湖南砂矿金刚石中顺磁氮的分配特点和金刚石归类问题

利用EPR检测了200多颗湖南砂矿金刚石。为53颗晶体测定了顺磁N的含量。阐明了砂矿金刚石中顺磁N分配的一般特点:具顺磁N信号者占30％,具较大顺磁N含量(10~(17)—10~(18)N原子/cm~3)者只占7％,属I_b型的晶体～2％。通过顺磋和红外光谱资料对比,发现了一些奇异现象,设想后者起因于混型晶的存在。为使金刚石正确归类,给出了一套测试方案,强调了紫外、红外光谱,紫外形貌照相和EPR等手段的联合使用。     

铂族元素在地壳中的富集:以布什维尔德杂岩为例

地幔是地壳铂族元素富集的主要源库。铂族元素迁移主要有两个途径:(1)地幔部分熔融物质侵入地壳;(2)地幔板片就位于俯冲/碰撞带。前一途径比后一途径重要得多。地幔物质进入地壳造成铂族元素富集并成为可供开采的主矿产而非副产品,这一过程可包含许多成矿作用机制:(i)基性侵入体中Ni-Cu硫化物矿浆的发育,岩浆冷却与分离结晶作用导致富含Cu,Pt,Pd的硫化物矿浆的形成;(ii)层状侵入体一定层位形成高品位的铂族元素硫化物层,伴生或不伴生铬铁岩;(iii)富铂族元素及硫化物的岩浆沿着层状侵入体的边缘就位;(iv)直至层状侵入体结晶分异作用晚期的硫化物不混溶滞后分离;(v)不发育硫化物不混溶作用的铬铁矿结晶作用;(vi)低程度硫化物浸染带中的热液作用与铂族元素富集;(vii)乌拉尔-阿拉斯加型侵入体重结晶过程中的铂族元素与铬铁矿的次生富集作用,岩体在风化过程中形成砂矿床;(viii)黑色页岩形成过程中Pt的富集。南非布什维尔德火成杂岩蕴藏世界Pt资源的75%,Pd资源的54%,Rh资源的82%,并具有(ii)、(iii)、(iv)、(v)、(vi)成矿作用的实例。在这些作用中,作用(ii)形成的现有经济储量和资源量占90%,作用(iii)占9%。Merensky矿层(占总资源量30%)是一个铂族元素富集层位,它含1~3铬铁矿薄层,在可采宽度内硫化物平均含量为1%~3%(质量分数)。硫化物一般被认为是铂族元素的主要聚集体。该矿层由两个或两个以上含硫化物的基性热岩浆上升汇聚而成。这些岩浆的汇聚造成超镁铁质堆晶岩的厚度(主要是斜方辉石岩,某些地区包括橄榄岩)变化于50cm至数米之间。开采通常集中在厚度不到1m的地带。矿层的成因至今仍存在争议,一些观点认为铂族元素来自下部上升的热液流体,另一些观点认为铂族元素来自上部岩浆的硫化物沉降作用,并形成了Merensky辉石岩。已经知道矿层上覆的辉石岩、苏长岩和斜长岩中矿物来自两种岩浆类型:一种富含MgO(12%,质量分数)和Cr,而贫Al2O3(12%);另一种含典型的粒玄岩成分。UG-2铬铁岩含有全部经济资源量的58%,由一0.6~1m厚的铬铁岩层(有时见辉石岩夹层)和上覆的1~3层由铬铁矿所构成的薄层。虽然硫化物被认为至少是某些情况下对铂族元素的富集起作用,但UG-2的硫化物含量(0.5%~1.5%)显著低于Merensky矿层。UG-2层之下共有13个铬铁岩层位,所有的都含铂族元素,虽然铂族元素总含量和(Pt+Pd)/(Ru+Ir+Os)比值远低于UG-2。UG-2内所含的辉石岩"夹层"具高的87Sr/86Sr比值,说明与顶部熔融岩石的混合促进了铬铁岩和硫化物的形成。作用(iii)的主要实例是Platreef。目前它占总资源量的9%。不过,沿该带正积极开展找矿勘探工作,这一比例将来还会提高。这一矿层的厚度比Merensky和UG-2都要大,目前开采厚度达50多米。Platreef呈带状,上部为斜方辉石岩的堆晶岩;下部为辉石岩、长石辉石岩和苏长岩,它们与页岩、铁矿层和白云岩强烈相互作用,直接形成了底盘岩石。笔者认为Platreef是不同期次岩浆作用的结果,这些作用形成了不同的单元产物,包括布什维尔德主岩浆房的UG-2和Merensky矿层。新的岩浆进入主岩浆房会造成先存岩浆移位、岩浆错动并会冲破岩浆房的壁。圆筒状、带状岩管中的超镁铁岩含极高的Pt品位,在布什维尔德杂岩的下部切穿堆晶层,被认为是热液再活化的产物。它们现在未被开采,只是构成存封的铂族元素资源,对整个杂岩体资源没有重要的贡献。     

