The gravity method in groundwater exploration in crystalline rocks: a study in the peninsular granitic region of Hyderabad, India

The application of variations in the earth's gravity in groundwater exploration on a regional scale, especially in sedimentary basins, metamorphic terrains, valley fills, and for buried alluvial channels, is well established. However, its use in hard crystalline rocks is little known. In granite, for example, the upper weathered layer is a potential primary aquifer, and the underlying fractured rock can form a secondary aquifer. Fracturing and weathering increases the porosity of a rock, thereby reducing the bulk density. Changes in gravity anomalies of 0.1–0.7 mGal for granites, due to weathering or variations in lithology, can be detected. To test the use of gravity as a groundwater exploration tool for crystalline rocks, a gravity survey of the peninsular shield granites underlying Osmania University Campus, Hyderabad, India, was undertaken. At the site, gravity anomalies reflect variations in the lithology and in the thickness of weathered zones. These anomalies also define the position of intrusives and lineaments. Areas of more deeply weathered granite that contain wells of higher groundwater yield are represented by negative gravity values. In the weathered zone, well yield has an inverse relation to the magnitudes of residual gravity. The study confirms the feasibility of gravity as a tool for groundwater exploration in crystalline rocks. Electronic Publication     

Estimation of seismic spectral acceleration in Peninsular India

Peninsular India (PI), which lies south of 24°N latitude, has experienced several devastating earthquakes in the past. However, very few strong motion records are available for developing attenuation relations for ground acceleration, required by engineers to arrive at rational design response spectra for construction sites and cities in PI. Based on a well-known seismological model, the present paper statistically simulates ground motion in PI to arrive at an empirical relation for estimating 5% damped response spectra, as a function of magnitude and source to site distance, covering bedrock and soil conditions. The standard error in the proposed relationship is reported as a function of the frequency, for further use of the results in probabilistic seismic hazard analysis.     

Analysis of Rainfall Over Different Homogeneous Regions of India in Relation to Variability in Westward Movement Frequency of Monsoon Depressions

Between 1941 and 2002 there has been a decreasing trend in the frequency of monsoon disturbances (MDs) during the summer monsoon season (June–September). This downwards trend is significant at the 99.9% level for the main monsoon phase (July–August) and the withdrawal phase (September); however, it is not significant during the onset phase (June). The variability in rainfall over the homogeneous regions of India on the sub-seasonal scale also shows a significant decreasing trend with respect to the amount of rainfall over Northwest India (NWI) and Central India (CEI) during all three phases of the monsoon. Meteorological observations reveal that there has been an eastward shift of the rainfall belt with time over the Indian region on the seasonal scale and that this shift is more prominent during the withdrawal phase. This decreasing trend in MDs together with its restricted westerly movement seem to be directly related to the decreasing trend in rainfall over CEI during both the main monsoon and withdrawal phases and over NWI during the withdrawal phase. The low-level circulation anomalies observed during two periods (period-I: 1951–1976; period-ii: 1977–2002) are in accordance with the changes in rainfall distribution, with comparatively more (less) rainfall falling over NWI, CEI and Southern Peninsular India (SPI) during period-I (period-ii), and are accompanied by a stronger (weaker) monsoon circulation embedded with an anomalous cyclonic (anti-cyclonic) circulation over CEI during the main monsoon and withdrawal phases. During the onset phase, completely opposite circulation anomalies are observed during both periods, and these are associated with more (less) rainfall over NWI, CEI and SPI during period-ii (period-I).     

Hydrogeological environment and groundwater occurrences of the alluvial aquifers in parts of the Central Ganga Plain, Uttar Pradesh, India

A detailed hydrogeological investigation was carried out in parts of the Central Ganga Plain, India, with the objective of assessing the aquifer framework and its resource potential. The area was studied because of its dual hydrogeological situation, that is water logging and soil salinization in the canal command areas and depletion of aquifers in the western part of the basin. A comprehensive investigation of the aquifer system between the Ganga River and Kali River revealed its lateral and vertical dimensions and hydrogeological characteristics. Moreover, study of the groundwater occurrences, movements and behaviour, in terms of water level fluctuation with time and space, confirms the coexistence of over exploitation as well as water logging in the area.

