Magma sources and petrogenesis of the early–middle Paleozoic backarc granitoids from the central part of the Qilian block,NW China

The petrology, geochemistry, geochronology, and Sr–Nd–Hf isotopes of the backarc granitoids from the central part of the Qilian block are studied in the present work. Both S- and I-type granitoids are present. In petrographic classification, they are granite, alkali feldspar granite, felsic granite, diorite, quartz diorite, granodiorite, and albite syenite. The SHRIMP ages are 402–447 Ma for the S-type and 419–451 Ma for the I-type granitoids. They are mostly high-K calc-alkaline granitoids. The S-type granitoids are weakly to strongly peraluminous and are characterized by negative Eu anomalies (Eu/Eu* = 0.18–0.79). The I-type granitoids are metaluminous to weakly peraluminous and are characterized mostly by small negative to small positive Eu anomalies (Eu/Eu* = 0.71–1.16). The initial (⁸⁷Sr/⁸⁶Sr) values are 0.708848–0.713651 for the S-type and 0.704230–0.718108 for the I-type granitoids. The ε_Nd(450 Ma) values are − 8.9–−4.1 and − 9.7–+ 1.9 for the S-type and I-type granitoids, respectively. The T_DM values are 1.5–2.4 Ga for the S-type and 1.0–2.3 Ga for the I-type granitoids. For the Qilian block, the backarc granitoid magmatism took place approximately 60 million years after the onset of the southward subduction of the north Qilian oceanic lithosphere and lasted approximately 50 million years. Partial melting of the source rocks consisting of the Neoproterozoic metasedimentary rocks of the Huangyuan Group and the intruding lower Paleozoic basaltic rocks could produce the S-type granitoid magmas. Partial melting of basaltic rocks mixed with lower continental crustal materials could produce the I-type granitoid magmas. Major crustal growth occurred in the late Archean and Meso-Paleoproterozoic time for the Qilian block. The magma generation was primarily remelting of the crustal rocks with only little addition of the mantle materials after 1.0 Ga for the Qilian block.     

Postcollisional magmatism: Geochemical constraints on the petrogenesis of Mesozoic granitoids in the Sulu orogen,China

A combined study of zircon U–Pb ages and Lu–Hf isotopes, mineral O isotopes, whole-rock elements and Sr–Nd isotopes was carried out for Mesozoic granitoids from the Shandong Peninsula in east-central China, which tectonically corresponds to the eastern part of the Sulu orogen that formed by the Triassic continental collision between the South and North China Blocks. Four plutons were investigated in this region, with the Linglong and Guojialing plutons from the northwestern part (Jiaobei) and the Kunyushan and Sanfoshan plutons from the southeastern part (Jiaodong). The results show that these granitoids mostly have high Sr, low Yb and Y contents, high (La/Yb)_N and Sr/Y ratios with negligible to positive Eu anomalies (Eu/Eu* = 0.69–1.58), which are similar to common adakites. On the other hand, they have relatively low MgO, Cr, Ni contents and thus low Mg#. Zircon U–Pb dating yields Late Jurassic ages of 141 ± 3 to 157 ± 2 Ma for the Linglong and Kunyushan plutons, but Early Cretaceous ages of 111 ± 2 to 133 ± 3 Ma for the Guojialing and Sanfoshan plutons. Some zircon cores from the Linglong and Kunyushan granitoids have Neoproterozoic U–Pb ages. All the granitoids have variably negative zircon ε_Hf(t) values of ?39.6 to ?5.4, with Mesoproterozoic to Paleoproterozoic Hf model ages of 1515 ± 66 to 2511 ± 97 Ma for the Sanfoshan pluton, but Paleoproterozoic to Paleoarchean Hf model ages of 2125 ± 124 to 3310 ± 96 Ma for the other three plutons. These indicate that the Mesozoic granitoids formed in the postcollisional stage and were derived mainly from partial melting of the subducted South China Block that is characterized by Paleoproterozoic juvenile crust and Neoproterozoic magmatic rocks along its northern edge. However, there are some differences between the Jiaobei and Jiaodong plutons. Compared to the Jiaodong granitoids, the Jiaobei granitoids have very old zircon Hf model ages of 3310 ± 96 Ma suggesting the possible involvement of a Paleoarchean crust that may be derived from the North China Block. Therefore, the continental collision between the two blocks would bring crustal materials from both sides into the subduction zone in the Triassic, yielding subduction-thickened crust as the magma source for the adakite-like granitoids. While lithospheric extension and orogenic collapse are considered a major cause for postcollisional magmatism, anatexis of the subducted mafic crust is proposed as a mechanism for chemical differentiation of the continental crust towards felsic composition.     

