Composition,radioactivity, and possible applications of kaolin deposits of Sinai,Egypt

This work discusses the composition, radioactivity, and possible utilization of the kaolin resources in Sinai which are hosted in thick sandstone sequences belonging to the Carboniferous (Wadi Khaboba) and Early Cretaceous (Wadi Iseila and Abansakar) ages. The characterization of kaolin was done by microscopic and SEM examination, supported by XRD and ICP-MS analyses. The studied kaolin resources consist of kaolinite, as the main constituent, associated with subsidiary dickite and halloysite, and minor contribution of smectite and illite. The most dominant non-clay mineral is quartz, besides minor gypsum, dolomite, and hematite. Ferrugination dominates, in most cases, at the upper boundaries of the kaolin lenses, suggesting possible supergene activity. The high Al₂O₃/SiO₂ ratio for the Cretaceous kaolin (0.54, in average) specifies its better grade relative to the Carboniferous kaolin (0.43, in average). The kaolin of the middle part of lens C in Wadi Iseila contains Si/Al molecular ratio of about unity, suggesting high-grade kaolin. The Carboniferous kaolin has enriched the radionuclides: U, Th, and Ra (at disequilibrium state due to leaching of eU relative to Ra) and the REE, relative to that of the Cretaceous age. The Carboniferous kaolin is characterized by a higher contribution of HREE (zircon signature), whereas LREE seems to be more influential for the Early Cretaceous kaolin (monazite signature). In spite of the very high CIA index (93 to 99), none of the analyzed kaolin deposits displays Ce abnormality. The high radioactivity of some Carboniferous kaolin can be a serious impediment for its utilization or its exportation. The kaolin of Sinai does not satisfy the international standards for paperwork industries and refractory manufacturing, but beneficiation may overcome this challenge. However, some lenses have high-grade kaolin with a low percentage of oxides of iron, magnesium, calcium, sodium, and potassium and a low radioactivity, hence nominated for the local refractory industry. The high-grade kaolin of Sinai fulfills the standards required for ceramics manufacturing in the global market. Grade 3 kaolin (< 30%, Al₂O₃) can be used in the manufacturing of white Portland cement and red glaze manufacturing on both local and global markets.     

Mineralogy,geochemistry, radioactivity and environmental impacts of Gabal Marwa granites,southeastern Sinai,Egypt

The Gabal Marwa area is located in the southeastern part of Sinai,Egypt.It comprises gneisses and migmatites,granodiorites and monzogranites.Field,petrographic,mineralogic and chemical investigations indicated that the Gabal Marwa granites are classified as granodiorites and monzogranites.The monzogranites constitute the most predominant rock unit exposed in the study area.They have been subjected to hydrothermal alterations,especially along the shear zones.Sericitization,desilicification,nametasomatism and development of spotty or dendritic manganese oxides are the most pronounced alteration features.These alterations resulted in the increase of TiO2,Al2O3,FeOt,MnO,CaO,MgO,Na2O,K2O and Cr,Zr,Rb,Y and Sr and the decrease of SiO2,P2O5,Ni,Zn,Ba and Nb.Radiometric studies indicated that the altered granites belong to high thorium,high uranium granites.The U,Th,U and Th,Th/U,Th and U-K variation diagrams suggested that magmatic processes controlled the distribution of these elements but the effect of hydrothermal alteration processes were clearly distinct.The Scanning Electron Microscope and X-ray Diffraction analyses indicated that the most important radioactive minerals include uranothorite,thorite,zircon,monazite and samarskite.Cinnabar and Mn minerals were also found.From the U,Th,Ra and K activity concentrations obtained for all the studied granitic samples,radium equivalent activity(Raeq),external hazard index(Hex),and internal hazard index(Hin),were calculated to assess the radiation hazard to human beings living in dwellings made of the studied granites.Altered monzogranites have radioactivity above the proposed acceptable level and,therefore,caution must be taken when these granites are used as building materials.     

