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1.
A magnetic study was carried out on lacustrine sediments from the Zoigê basin, Tibetan Plateau, in order to obtain a better understanding of palaeoclimatic changes there. Gyromagnetic remanence (GRM) acquisition is unexpectedly observed during static three-axis alternating field (AF) demagnetization in about 20 per cent of a large number of samples. X-ray diffraction (XRD) analysis on a magnetic extract clearly shows that greigite is the dominant magnetic mineral carrier. Scanning electron microscopy (SEM) reveals that the greigite particles are in the grain size range of 200–300  nm, possibly in the single-domain state. Greigite clumps of about 3  μm size are sealed by silicates. Fitting of XRD peaks yields a crystalline coherence length of about 15  nm, indicating that the particles seen in the SEM are polycrystalline.
  GRM intensities of most samples are of the same order as the NRM, while others show much stronger GRM although their magnetic properties are similar. Variation of the demagnetization sequence confirms that GRM is mainly produced perpendicular to the AF direction. The anisotropy direction can be derived from GRM, but more systematic studies are needed for detailed conclusions. An attempt to correct for GRM failed due to high GRM intensities and because smaller GRM acquisition was also found along the demagnetization axis. Behaviours of acquisition and AF demagnetization of GRM are comparable with those of NRM, ARM, IRM, indicating fine grain sizes of remanence carriers.  相似文献   

2.
In this paper, the mechanisms of low-temperature demagnetization of remanence in multidomain magnetite are considered. New experimental observations of the behaviour of the saturation isothermal remanence, thermoremanence and partial thermoremanence at low temperatures are presented. The results show that there are two main contributions to this low-temperature demagnetization. The first and predominant contribution (type-1 demagnetization) is due to 'kinematic' domain state reorganization and occurs throughout cooling from room temperature to the Verwey transition, T v , at 120–124  K. The second contribution arises from the change in anisotropy from cubic to monoclinic at T v , which changes the overall domain structure of the grain. On warming in zero field, some domain walls will not return to their original positions but will take up a position that leads to a lower net remanence (type-2 demagnetization). In stoichiometric magnetite, demagnetization does not occur at 130  K at the isotropic point, T k , contrary to some previous predictions. In non-stoichiometric magnetite, the influence of the Verwey transition is greatly reduced, and anomalous behaviour is observed at T k .  相似文献   

3.
Rock magnetic parameters are often used to recognize variations in the original magnetic mineralogy and for normalizing purposes in palaeointensity studies. Incipient weathering, however, is shown to have a profound but partly reversible influence on the rock magnetic properties of the marls of the Early Pliocene Trubi formation in southern Sicily (Italy). The remanence in the marls resides in single-domain (SD) magnetite grains, but the remanent coercive force (Hcr) shows a strong variation and most values observed are anomalously high ( Hcr) range 36–188 mT).
The enhanced coercivities are attributed to stress in the magnetite grains induced by surface oxidation at low temperature. Upon heating to 150 °C a reduction of coercivities occurs that can be explained by a stress reduction as a result of a reduction of Fe2- gradient due to a higher diffusion rate at elevated temperature. After heating to 150 °C, coercivities are quite uniform throughout the outcrop and the values are characteristic of SD magnetite (Hcr range 30–38 mT). The bulk susceptibility increases by 4–24 per cent, and the isothermal remanent magnetization (IRM) decreases by 5–11 per cent. The increase in anhysteretic remanent magnetization (ARM) is large: 20–242 per cent. The magnitude of the changes is related to the degree of weathering.
Another effect of heating the marl samples to 150 °C is a substantial reduction of the coercivities of the secondary overprint in the natural remanent magnetization. After heating. separation of the secondary and primary components by alternating-field demagnetization is more efficient. The usual difficulties of thermal demagnetization above 300 °C may thus be avoided by a combination of moderate heating to 150 °C and subsequent alternating-field demagnetization.  相似文献   

