Portable X-ray fluorescence identification of the Cretaceous–Paleogene boundary: Application to the Agost and Caravaca sections,SE Spain

It is shown that portable X-ray fluorescence (pXRF) is a powerful tool for the identification and geochemical characterization of prospective Cretaceous–Paleogene (K–Pg) boundary sites. Field measurements in two well-known K–Pg boundary sequences, located at Agost and Caravaca, SE Spain, have been performed. A sizable enrichment around the K–Pg horizon of several elements such as K, Ti, Fe, Ni, Cr, Cu, Zn, As or Pb, together with a strong reduction in the Ca content, is found with the pXRF instrument. These observations represent a primary geochemical signature of the K–Pg boundary in distal marine sections such as those of Agost and Caravaca. Also, the intensities of the pXRF peaks correlate well with elemental composition data obtained by inductively coupled plasma-mass spectrometry (ICP-MS) on collected samples. Hence, the pXRF field measurements are shown to provide fast and useful quantitative information about K–Pg boundary sequences.     

Charophytes from the Cretaceous – Paleogene transition in the Pingyi Basin (Eastern China) and their Eurasian correlation

Charophytes from uppermost Campanian to Paleocene deposits in the Pingyi Basin (Shandong Province, Eastern China) are studied from the perspectives of taxonomy, paleoecology, biogeography, and biostratigraphy. The taxonomy of charophytes used by previous authors is revisited based on a study of intraspecific gyrogonite polymorphism, facilitating comparisons between China and Europe. A number of synonymies are proposed. Gobichara deserta is confirmed as a younger synonym of Microchara cristata. The genus Euaclistochara Z. Wang is shown to be a younger synonym of Lamprothamnium J. Groves. Charophyte assemblages from the Pingyi Basin were generally species-poor but showed a high degree of variation depending on the paleoenvironment. During the latest Campanian–Maastrichtian, brackish water assemblages were monospecific, formed by Feistiella anluensis. Permanent lakes were dominated by Microchara cristata and Peckichara praecursoria. Lamprothamnium ellipticum and Mesochara voluta inhabited the overbank ponds near braided rivers. The Paleocene was much more homogeneous and was dominated by Peckichara varians in permanent lakes. A new biozonation is proposed which encompasses two biozones based on species with broad paleoecological requirements and a Eurasiatic distribution. These are the Microchara cristata biozone starting in the latest Campanian and lasting at least until the earliest Danian and the Peckichara varians biozone encompassing the late Danian–earliest Eocene. These biozones allow direct correlation between Chinese and European basins.     

Occurrence of palygorskite and sepiolite in upper Paleocene–middle Eocene marine deep sediments of the Lagonegro Basin (Southern Apennines—Italy): Paleoenvironmental and provenance inferences

A mineralogical and geochemical study of clay lithologies and a biostratigraphic analysis of the carbonates from the deep-sea Lagonegro Basin (Southern Apennines—Italy) have been carried out to deduce in general the provenance of clay sediments and their paleoenvironmental conditions and particular to recognize the signature of the Paleocene–Eocene climatic global warming. The analysed succession comprising a wide stratigraphic interval of the Sannio Unit, spanning between Albian to the upper Oligocene–lower Miocene, is exposed near Accettura and Stigliano villages. Eighteen clay samples were analysed by XRD, XRF, SEM, TG-DTA. Their age was framed by biostratigraphic analyses carried out on carbonate sediments. Mineral assemblage of the clay sediments includes quartz, carbonates (calcite and dolomite), feldspars (plagioclase and k-feldspars), hematite, randomly illite/smectite mixed layers with a low illite percentage, kaolinite, discrete illite–muscovite, chlorite, palygorskite and sepiolite. The low illite percentage in randomly illite/smectite mixed layers indicates low diagenetic conditions for the studied successions. These features are unique for the Cretaceous–Tertiary successions of the Lagonegro domain and are particularly significant for the preservation of the native mineralogical assemblage useful to determine the provenance and paleoenvironmental conditions of the clayey sediments. Palygorskite and sepiolite are concentrated in the upper Paleocene–middle Eocene stratigraphic interval and particularly in the upper part of the early Eocene—lower part of the middle Eocene (biozone of Blow P 9–12). Clay sediments rich in palygorskite and sepiolite show a higher P₂O₅ amount and a lower kaolinite percentage, compatible with warm and arid climatic conditions typical of the global warming event well recorded in the southern tethyan margin. Likely palygorskite and sepiolite formed in lagoonal environment in nearby carbonate platform margins and then they were transported into the Lagonegro Basin as indicated by the well developed habitus of palygorskite. During the Paleogene the Lagonegro Basin and the nearby carbonate platforms represented a key sector the southern paleodomains of the Tethys. The discovery of these minerals gives a contribution to the reconstruction paleoenvironmental conditions of the Tethian paleo-margin during the early–middle Eocene.     