南祁连党河南山花岗岩类特征及其构造环境

党河南山地区地处南祁连重要成矿带,区内花岗岩类岩体包括扎子沟岩体、鸡叫沟岩体及贾公台岩体,伴有不同程度的金、铜矿化。扎子沟岩体主要由花岗闪长岩组成,侵位于震旦纪火山岩系。鸡叫沟岩体主要由石英二长闪长岩组成,贾公台岩体主要由斜长花岗岩组成,两者侵位于奥陶纪碎屑岩系。3个岩体Rb-Sr等时线年龄分别为(510.85±14)Ma、(395.06±51)Ma及(355±91)Ma,前者对应于早-中寒武世,后二者对应于志留纪-泥盆纪。3个岩体均属于钙碱性花岗岩系列,其中扎子沟岩体属于该系列的中钾花岗闪长岩系列,鸡叫沟岩体属于高钾二长岩系列,贾公台岩体属于低钾奥长花岗岩系列。综合岩相学、岩石化学及微量元素和稀土元素的地球化学特征,区内3个岩体均形成于I型活动陆缘环境,为中南祁连造山带加里东期构造岩浆活动的产物。     

Geochemistry of the Bafoussam Pan-African I- and S-type granitoids in western Cameroon

The Bafoussam area in western Cameroon is part of the Central African Orogenic Belt. It is dominated by granitoids which belong to the Pan-African syn- to post-collisional post-650 Ma group. Syenogranites are predominant, but alkali-feldspar granite, monzogranite, quartz-monzonite and quartz-monzodiorite occur as well. Four granitoid suites, biotite granitoids and deformed biotite granitoids with amphibole, megafeldspar granitoids with megacrysts and two-mica granitoids with primary muscovite and igneous garnet are distinguished. The granites can be assigned to high-K calc-alkalic to shoshonitic series. The partly shoshonitic biotite granitoids are metaluminous to weakly peraluminous and can be labelled as a highly fractionated I-type suite. The megafeldspar granitoids are weakly peraluminous with I-type character whereas the two-mica granitoids are weakly to strongly peraluminous and belong to an S-type suite. Emplacement ages at 558–564 Ma for the two-mica granitoids have been dated from monazite by the EMP Th–U–Pb method.The REE in the biotite granitoids are moderately fractionated with (La/Lu)_N = 23–38. Enrichment of Nb and Ta varies by one order of magnitude. The megafeldspar granitoids show homogeneous and strongly fractionated REE patterns with (La/Lu)_N = 27–42. The primitive mantle-normalized element patterns are homogeneous with marked negative Ba, Nb, Ta, Sr, Eu and Ti anomalies. The two-mica granitoids are characterized by low to moderate total REE contents with strongly fractionated REE expressed by (La/Lu)_N ranging from 7 to 59. The negative Nb and Ta anomalies are less significant. Nd and Sr whole-rock isotope data confirm different sources for the granitoid suites. The source of the I-type biotite granitoids was probably a juvenile mantle which has been variably metasomatized. The source of the I-type megafeldspar granitoids is characterized by juvenile mantle and lower crust components. Anatectic melts of the upper continental crust with variable contribution of lower continental crust or mantle melts can explain the heterogeneous isotopic signatures of the S-type two-mica granitoids. It is suggested that the melting of these sources was successively initiated by the rising isotherms during a syn- to post-collisional setting which followed a subduction.     

南祁连党河南山花岗岩类地球化学及其金铜矿化

南祁连党河南山地区地处南祁连重要成矿带,金铜矿化广布,该矿化与中酸性花岗岩类关系密切.为揭示区域成矿地质背景,查明大地构造的时空演化,并深入研究该地区金铜矿化的成矿规律与控矿因素,对区内主要花岗岩体及其金铜矿化进行了系统的地质地球化学研究.研究表明,区内花岗岩类岩体包括扎子沟岩体、鸡叫沟岩体及贾公台岩体.综合岩相学、岩石化学及微量稀土元素地球化学特征,区内3个岩体均形成于I型活动陆缘环境,为中南祁连造山带加里东期构造岩浆活动的产物.扎子沟岩体与该区金铜矿化不构成物源关系,但其岩浆期后热水溶液可造成火山岩系金、铜组分活化迁移,并在有利构造场所富集成矿,鸡叫沟岩体和贾公台岩体分别是黑刺沟金矿和贾公台金矿的控矿母岩.     

Shrimp U–Pb zircon geochronology,geochemistry, and Nd–Sr isotopic study of contrasting granites in the Emeishan large igneous province,SW China