4.
Summary. A theoretical investigation of the way in which an isotropic rock containing single-domain particles acquires both IRM and ARM (or TRM) has indicated that stationary single-axis alternating field (af) demagnetization with the af axis at an angle to the remanence vector should produce progressive angular changes in a single-component remanence as demagnetization proceeds. Just before the remanence is completely removed it should lie at 90° to the af axis irrespective of the original orientation of the remanence (apart from 0°). Experimental observations on a rock sample support these deductions.
This analysis has been extended to investigate the way in which ARM (or TRM) and IRM are demagnetized by static three-axis demagnetization methods which are used by some workers in palaeomagnetism. Theory, in conjunction with the use of a numerical model, predicts that an ARM or TRM should not undergo significant direction changes when these methods are applied but an IRM should undergo progressive direction changes as demagnetization proceeds, usually moving until it makes an angle of cos−1 (1/3) with each of the three af axes just before it is removed. Confirmation that such changes do occur have been obtained by experiments on a rock sample. The relative merits of static and tumbling af demagnetization methods are also discussed.  相似文献   

5.
Palaeomagnetic and geochronological measurements have been carried out on the late Pleistocene basaltic–andesitic unit of Monte Chirica–Costa Rasa, on the island of Lipari (Aeolian Archipelago). The lava flow sequence is about 10  m thick and has been sampled in detail. Magnetic properties are rather uniform; Curie temperatures of 540° to 580 °C, and the saturation IRM reached at applied values of 0.1  T point to titanomagnetite as the main magnetization carrier. Thermal and AF demagnetization have shown the presence of secondary magnetization components. These were removed mostly at 450°–500 °C or 20–30  mT, indicating a highly stable ChRM with directions from transitional to reverse. Where a ChRM could not be isolated by application of the demagnetization techniques, the converging remagnetization circles method gave a mean ChRM value fully comparable with that obtained from other methods. 40Ar/39Ar determinations were performed on two lava flows, in the lower and upper parts of the sequence. The former shows a transitional ChRM direction and a whole-rock age of 157±12  ka, the latter a reverse direction, a whole-rock age of 143±17  ka and a ground-mass age of 128±23  ka. The radiometric data and the reconstructed stratigraphy, which indicate ages of 150±10  ka and 104±3.5  ka, respectively, for the volcanic units at the bottom and top of the Monte Chirica–Costa Rasa unit, suggest that the reverse directions recorded in Lipari are related to the Blake event.  相似文献   

6.
About six separately orientated cores were collected at each of 14 sites distributed throughout the arcuate, west-dipping, 6  km thick, Freetown layered igneous complex. Alternating field and thermal demagnetization both isolate a stable component of remanent magnetism which corresponds to a palaeomagnetic south pole from 13 sites (nine reverse, four normal polarity) at 82.9°S, +32.7°E ( α 95 = 5.6°). This is indistinguishable from that reported in 1971 based on alternating field demagnetization of cores from 10 orientated hand samples.
  The difference between the Freetown pole (age: 193 ± 3  Ma) and other mid-Jurassic poles from West Africa could be due to its greater age. The difference between the whole West African Jurassic pole group and the Karoo pole from southern Africa, however, suggests moderate (∼10°) differential rotation of West Africa relative to the Kaapvaal craton.
  A prevalent magnetic foliation fabric coincides generally with the petrological layering, as might be expected, but a ubiquitous magnetic lineation is predominantly down-dip. This is compatible with a down-dip pyroxene lineation reported to be present in some field outcrops, and interpreted in terms of late-stage deformation during the slow crystallization and cooling of the large igneous body. However, a fold test shows that the igneous layering had already achieved its present attitude before the Complex cooled to ∼570 °C (the maximum blocking temperature of the characteristic remanence).  相似文献   