Cyclostratigraphic and chronostratigraphic correlations in the Barremian–Aptian shallow-marine carbonates of the central-southern Apennines (Italy)

We present a high-resolution sedimentological analysis of Barremian–Aptian shallow-water carbonates from two cores (S. Maria 6 and 4) that were drilled in the central Apennines (central Italy) and one section (Monte Faito) that crops out in the southern Apennines (southern Italy). The aims of this work are (a) to propose a high-resolution correlation of sections that are located approximately 170 km apart in different tectonic units and paleogeographic domains using a microstratigraphic (cm-scale) approach and (b) to reveal global and regional mechanisms that control the stratigraphic architecture of these carbonate platform strata.A composite S. Maria section was assembled by integrating the sedimentologic and biostratigraphic analyses of the two cores, which overlap each other across the Barremian–Aptian boundary. Both the S. Maria and the Monte Faito sections show repetitive facies patterns that are expressed as elementary cycles, which are hierarchically grouped into bundles and superbundles. The elementary cycles are meter-scale sedimentary units that are bounded by subaerial erosion surfaces, which directly overlie subtidal deposits. This implies that they formed under the influence of relative sea-level fluctuations. In both sections, the superbundles are organized into Transgressive/Regressive Facies Trends (T/RFTs), which are considered to be expressions of lower-frequency relative sea-level changes.These deposits, like their Cretaceous analogues of other areas of the Apennines, show evidence of astronomically controlled eustatic oscillations, which are reflected in the hierarchical organization of their stacking patterns. They also exhibit a sequence-stratigraphic configuration that is best recognizable in the superbundles and T/RFTs. Based on integrated stratigraphic criteria, a high-resolution regional correlation between S. Maria and Monte Faito was developed and compared with the reference section of Monte Raggeto (M. Maggiore, southern Apennines, Italy), where biostratigraphic and cyclostratigraphic studies have been complemented by magneto- and isotope-stratigraphy.We also propose a chronostratigraphic correlation between our T/RFTs and the Tethyan stratigraphic cycles of Hardenbol et al. (1998). Based on the cyclostratigraphic interpretation and orbital chronostratigraphy of the studied interval, we estimate a minimum duration of 5.2 my for the Barremian interval, which is similar to the 4.5 my duration from the Geological Time Scale of Gradstein et al., (2012).     

New data for the kinematic interpretation of the Alps–Apennines junction (Northwestern Italy)

Alps and Apennines are juxtaposed within an approximately 100 km-wide area covered by the Upper Eocene to Miocene successions of the Tertiary Piedmont Basin. The Upper Eocene–Oligocene evolution of this area was characterized to the north and west by the propagation of the SE-verging Southalpine thrust-fold belt that can be traced from the Po Plain subsurface until the Torino Hill-Saluzzese area, and to the south by a high-angle, broadly E–W oriented megashear zone that led to the juxtaposition of different crustal levels and controlled the development of a mosaic of partly independent sub-basins. Since the latest Oligocene the N-verging Apenninic tectonics prevailed in the collisional system and the Tertiary Piedmont Basin evolved as a wide thrust-top basin, bounded to the north by the N-verging Monferrato arc and characterized by a tectono-sedimentary evolution recording changes of subsidence and shift of depocentres in relation to crustal structures.     