Impacts of dolomitization on the petrophysical properties of El-Halal Formation, North Sinai, Egypt

The Cenomanian marine sequence in north Sinai is mostly represented by El-Halal Formation. Petrographically, it is composed of four microfacies, namely: (1) dolomitic micrite, (2) dolomicrite, (3) dolowackestone and (4) dolosparite. The assigned pore volume (10–25%) could be differentiated into: micro intercrystalline pore spaces, micro to meso vugs and micro pore channels. The present pore spaces are frequently reduced by drusy and/or xenotopic dolosparite and micro sparry calcite. El-Halal Formation has been deposited in a restricted marine platform (SMF-23, FZ-8) with a progressive shallowing sea level upward. The diagenetic history has been controlled by cementation, dolomitization, aggrading neomorphism and creation of authigenic illite. Petrophysically, the studied samples could be grouped into three petrophysical facies: (1) dolomitic micrite/dolomicrite facies, (2) dolowackestone and (3) dolosparite. The permeability (ave. 3.54, 12.9 and 0.49 md, respectively) is dependent on the pore channel radius (ave. 1.03, 1.92 and 0.19 μm, respectively) and porosity (ave. 22.1%, 25.8% and 11.4%, respectively); it could be related to the electrical tortuosity as well (ave. 3.28, 1.40 and 5.06, respectively). The apparent formation resistivity factor was measured at five consequent saline concentrations of 6, 30, 60, 90 and 120 kppm and the true one has been calculated. It is controlled by the effective porosity and electrical tortuosity. Though dolomitization has an enhancing effect on the studied petrophysical features, it had a reducing effect in its first stages of invasion through filling the pore spaces and in the last stages through the aggrading neomorphism.     

Seismicity of Sinai Peninsula, Egypt

The Sinai Peninsula has a triangular shape between the African and Arabian Plates and is bounded from the western and eastern borders by the Gulf of Suez and Gulf of Aqaba–Dead Sea rift systems, respectively. It is affected by strong and destructive earthquakes (e.g., March 31, 1969 and November 22, 1995) and moderate earthquakes (m _b?>?5) throughout its history. After the installation of the Egyptian National Seismic Network (ENSN), a great number of earthquakes has been recorded within and around Sinai. Consequently, the seismogenic source zones and seismotectonic behavior can be clearly identified. Available data, including both historical and instrumental (1900–1997), have been collected from national and international data centers. While the data from 1998 till December 2007 are gathered from ENSN bulletins. The seismogenic source zones that might affect Sinai Peninsula are defined more precisely in this work depending on the distribution of earthquakes, seismicity rate (a value), b value, and fault plane solution of the major earthquakes. In addition, the type of faults prevailed and characterized these zones. It is concluded that the Gulf of Aqaba zone–Dead Sea transform zone, Gulf of Suez rift zone, Cairo–Suez District zone, and Eastern Mediterranean dislocation zone represent the major effective zones for Sinai. Furthermore, there are two local seismic zones passing through Sinai contributing to the earthquake activities of Sinai, these are the Negev shear zone and Central Sinai fault (Themed fault) zone. The source parameters, a and b values, and the maximum expected moment magnitude have been determined for each of these zones. These results will contribute to a great extent in the seismic hazard assessment and risk mitigation studies for Sinai Peninsula to protect the developmental projects.     

A Pan-African core complex in the Sinai,Egypt

In the late Precambrian history of the Wadi Kid area in the Sinai, Egypt, two deformation phases are clearly recognized. The first phase, D₁ (pre-620 Ma), produced a steep regional foliation, axial planar to upright F₁ folds, in rocks of a lower-greenschist grade. This compressional phase of deformation is interpreted in terms of subduction in an island-arc setting. The second phase, D₁ (post-620 Ma), is mainly expressed by the widespread development of sub-horizontal mylonitic zones with a total thickness of 1.5 km. Shear sense indicators give a consistent regional transport direction to the northwest, with local indications of reversal to the southeast. This event is associated with regional LP/HT metamorphism, indicative of high thermal gradients. Because of the LP/HT metamorphism, the change in geochemical nature of the granitoids, and the orientation of the dykes, we interpret the mylonitic zones as low-angle normal shear zones related to core-complex development during an extensional event with the transport reversal being induced by doming. We postulate that orogenic collapse was responsible for the transition from the D₁ compressional phase to the D₁ extensional phase.     