The Cida A-type granitic stock (∼ 4 km²) and Ailanghe I-type granite batholith (∼ 100 km²) in the Pan-Xi (Panzhihua-Xichang) area, SW China, are two important examples of granites formed during an episode of magmatism associated with the Permian Emeishan mantle plume activity. This is a classic setting of plume-related, anorogenic magmatism exhibiting the typical association of mantle-derived mafic and alkaline rocks along with silicic units. SHRIMP zircon U–Pb data reveal that the Cida granitic pluton (261 ± 4 Ma) was emplaced shortly before the Ailanghe granites (251 ± 6 Ma). The Cida granitoids display mineralogical and geochemical characteristics of A-type granites including high FeO^⁎/MgO ratios, elevated high-field-strength elements (HFSE) contents and high Ga/Al ratios, which are much higher than those of the Ailanghe granites. All the granitic rocks show significant negative Eu anomalies and demonstrate the characteristic negative anomalies in Ba, Sr, and Ti in the spidergrams. It can be concluded that the Cida granitic rocks are highly fractionated A-type granitoids whereas the Ailanghe granitic rocks belong to highly evolved I-type granites.The Cida granitoids and enclaves have Nd and Sr isotopic initial ratios (ε_Nd(t) = − 0.25 to + 1.35 and (⁸⁷Sr/⁸⁶Sr)_i = 0.7023 to 0.7053) close to those of the associated mafic intrusions and Emeishan basalts, indicating the involvement of a major mantle plume component. The Ailanghe granites exhibit prominent negative Nb and Ta anomalies and weakly positive Pb anomalies in the spidergram and have nonradiogenic ε_Nd(t) ratios (− 6.34 to − 6.26) and high (⁸⁷Sr/⁸⁶Sr)_i values (0.7102 to 0.7111), which indicate a significant contribution from crustal material. These observations combined with geochemical modeling suggest that the Cida A-type granitoids were produced by extensive fractional crystallization from basaltic parental magmas. In contrast, the Ailanghe I-type granites most probably originated by partial melting of the mid-upper crustal, metasedimentary–metavolcanic rocks from the Paleo-Mesoproterozoic Huili group and newly underplated basaltic rocks.In the present study, it is proposed that petrogenetic distinctions between A-type and I-type granites may not be as clear-cut as previously supposed, and that many compositional and genetically different granites of the A- and I-types can be produced in the plume-related setting. Their ultimate nature depends more importantly on the type and proportion of mantle and crustal material involved and melting conditions. Significant melt production and possible underplating and/or intrusion into the lower crust, may play an important role in generating the juvenile mafic lower crust (average 20 km) in the central part of the Emeishan mantle plume.     

中国南天山晚石炭世—早二叠世花岗质侵入岩的岩石成因与地壳增生

晚石炭世—早二叠世在中亚南天山造山带形成了大量的花岗质侵入岩.中国境内这些岩体以晚石炭世Ⅰ型花岗岩、早二叠世Ⅰ型和S型花岗岩以及最晚期的A型花岗岩为代表.不同类型的岩石在源区特征和岩浆形成的温压条件上存在一定的差异,而这些差异性反映了该时期内构造环境的演化过程.本文选取铁列克岩体、盲起苏岩体、英买来岩体、川乌鲁杂岩体、...     

Zircon U–Pb ages and Sr–Nd isotope ratios for the Sirstan granitoid body,NE Iraq: Evidence of magmatic activity in the Middle Cretaceous Period

The Sirstan granitoid (SG), comprising diorite and granodiorite, is located in the Shalair Valley area, in the northeastern part of Iraq within the Sanandaj–Sirjan Zone (SSZ) of the Zagros Orogenic Belt. The U–Pb zircon dating of the SG rocks has revealed a concordia age of 110 Ma, which is interpreted as the age of crystallization of this granitoid body during the Middle Cretaceous. The whole-rock Rb–Sr isochron data shows an age of 52.4 ± 9.4 Ma (MSWD = 1.7), which implies the reactivation of the granitoid body in the Early Eocene due to the collision between the Arabian and Iranian plates. These rocks show metaluminous affinity with low values of Nb, Ta and Ti compared to chondrite, suggesting the generation of these rocks over the subduction zone in an active continental margin regime. The SG rocks are hornblende-bearing I-type granitoids with microgranular mafic enclaves. The positive values of ?_Nd (t = 110 Ma) (+0.1 to +2.7) and the low (⁸⁷Sr/⁸⁶Sr)_i ratios (0.7044 to 0.7057) indicate that the magma source of the SG granitoids is a depleted subcontinental mantle. The chemical and isotope compositions show that the SG body originated from the metasomatic mantle without a major role for continental contamination. Our findings show that the granitoid bodies distributed in the SSZ were derived from the continuous Neo-Tethys subduction beneath the SSZ in Mesozoic times and that the SSZ was an active margin in the Middle Cretaceous.     

Petrogenesis of Lingshan highly fractionated granites in the Southeast China: Implication for Nb-Ta mineralization