Fluid–rock interaction across the South Tibetan Detachment,Garhwal Himalaya (India): Mineralogical and geochemical evidences

The Malari Leucogranite in the Garhwal Himalaya is cut across by a continental-scale normal fault system called the South Tibetan Detachment (STD). A mineralogical, geochemical and fluid inclusion study of samples from the fault zone of the Malari Granite was performed to reveal the imprints of fluid–rock interaction. Fluid inclusion assemblages observed in the alteration zone indicate the presence of NaCl-dominated aqueous fluids with varied salinity of 6–16 wt.% of NaCl equivalent. Mineralogical changes include the alteration of feldspar to muscovite and muscovite to chlorite. This alteration took place at temperatures of 275°–335°C and pressures between 1.9 and 4.2 kbars as revealed by the application of chlorite thermometry, fluid isochores, and presence of K-feldspar+muscovite+chlorite+quartz mineral assemblage. Geochemical mass-balance estimates predict 32% volume loss during alteration. An estimated fluid/rock ratio of 82 is based on loss of silica during alteration, and reveals presence of a moderately low amount of fluid at the time of faulting.     

The Hell Creek Formation and its contribution to the Cretaceous–Paleogene extinction: A short primer

Although it represents but one geographic data point, the uppermost Maastrichtian Hell Creek Formation (HCF), exposed in the upper Great Plains of the North American craton, remains the most studied source for understanding the final ∼1.5 Myr of the Mesozoic Era in the terrestrial realm. Because it lies conformably below the earliest Paleocene Fort Union Formation, and together these two units preserve a rich fauna and flora, much of what is understood about the terrestrial Cretaceous–Paleogene (K–Pg) boundary comes from this sequence.The HCF has been reconstructed as an expansive, fluvially drained, low coastal plain, built out, to the west, against the Laramide Orogen, and to the east, against the ultimate transgression (Cannonball) of the Western Interior Sea. Its meandering rivers and moist soils supported a multi-tiered angiosperm-dominated flora and rich insect and vertebrate faunas, including dinosaurs, crocodilians, squamates, turtles, and mammals. A dramatic facies change representing the initiation of catastrophic flooding is preserved, within available levels precision, at the K–Pg boundary.High-precision stratigraphy has proven difficult in this lenticular fluvial system. Where present, the boundary can be recognized by the bipartite boundary claystone; otherwise, palynostratigraphy has proven a powerful tool. Numerical dates have been successfully obtained from in tonsteins at the boundary and above, in the Fort Union; however, these have proven elusive below the boundary within the HCF. The K–Pg boundary in this region is dated at 66.043 Ma (Renne et al., 2013). Magnetostratigraphic studies have been carried out in the HCF; although all but one have lacked numerical dates, these have been used for correlations of widespread, disjunct exposures and for the estimation of sedimentation rates.The palynoflora is largely homogenous through the HCF; at the K–Pg boundary, it shows an abrupt ∼30% extinction. This makes it a powerful tool for identification of the K–Pg boundary, although because the boundary is identified on absence of Cretaceous taxa rather than presence of earliest Paleocene taxa, several competing methods have been applied to identifying the K–Pg boundary using pollen.The macroflora, consisting largely of leaves, consists of three successive floras, showing increasing diversity through the HCF. The ultimate of these three floras undergoes an abrupt 57% extinction; taken as a whole, however, the macroflora undergoes a 78% extinction at the K–Pg boundary.The best data available for dinosaurs – including archaic Aves – show an abrupt extinction. By contrast, salamanders and other lissamphibians, as well as chelonians, cross the boundary virtually without perturbation. Squamates appear to have suffered significant extinctions at the K–Pg boundary, as did euselachians (elasmobranchs) and insects. Mammals suffered a 75% extinction; however, some of this figure cannot be shown to have occurred in less than the last 500 kyr of the Cretaceous, and thus has been potentially attributable to causes other than a bolide impact. Taken together, the survivorship patterns are concordant with the catastrophic inception of ubiquitous flooding characterizing the K–Pg boundary.While the key K–Pg boundary question in the HCF was once the rate of the biotic extinction, it has moved to the distinction between single-cause scenarios, with the Chicxulub bolide as agent of extinction, and multi-cause scenarios, uniting habitat partitioning, Deccan flood-basalt volcanism, climate change, competition, and bolide impact. Not every potential environmental perturbation need be a mechanism for the extinction: parsimony and the data continue to be concordant with a bolide impact as the single agent of the terrestrial K–Pg mass extinction.     