A-type volcanics in Central Eastern Sinai, Egypt

Alkaline rhyolitic and minor trachytic volcanics were erupted 580–530 Ma ago. They occur with their A-type intrusive equivalents in Sinai, southern Negev and southwestern Jordan. At Taba-Nuweiba district, these volcanics outcrop in three areas, namely, Wadi El-Mahash, Wadi Khileifiya and Gebel El-Homra. Mineralogically, they comprise alkali feldspars, iron-rich biotite and arfvedsonite together with rare ferro-eckermannite. Geochemically, the older rhyolitic volcanics are highly evolved, enriched in HFSE including REE and depleted in Ca, Mg, Sr and Eu. The rhyolitic rocks of Wadi El-Mahash and Gebel El-Homra are enriched in K₂O content (5.3–10.1 wt.%) and depleted in Na₂O content (0.08–2.97 wt.%), while the rhyolites of Wadi Khileifiya have normal contents of alkalis. Their REE patterns are uniform, parallel to subparallel, fractionated [(La/Yb)_n = 5.4] and show prominent negative Eu-anomalies. They are classified as alkali rhyolites with minor comendites. The younger volcanics are classified as trachyandesite and quartz trachyte (56.6–62.9 wt.% SiO₂). Both older and younger volcanics represent two separate magmatic suites. The overall mineralogical and chemical characteristics of these volcanics are consistent with within plate tectonic setting. It is suggested that partial melting of crustal rocks yielded the source magma. Lithospheric extension and crustal rupture occurred prior to the eruption of these volcanics. The rather thin continental crust (35 km) as well as the continental upheaval and extensive erosion that preceded their emplacement favoured pressure release and increasing mantle contribution. The volatiles of the upper mantle were important agents for heat transfer, and sufficient for the anatexis of the crustal rocks. A petrogenetic hypothesis is proposed for the genesis of the recorded potassic and ultrapotassic rhyolitic rocks through the action of dissolved volatiles and their accumulation in the uppermost part of the magma chamber.     

Integrated diagenesis and sequence stratigraphic study of tidal sandstones: the Adedia Formation (Cambro-Ordovician), Sinai, Egypt

This work examines the different effects meteoric versus marine diagenesis had on Cambro-Ordovician tidal sandstones during episodes of fluctuating sea level. The distribution of diagenetic fabrics was compared to a sequence stratigraphic framework. Initially, a rise in relative sea level (RSL) resulted in deposition of transgressive systems tract sands directly onto crystalline basement. These sandstones display evidence of limited cementation by marine, grain-fringing dogtooth-like and fibrous calcite. A fall in RSL resulted in the progradation of a tidal flat complex and deposition of highstand systems tract (HST) and lowstand systems tract (braided fluvial) sandstones. Contemporaneous meteoric-water flux into sands of all the systems tracts occurred. Sequence boundaries (SB) are marked by fluvial incision of tidal sands and by the development of palaeosols. Meteoric incursion during sea-level lowstands resulted in the dissolution and kaolinitization of feldspars, micas and mud intraclasts in all systems tracts, but is most extensive in HST sandstones below the SB. The effect of meteoric-water flux on the dissolution of marine calcite cements is poorly known. Mesogenetic alterations include intergranular pressure dissolution and formation of variable amounts of syntaxial quartz overgrowths in all systems tracts. Telogenetic alteration (i.e. weathering) in the sandstones includes the formation of goethite and calcite. Thus, the integration of diagenesis with sequence stratigraphy provides a useful tool with which to understand reservoir-quality distribution in sand-dominated, tidal sediments.     

