin are very poor. The spring flood period when more than half of the annual runoff is supplied from the river to the sea in a short time is understood more poorly. The report considers the comparison results for the grain-size compositions of the SPM and the bottom sediments. The data of laser and hydraulic techniques of the grain-size analysis are compared. The short-period variations of the SPM concentration and composition representing two diurnal peaks of the tide level are studied. It is found that the SPM is mainly transferred during the spring flood as mineral aggregates up to 40 μm diameter. The sandysilty fraction of the riverine SPM settles in the delta branches and channels, and the bulk of the fine pelitic matter is supplied to the sea. The mineral and chemical composition of the Severnaya Dvina River SPM is determined by the supply of substances from the drainage basin. This substance is subjected to intense mechanic separation during the transfer to the sea. The key regularities of the formation of the mineral composition of the SPM during the flood time are revealed. The effect of the grain-size composition of the SPM on the distribution of the minerals and elements studied in the dynamic system of the river mouth are characterized.     

The inhabitants of the spring ice,under-ice water,and sediments of the white sea in the estuarine zone of the Severnaya Dvina River

The data on the supra-ice snow, ice, under-ice water, and benthic algal flora obtained in 2007–2008 by sampling in the estuary of the Severnaya Dvina River are analyzed. The river ice and under-ice water in the estuarine zone and in the channel part of the Severnaya Dvina differed greatly in the algal flora’s composition. The fresh water species never exceeded 8.6%, while the ice algae composed 90–96% of the total ice inhabitants’ biomass. In the under-ice water, this value did not exceed 58–64%. The bacteria in the ice composed not more than 2.5–10% of the total biomass, while, in the under-ice water, 36–49%. The shares of ciliates (0.04%) and nematodes (0.005–1.6%) in the total biomass were negligible. In the estuarine zone, the ice was inhabited mainly by nematodes (78% of the total biomass), while, in the river, their share decreased to 9%. The contribution of bacteria was 15% in Dvina Bay and increased to 61% in the river. The importance of algae in the snow was minor: 7% of the total biomass in the marine zone and 30% in the river region. High species diversity of the algal flora in the sandy and sandy-silty littoral grounds was revealed. The values of the total biomass of the bottom algal flora (0.38 g C/m²) were only two to three times lower than the values revealed in similar habitats in the summer. The epipelithic forms (0.15 g C/m²) dominated, being represented by 46 species of algae (49%). The shares of epipsammonic (0.12 g C/m²) and planktonic (0.11 g C/m²) species were almost equal to each other: 25 and 22 species, respectively (27 and 24%).     

Grain-size composition of the suspended particulate matter in the marginal filter of the Severnaya Dvina River

The quantitative distribution and grain-size composition of the suspended particulate matter (SPM) in the marginal filter of the Severnaya Dvina River during the summer low-water periods of 2001–2005 were first analyzed in seawater on board of the vessel immediately after its sampling (without preliminary treatment) using a Coulter counter. This analysis revealed the main regularities in the transformation of the grain-size spectra at successive salinity steps of the marginal filter as well as the boundaries between these steps based on the data obtained by direct complex studies of the SPM dispersion. It is established that the water salinity is the main factor that controls the changes in the grain-size distribution and the composition of the particulate matter in the marginal filter. The concentrations of the pelitic fraction and the salinity demonstrate negative correlations between each other. It is shown that the areas characterized by the mass development of phytoplankton are located along the outer boundary of the marginal filter (at the biological step), where the salinity amounts to 23–24 psu. The content of the suspended forms of some chemical (lithogenic) elements and the C_org indicating the SPM’s genetic composition and their relations with the grain-size composition of the latter and the environments are studied.     

Distribution of some rare and trace elements in modern bottom sediments of the Caspian Sea

The features of the distribution of some rare and trace elements in modern bottom sediments of the Caspian Sea have been studied from samples collected during cruises 35, 39, and 41 of the R/V Rift and the cruise of the R/V Nikifor Shurekov in 2013. It was established that bottom sediments in different areas of the Caspian Sea vary to some degree in the contents of Zr, Hf, Th, V, Cr, Co, Ni, Cu, Sr, and Ba in comparison to suspended matter discharged by the Volga River and rivers originating in the Caucasus. As follows from the results of a comparison of the geochemical features of modern bottom sediments of the Volga River delta and different sedimentary subsystems of the Caspian Sea with the chemical composition of Middle Archean granitoids and Paleozoic and Mesozoic–Cenozoic basalts, which are regarded as geochemical images of such provenance areas as the basement of East European Platform, Urals, and Caucasus, none of these regions is considered the dominant provenance area for all sedimentary subsystems of the Caspian Sea region. Here, the revealed similarity between modern bottom sediments of the northern, central and southern Caspian Sea regions, the Volga River delta, and Post-Archean average Australian shale (PAAS) in some parameters, including REE spectra, assumes that the Volga River discharge plays a dominant role in the formation of the geochemical image of Caspian Sea subsystems. The role of clastics, including the fine-grained fraction, which is supplied to the Caspian Sea from the Caucasus region and Elburz Mountains, is insignificant already in the coastal area, which is determined both by influence of the marginal filter (MF) and large-scale cholestatic current circulation.     