Whole rock major and trace element and Sr-, Nd- and Hf-isotope data, together with zircon U-Pb, Hf- and O-isotope data, are reported for the Nb-Ta ore bearing granites from the Lingshan pluton in the Southeastern China, in order to trace their petrogenesis and related Nb-Ta mineralization. The Lingshan pluton contains hornblende-bearing biotite granite in the core and biotite granite, albite granite and pegmatite at the rim. In addition, numerous mafic microgranular enclaves occur in the Lingshan granites. Zircon SIMS U-Pb dating gives consistent crystallization ages of ca. 132 Ma for the Lingshan granitoids and enclaves, consistent with the Nb-Ta mineralization age of ∼132 Ma, indicating that mafic and felsic magmatism and Nb-Ta mineralization are coeval. The biotite granites contain hornblende, and are metaluminous to weakly peraluminous, with high initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7071–0.7219, negative ε_Nd(t) value of −5.9 to −0.3, ε_Hf(t) values of −3.63 to −0.32 for whole rocks, high δ¹⁸O values and negative ε_Hf(t) values for zircons, and ancient Hf and Nd model ages of 1.41–0.95 Ga and 1.23–1.04 Ga, indicating that they are I-type granites and were derived from partial melting of ancient lower crustal materials. They have variable mineral components and geochemical features, corresponding extensive fractionation of hornblende, biotite and feldspar, with minor fractionation of apatite. Existence of mafic microgranular enclaves in the biotite granites suggests a magma mixing/mingling process for the origin of the Lingshan granitoids, and mantle-derived mafic magmas provided the heat for felsic magma generation. In contrast, the Nb-Ta mineralized albite granites and pegmatites have distinct mineral components and geochemical features, which show that they are highly-fractionated granites with extensive melt and F-rich fluid interaction in the generation of these rocks. The fluoride-rich fluids induce the enrichment in Nb and Ta in the highly evolved melts. Therefore, we conclude that the Nb-Ta mineralization is the result of hydrothermal process rather than crystal fractionation in the Lingshan pluton, which provides a case to identify magmatic and hydrothermal processes and evaluate their relative importance as ore-forming processes.     

Crustally-derived granites in the Panzhihua region,SW China: Implications for felsic magmatism in the Emeishan large igneous province

In the Panxi region of the Late Permian (~ 260 Ma) Emeishan large igneous province (ELIP) there is a bimodal assemblage of mafic and felsic plutonic rocks. Most Emeishan granitic rocks were derived by differentiation of basaltic magmas (i.e. mantle-derived) or by mixing between crustal melts and primary basaltic magmas (i.e. hybrid). The Yingpanliangzi granitic pluton within the city of Panzhihua intrudes Sinian (~ 600 Ma) marbles and is unlike the mantle-derived or hybrid granitic rocks. The SHRIMP zircon U–Pb ages of the Yingpanliangzi pluton range from 259 ± 8 Ma to 882 ± 22 Ma. Younger ages are found on the zircon rims whereas older ages are found within the cores. Field relationships and petrography indicate that the Yingpanliangzi pluton must be < 600 Ma, therefore the older zircons are interpreted to represent the protolith age whereas the younger analyses represent zircon re-crystallization during emplacement. The Yingpanliangzi granites are metaluminous and have negative Ta–Nb_PM anomalies, low εNd_{(260 Ma)} values (? 3.9 to ? 4.4), and high I_Sr (0.71074 to 0.71507) consistent with a crustal origin. The recognition of a crustally-derived pluton along with mantle-derived and mantle–crust hybrid plutons within the Panxi region of the ELIP is evidence for a complete spectrum of sources. As a consequence, the types of Panxi granitoids can be distinguished according to their ASI, Eu/Eu*, εNd_(T), εHf_(T), T_Zr(°C) and Nb–Ta_PM values. The diverse granitic magmatism during the evolution of the ELIP from ~ 260 Ma to ~ 252 Ma demonstrates the complexity of crustal growth associated with LIPs.     

Petrological and geochemical characteristics of Zhaibei granites in Nanling region,Southeast China: Implications for REE mineralization

Mineralization with ion adsorption rare earth elements (REEs) in the weathering profile of granitoid rocks from Nanling region of Southeast China is an important REE resource, especially for heavy REE (HREE) and Y. However, the Jurassic granites in Zhaibei which host the ion adsorption light REE (LREE) ores are rare. It is of peraluminous and high K calc-alkaline composition, which has similar geochemical features of high K₂O + Na₂O and Zr + Nb + Ce + Y contents and Ga/Al ratio to A-type granite. Based on the chemical discrimination criteria of Eby [Geology 20 (1992) 641], the Zhaibei granite belongs to A1-type and has similar source to ocean island basalts. The rock is enriched in LREE and contains abundant REE minerals including LREE-phosphates and halides. Minor LREE was also determined in the feldspar and biotite, which shows negligible and negative Eu anomalies, respectively. This indicates that the Zhaibei granite was generated by extreme differentiation of basaltic parent magmas. In contrast, granites associated with ion adsorption HREE ores contain amounts of HREE minerals, and show similar geochemical characteristics with fractionated felsic granites. Note that most Jurassic granitoids in the Nanling region contain no REE minerals and cannot produce REE mineralization. They belong to unfractionated M-, I- and S-type granites. Therefore, accumulation of REE in the weathering profile is controlled by primary REE mineral compositions in the granitoids. Intense fractional crystallization plays a role on REE enrichment in the Nanling granitoid rocks.     