Natural radioactivity in basement rocks and stream sediments, Sharm El Sheikh Area, South Sinai, Egypt: radiometric levels and their significant contributions

The present study examines the natural radioactivity in basements rocks including granites and associated dikes besides stream sediments in Sharm El Sheikh area. Two main rock units are concerned; granites pertaining to Younger Granites of Precambrian age and clastic sedimentary rocks related to Miocene and Pliocene ages. This area is traversed by two shear zones that were delineated as the master fractures trending NW and NNE and controlling uranium and thorium enrichment in granites and dikes. The field and laboratory radiometric measurements revealed radiometric anomalies, in particular, along shear zones. The results of radiometric analyses including concentrations of equivalent uranium (eU), equivalent thorium (eTh), Ra, and K radionuclides as well as the calculated ratios eTh/eU and eU/Ra for representative samples belonging to all rock varieties, revealed that the felsic dikes have the highest values of the average radionuclides potential followed by the alkali feldspar granites, while the mafic dikes display the lowest radioactivity potential. On the other hand, the trends defined in the variation of uranium and thorium reflects the amount of remobilization of uranium that has occurred within the plutons. The eTh and eU/eTh ratios shows a negative correlation, suggesting that distribution of uranium and thorium was at least controlled by magmatic differentiation, while, the positive correlation between eU and eU/eTh ratios indicates enrichment of uranium through post magmatic processes. Some precautions and recommendations are proposed to avoid any possible environmental impacts from shear zone areas with high intensity of natural radiation sources.     

Allogenic and autogenic controls on facies and stratigraphic architecture of the Lower Jurassic Mashabba Formation,Gebel Al-Maghara,North Sinai,Egypt

The Lower Jurassic Mashabba Formation crops out in the core of the doubly plunging Al-Maghara anticline, North Sinai, Egypt. It represents a marine to terrestrial succession deposited within a rift basin associated with the opening of the Neotethys. Despite being one of the best and the only exposed Lower Jurassic strata in Egypt, its sedimentological and sequence stratigraphic framework has not been addressed yet. The formation is subdivided informally into a lower and upper member with different depositional settings and sequence stratigraphic framework. The sedimentary facies of the lower member include shallow-marine, fluvial, tidal flat and incised valley fill deposits. In contrast, the upper member consists of strata with limited lateral extension including fossiliferous lagoonal limestones alternating with burrowed deltaic sandstones. The lower member contains three incomplete sequences (SQ1-SQ3). The depositional framework shows transgressive middle shoreface to offshore transition deposits sharply overlain by forced regressive upper shoreface sandstones (SQ1), lowstand fluvial to transgressive tidal flat and shallow subtidal sandy limestones (SQ2), and lowstand to transgressive incised valley fills and shallow subtidal sandy limestones (SQ3). In contrast, the upper member consists of eight coarsening-up depositional cycles bounded by marine flooding surfaces. The cycles are classified as carbonate-dominated, siliciclastic-dominated, and mixed siliciclastic-carbonate. The strata record rapid changes in accommodation space. The unpredictable facies stacking pattern, the remarkable rapid facies changes, and chaotic stratigraphic architecture suggest an interplay between allogenic and autogenic processes. Particularly syndepositional tectonic pulses and occasional eustatic sea-level changes controlled the rate and trends of accommodation space, the shoreline morphology, the amount and direction of siliciclastic sediment input and rapid switching and abandonment of delta systems.     