Mineralogical and geochemical spatial analyses of a waste-rock dump at the Libiola Fe–Cu sulphide mine (Eastern Liguria,Italy)

In this work, we investigated a 3 ha sulphide-bearing waste-rock dump (Libiola Mine, Italy) using mineralogical, geochemical, and geostatistical analyses. The dumped materials were highly heterogeneous in grain size and lithology and varied both laterally and vertically. Other than the host rock of the ore, basalts and serpentinites, the dumped materials contained high amounts of low-grade chalcopyrite- and pyrite-rich mineralisations. Due to these characteristics and to the absence of minerals able to neutralise acidity, this waste-rock dump can be classified as an acid mine drainage (AMD) producer. The study confirms that AMD is still active and, in the best scenario, can persist for up to 6.17 × 10³ years. The consequences of this process are of serious environmental concern as it involves strong acidification of the circulating waters, the release of potentially toxic metals into the soil, streams and rivers and the precipitation of huge quantities of secondary Fe-oxides and Fe-oxyhydroxides.     

The Cretaceous–Paleogene unconformity in England: Uplift and erosion related to the Iceland mantle plume

During the late Cretaceous to early Paleogene, the present-day area of Britain and Ireland emerged from nearly total submergence by the chalk sea. What mechanism was responsible for this major marine regression? Combined studies of Paleogene depositional sequences offshore and coeval igneous rocks onshore, show that significant episodic uplift of northern Britain was at that time largely controlled by the early development of the Iceland mantle plume. How far south did this influence of the Iceland plume extend across England, and even beyond? We present new maps of the structure and denudation of the chalk surface in southern England. Some 500 m thickness of chalk was removed from the crest of a Chilterns–East Anglia dome before deposition of the earliest Paleogene sediments. Allowing for isostatic amplification by erosion, minimum uplift of the chalk surface above sea level was c.125 m. Early Paleogene crustal shortening of that chalk surface was by a factor of at most 1.01, contributing a maximum uplift of 25 m of the floor of the chalk sea. Compressional forces were not the main cause of the Cretaceous–Paleogene unconformity in southern England, as in the interpretation of this event as a distant reflection of the development of the Alps to the south. Postulated contemporary changes in global sea-level are also inadequate to account for the development of the unconformity in southern England. Here we suggest with some confidence that the main vertical surface movements involved in creating the unconformity were controlled by the Iceland mantle plume, as in northern Britain. We speculate that another hotspot, in Central France, may have influenced Paleogene sedimentation in the Paris Basin in a comparable fashion. We consider how to distinguish between our proposed mantle control of regional relative sea-level and global controls of Paleogene sea level.     

Cretaceous–Paleogene Boundary in the Sequences of the Northeastern Caucasus,Dagestan: Sedimentology,Geochemistry, and Biota

Lithology and Mineral Resources - The results of integrated study of the Cretaceous/Paleogene transition in the northeastern Caucasus are reported. The lithological, geochemical and...     

Late Maastrichtian cephalopods,dinoflagellate cysts and foraminifera from the Cretaceous–Paleogene succession at Lechówka,southeast Poland: Stratigraphic and environmental implications

The Lechówka section comprises the most complete Cretaceous–Paleogene (K-Pg) boundary succession in Poland and is among 29 sites worldwide with the youngest ammonite record. Here, cephalopods (ammonites and nautilids), organic-walled dinoflagellates (dinocysts) and foraminifera from the uppermost Maastrichtian interval are studied. In terms of ammonite biostratigraphy, the upper Maastrichtian Hoploscaphites constrictus crassus Zone is documented up to a level 120 cm below the K-Pg boundary. There is no direct, ammonite-based evidence of the highest Maastrichtian H. constrictus johnjagti Zone. However, the predominance of the dinocyst marker taxon Palynodinium grallator suggests the presence of the equivalent of the uppermost Maastrichtian Thalassiphora pelagica Subzone, which is correlatable with the H. c. johnjagti ammonite Zone. The planktonic foraminiferal assemblage is coeval with that from the H. c. johnjagti Zone as well. These data indicate that the top of the Maastrichtian at Lechówka is complete within the limits of biostratigraphic resolution, albeit slightly condensed. The dinocyst and foraminiferal assemblages are dominated by taxa that are characteristic of high-energy, marginal marine environments. A reduction in test size among the calcareous epifaunal benthic foraminifera is observed at a level 50 cm below the K-Pg boundary, which is possibly related to environmental stress associated with Deccan volcanism.     