露头剖面层序中的海平面变化研究

在以往的沉积研究中，常常用露头剖面中的相对水深变化来讨论海平面的变化规律，本文通过对塔里木盆地北部寒武纪反映相对海平面变化的上超点变化曲线与肖尔布拉克地区寒武系露头剖面中相对水深变化曲线的对比研究发现，上超点变化曲线与相对水深变化曲线具有明显的差异，前者在寒武纪呈持续上升趋势，而后者除早期有一快速上升外，总体呈持续下降趋势，这说明相对水深变化虽与海平面变化存在着本质的联系，但单凭露头剖面中相对水深     

A SUMMARY OF THE CENOZOIC AND PSYCHOZOIC DEPOSITS WITH SPECIAL REFERENCE TO ASIA

INTRODUCTION Since the publication of Dr. J. G. Andersson's important "Essays onthe Cenozoic of Northern China" in 1923 much material has accumulated, partlyas the result of the explorations by the Geological Survey of China and partlythrough the expeditions sent out by other institutions, especial1y the Central     

吉林南部晚寒武世凤山期三叶虫动物群兼论寒武－奥陶系界线

吉林南部晚寒武世及早奥陶世地层层序连续完整，三叶虫化石丰富。本文将上寒武统凤山阶划分为５个生物带，并与有关地区进行对比，讨论了寒武－奥陶系界线。三叶虫包括５３个种，分属２６个属。由于篇幅所限，仅描述少数属种。     

福建镇海一带玄武岩柱状节理的动力学研究：兼论柱状节理的成因

根据流体动力学和自组织理论,研究了玄武岩柱状节理形成的动力学特征,并应用福建镇海一带玄武岩平均化学成分,估算出动力学方程中所涉及的参数,求出了断面直径与节理柱体长度之间的函数关系,并用数值计算方法,求出了R_a,d和L的值,其结果与该地区的地质实际基本吻合,最后探讨了柱状节理的成因机理,并把柱状节理的形成过程划分为两个阶段:(1)热耗散-对流阶段,(2)冷却-收缩阶段。     

郴怀断褶带的地质发展史兼论华夏系方向构造问题

郴怀断褶带位处湘南、粤北,自茶陵、永兴、郴县、宜章而向阳山、怀集,直至封开左近,计500公里以上,宽在40—50公里之数。成北北东、南南西向,横斜穿行于南岭山系。此构造带为由一系列发育于晚古生界至早中生界线状过渡型褶皱及平行轴向之冲断裂带组成。     

SOME METHODS TO STUDY SURFACE TEXTURES OF SAND GRAINS

For the study of the surface textures of quartz sand grains the normal microscope was used, besides the sofar generally applied electron microscope, and a new method was developed for using incident illumination. Grains from a desert sand and a river sand were studied, the former grains displayed textures not described yet by previous authors, the latter grains possessed a variety of textures, some of which have been found with beach sand grains, others with glacial sand grains by previous investigators.     

渤海孔店组及其油气勘探意义

孔店组是古近系最古老的地层单元,它的建组命名地点为河北省黄骅县孔1井。完整的孔店组总厚度超过2500m,自上而下包括3个地层单元:孔一段、孔二段和孔三段,也被称为"红—黑—红"段,3个岩性段组成一个完整沉积旋回,底部与中生界、顶部与沙河街组为不整合接触。渤海孔店组有自己的特点,从岩性上,可分为洪积扇、坡积和正常沉积3种基本类型,洪积扇的岩性为紫红色泥岩、凝灰质砂岩、凝灰岩的不等厚互层;坡积物以砂砾岩为主夹薄层泥岩,下部为紫红色泥岩与含砾粗砂岩互层;从构造上,分为断超式和双断式两种类型。不同类型的孔店组在渤海含油气区有不同的分布。孔店组本身就是一套完整的生储盖组合,孔二段是较好的生油岩,孔一段和孔三段可形成较好储盖条件,可以形成中等规模的油气藏,对油气勘探有着重要的意义。     