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Electronic Supplementary Material Supplementary material is available for this article at

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Resumen Una investigación hidrogeológica detallada se llevó a cabo en partes de la Llanura de Ganga Central, India, con el objetivo de evaluar la estructura del acuífero y su potencial del recurso. El área fue estudiada por su doble situación hidrogeológica, es decir la saturación con agua y salinización de suelos en las áreas dominadas por el canal y vaciamiento de acuíferos en el la parte occidental de la cuenca. Una investigación completa del sistema acuífero entre el Río Ganga y el Río Kali, reveló sus dimensiones verticales y laterales y las características hidrogeológicas. Además, los estudios sobre la ocurrencia del agua subterránea, sus movimientos y comportamiento, en lo que se refiere al nivel de agua, y a su fluctuación en el tiempo y el espacio, confirma la co-existencia en el área de sobre- explotación así como de saturación con agua.

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Résumé L'objectif de cette étude hydrogéologique détaillée de portions de la Plaine Centrale du Gange est de déreminer la structure aquifère et la ressource potentielle. L'intérêt de la zone repose sur sa dualité du point de vue hydrogéologique, les zones influencées par le canal présentent une remontée de la nappe avec une salinisation des sols, la portion Ouest du bassin présente une baisse du niveau des aquifères. Par cette étude, le système aquifère compris entre la rivière du Gange et la rivière Kali révèle ses dimensions latérales et verticales ainsi que ses caractéristiques hydrogéologiques. De plus, l'étude des événements, des mouvements et du régime hydrogéologique affectant le niveau phréatique confirme la co-existence de surexploitation et de saturation des sols dans la région.

     

Geographic Information System and groundwater quality mapping in Panvel Basin,Maharashtra, India

Panvel Basin of Raigarh district, Maharashtra, India is the study area for groundwater quality mapping using the Geographic Information System (GIS). The study area is typically covered by Deccan basaltic rock types of Cretaceous to Eocene age. Though the basin receives heavy rainfall, it frequently faces water scarcity problems as well as water quality problems in some specific areas. Hence, a GIS based groundwater quality mapping has been carried out in the region with the help of data generated from chemical analysis of water samples collected from the basin. Groundwater samples show quality exceedence in terms of chloride, hardness, TDS and salinity. These parameters indicate the level of quality of groundwater for drinking and irrigation purposes. Idrisi 32 GIS software was used for generation of various thematic maps and for spatial analysis and integration to produce the final groundwater quality map. The groundwater quality map shows fragments pictorially representing groundwater zones that are desirable and undesirable for drinking and irrigation purposes.     

Structural studies and their bearing on the Early Precambrian history of the Dharwar tectonic province,southern India

In the Dharwar tectonic province, the Peninsular Gneiss was considered to mark an event separating the deposition of the older supracrustal Sargur Group and the younger supracrustal Dharwar Supergroup. Compelling evidence for the evolution of the Peninsular Gneiss, a polyphase migmatite, spanning over almost a billion years from 3500 Ma to 2500 Ma negates a stratigraphic status for this complex, so that the decisive argument for separating the older and younger supracrustal groups loses its basis. Correlatable sequence of superposed folding in all the supracrustal rocks, the Peninsular Gneiss and the banded granulites, indicate that the gneiss ‘basement’ deformed in a ductile manner along with the cover rocks. An angular unconformity between the Sargur Group and the Dharwar Super-group, suggested from some areas in recent years, has been shown to be untenable on the basis of detailed studies, A number of small enclaves distributed throughout the gneissic terrane, with an earlier deformational, metamorphic and migmatitic history, provide the only clue to the oldest component which has now been extensively reworked.     

Groundwater quality and its change over a decade: An analysis of a coastal urban environment from the west coast of India

Mangalore, one of the fastest growing cities along the west coast of India has witnessed a leap in industrialisation and urbanisation during the last decade. This study focuses on the quality of the groundwater of Mangalore city. The results are compared with an earlier study to record the change in water quality over a decade. HCO₃ and Na were found exceeding the highest desirable limit of the World Health Organisation (WHO) and Indian Standards Institute (ISI) standards for drinking water. The pH values at seven localities are not within the limits prescribed by WHO or ISI (highest desirable level or maximum permissible level). The present study shows that there has been an enrichment of chemical constituents during the last decade and that the Gurupur River, which flows parallel to the coast, plays an important role in impeding saltwater intrusion along the coast.     