Studying travertines for neotectonics investigations: Middle–Late Pleistocene syn-tectonic travertine deposition at Serre di Rapolano (Northern Apennines, Italy)

Middle–Late Pleistocene tectonic activity has been inferred through studies on travertine deposits exposed in a tract of the hinterland Northern Apennines. A detailed study on the relationships between tectonics and travertine deposition coupled with ²³⁰Th/²³⁴U age determination of travertines at Cava Oliviera quarry, located close to Serre di Rapolano village (southern Tuscany, Northern Apennines), allowed us to recognise Pleistocene faults, whose activity has been referred to 157–24 ka, at least. Travertine deposition was tectonically controlled by WSW-ENE striking, oblique and normal faults, associated to a main fault (named as the Violante Fault). This structure dissected a regional normal fault (known as the Rapolano Fault) Early–Middle Pliocene in age, which bounded the eastern side of the Pliocene Siena Basin, and gave rise to space accommodation for clayey and sandy marine sediments. Hydrothermal circulation (and related travertine deposition) was favoured by the damaging enhancement due to the fault–fault intersection. Tectonic activity has been also documented by deformation recorded by travertines, which suggest a main tectonic event between 64 ± 5 and 40 ± 5 ka. The tectonic activity described for the study area agrees with the Quaternary tectonic evolution documented in the surrounding areas (e.g. Mt. Amiata and Mt. Vulsini), as well as the Tyrrhenian margin of the Central Apennines, indicating that a widespread tectonic activity affected the inner part of the Apennines until the latest Quaternary.     

Cretaceous sedimentary–volcanogenic complexes of the Kamchatka Isthmus: Structure,composition and geodynamic formation conditions

New data on the chemical and rare-element composition and age of the rocks referred earlier to the Iruney suite of the Kamchatka Isthmus are received. In the recent structure these rocks compose the structural–strata complexes of the nappe-folded Lesnovsky Rise. Radiolarian analysis data substantiate that the deposits belonging to the Ening series and the middle and upper parts of the Iruney suite were formed in a single sedimentation basin in the Campanian time. The discovery of a new occurrence of Prunobrachidae representatives on the Kamchatka Peninsula allows us to draw wide interregional correlations and reconstruct the sedimentation conditions. The studied volcanites relate to different igneous series and were formed in geodynamic conditions of the marginal sea and the volcanic arc. The igneous rocks of the Ening stratum are similar to the N-MOR and OI basalts that were formed within the marginal sea (Iruney Marginal Sea) basin. The Upper Cretaceous formations of the eastern slope of the Sredinny Range were formed within the volcanic rise with the island-arc type of volcanism. The younger Eocene igneous rocks of the neo-autochthon (granites and granodiorites) and the volcanic rocks of the Kinkil suite mark a new orogenic stage of development of the Kamchatka margin.     

Soil slip susceptibility assessment using mechanical–hydrological approach and GIS techniques: an application in the Apuan Alps (Italy)

This study aims at contributing to the soil slip susceptibility assessment in a typical basin of the southern Apuan Alps, Italy. On June 1996, this basin (Cardoso Torrent, 13 km² large) was hit by an extremely heavy rainstorm (maximum intensity of about 160 mm/h), which caused many landslides (debris slide–debris flows) and valley bottom flows (hyperconcentrated flows), destruction and deaths. Detailed surveys provided the characterization of the main factors (geological, geomorphologic, hydrological, hydrogeological and geotechnical) which contributed in triggering landslides. In order to evaluate the soil slip susceptibility in this area, a physically based model was applied and a GIS analysis of digital elevation model was performed. This approach couples a mechanical model based on an infinite slope form of the Mohr–Coulomb failure criterion, and a steady-state hydrological one (a modified version of Shalstab, which considers the cohesion of the debris material potentially involved in landsliding). GIS techniques allowed evaluating the effects of topographic convergence and drainage area on slope failure. In this way, based on the infiltration rate, the triggering of the June 1996 landslides was simulated and the critical rainfall thresholds assessed at about 200–250 mm/24 h.     