Paleoclimate record in the Nubian Sandstone Aquifer,Sinai Peninsula,Egypt

Sixteen groundwater samples collected from production wells tapping Lower Cretaceous Nubian Sandstone and fractured basement aquifers in Sinai were analyzed for their stable isotopic compositions, dissolved noble gas concentrations (recharge temperatures), tritium activities, and ¹⁴C abundances. Results define two groups of samples: Group I has older ages, lower recharge temperatures, and depleted isotopic compositions (adjusted ¹⁴C model age: 24,000–31,000 yr BP; δ¹⁸O: − 9.59‰ to − 6.53‰; δ²H: − 72.9‰ to − 42.9‰; < 1 TU; and recharge T: 17.5–22.0°C) compared to Group II (adjusted ¹⁴C model age: 700–4700 yr BP; δ¹⁸O: − 5.89‰ to − 4.84‰; δ²H: − 34.5‰ to − 24.1‰; < 1 to 2.78 TU; and recharge T: 20.6–26.2°C). Group II samples have isotopic compositions similar to those of average modern rainfall, with larger d-excess values than Group I waters, and locally measurable tritium activity (up to 2.8 TU). These observations are consistent with (1) the Nubian Aquifer being largely recharged prior to and/or during the Last Glacial Maximum (represented by Group I), possibly through the intensification of paleowesterlies; and (2) continued sporadic recharge during the relatively dry and warmer interglacial period (represented by Group II) under conditions similar to those of the present.     

Characteristic features of salt tectonics offshore North Sinai, Egypt

Salt tectonic along offshore North Sinai was studied using seismic reflection data. The study revealed and identified various types of salt tectonics and structures in the study area. The triggering mechanism of salt tectonics was attributed to the pressure regime initiated from overloading sediments on the Messinian evaporites. The sediment load of 3,000?m exceeds the critical load (more than 1,000?m) and hence creates a pressure zone. The salt-generated structures resulted from thin-skinned extension that is driven by gravity gliding of the overloading sediments above the Messinian evaporite boundary, which acts as a detachment layer. These structures comprise normal growth faults and keystone grabens, trending roughly perpendicular to the slope of the continental margin. Salt tectonics in the study area were also triggered by the deformation of the movement of evaporite layer that causes stretching and fragmentation of the evaporite layer. Moving salt layer took place laterally and vertically, causing lateral and vertical pressures inside the Pliocene sediments. These movements of sediments led to the formation of salt rollers, salt weld, salt diapirs, rollover structures, and fault blocks. The interpretation of seismic data illustrates that the evaporite layer was switched off between the famous reflector M at its top and another reflector N at its base. M reflector is present and can be traced across the whole study area, while the N reflector pinched out in some parts of the study area.     

Opaque mineralogy and magnetic investigation of some basaltic occurrences, Sinai, Egypt

Ore microscopic investigation of the Fe?CTi oxide minerals was carried out on samples from three Oligo-Miocene basaltic occurrences from Sinai, Egypt. These occurrences are Gebel Maghara (north Sinai), Rageibet Naama (central Sinai), and Wadi Matulla (west Sinai). The results and correlations of magnetic parameters such as NRM intensity and susceptibility, coercive force H _c, and the ratio M _r/M _s, H _c and Q value, the ratio M _r/M _s, saturation magnetization M _s, and K are discussed in light of opaque mineralogical studies. It has been found that the variations in the magnetic properties of the basaltic occurrences are strongly dependent on the crystallite size and nature and style of exsolution textures and fabrics. The latter are controlled by the cooling conditions, being most sensitive to the partial pressure of oxygen in the melt.     

Geochemistry and mineral chemistry of Pan-African amphibolites of South Sinai,Egypt

In the Wadi Feiran area, amphibolites occur as inclusions, bands, linear bodies of variable thickness and irregular lenses in para-geneisses. Chemical evidence indicates that these amphibolites display an igneous origin and were derived from magma essentially of tholelitic rather than alkaline composition; transitional in character between continental and island-arc. The chemistry of amphiboles, related to pressure and temperature conditions of meta-morphism, showed that they were formed under low pressure and high temperature conditions.     