7.
The acquisition of a gyroremanent magnetization (GRM) by single-domain (SD) greigite particles during alternating-field (AF) demagnetization is demonstrated. Previous palaeomagnetic studies failed to identify the presence of authigenic greigite in the glacio-marine clays studied. These clays formed the subject of an earlier debate about the validity of a Late Weichselian geomagnetic excursion (the Gothenburg Flip) in southern Sweden. The greigite carries a stable chemical remanent magnetization (CRM), which coexists with a detrital remanent magnetization (DRM) carried by magnetite. AF demagnetization could not isolate the primary remanence in the sediments where magnetite and greigite coexist, due to the overlapping coercivity spectra of the two minerals and the inability to determine the time lag between sediment deposition and CRM formation. Thermal demagnetization removed the CRM at temperatures below 400 C, but this method was hindered by the unconsolidated nature of the sediments and the formation of secondary magnetic minerals at higher temperatures. The results suggest that the low-coercivity DRM carried by magnetite was mistaken for a 'viscous' component in the earlier studies. Hence the former debate about the record of the Gothenburg Flip may have been based on erroneous palaeomagnetic interpretations or non-reproducible results. AF demagnetization procedures applied to samples suspected of bearing SD magnetic particles (such as greigite) should be carefully selected to recognize and account for GRM acquisition.  相似文献   

8.
In the pseudo-Thellier method for relative palaeointensity determinations (Tauxe et al. 1995) the slope of the NRM intensity left after AF demagnetization versus ARM intensity gained at the same peak field is used as a palaeointensity measure. We tested this method on a marine core from the Azores, spanning the last 276  kyr. We compared the pseudo-Thellier palaeointensity record with the conventional record obtained earlier by Lehman et al . (1996 ), who normalized NRM by SIRM. The two records show similar features: intensity lows with deviating palaeomagnetic directions at 40–45  ka and at 180–190  ka. The first interval is associated with the Laschamps excursion, while the 180–190  ka low represents the Iceland Basin excursion (Channell et al. 1997). The pseudo-Thellier method, in combination with a jackknife resampling scheme, provides error estimates on the palaeointensity.
  Spectral analysis of the rock magnetic parameters and the palaeointensity estimates shows orbitally forced periods, particularly 23  kyr for climatic precession. This suggests that palaeointensity is still slightly contaminated by climate. Fuzzy c -means cluster analysis of rock magnetic and geochemical parameters yields a seven-cluster model of predominantly calcareous clusters and detrital clusters. The clusters show a strong correlation with climate, for example samples from detrital clusters predominantly appear during rapid warming. Although both the pseudo-Thellier palaeointensity m a and fuzzy clusters show climatic influences, we have not been able to find an unambiguous connection between the clusters and m a .  相似文献   

9.
Palaeomagnetic results are presented from a volcanic sequence in Zhijin County, Guizhou Province, Southern China. The lavas and associated volcanic breccias comprising the sequence represent a southern extension of the Emeishan volcanic province. Biostratigraphic dating of interbedded limestone units and stratigraphic constraints indicate that the section formed during the late Permian (∼263–255  Ma), and is thus somewhat older than the Emei stratotype section in Sichuan Province, and close in age to reported estimates of the termination of the Permo-Carboniferous (Kiaman) reverse superchron. Rock magnetic analyses and reflected light microscopy indicate that the magnetic mineralogy of the lava units is dominated by fresh, primary magnetites containing a significant fraction of single-domain grains. Thermal demagnetization behaviour of the breccia units is poor, but most lava samples have one or two components of remanence above 250 °C. The normal polarity characteristic remanence held by the lavas implies a post-Kiaman age for this succession and suggests that the termination of the Kiaman occurred prior to 263  Ma, supporting recently published estimates. According to standard criteria, Thellier palaeointensity results from the lavas are of good quality and reveal that the dipole field strength was comparatively low shortly after the termination of the superchron. 80 per cent of samples record relative VDM values in the range 42–52 per cent of the present-day value, supporting recent studies of mid-Kiaman field intensity. This suggests that a low-energy dipole existed at least between 300 and 255  Ma and does not appear to have been confined to the stable reverse polarity interval.  相似文献   