南秦岭勉略带北光头山花岗岩体群的成因及其构造意义

南秦岭勉略带北部花岗岩体从闪长岩到花岗闪长岩和花岗岩变化,反映了钙碱性岩岩石组合特征,矿物组成以长石、石英、黑云母和少量角闪石为主,副矿物有锆石、磷灰石、磁铁矿和榍石,岩石化学上它们相对高K、Sr,Zr／Y比值较高,富集LEE和LILE,贫化HFSE,与后碰撞富钾钙碱性I型花岗岩特征一致。此外,它们明显亏损Nb、Ta,低Y、Yb和有较高的 LaN／YbN和Sr／Y比值,多数岩体发育淬冷岩浆结构的暗色闪长质微粒包体,包体与寄主花岗岩的稀土及微量元素存在明显差异,证明它们是地壳增厚背景下,可能由下部地壳拆沉作用导致的分别来自幔源和下部地壳熔融的二元岩浆混合演化的产物。个别高分异岩体的Fetot／Mg比值高、明显亏损Sr、Ba、Ti、P,呈现了向强分异A型花岗岩过渡的后碰撞富钾过铝偏碱性花岗岩特征。因此,结合西部岩体形成年代早于东部岩体分析,西部形成时代较早偏中基性的含有大量闪长质微粒包体的岩体代表了早期下部地壳拆沉作用的发生,东部形成较晚分异程度高的高钾钙碱性Ⅰ型花岗岩体的出现指示了南、北两大陆块碰撞汇聚后向伸展的转折,而更晚期高度分异的姜家坪富钾花岗岩体的出现则表明秦岭造山带已进入主碰撞结束期的伸展拉张演化阶段,并预示了新的板内演化期的到来。     

The Zaderzhninskoe gold deposit: Mineral composition,fluid inclusions,and age (South Verkhoyansk region)

Based on results of study of the regional position, chemical composition of ores, fluid inclusions, and age relationships between mineralization and igneous rocks, we propose a geological and genetic model for the formation of gold mineralization of the Zaderzhninskoe deposit. Mineralization is located in the tectonic node of the intersection of two regional structures in the supraintrusive zone of a latent granitoid pluton among the terrigenous rocks of the Verkhoyansk complex, which are regionally metamorphosed to the greenschist facies. The sequential deposition of three types of mineralization—Au-quartz (including early low-gold Au-As and late productive Au-Pb-Zn mineralization), Au-rare-metal, and Au-silver—has been established. The Au-Bi (Te) assemblage contains native bismuth, bismuthinite, hedleyite, Bi sulfotellurides, gustavite group minerals, and secondary minerals—Bi oxides and Bi tellurites with low-grade gold. Hg-containing electrum and kustelite, Ag-Sb and Ag-Pb-Sb sulfosalts, stutzite, Te-Pb-containing canfieldite, freibergite, and Au and Ag sulfides are indicator minerals of the Au-Ag (Sb) assemblage. Ore formation occurred at temperatures from 90 to 340 °C, with the participation of lowly and moderately concentrated solutions with CO₂ ± CH₄ ± N₂ gas phase. A decrease in temperature from Au-quartz mineralization (200-220 °C) to the late epithermal one (160 °C) and a slight increase in the concentration of solutions (up to 10 wt.% NaCl equiv.) have been established. The deposit resulted from the intricate multistage geodynamic evolution of the South Verkhoyansk region. Ore-forming processes are associated with the evolution of magmatic objects. Dating of igneous rocks yields the following ages: diorites—130-137 Ma (Rb-Sr), spessartites—126 ± 3 Ma (Rb-Sr), and kersantites—115 ± 1.7 Ma (Ar/Ar). Early concordant Au-quartz (Au-As) mineralization of the deposit is comparable with metamorphic-related Au-quartz veins of the Yur-Bular type, and its age is taken as > 137 Ma. The time of formation of Au-quartz (Au-Pb-Zn) mineralization is estimated at 123.5 ± 1.6 Ma (Ar/Ar) and is coeval with the time of intrusion of the Early Cretaceous granitoids of the South Verkhoyansk region. The imposed low-temperature mineralization undoubtedly has a younger age. Its formation was followed by the successive deposition of Au-rare-metal mineralization at the final stage of formation of granitoid plutons (~ 120 Ma) and Au-Ag mineralization in the period 100 ± 5 Ma, i.e., the time of formation of late-stage granodiorite-granite intrusions.     

Zircon U–Pb geochronology and petrology of intrusive rocks in the C-North and Baghak districts,Sangan iron mine,NE Iran

Porphyritic granitoids that host the Sangan iron mine deposit belong to the Khaf–Kashmar–Bardaskan volcanoplutonic belt in northeastern Iran. These intrusive rocks, mostly quartz monzonite to syenogranite porphyries, have been divided into three groups on the basis of crosscutting relationships and zircon U–Pb dating: (1) group 1, 42.3 ± 0.8 Ma, (2) group 2, 40.0 ± 0.5 Ma, and (3) group 3, 39.2 ± 0.6 Ma. The group 1 and 2 rocks host magnetite mineralization, whereas the group 3 intrusions are interpreted as syn-mineralization. They have features typical of high-K alkali-calcic to calc-alkalic magnesian rocks and are metaluminous to weakly peraluminous formed in a volcanic arc setting. Mantle-normalized, trace-element spider diagrams display enrichment in large ion lithophile elements, such as Rb, Ba, K, and Cs, and depletion in high field strength elements, e.g., Nb, Ti, Ta, Zr, Y, and heavy rare earth elements, with moderate to strong light rare earth elements enrichment ((La/Yb)_N = 24.8–7.6) and a negative Eu anomaly. The parental magmas are probably derived from partial melting of mantle that had been metasomatized by a slab-derived fluid. During the upward migration of these melts, additional input of crustal materials could account for the high K characteristic for most of the intrusive rocks around the Sangan mine area.Textural evidence and mineral assemblages indicate the Sangan Fe-skarn is an oxidized magmatic-hydrothermal system caused by the group 3 intrusions.     