Neoselachians and Chimaeriformes (Chondrichthyes) from the latest Cretaceous–Paleogene of Sierra Baguales,southernmost Chile. Chronostratigraphic,paleobiogeographic and paleoenvironmental implications

This paper discusses a well-represented fossil record of cartilaginous fishes (Chondrichthyes) from southern South America. The recovered samples allow the recognition of three assemblages with chronostratigraphic and paleogeographic value: i) typical Maastrichtian sharks and rays with affinities to eastern Pacific fauna, including the taxa Ischyrhiza chilensis, Serratolamna serrata, Centrophoroides sp. associated to Carcharias sp., and Dasyatidae indet.; ii) a scarce reworked assemblage of Paleocene–Early Eocene age including the taxa Otodus obliquus and Megascyliorhinus cooperi; iii) a rich assemblage with reworked taxa of Early to Middle Eocene age, together with autochthonous deposited Middle to Late Eocene taxa with close affinities to paleoichthyofaunas recovered from the North Atlantic, represented by Carcharias ‘hopei’, Odontaspis winkleri, Carcharoides catticus, Macrorhizodus praecursor, Carcharocles auriculatus, Striatolamia sp., Striatolamia macrota, Hexanchus agassizi, Notorhynchus sp., Myliobatis sp., Abdounia sp., Pristiophorus sp., Squatina sp., cf. Rhizoprionodon sp., Ischyodus sp., and one new species, Jaekelotodus bagualensis sp. nov. The studied samples include for the first time taxa with well established chronostratigraphic resolutions as well as taphonomic information that help clarifying the age of the fossil-bearing units. In addition, they provide relevant information about the evolution of the Magallanes (=Austral) Basin from the Upper Cretaceous to the Paleogene, suggesting a probable connection with the Quiriquina Basin of south-central Chile during the latest Cretaceous. Finally, the studied assemblages indicate a latitudinal pattern of distribution that provides valuable data on the environmental evolution and temperature of southern South America during the Paleogene.     

Stratigraphy,palaeoenvironments and geochemistry across the Triassic–Jurassic boundary transition at Carnduff,County Antrim,Northern Ireland

The latest Triassic to earliest Jurassic transition has been widely studied due the occurrence of a major global extinction associated with a global hyperthermal event in this interval. Furthermore, a number of distinct geochemical events in the global carbon cycle can be recognised in the stable-isotope record across this boundary interval at many localities. Two fully-cored boreholes from East Antrim in Northern Ireland (Carnduff-1 and Carnduff-2) have penetrated sediments of latest Triassic to Early Jurassic age (Rhaetian to Early Sinemurian). Ammonites, foraminifera, ostracods and palynomorphs provide a robust chronology as well as insights to palaeoenvironmental conditions during this period. The sedimentary and palynological evidence support a largely marginal-marine setting for the sediments of the Triassic Penarth Group while a range of palaeontological evidence shows that the Early Jurassic Waterloo Mudstone Formation represents shallow-marine, shelf conditions that represent generally well-oxygenated bottom waters, with little evidence for dysoxia. Detailed ammonite biostratigraphy (ammonites first occur about 7.5 m up from the base of the Lias Group) indicates that the cores represent largely continuous sedimentation through the Hettangian and earliest Sinemurian (to Turneri Chronozone, Birchi Subchronozone). Stable-isotope analysis of both carbonate and organic carbon show a distinct carbon isotope excursion (CIE) in both fractions through the Cotham and Langport members (Lilstock Formation, Penarth Group, latest Triassic) which are considered to correlate with the distinctive ‘Initial’ CIE witnessed in SW England and probably the GSSP and other sites across the world.     