Major and Trace Elements in Water and Suspended Matter of the Northern Dvina River and Their Annual Discharge into the White Sea

Oceanology - The results of continuous four-year-long investigations (from May 2015 to April 2019) of the elemental composition of water and suspended matter in the Northern Dvina River are given....     

Genesis of organic matter in the Kara Sea bottom sediments

Based on simultaneous use of organic and geochemical indicators (δ¹³C, C/N, and n-alkanes), the genesis of organic matter (OM) in recent bottom sediments of the Kara Sea was characterized. Maps for percentages and absolute masses of marine and terrigenous OM were drawn. The masses of buried marine and terrigenous OM were compared to its supply to the sea and onto the sea bottom.     

The holocene biochronostratigraphy and paleoenvironment in Dvina Bay from benthic foraminiferal studies of the White Sea

The compositional changes and frequency variations in the foraminiferal communities through the sediment section across Dvina Bay allow us to identify 14 ecological-stratigraphic zones. Based on the ¹⁴C dates for the foraminiferal tests, the distinguished ecozones correspond to the appropriate Holocene stages and substages. Because most of the foraminiferal species identified in the Holocene sediments are abundant and diverse in the modern oceans, they provide a powerful tool for the reconstruction of the paleoenvironmental changes during the Holocene.     

Forms of some metals in the suspended sediments of the Northern Dvina River and their seasonal variations

The results of the analysis of samples of the Northern Dvina River’s suspended particulate matter obtained by the sedimentation method from large water volumes in the periods of the spring high water and summer low water are presented. By the method of sequential leaching using different reagents, four fractions have been separated: the F1 is the sorbed complex and carbonates, the F2 is the amorphous hydroxides of Fe and Mn, the F3 is the form connected with the organic matter, and the F4 is the residual or silicate-detrital (inert) form. The data have shown that all ten elements determined were grouped with respect to the ratio of the distinguished forms: F4 is the predominant form for Al and Fe (73–88% of all the forms; however, the summer sample contains only 38% of this form of iron, and F2 is the predominant form for this period with 46.6%). As to Mn, the F1, F2, and F4 are nearly equally distributed in the spring high water samples, and only the F3 form is less important (5.4%). In the summer sample, the manganese sorbed complex is predominant (53.5%); for Cu, Ni, Cr, and Co, the inert F4 form is predominant (60–70%) in the sample of the spring suspended matter. The summer low water suspended matter has a lower F4 contribution (25–45%); for Zn, Pb, and Cd, the equal distribution of the forms in the spring samples is typical, while the summer suspended matter differs by the F2 form’s predominance (53–61% for Zn and Pb). The main conclusion from the acquired data is that the geochemical mobility of all the studied elements, except for cadmium, in the summer low water suspended matter is higher than in the spring suspended matter. The more intensive biogeochemical processes in August, the high level of organic matter, and the higher contribution of phytoplankton lead to the intensification of the metals’ geochemical activity in the Northern Dvina suspended matter in the end of the summer compared to the spring high water period when the physical processes are predominant over the biogeochemical ones due to the high speeds of the freshened waters flow.     

Specific features of the distribution of heavy metals in bottom sediments in the Northeast part of the Black Sea

We study the distribution of Fe, Mn, Co, Ni, Cu, Zn, Cd, Hg, Ag, and Au in present-day and ancient bottom sediments in the shelf, slope, and deep-trench areas of the northeast part of the Black Sea. The samples were taken in 1990 in the Crimean, Kerch-Taman, and Caucasian regions. The revealed character of the fields of concentration of metals does not allow one to establish exact regularities in the distribution of Mn, Co, and Cu with Fe. It is shown that the values of the ratios of concentrations of metals increase in the following direction: Au/Cu → Zn/Cu → Co/Fe → Ni/Fe → Mn/Fe → Hg/Cu → Ag/Cu → Cu/Fe. The data on Ag are presented for the first time.     

Dinoflagellate cysts in the surface sediments of the White Sea

Dinoflagellate cysts were studied in 42 samples from the surface sediments of the White Sea. The total concentration of dinocysts varies from single cysts to 25 000 cyst/g of dry sediments, which reflects the biological productivity in the White Sea waters and the regional particular features of the sedimentation processes. The highest concentrations are observed in silts; they are related to the regions of propagation of the highly productive Barents Sea waters in the White Sea. Generally, the spatial distribution of dinocysts species in the surface sediments corresponds to the distribution of the major types of water masses in the White Sea. The cysts of the relatively warm-water species (Operculodinium centrocarpum, Spiniferites sp.) of North Atlantic origin that dominate in the sediments indicate an intensive intrusion of the Barents Sea water masses to the White Sea along with hydrological dwelling conditions in the White Sea favorable for the development of these species during their vegetation period. The cold-water dinocyst assemblage (Islandinium minutum, Polykrikos sp.) is rather strictly confined to the inner parts of shallow-water bays, firstly, those adjacent to the Onega and Severnaya Dvina river mouths.     