10.
Summary. Magnetic extracts were prepared from samples of Upper Jurassic and Lower Cretaceous pelagic limestones from France and Spain. Thermomagnetic analysis of the magnetic extracts using a microbalance required careful monitoring of base weight changes during heating. Heating in argon gas atmosphere induced production of magnetite during heating while slight oxidation occurred during heating in air. the dominant Curie temperature detected by the thermomagnetic analyses was the 585°C Curie temperature of magnetite. the 680°C Curie temperature of haematite was only detected when isothermal remanent magnetism (IRM) data indicated large concentrations of haematite. Even when IRM data indicated its presence, the thermomagnetic analyses did not detect the Neel temperature of goethite. Although thermomagnetic analyses of magnetic extracts provide more direct identification of the dominant, strongly ferromagnetic minerals, IRM acquisition and subsequent thermal demagnetization is a superior technique in detecting high coercivity, weakly ferromagnetic minerals such as goethite and haematite.  相似文献   

11.
Measurements of anhysteretic (ARM) and isothermal (IRM) remanences in cores 6 and 8 from Big Moose Lake reveal evidence for changes in magnetic mineralogy and grain size within and between the two cores. It is proposed that changes in the strength and demagnetization characterizations of the IRM reflect the accumulation of atmospherically deposited magnetic minerals resulting from industrial processes. The record of magnetite deposition especially in Core 6 parallels that for coal soot at the site. In both cores, the record of haematite deposition parallels that for several anthropogenic indicators.This is the fourth of a series of papers to be published by this journal which is a contribution of the Paleoecological Investigation of Recent Lake Acidification (PIRLA) project. Drs. D. F. Charles and D. R. Whitehead are guest editors for this series.  相似文献   

12.
The remanent magnetic properties of an 88  m bore core are unrelated to either the dolomite content or the sedimentological textures and are considered to be carried primarily by biogenetic magnetite that was cemented in during very early diagenesis. Individual readings represent time intervals of c . 720 ± 32  yr and, after 40  mT partial demagnetization, they provide an almost continuous record of averaged geomagnetic secular variations over a period of some 3.17  Myr. The magnitude of directional secular variation is twice that of the present day, despite being smoothed, and the secular variations appear to grade into polarity transitions, suggesting no difference in their mechanisms. The rates of change in direction between subjacent levels in the core have a log-normal distribution which extends smoothly beyond 90° and has a median value of 13°/700  yr, the same as for unsmoothed European secular variation during the last 2000  yr. The intensity of remanence, after 40  mT partial demagnetization, appears to provide a reasonable approximation to geomagnetic field intensity. This tends to be weaker when the direction is moving faster, reflecting averaging, but is unrelated to the distance of the vector from the mean direction; that is, it depends on the rate of change and not on the virtual pole latitude. The virtual poles, after correction for tectonic rotations about horizontal and vertical axes, have latitudes that form a strongly platykurtic Fisherian distribution, while their longitudes have a circular distribution on which are superimposed two Gaussian peaks, 180° apart. This bore core thus provides detailed information of smoothed geomagnetic secular variation in the Lower Cretaceous (127 ± 3  Ma) which shows clear regularities in behaviour, some related to changes in the Earth's orbital parameters.  相似文献   

13.
Summary. Two sedimentary cores from the western Pacific display a palaeo-magnetic record of the late Cretaceous long normal interval and the boundary reversed interval corresponding to seafloor spreading anomalies 33–34. Near the young end of this reversed interval, a systematic excursion of inclinations is observed in both cores. Samples are very stable to both alternating field and thermal demagnetization. Blocking temperatures and Curie points suggest that the remanence is carried primarily by magnetite, but with an additional contribution from hematite. Approximate sedimentation rates derived from biostratigraphy suggest that the excursion had a duration of between 46 000 and 54 000yr and occurred about 236000–303000 yr before the succeeding polarity reversal. The excursion, thus, may represent an aborted geomagnetic field reversal.  相似文献   