Neoproterozoic,Paleozoic, and Mesozoic granitoid magmatism in the Qinling Orogen,China: Constraints on orogenic process

The Qinling Orogen is one of the main orogenic belts in Asia and is characterized by multi-stage orogenic processes and the development of voluminous magmatic intrusions. The results of zircon U–Pb dating indicate that granitoid magmatism in the Qinling Orogen mainly occurred in four distinct periods: the Neoproterozoic (979–711 Ma), Paleozoic (507–400 Ma), and Early (252–185 Ma) and Late (158–100 Ma) Mesozoic. The Neoproterozoic granitic magmatism in the Qinling Orogen is represented by strongly deformed S-type granites emplaced at 979–911 Ma, weakly deformed I-type granites at 894–815 Ma, and A-type granites at 759–711 Ma. They can be interpreted as the products of respectively syn-collisional, post-collisional and extensional setting, in response to the assembly and breakup of the Rodinia supercontinent. The Paleozoic magmatism can be temporally classified into three stages of 507–470 Ma, 460–422 Ma and ∼415–400 Ma. They were genetically related to the subduction of the Shangdan Ocean and subsequent collision of the southern North China Block and the South Qinling Belt. The 507–470 Ma magmatism is spatially and temporally related to ultrahigh-pressure metamorphism in the studied area. The 460–422 Ma magmatism with an extensive development in the North Qinling Belt is characterized by I-type granitoids and originated from the lower crust with the involvement of mantle-derived magma in a collisional setting. The magmatism with the formation age of ∼415–400 Ma only occurred in the middle part of the North Qinling Belt and is dominated by I-type granitoid intrusions, and probably formed in the late-stage of a collisional setting. Early Mesozoic magmatism in the study area occurred between 252 and 185 Ma, with the cluster in 225–200 Ma. It took place predominantly in the western part of the South Qinling Belt. The 250–240 Ma I-type granitoids are of small volume and show high Sr/Y ratios, and may have been formed in a continental arc setting related to subduction of the Mianlue Ocean between the South Qinling Belt and the South China Block. Voluminous late-stage (225–185 Ma) magmatism evolved from early I-type to later I-A-type granitoids associated with contemporaneous lamprophyres, representative of a transition from syn- to post-collisional setting in response to the collision between the North China and the South China blocks. Late Mesozoic (158–100 Ma) granitoids, located in the southern margin of the North China Block and the eastern part of the North Qinling Belt, are characterized by I-type, I- to A-type, and A-type granitoids that were emplaced in a post-orogenic or intraplate setting. The first three of the four periods of magmatism were associated with three important orogenic processes and the last one with intracontinental process. These suggest that the tectonic evolution of the Qinling Orogen is very complicated.     

The Mesozoic tectono-magmatic evolution at the Paleo-Pacific subduction zone in West Borneo

Metamorphic and magmatic rocks are present in the northwestern part of the Schwaner Mountains of West Kalimantan. This area was previously assigned to SW Borneo (SWB) and interpreted as an Australian-origin block. Predominantly Cretaceous U-Pb zircon ages (c. 80–130 Ma) have been obtained from metapelites and I-type granitoids in the North Schwaner Zone of the SWB but a Triassic metatonalite discovered in West Kalimantan near Pontianak is inconsistent with a SWB origin. The distribution and significance of Triassic rocks was not known so the few exposures in the Pontianak area were sampled and geochemical analyses and zircon U-Pb ages were obtained from two meta-igneous rocks and three granitoids and diorites. Triassic and Jurassic magmatic and metamorphic zircons obtained from the meta-igneous rocks are interpreted to have formed at the Mesozoic Paleo-Pacific margin where there was subduction beneath the Indochina–East Malaya block. Geochemically similar rocks of Triassic age exposed in the Embuoi Complex to the north and the Jagoi Granodiorite in West Sarawak are suggested to have formed part of the southeastern margin of Triassic Sundaland. One granitoid (118.6 ± 1.1 Ma) has an S-type character and contains inherited Carboniferous, Triassic and Jurassic zircons which indicate that it intruded Sundaland basement. Two I-type granitoids and diorites yielded latest Early and Late Cretaceous weighted mean ages of 101.5 ± 0.6 and 81.1 ± 1.1 Ma. All three magmatic rocks are in close proximity to the meta-igneous rocks and are interpreted to record Cretaceous magmatism at the Paleo-Pacific subduction margin. Cretaceous zircons of metamorphic origin indicate recrystallisation at c. 90 Ma possibly related to the collision of the Argo block with Sundaland. Subduction ceased at that time, followed by post-collisional magmatism in the Pueh (77.2 ± 0.8 Ma) and Gading Intrusions (79.7 ± 1.0 Ma) of West Sarawak.     