Assessment of the groundwater potential and quality in Bhatsa and Kalu river basins of Thane district, western Deccan Volcanic Province of India

Scarcity of groundwater necessitates the present study to evaluate groundwater potential and quality for designing suitable water management plans in the Bhatsa and Kalu river basins in the Thane district in the western Deccan volcanic province of India. A Geographical Information System platform is used to integrate and spatially analyse multiparametric data comprised of satellite, topographical, geological and hydrogeological information to generate several thematic maps, including groundwater potential zonation map. This study reveals that 70% of the area has medium to low groundwater potential, while only 10% has high potential. The static and dynamic groundwater potentials are estimated to be 10.7 and 4.8% of the annual rainfall. The groundwater quality in terms of hardness, total dissolved solids, salinity and chloride is suitable for domestic and irrigational purposes. A database is developed for sustainable water management program for the region and areas where suitable water conservation techniques need to be adopted are identified.     

Assessment of groundwater pollution due to tannery industries in and around Dindigul, Tamilnadu, India

The overexploitation of groundwater in some parts of the country induces water quality degradation. The untreated industrial effluents discharged on the surface causes severe groundwater pollution in the industrial belt of the country. This poses a problem of supply of hazard free drinking water in the rural parts of the country. There are about 80 tanneries operating in and around Dindigul town in upper Kodaganar river basin, Tamilnadu, India. The untreated effluents from the tanneries have considerably affected the quality of groundwater in this area. To assess the extent of groundwater deterioration, a detailed analysis of groundwater quality data has been carried out. The concentration of cations such as Calcium (Ca²⁺), Magnesium (Mg²⁺), Sodium (Na⁺) and Potassium (K⁺), and anions such as Bicarbonate (HCO₃^–), Sulphate (SO₄^2–), Chloride (Cl^–) and Nitrate (NO₃^–) in the groundwater have been studied. Apart from these constituents, pH, electrical conductivity (EC), total dissolved solid and total hardness (TH as CaCO₃) were also studied. The correlation of these constituents with the EC has been carried out. The highest correlation is observed between EC and chloride with a correlation coefficient of 0.99. Progressive reduction in correlation coefficients for Mg²⁺, (Na⁺ + K⁺), Ca²⁺ and SO₄^2– are observed as 0.91, 0.87, 0.86 and 0.56, respectively. It is found that the quality of groundwater in the area under investigation is deteriorated mainly due to extensive use of salt in the leather industries.     

Radioactive element distribution and rare-metal mineralization in anorogenic acid volcano-plutonic rocks of the Neoproterozoic Malani Felsic Province,western Peninsular India

The Anorogenic Malani Felsic Province (MFP) of western Peninsular India consists of peralkaline, metaluminous to mildly peraluminous A-type granites-acid volcanics with minor basic volcanics and dykes. The suite is bimodal in nature that characterized by volcano-plutonic ring structures and radial dykes. The granitoids of Siwana and Kundal areas of MFP are traversed by numerous quartz veins with fluoride, iron encrustations, druses and knots of pegmatite phases. Petrographically, they show cloudy, patchy perthitic textures; spherulite form of alkali amphibole and alkali pyroxenes; alteration of K-Na-feldspar to kaolin/sericite, magnetite to haematite; growth of granophyres/perthite/rapakivi like textures. They are enriched in SiO₂, Na₂O+K₂O, Fe/Mg, Rb, Zr, Y, Ga, REE (except Eu) and depleted in MgO, CaO, Mg#, P, Ti, Sr, Ni, Cr, Co and V. Uniform REE patterns, parallel to sub-parallel, LREE enriched over HREE and prominent negative Eu-anomalies are the characteristics of these granitoids. Geochemical parameters satisfy the A-type nature of granitoids and crustal origin of these rocks. These granitoids are high heat producing granitoids because of their high content of radioactive elements (U, Th, K), and can be classified as granite (Type I) (avg. 7.18 μWm⁻³), rhyolite and trachyte (Type II) (avg. 4.47 μWm⁻³) and acid dyke (Type III) (avg. 14.53 μ Wm⁻³). The average total heat generation unit (HGU) of Type I (17.10 HGU), Type II (10.64 HGU) and Type III (35.31 HGU) are much higher than the average value of continental crust (3.8 HGU), which imply a possible linear relationship among the surface heat generations in the MFP. Field, petrography and whole rock geochemical characteristics suggest potentiality for rare metals and rare earth elements mineralization in the studied granitoids of the MFP.     