钱塘江中下游沉积物磁性特征及其对沉积动力环境的指示意义

利用2010年1月与2010年8月采集的钱塘江中下游河床沉积物粒度和磁性测量数据以及2010年8月测量的流速数据,分析了沉积物粒度和磁性的时空分布特征,探讨了粒度和磁性参数对沉积动力环境的指示意义.结果表明:(1)冬季河床沉积物以粉砂和黏土为主,夏季以粉砂和砂为主,沉积物粒度呈现从中游到富春江水库逐渐变细、近口段到河口...     

Lithological and geochemical typification of surface bottom sediments in the Kara Sea

The Kara Sea is part of the Western Arctic shelf of Eurasia. The deposition of sediments in this shallow sea is largely determined by solid runoff from two great Siberian rivers (the Yenisei and Ob) and the glacial periods when the sea area repeatedly (during the Quaternary) dried up and was covered by continental glaciers. The rise of the World Ocean due to Holocene warming resulted in a significant expansion of the sea area to the south and complete degradation of the ice sheet. In this article, new data on the geochemical composition of the surface (0- to 2-cm) layer of sea-bottom sediments are considered, which reflects the spatial distribution of marine sediments during the maximum sea level. Cluster analysis of the variance for 24 chemical elements reveals sediment chemotypes, and critical analysis of their relationship with lithotypes is performed. The presented data have been collected on cruises of the R/V Akademik Boris Petrov in 2000, 2001, and 2003 and the R/V Akademik Mstislav Keldysh in 2015.     

The reflection of the present distribution of the primary production in the bottom sediments of the Sea of Okhotsk

Using the authors’ data obtained during expeditions to the Sea of Okhotsk during the last decade, the primary phytoplankton production and the distribution of organic carbon and chlorophyll a degradation products (chlorin) in the bottom sediments were studied. Using the authors’ and published data, the spatial distribution of the production and paleoproduction indicators was plotted. The ratios of the chlorin and C_org content in the sediments was considered, and the correlation between these parameters was revealed. It was shown that the average annual primary production of phytoplankton and the paleoproduction indices were maximum in the coastal and upwelling zones and decreased towards the sea’s center. A quantitative correlation was found between the distribution of the present primary production in the photic layer and that of the rates of the accumulation of organic matter buried within the surface sediments. As a result, it was shown that the content of chlorin and C_org in the marine bottom sediments may be used to reconstruct the paleoproduction variability of the past.     

Heavy-mineral variability in bottom sediments of the lower Chesapeake Bay,Virginia

Heavy minerals in bottom-sediment samples of the lower Chesapeake Bay show distribution patterns and interrelationships that denote characteristic mineral suites associated with defined geographic provinces. The Baymouth province has a garnet—hornblende—pyroxene suite, which is largely attributed to the influx of littoral and shelf sediments; the Eastern Shore province has a similar suite, derived largely from coastal erosion of the Eastern Shore peninsula. The Northern and Combined River provinces have a zircon—tourmaline—staurolite assemblage, which reflects derivation from an Appalachian Piedmont—Atlantic Coastal Plain sourceland. The Western Shore province is associated with a zircon—epidote—staurolite assemblage, apparently derived jointly from tributary influx and coastal erosion of the western shore. Factor analysis identified two major factors that account for 63% of the total variation in the relative amounts of the seven most common heavy minerals. The dominant factor (44%) is based on a zircon—hornblende—staurolite—pyroxene relationship, which indicates that mineral stability, as influenced by sediment maturity, is a major contributing factor. The second factor (19%) based on a tourmaline—epidote—staurolite—garnet relationship indicates that provenance is another major cause of heavy-mineral variability within the lower bay.     

Seasonal and Inter Annual Variations between Concentrations and Fluxes of Dissolved and Particulate Organic Carbon,Iron and Manganese from the Northern Dvina River to the White Sea

Oceanology - The paper presents new data on concentrations and fluxes of organic carbon, iron, and manganese in waters of the mouth area of the Northern Dvina River. The work was conducted within...     

黄河尾闾及近岸沉积物中重金属的含量分布及生态风险评价

为了解黄河尾闾及近岸沉积物中重金属的污染特征,采用电感耦合等离子体质谱仪(ICP-MS)测定了黄河河道和河口48个样品中Cr、Cu、Zn、Cd、Pb和As等6种重金属的含量,并对其分布和生态风险进行了评价。结果表明,黄河尾闾及近岸重金属的总含量沿河道至河口方向呈现先增加后降低再增加的趋势,至近岸B断面,As、Pb、Cd和Zn含量呈明显增加趋势,Cu和Cr含量增加幅度较小;黄河河口沉积物中重金属浓度明显高于河道沉积物中重金属的浓度。与我国其他流域相比,研究区域重金属含量处于较低水平。潜在生态风险评价结果表明,黄河尾闾及近岸沉积物6种重金属潜在生态风险系数从高到低依次为:CdAsPbZnCuCr,黄河尾闾及近岸沉积物的潜在生态风险主要由Cd和As引起,两者的贡献率分别为55.90%和29.54%,研究区域生态风险低,污染轻。研究结果将为黄河尾闾及近岸生态保护、环境管理和污染治理提供一定基础数据。