Retrogressive fabric development during exhumation of the Voltri Massif (Ligurian Alps,Italy): arguments for an extensional origin and implications for the Alps–Apennines linkage

Geological mapping coupled with structural investigations carried out in the Voltri Massif (eastern Ligurian Alps, Italy) provide new data for the interpretation of the tectonic context controlling main fabric development during exhumation of its high-pressure core. The Voltri Massif is here interpreted as a c. 30 km-long eclogite-bearing, asymmetric dome formed by the progressive verticalisation of the regional, second-phase mylonitic foliation developed during retrogressive greenschist metamorphic conditions. In this light, the exhumation history is driven by a ductile-to-brittle extensional process, operating through low-angle, top-to-the-W multiple detachment systems. A Late Eocene–Early Oligocene age for this extensional episode is proposed on the basis of structural correlations, stratigraphic and radiometric constraints. In this scenario, the Voltri Massif is interpreted as an extensional domain developed to accommodate the Late Eocene–Early Oligocene arching of the Western Alps–Northern Apennines orogenic system.     

Rn and CO2 soil–gas geochemical characterization of thermally altered clays at Orciatico (Tuscany,Central Italy)

The physical properties of clay allow argillaceous formations to be considered geological barriers to radionuclide migration in high-level radioactive-waste isolation systems. As laboratory simulations are short term and numerical models always involve assumptions and simplifications of the natural system, natural analogues are extremely attractive surrogates for the study of long-term isolation. The clays of the Orciatico area (Tuscany, Central Italy), which were thermally altered via the intrusion of an alkali-trachyte laccolith, represent an interesting natural model of a heat source which acted on argillaceous materials. The study of this natural analogue was performed through detailed geoelectrical and soil–gas surveys to define both the geometry of the intrusive body and the gas permeability of a clay unit characterized by different degrees of thermal alteration. The results of this study show that gas permeability is increased in the clay sequences subjected to greater heat input from the emplacement of the Orciatico intrusion, despite the lack of apparent mineral and geotechnical variations. These results, which take into consideration long time periods in a natural, large-scale geological system, may have important implications for the long-term safety of underground storage of nuclear waste in clay formations.     

An interdisciplinary approach to the collapse of the port and degradation of freshwater resources at Panama Viejo (Panama), 1519–1671

The Archaeological Site of Panama Viejo (Panama) comprises a protected area of 28 km² within present-day Panama City, on America's Pacific coast. In 1519, the Spaniards founded the city of Panama Viejo to secure a natural port in an area inhabited by indigenous peoples since at least the eighth century CE. The site, along the coastline and between two rivers, became a principal gateway for goods and people travelling between Europe and Pacific settlements to the east (Realejo) and the west (Trujillo, Lima, Arica). Within one century, however, Panama Viejo's natural port and freshwater infrastructure collapsed, leading to the city's relocation after corsairs attacked it in 1671. This study combines archaeological, geographical and historical analyses to explain how and why human interactions with the local environment made the settlement increasingly untenable.     

Combining textural and geochemical investigations to explore the dynamics of magma ascent during Plinian eruptions: a Somma–Vesuvius volcano (Italy) case study

Trigger mechanisms and syn-eruptive processes of Plinian eruptions are poorly understood especially in the case of mafic powerful events. In the last decades, the combined geochemical and textural studies on volcanic rocks have proven to be fundamental tools for exploring the dynamics of magma ascent in volcanic conduits and for improving our ability to interpret volcano-monitoring signals and assess hazard. In this case study, we quantitatively investigate 2D and 3D micro-textural, geochemical, and isotopic features of pyroclastic rocks erupted during the Pomici di Base Plinian eruption (22 ka), the generally acknowledged first and most powerful event of the Somma–Vesuvius volcano. A peculiar aspect of this eruption is its high intensity that remained stable during the entire Plinian phase despite the strong magma compositional variation towards mafic terms. We infer that the transfer of magma towards the surface was intensified by the occurrence of rapid vesiculation pulses driven by limestone assimilation (skarn recycling) during magma ascent through the carbonatic bedrock. We conclude that limestone assimilation can hence be a syn-eruptive process, able to trigger further gas nucleation with deep impact on the eruption intensity, particularly crucial in the case of mafic/intermediate magma compositions.