Nitrate pollution and its distribution in the groundwater of Srikakulam district, Andhra Pradesh, India

The complex depositional pattern of clay and sand in most of the areas controlled the vertical and lateral movement of nitrate in groundwater. The variation of nitrate concentration at different groundwater levels and the lateral distribution of nitrate in the groundwater at two sites indicated the filtration of nitrate by clayey formations. A rural agricultural district located in the Vamsadhara river basin, India was selected for studying the lateral and vertical distribution of nitrate in the groundwater and the association of nitrate with other chemical constituents. The nitrate concentrations in the groundwater are observed to vary between below detectable limit and 450 mg NO₃/L. The sources for nitrate are mainly point sources (poultry farms, cattleshed and leakages from septic tanks) and non-point sources (nitrogenous fertilisers). The nitrate concentrations are increased after fertiliser applications. However, very high concentrations of nitrate are derived from animal wastes. Relatively better correlations between nitrate and potassium are observed (R = 0.74 to 0.82). The better relationship between these two chemical constituents in the groundwater may be due to the release of potassium and nitrate from both point and non-point sources. The nitrate and potassium concentrations are high in the groundwater from clayey formations.     

Groundwater quality and its suitability for drinking and agricultural use in Chithar River Basin, Tamil Nadu, India

Hydrochemistry of groundwater in Chithar Basin, Tamil Nadu, India was used to assess the quality of groundwater for determining its suitability for drinking and agricultural purposes. Physical and chemical parameters of groundwater such as electrical conductivity, pH, total dissolved solids (TDS), Na⁺, K⁺, Ca²⁺, Mg²⁺, Cl^–, HCO₃^–, CO₃^2–, SO₄^2–, NO^–₃, F^–, B^– and SiO₂ were determined. Concentrations of the chemical constituents in groundwater vary spatially and temporarily. Interpretation of analytical data shows that mixed Ca–Mg–Cl, Ca–Cl and Na–Cl are the dominant hydrochemical facies in the study area. Alkali earths (Ca²⁺, Mg²⁺) and strong acids (Cl^–, SO₄^2–) are slightly dominating over alkalis (Na⁺, K⁺) and weak acids (HCO₃^–, CO₃^2–). The abundance of the major ions is as follows: Na⁺ Ca²⁺ Mg²⁺ > K⁺ = Cl^– > HCO₃^–> SO₄^2– > NO₃^– > CO₃^2– . Groundwater in the area is generally hard, fresh to brackish, high to very high saline and low alkaline in nature. High total hardness and TDS in a few places identify the unsuitability of groundwater for drinking and irrigation. Such areas require special care to provide adequate drainage and introduce alternative salt tolerance cropping. Fluoride and boron are within the permissible limits for human consumption and crops as per the international standards.     

Regional hydrostratigraphy and groundwater flow modeling in the arsenic-affected areas of the western Bengal basin, West Bengal, India

The first documented interpretation of the regional-scale hydrostratigraphy and groundwater flow is presented for a ～21,000-km² area of the arsenic-affected districts of West Bengal [Murshidabad, Nadia, North 24 Parganas and South 24 Parganas (including Calcutta)], India. A hydrostratigraphic model demonstrates the presence of a continuous, semi-confined sand aquifer underlain by a thick clay aquitard. The aquifer thickens toward the east and south. In the south, discontinuous clay layers locally divide the near-surface aquifer into several deeper, laterally connected, confined aquifers. Eight 22-layer model scenarios of regional groundwater flow were developed based on the observed topography, seasonal conditions, and inferred hydrostratigraphy. The models suggest the existence of seasonally variable, regional, north–south flow across the basin prior to the onset of extensive pumping in the 1970s. Pumping has severely distorted the flow pattern, inducing high vertical hydraulic gradients across wide cones of depression. Pumping has also increased total recharge (including irrigational return flow), inflow from rivers, and sea water intrusion. Consequently, downward flow of arsenic contaminated shallow groundwater appears to have resulted in contamination of previously safe aquifers by a combination of mechanical mixing and changes in chemical equilibrium.     

Nature and origin of arsenic carriers in shallow aquifer sediments of Bengal Delta,India