14.
A continental sequence of red beds and interbedded basaltic layers crops out in the Sierra Chica of Córdoba Province, Argentina (31.5°S, 64.4°W). This succession was deposited in a half-graben basin during the Early Cretaceous. We have carried out a palaeomagnetic survey on outcrops of this basin (147 sites in seven localities). From an analysis of IRM acquisition curves and detailed demagnetization behaviour, three different magnetic components are identified in the volcanic rocks: components A, B and X are carried by single- or pseudo-single-domain (titano) magnetite, haematite and multidomain magnetite, respectively. Component A is interpreted as a primary component of magnetization because it passes conglomerate, contact, tilt and reversal tests. The carrier of the primary magnetization, fine-grained (titano)magnetite, is present in basalts with a high degree of deuteric oxidation. This kind of oxidation is interpreted to have occurred during cooling. Components B and X are discarded because they are interpreted as recent magnetizations. In the sedimentary rocks, haematite and magnetite are identified as the carriers of remanence. Both minerals carry the same component, which passes a reversal test. The calculated palaeomagnetic pole, based on 55 sites, is Lat. 86.0°S, Long. 75.9°E ( A 95=3.3, K =35). This palaeomagnetic pole supersedes four with anomalous positions reported in previous papers.  相似文献   

15.
Low-field magnetic susceptibility and its anisotropy (AMS) were measured for a suite of sandstone and siltstone samples. AMS orientations measured on two systems (Bartington and Digico) differed before thermal treatment of the samples but became the same after thermal demagnetization in air to 600 °C. Six position measurement schemes for the Bartington system do not eliminate the effects of specimen inhomogeneity and other errors, whereas 12- and 24-position measurements give good agreement with the Digico anisotropy meter and with the observed petrofabric. Thermal demagnetization from temperatures between 400 and 650 °C had the effect of enhancing both the magnetic susceptibility and AMS. Although the most profound mineralogical change due to heating was the conversion of kaolinite into metakaolin, IRM, XRD, DTA and Mössbauer spectroscopic analysis demonstrate that the changes in magnetic properties were due to the transformation upon heating of trace amounts of sulphides into magnetite and/or maghemite and haematite. Both magnetic susceptibility and the degree of anisotropy decrease with higher-temperature thermal demagnetization due to the oxidation of the newly formed magnetite and/or maghemite into haematite. The magnetic foliation of the newly formed magnetite/maghemite and haematite is parallel to the bedding, possibly following the orientation of the original sulphides.  相似文献   

16.
Mineral and isothermal magnetic properties of Al-, Mn- and Ni-substituted haematites were characterized and their relationships evaluated in order to interpret better the results of magnetic analyses of soils and recent sediments. Aluminium, manganese and nickel haematites generally behaved as single-domain (SD) particles. The influence of incorporated Al on the magnetic behaviour of haematite was consistent with Al acting as a paramagnetic dilutent. Mass magnetic susceptibility ( χ ) and SIRM800 decreased as the level of Al substitution increased. Incorporation of Mn and Ni increased χ , which could be associated with enhancement of the spin canting effect of haematite. The stability of SIRM800 to demagnetization for Al-haematite appears to be related to a defect mechanism associated with the development of smaller crystallites arising from Al substitution. Magnetic domain rotation or flipping was probably inhibited, being blocked by structural defects during magnetization and demagnetization, and resulted in a low but stable partial SIRM (SIRM800 ). %IRM/SIRM800 demagnetization curves and estimated ( B o )CR values of ≤100  mT for Mn-haematite indicate pseudo-single-domain/multidomain-like behaviour despite Mn-haematite having particle and crystallite dimensions similar to Ni-haematite, which did not show this behaviour. Data indicate that parameters involving unsaturated, partial SIRM should be used with caution in magnetic studies of soils and sediments.  相似文献   

17.
Summary. After thermal and alternating field (AF) cleaning, the characteristic high blocking temperature A component of natural remanent magnetization (NRM) of the Tudor gabbro of southern Ontario has a mean direction D = 326°, I =–46° ( k = 132, α95= 4.8°, N = 8 sites). The corresponding palaeopole, 133°E, 12°N ( dp = 4°, dm = 6°), confirms the palaeopole 137°E, 17°N (α95= 8.4°) reported earlier by Palmer & Carmichael, based on AF cleaning only. The A NRM has unblocking temperatures > 515–525°C which exceed the estimated 500°C peak temperature reached locally during ∼ 1050 Ma Grenvillian regional metamorphism. The A NRM therefore predates metamorphism and is probably a primary thermoremanence (TRM). The age of the Tudor NRM has previously been taken to be about 675 Ma, but recent 40Ar/39Ar dating by Baksi has shown that this is the time of post-metamorphic cooling to 200–250°C. Hornblendes record initial cooling of the intrusion to 590±20°C at 1110 Ma and this is the best estimate of the age of the A remanence. Successful Thellier-type palaeointensity determinations on 11 Tudor samples confirm that the A NRM is a TRM and indicate a palaeofield at this time of 18–27 μT, about 50–70 per cent of the present field intensity at 27° magnetic latitude. The anomalous Tudor A palaeopole, which lies well to the west of both 1000–800 Ma Grenvillian palaeopoles and 1100–1050 Ma poles from Interior Laurentia, is interpreted as recording divergence between Grenvillia and Interior Laurentia just before the Grenvillian orogeny, rather than a post-metamorphic extension of the apparent polar wander path as previously assumed.  相似文献   