新疆东天山觉罗塔格地区花岗岩类年代学、构造背景及其成矿作用研究

东天山觉罗塔格地区岩浆岩非常发育,以花岗岩类分布最为广泛,对其研究还较为薄弱。本文对觉罗塔格地区主要的花岗岩类岩体系统开展了地质特征研究并进行了同位素精确测年,报道了区内16个主要花岗岩类岩体的锆石LA-ICPMS U-Pb年龄：镜儿泉岩体376.9±3.1Ma、西凤山岩体349.0±3.4Ma、石英滩岩体342±11Ma、长条山岩体337.4±2.8Ma、天目岩体320.2±3.1Ma、百灵山岩体317.7±3.7Ma、白石泉岩体303±18Ma、迪坎岩体288.0±2.5Ma、黄山岩体288±17Ma、白山东岩体284.5±4.5Ma、管道岩体284.1±5.8Ma、红石岩体282.7±4.2Ma、陇东岩体276.2±2.5Ma、多头山岩体271.7±5.5Ma、双岔沟岩体252.4±2.9Ma、土墩岩体246.2±2.6Ma,上述定年结果为研究区岩浆活动与区域构造演化及深部过程的关系研究提供了可靠的年代学支持。结合前人已有的部分年代学成果认为,觉罗塔格地区花岗岩类的形成年龄分布在386~230Ma之间,岩浆活动可分为晚泥盆世(386.5~369.5Ma)、早石炭世(349~330Ma)、晚石炭世-晚二叠世(320~252Ma)、早中三叠世(246~230Ma)等4个阶段。前3个阶段岩浆活动具有持续时间逐渐变长、岩浆活动逐渐加剧的特点,并在第三阶段达到顶峰,而第四阶段岩浆活动则明显变弱。花岗岩类岩浆活动在时空分布上表现为,自哈尔里克-大南湖岛弧带→阿奇山-雅满岛弧带→康古尔-黄山韧性剪切带,岩体侵位由早到晚; 自研究区东部→中西部→沿韧性剪切带,岩体侵位由老到新。结合区域构造演化研究成果认为,觉罗塔格地区花岗质岩浆活动与区域构造演化具有很强的耦合关系,花岗岩类在前碰撞阶段、主碰撞阶段、后碰撞阶段、板内阶段等4个构造演化阶段均有发育,与花岗岩类在时间分布上的4个阶段完全对应,其中尤以后碰撞构造演化阶段花岗岩类的分布最广泛、岩浆活动最强烈。觉罗塔格地区与4个阶段花岗岩类有关的成矿作用由早到晚具有无明显矿化→斑岩型铜矿、火山岩型铁矿→韧性剪切带型金矿、夕卡岩型银(铜)矿→斑岩-石英脉型钼矿的演化特点,其中以对应于主碰撞阶段的斑岩型铜矿和后碰撞阶段的韧性剪切带型金矿最为发育。本文系统阐述了东天山觉罗塔格地区中酸性岩体的时空格架、与区域构造演化的耦合、与成矿作用的关系,为北疆地区晚古生代特别是后碰撞背景下的岩浆演化及其成矿关系的研究提供了有力支持。     

Geochemistry and U–Pb SHRIMP zircon chronology of granitoids and microgranular enclaves from Jhirgadandi Pluton of Mahakoshal Belt,Central India Tectonic Zone,India

The northern part of Central India Tectonic Zone (CITZ) is delineated by an arc-shaped supracrustal belt commonly referred to as Mahakoshal Belt, which is considered as a product of intense rifting of sialic crust that occurred at ca 2400–2600 Ma. Several granitoid plutons intrude the Parsoi Formation of Mahakoshal Belt. Among these, an elliptical small stock-like granitoid body trending E–W is exposed in and around Jhirgadandi region of Mahakoshal Belt, referred herein as Jhirgadandi Pluton. It is composed of minor amount of mafic rocks (diorite) and predominant granitoids. Country-rock pelitic xenoliths and microgranular enclaves (ME) are commonly hosted in granitoids but are absent in diorite. The ME exhibit typical magmatic texture with a Bt(±Cpx ± Hbl)-Pl-Kf-Qtz-Mag-Ap assemblage, similar to that in host granitoids but with contrasting mineral proportions. Whole-rock molar Al₂O₃/(CaO + Na₂O + K₂O) (A/CNK) ratios of diorite (0.63–0.72), ME (0.69–1.21) and granitoids (0.83–1.05) suggest their nature largely metaluminous (I-type) to rarely peraluminous (S-type) granitoids. On most binary plots involving silica, two distinct compositional paths can be recognized; one formed by an array of differentiating diorite and ME, and another by fractionating granitoids gradually depleting in compatible elements. It is most likely that ME were generated by progressive and concurrent mixing of coeval pristine mafic (diorite) and granitoid magmas and fractionation processes. However, coherent and identical trace elements (except for Sr, Th, Y and Ni) and REE patterns for ME-granitoid pairs most likely suggest partial to near-complete chemical equilibration through varying degrees of diffusion process across the ME – partly crystalline host granitoid boundary. High-precision U–Pb SHRIMP zircon ²⁰⁶Pb/²³⁸U ages for ME (1758 ± 19 Ma) and host granitoid (1753 ± 9.1 Ma) from Jhirgadandi Pluton further support the notion that they were coeval. The obtained age (∼1750 Ma) of Jhirgadandi Pluton also points to the existence and role of Super-Columbian continental component in the evolution of Mahakoshal Belt of the CITZ.     