Sediments from shallow aquifers in Bengal Delta, India have been found to contain arsenic. Rivers of Ganga-Brahmaputra system, responsible for depositing these sediments in the delta, have created a store of arsenic. Geomorphological domains with different depositional styles regulate the pattern of distribution of zones with widely different content of groundwater arsenic. The high arsenic zones occur as narrow sinuous strips confined to channel deposits. A few iron-bearing clastic minerals and two post-depositional secondary products are arsenic carriers. Secondary siderite concretions have grown on the surface of the clastic carriers in variable intensity. The quantity of arsenic in all clastic carriers is in excess of what is generally expected. Excess arsenic is contributed by the element adsorbed on the concretion grown on the surface of the carriers, which adds up to the arsenic in the structure of the minerals. Variable abundance of concretions is responsible for the variable quantity of arsenic in the carriers and the sediment samples. Fe²⁺ for the growth of siderite concretions is obtained from the iron-bearing clastic carriers. The reaction involves reduction of trivalent iron to bivalent and the required electron is obtained by transformation of As³⁺ to As⁵⁺. It is suggested that oxidation of As³⁺ to As⁵⁺ is microbially mediated. In the Safe zone arsenic is retained in the carriers and groundwater arsenic is maintained below 0.05 mg/l. In the Unsafe zone sorbed arsenic is released from the carriers in the water through desorption and dissolution of concretion, thereby elevating the groundwater arsenic level to above 0.05 mg/l.     

Gradient profiling for the investigation of groundwater saturated fractures in hard rocks of Uttar Pradesh,India

Gradient profiling (GP) has been successfully utilized as a preliminary tool to identify fractured zones saturated with groundwater in hard-rock areas of Robertsganj, Sonebhadra district, Uttar Pradesh, India. Conducting geoelectrical sounding at randomly selected places may not provide fruitful results since fractures are sparsely distributed in hard rocks. In gradient profiling, current electrodes with large separation remain fixed while the potential dipole is moved between the current electrodes in the central one-third portion of the profile at a small station interval. A GP survey was conducted along seven profiles having different lengths in two small sectors of the study area. Low resistive zones have been identified which correspond to the fractured zones. A few geoelectrical soundings were carried out to investigate the depth and thickness of the fractured zones. Two test boreholes, one drilled in each sector, yielded continuous discharge of fresh water (18,000–24,000 L/h). The present study confirms the findings of previous work that the GP survey is a powerful initial technique that identifies the presence of a fractured zone, especially in a hard-rock area covered with a thin soil layer.     

Optimizing a piezometric network in the estimation of the groundwater budget: a case study from a crystalline-rock watershed in southern India

An estimate of the groundwater budget at the catchment scale is extremely important for the sustainable management of available water resources. Water resources are generally subjected to over-exploitation for agricultural and domestic purposes in agrarian economies like India. The double water-table fluctuation method is a reliable method for calculating the water budget in semi-arid crystalline rock areas. Extensive measurements of water levels from a dense network before and after the monsoon rainfall were made in a 53 km² watershed in southern India and various components of the water balance were then calculated. Later, water level data underwent geostatistical analyses to determine the priority and/or redundancy of each measurement point using a cross-validation method. An optimal network evolved from these analyses. The network was then used in re-calculation of the water-balance components. It was established that such an optimized network provides far fewer measurement points without considerably changing the conclusions regarding groundwater budget. This exercise is helpful in reducing the time and expenditure involved in exhaustive piezometric surveys and also in determining the water budget for large watersheds (watersheds greater than 50 km²).     

A comparative evaluation of groundwater suitability for irrigation and drinking purposes in two intensively cultivated districts of Punjab, India

Punjab is the most cultivated state in India with the highest consumption of fertilizers. Patiala and Muktsar districts are two agricultural dominated districts of Punjab located in extreme south-east and south-west of the state. This paper highlights temporal variations of the groundwater quality and compares its suitability for irrigation and drinking purpose in these two districts. Water samples were collected in March and September 2003, representing the pre-monsoon and post-monsoon seasons, respectively. Water samples were analysed for almost all major cations, anions, dissolved heavy metals and turbidity. Parameters like sodium adsorption ratio, % sodium, residual sodium carbonate, total hardness, potential salinity, Kelley’s ratio, magnesium ratio, index of base exchange and permeability index were calculated on the basis of chemical data. A questionnaire was also used to investigate perception of villagers on taste and odour. Comparison of the concentration of the chemical constituents with WHO (world health organization) drinking water standards of 2004 and various classifications show that present status of groundwater in Patiala is better for irrigation and drinking purposes except for a few locations with a caution that it may deteriorate in near future. In Muktsar, groundwater is not suitable for drinking. Higher total hardness (TH) and total dissolved solids at numerous places indicate the unsuitability of groundwater for drinking and irrigation. Results obtained in this forms baseline data for the utility of groundwater. In terms of monsoon impact, Patiala groundwater shows dilution and flushing but Muktsar samples show excessive leaching of different chemical components into the groundwater leading to the enrichment of different anions and cations indicating pollution from extraneous sources. No clear correlation between the quality parameters studied here and perceived quality in terms of satisfactory taste response were obtained at electrical conductivity values higher than the threshold minimum acceptable value.     