18.
A palaeomagnetic study of 115 samples (328 specimens) from 22 sites of the Mid- to Upper Cretaceous Bagh Group underlying the Deccan Traps in the Man valley (22°  20'N, 75°  5'E) of the Narmada Basin is reported. A characteristic magnetization of dominantly reverse polarity has been isolated from the entire rock succession, whose depositional age is constrained within the Cretaceous Normal Superchron. Only a few samples in the uppermost strata have yielded either normal or mixed polarity directions. The overall mean of reverse magnetization is D m=144°, I m=47° ( α 95=2.8°, k =152, N =18 sites) with the corresponding S-pole position 28.7°S, 111.2°E ( A 95=3.1°) and a palaeolatitude of 28°S±3°. The characteristic remanence is carried dominantly by magnetite. Similar magnetizations of reverse polarity are also exhibited by Deccan basalt samples and a mafic dyke in the study area. This pole position falls near the Late Cretaceous segment of the Indian APWP and is concordant with poles reported from the Deccan basalt flows and dated DSDP cores (75–65  Ma) of the Indian Ocean. It is therefore concluded that the Bagh Group in the eastern part of the Narmada Basin has been pervasively remagnetized by the igneous activity of Deccan basalt effusion. This overprinted palaeomagnetic signature in the Bagh Group indicates a counter-clockwise rotation by 13°±3° and a latitudinal drift northwards by 3°±3° of the Indian subcontinent during Deccan volcanism.  相似文献   

19.
A newly developed field distribution measuring system based on a high- T c SQUID has been employed in the study of magnetic mineral distribution in several Permian sedimentary rocks. The instrument consists of a small, 1.4×1.4 mm sized YBaCu-oxide SQUID magnetic field sensor that is operated in a thin-walled dewar, so that the sample's surface, at room temperature, can be scanned at a distance of only ∼1.5 mm. The samples were subjected to a saturation remanence perpendicular to the surface and the scanning measurements in zero field reveal that the magnetization might be carried by only a small part of a sample, in one case associated with secondary oxide phases. High-resolution magnetic scans can aid in the interpretation of the magnetic remanence acquisition process.  相似文献   

20.
Magnetic remanence vectors for 1737 samples from two ∼100 m cores of Lake Baikal sediments are reported along with complete magnetic susceptibility profiles obtained from a pass-through system. Chronological control is established by means of two independent correlations; first, by matching susceptibility variations to the oceanic oxygen isotope record and second, by matching the relative palaeointensity variations to the SINT-800 global reference curve. These both imply an average deposition rate of 15 cm kyr–1 and a basal age of ∼640 ka. Spectral analysis reveals the presence of Milankovitch signals at ∼100 kyr (eccentricity), ∼41 kyr (obliquity) and ∼23 and ∼19 kyr (precession). Stable remanence vectors are almost all of normal polarity. The few exceptions comprise brief intervals of low and/or negative inclinations which probably represent geomagnetic excursions. However, these are far less numerous than the high sedimentation rate would lead one to expect. Furthermore, only four of them can be readily matched to the—still poorly understood—global pattern. These are the Laschamp, the Albuquerque, the Iceland Basin and perhaps the West Eifel excursions which occurred at ∼38 000, ∼146 000, at 180 000–190 000 and at 480 000–495 000 yr ago, respectively.  相似文献   

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