Structural architecture and tectonic evolution of the Maghara inverted basin,Northern Sinai,Egypt

Large NE–SW oriented asymmetric inversion anticlines bounded on their southeastern sides by reverse faults affect the exposed Mesozoic and Cenozoic sedimentary rocks of the Maghara area (northern Sinai). Seismic data indicate an earlier Jurassic rifting phase and surface structures indicate Late Cretaceous-Early Tertiary inversion phase. The geometry of the early extensional fault system clearly affected the sense of slip of the inverted faults and the geometry of the inversion anticlines. Rift-parallel fault segments were reactivated by reverse slip whereas rift-oblique fault segments were reactivated as oblique-slip faults or lateral/oblique ramps. New syn-inversion faults include two short conjugate strike-slip sets dissecting the forelimbs of inversion anticlines and the inverted faults as well as a set of transverse normal faults dissecting the backlimbs. Small anticline–syncline fold pairs ornamenting the steep flanks of the inversion anticlines are located at the transfer zones between en echelon segments of the inverted faults.     

Pan-African high-grade metamorphism of southern Sinai,Egypt, fluid inclusion evidence

Fluid inclusions in the leucosomes of Wadi Feiran migmatites showed that CO ₂ , H₂O and (H₂O-CO₂) fluids were likely to have been present when partial melting began in these rocks. Low salinity, aqueous fluid, to a lesser extent, CO₂-rich fluids are the most abundant fluids. The present study suggests that high-density CO₂ inclusions were formed at the earliest stage, while H₂O inclusions were formed at the late stage. In an intermediate stage, low-density CO₂ and H₂O, CO₂ inclusions were formed. At the early stage of uplift and during melt crystallization, the CO₂-bearing vapour was trapped at grain boundaries. At the late stage of uplift, H₂O released at the time of crystallization of the melt was trapped as inclusions.     

Upper Jurassic record of Polyphylloseris (Egypt, Northern Sinai)

Genus Polyphylloseris is a scleractinian colonial coral that has been established by d’Orbigny (1849) from the Neocomian of Yonne, France. The genus is characterized by having elevated domal calices that are mammillar or craterlike in shape and with porous confluent septa. Columella is absent or rudimentary, and the lower surface of the corallum is covered with a thick and wrinkled holotheca. Specimens having the above-mentioned characteristics have been collected from the Upper Jurassic Arousiah Member of the Masajid Formation (Callovian–Oxfordian) of Gebel Maghara, Northern Sinai, Egypt. They are characterized by having a cupolate colonial form and porous pennulate septa which reach 40–50 in number. Based on these characters and other characters such as density of septa, height, and width of mammillar calices, the studied material is attributed to a new species named Polyphylloseris magharensis. The new species is a first undoubted record of Polyphylloseris in the Jurassic. Previously recorded undoubted ages of the genus are Early and Late Cretaceous. The fewer number of septa and the smaller-sized and closer mammillar calices allow differentiation of the species from other species such as Polyphylloseris icaunensis d’Orbigny and Polyphylloseris convexa d’Orbigny.     

Geochemical and isotopic evolution of groundwater in the Wadi Watir watershed,Sinai Peninsula,Egypt

The Wadi Watir delta in the Wadi Watir watershed is a tourist area in the arid southeastern part of the Sinai Peninsula, Egypt, where development and growth of the community on the delta are constrained by the amount of groundwater that can be withdrawn sustainably. To effectively manage groundwater resources in the Wadi Watir delta, the origin of groundwater recharge, groundwater age, and changes in groundwater chemistry in the watershed needs to be understood. Mineral identification, rock chemistry, water chemistry, and the isotopes of hydrogen, oxygen, and carbon in groundwater were used to identify the sources, mixing, and ages of groundwater in the watershed and the chemical evolution of groundwater as it flows from the upland areas in the watershed to the developed areas at the Wadi Watir delta. Groundwater in the Wadi Watir watershed is primarily from recent recharge while groundwater salinity is controlled by mixing of chemically different waters and dissolution of minerals and salts in the aquifers. The El Shiekh Attia and Wadi El Ain areas in the upper Wadi Watir watershed have different recharge sources, either from recharge from other areas or from different storm events. The downgradient Main Channel area receives groundwater flow primarily from the El Shiekh Attia area. Groundwater in the Main Channel area is the primary source of groundwater supplying the aquifers of the Wadi Watir delta.