Arsenic enrichment in groundwater in the middle Gangetic Plain of Ghazipur District in Uttar Pradesh,India

Groundwater with high geogenic arsenic (As) is extensively present in the Holocene alluvial aquifers of Ghazipur District in the middle Gangetic Plain, India. A shift in the climatic conditions, weathering of carbonate and silicate minerals, surface water interactions, ion exchange, redox processes, and anthropogenic activities are responsible for high concentrations of cations, anions and As in the groundwater. The spatial and temporal variations for As concentrations were greater in the pre-monsoon (6.4–259.5 μg/L) when compared to the post-monsoon period (5.1–205.5 µg/L). The As enrichment was encountered in the sampling sites that were close to the Ganges River (i.e. south and southeast part of Ghazipur district). The depth profile of As revealed that low concentrations of NO₃⁻ are associated with high concentration of As and that As depleted with increasing depth. The poor relationship between As and Fe indicates the As release into the groundwater, depends on several processes such as mineral weathering, O₂ consumption, and NO₃⁻ reduction and is de-coupled from Fe cycling. Correlation matrix and factor analysis were used to identify various factors influencing the gradual As enrichment in the middle Gangetic Plain. Groundwater is generally supersaturated with respect to calcite and dolomite in post-monsoon period, but not in pre-monsoon period. Saturation in both periods is reached for crystalline Fe phases such as goethite, but not with respect to poorly crystalline Fe phases and any As-bearing phase. The results indicate release of arsenic in redox processes in dry period and dilution of arsenic concentration by recharge during monsoon. Increased concentrations of bicarbonate after monsoon are caused by intense flushing of unsaturated zone, where CO₂ is formed by decomposition of organic matter and reactions with carbonate minerals in solid phase. The present study is vital considering the fact that groundwater is an exclusive source of drinking water in the region which not only makes situation alarming but also calls for the immediate attention.     

Seasonal variation of groundwater quality in a part of Guntur District, Andhra Pradesh, India

The area in Guntur district, Andhra Pradesh, India, is selected to discuss the impact of seasonal variation of groundwater quality on irrigation and human health, where the agriculture is the main livelihood of rural people and the groundwater is the main source for irrigation and drinking. Granite gneisses associated with schists and charnockites of the Precambrian Eastern Ghats underlie the area. Groundwater samples collected seasonally, pre- and post-monsoons, during three years from forty wells in the area were analyzed for pH, EC, TDS, TA, TH, Ca²⁺, Mg²⁺, Na⁺, K⁺, CO₃²⁻, HCO₃⁻, Cl⁻, SO₄²⁻, NO₃⁻and F⁻. The chemical relationships in Piper’s diagram, Chebotarev’s genetic classification and Gibbs’s diagram suggest that the groundwaters mainly belong to non-carbonate alkali type and Cl⁻ group, and are controlled by evaporation-dominance, respectively, due to the influence of semi-arid climate, gentle slope, sluggish drainage conditions, greater water–rock interaction, and anthropogenic activities. A comparison of the groundwater quality in relation to drinking water quality standards proves that most of the water samples are not suitable for drinking, especially in post-monsoon period. US Salinity Laboratory’s and Wilcox’s diagrams, and %Na⁺ used for evaluating the water quality for irrigation suggest that the majority of the groundwater samples are not good for irrigation in post-monsoon compared to that in pre-monsoon. These conditions are caused due to leaching of salts from the overlying materials by infiltrating recharge waters. A management plan is suggested for sustainable development of the area.     

Association of hydrogeological factors in temporal variations of fluoride concentration in a crystalline aquifer in India

The major part of groundwater in India is found in granitic aquifers. Fluoride in groundwater from a crystalline aquifer in a semi-arid region of granitic rocks in India, known as Maheshwaram watershed, was analyzed for spatial and temporal variability during 1999–2002 to assess the effect of hydrogeological factors on fluoride concentration. Samples were collected from 32 representative wells in the area for the pre- and post-monsoon seasons and analyzed for F content. The CHESS computer program was used to calculate ionic activities of aqueous species and the mineral saturation index (SI) for calcite and fluorite. The GARDENIA computer program was used to calculate the recharge values in the study area. The influences of dissolution kinetics of fluoride minerals and recharge from rainfall on fluoride concentration were of interest and results clearly indicate that fluoride content in groundwater depends on the interaction period of groundwater with host rock. Results could also be utilized for designing remedial measures particularly with dilution method in an optimal way.