Zircon U-Pb ages and geochemistry of the Wenquan Mo-bearing granitioids in West Qinling,China: Constraints on the geodynamic setting for the newly discovered Wenquan Mo deposit

East Qinling is the largest porphyry molybdenum province in the world; these Mo deposits have been well documented. In West Qinling, however, few Mo deposits have been discovered although granitic rocks are widespread. Recently, the Wenquan porphyry Mo deposit has been discovered in Gansu province, which provides an insight into Mo mineralization in West Qinling. In this paper we report Pb isotope compositions for K-feldspar and sulfides, S isotope ratios for sulfides, the results obtained from petrochemical study and from in situ LA-ICP-MS zircon U-Pb dating and Hf isotopes. The granitoids are enriched in LILE and LREE, with REE and trace element patterns similar to continental crust, suggesting a crustal origin. The Mg^# (40.05 to 56.34) and Cr and Ni contents are high, indicating a source of refractory mafic lower crust. The ε_Hf(t) values of zircon grains from porphyritic monzogranite range from ? 2.9 to 0.6, and from granitic porphyry vary from ? 3.3 to 1.9. The zircons have T_DM2 of 1014 to 1196 Ma for the porphyritic monzogranite and 954 to 1224 Ma for the granitic porphyry, implying that these granitoids were likely derived from partial melting of a Late Mesoproterozoic juvenile lower crust. The Pb isotope compositions of the granitoids are similar to granites in South China, showing that the magma was sourced from the middle–lower crust in the southern Qinling tectonic unit. The Pb isotopic contrast between the Mo-bearing granitoids and ores shows that the Pb in the ore-forming solution was derived from fractionation of a Triassic magmatic system. δ³⁴S values of sulfides are between 5.02 and 5.66‰, similar to those associated with magmatic-hydrothermal systems. LA-ICP-MS zircon U-Pb dating yields crystallization ages of 216.2 ± 1.7 and 217.2 ± 2.0 Ma for the granitoids, consistent with a previously reported molybdenite Re-Os isochron age of 214.4 ± 7.1 Ma. This suggests that the Mo mineralization is related to the late Triassic magmatism in the West Qinling orogenic belt. In view of these geochemical results and known regional geology, we propose that both granitoid emplacement and Mo mineralization in the Wenquan deposit resulted from the Triassic collision between the South Qinling and the South China Block, along the Mianlue suture. Since Triassic granitoid plutons commonly occur along the Qinling orogenic belt, the Triassic Wenquan Mo-bearing granitoids highlight the importance of the Triassic tectono-magmatic belt for Mo exploration. In order to apply this metallogenic model to the whole Qinling orogen, further study is needed to compare the Wenquan deposit with other deposits.     

Adakite-like signature of porphyry granitoid stocks in the Meiduk and Parkam porphyry copper deposits,NE of Shahr-e-Babak,Kerman, Iran: Constrains on geochemistry

The Middle Miocene porphyry granitoid stocks of Meiduk and Parkam porphyry copper deposits are intruded in the north-western part of the Dehaj-Sarduiyeh volcano-sedimentary belt in the south-eastern extension of the Urumieh-Dukhtar Magmatic Arc (UDMA) in Iran. The porphyritic to microgranular granitoids are mainly consist of quartz diorite, granodiorite and diorite. The whole rock geochemical analyses of these rocks reveals sub-alkaline, calc-alkaline, meta-peraluminous and I-type characteristics. Their geochemical characteristics such as Al₂O₃ content of 13.51–17.05 wt%, high Sr concentration (mostly >400 ppm), low Yb (an average of 0.74 ppm) and Y (an average of 9.02 ppm) contents, strongly differentiated REE patterns (La/Yb ≥ 20), lack of Eu anomaly (Eu/Eu¹ ≥ 1) are indicative of adakitic signature. Their enrichment in low field strength elements (LFSE) and conspicuous negative anomalies for Nb, Ta and Ti are typical of subduction related magmas. Detailed petrological studies and geochemical data indicated that Meiduk and Parkam porphyry granitoids were derived from amphibole fractionation of hydrous melts at a depth of >40 km in a post-collisional tectonic setting.