FORMULATION AND USE OF FLUORESCENT TRACER COATINGS IN SEDIMENT TRANSPORT STUDIES

Commercially available, daylight and near-ultraviolet fluorescent, colored dyes can be used in long- or short-lived surface coatings on coarse sediments. Such tracer coatings make possible day- or nighttime visual and quantitative determination of river or beach sediment transport. Testing of five commercial coatings led to formulation of two additional coatings. A wide selection of dye colors is available for use in four coating mixtures. All coatings are insoluble in fresh or saline water. Single-application coating thicknesses range between 0.0003 and 0.0024 inches. Still air drying time at room temperature for separated particles varies from 40 seconds to 14 minutes depending on coating mixture used. Volume production of marked particles in the field is possible. Extensive sediment sampling in particle transport studies possibly may be eliminated by measuring visible light emission from coated particles under nearultraviolet excitation. A battery operated, portable photometer was assembled from a light cell, linear amplifier, and metering circuit. Laboratory calibration indicates that 5% differences in areal concentration of marked particles at given sampling locations can be determined. Color coded sizes of fluorescent sand and gravel were used in a test of foreshore sediment transport pattern over a single tidal cycle. Initial trajectory (minimum transport angle) of particles moved by beach drifting is approximately equal to deep water angle of wave approach relative to the shoreline. Angular magnitude of the dispersion zone for each group of particles seems to be a function of particle size and point of introduction on the foreshore. Minimum average transport velocity of particles was 0.42 ft./min under test conditions.     

黄铁矿中金赋存状态的电子探针研究和超微粒金的发现

利用电子探针研究贵州某微细浸染型金矿床中黄铁矿,发现四颗超微粒金。本文阐述了用电子探针发现超微粒金的理论依据和应注意的技术问题;介绍了电子探针分析的检测极限计算方法与测试技术,并测定了黄铁矿中微量金的含量,提出微量金存在形式的新设想。     

海南岛石碌群中双峰火山岩Sm—Nd同位素特征兼论石碌铁矿成矿背景

对海南岛石碌群第６层及其相当层位中海相双峰火山岩Ｓｍ－Ｎｄ同位素，微量和稀土元素的研究表明，位于火山岩带西段军营和石碌的细碧岩具有Ｎ－ＭＯＲＢ特征，在中段和东段芙蓉田和兰洋的变拉斑玄武岩具有Ｅ－ＭＯＲＢ和ＩＲＴ（初始裂谷拉斑玄武岩）特征。石碌群的玄武岩和石碌Ｆｅ－Ｃｏ－Ｃｕ矿床分别与红海裂谷中南段的新生代玄武岩和Ａｔｈａｎｔｉｓ Ⅱ ＤｅｅＰ多金属矿床有许多相同之处。双峰火山岩的另一端元为壳源型石     

GEOLOGY OF NINGAN DISTRICT (KIRIN),WITH SPECIAL REFERENCE TO THE ORIGIN OF CHINGPOHU AND TIAOSHUILOU FALLS

This paper was originally written as a chapter of the report of theScientific Expedition to the Ningan and Muleng Districts (宁安县,穆稜县)organized by the Research Institute of Harbin during the autumn of last year     

GEOLOGY OF THE GORGE DISTRICT OF THE YANGTZE (FROM ICHANG TO TZEKUEI) WITH SPECIAL REFERENCE TO THE DEVELOPMENT OF THE GORGES.

As the Gorge District of the Yangtze is one of the few areas in China that can deservedly boast before the world its scenic grandeur as well as beauty, it has been long felt that a systematic account of its geological conditions would open another aspect of interest to the scientific travellers. There are already on the record the observations of Pumpelly, Richthofen, Abendanon, Willis and Blackwelder, Noda and others; but the results of their work, important as they are in certain respects, seem to ind...     

GEOLOGY OF THE GORGE DISTRICT OF THE YANGTZE (FROM ICHANG TO TZEKUEI) WITH SPECIAL REFERENCE TO THE DEVELOPMENT OF THE GORGES.

As the Gorge District of the Yangtze is one of the few areas in China that can deservedly boast before the world its scenic grandeur as well as beauty, it has been long felt that a systematic account of its geological conditions would open another aspect of interest to the scientific travellers. There are already on the record the observations of Pumpelly, Richthofen, Abendanon, Willis and Blackwelder, Noda and others; but the results of their work, important as they are in certain respects, seem to ind...     

论接触交代矽卡岩型多金属矿床的矿质来源—以铅同位素组成为依据

本文以铅同位素组成为线索，讨论了与中酸性侵入岩有关的接触交代矽卡岩型铜铅锌多金属矿床的矿质来源，得出了该类矿床矿质的岩浆源、岩浆与围岩混合源及多源混合源三种来源。