Geophysical Study of the Valle Fértil Lineament Between 28°45′S and 31°30′S: Boundary Between the Cuyania and Pampia Terranes

A gravimetric and magnetometric study was carried out in the north-eastern portion of the Cuyania terrane and adjacent Pampia terrane. Gravimetric models permitted to interpret the occurrence of dense materials at the suture zone between the latter terranes. Magnetometric models led to propose the existence of different susceptibilities on either side of the suture. The Curie temperature point depth, representing the lower boundary of the magnetised crust, was found to be located at 25 km, consistent with the lower limit of the brittle crust delineated by seismic data; this unusually thick portion of the crust is thought to release stress producing significant seismicity.

Moho depths determined from seismic studies near western Sierras Pampeanas are significantly greater than those obtained from gravimetric crustal models.

Considering mass and gravity changes originated by the flat-slab Nazca plate along Cuyania and western Pampia terranes, it is possible to reconcile Moho thickness obtained either by seismic or by gravity data. Thus, topography and crustal thickness are controlled not only by erosion and shortening but by upper mantle heterogeneities produced by: (a) the oceanic subducted Nazca plate with “normal slope” also including asthenospheric materials between both continental and oceanic lithospheres; (b) flat-slab subducted Nazca plate (as shown in this work) without significant asthenospheric materials between both lithospheres. These changes influence the relationship between topographic altitudes and crustal thickness in different ways, differing from the simple Airy system relationship and modifying the crustal scale shortening calculation. These changes are significantly enlarged in the study area. Future changes in Nazca Plate slope will produce changes in the isostatic balance.     

Crustal attenuation in the Southern Andean retroarc (38°–39°30′ S) determined from tectonic and gravimetric studies: The Lonco-Luán asthenospheric anomaly

The western retroarc of the Southern Andes between 38° and 40° S is formed by a NNW-elongated ridge not associated with stacked thrust sheets. On the contrary, during the last 4–3 Ma this ridge was affected by extensional deformation, regional uplift and related folding on a very broad scale. Receiver function analysis shows that the drainage divide area and adjacent retroarc lie over an attenuated crust. Expected crustal thickness at these latitudes is around 38 km, whereas in this part of the retroarc the thickness is less than 32 km. The causes for such attenuation have been linked to a moderate steepening of the subducted Nazca plate beneath the South American plate, which is suggested by a westward shift and narrowing of the magmatic arc during the last 4 to 5 Ma. Gravimetric studies show that the upper plate did not react homogeneously to slab steepening, but ancient sutures and lithospheric discontinuities deeply buried under Mesozoic to Cenozoic sequences in the retroarc were locally reactivated. These processes resulted in an asthenospheric anomaly that correlates at the surface with the area of Pliocene to Quaternary doming, widespread extension and three radial troughs. Two of the troughs have accommodated substantial amounts of extension, but the third was probably aborted at an early stage. Moreover, the presence of an anomalous concentration of calderas and large volcanic centers over the proposed asthenospheric anomaly, and their age distribution, may indicate minor migration of the asthenospheric anomaly between 4 and 2 Ma through the western South American plate.     

Talc friction in the temperature range 25°–400 °C: Relevance for Fault-Zone Weakening

Talc is one of the weakest minerals that is associated with fault zones. Triaxial friction experiments conducted on water-saturated talc gouge at room temperature yield values of the coefficient of friction, μ (shear stress, τ/effective normal stress, σ′_N) in the range 0.16–0.23, and μ increases with increasing σ′_N. Talc gouge heated to temperatures of 100°–400 °C is consistently weaker than at room temperature, and μ < 0.1 at slow strain rates in some heated experiments. Talc also is characterized by inherently stable, velocity-strengthening behavior (strength increases with increasing shear rate) at all conditions tested. The low strength of talc is a consequence of its layered crystal structure and, in particular, its very weak interlayer bond. Its hydrophobic character may be responsible for the relatively small increase in μ with increasing σ′_N at room temperature compared to other sheet silicates.Talc has a temperature–pressure range of stability that extends from surficial to eclogite-facies conditions, making it of potential significance in a variety of faulting environments. Talc has been identified in exhumed subduction zone thrusts, in fault gouge collected from oceanic transform and detachment faults associated with rift systems, and recently in serpentinite from the central creeping section of the San Andreas fault. Typically, talc crystallized in the active fault zones as a result of the reaction of ultramafic rocks with silica-saturated hydrothermal fluids. This mode of formation of talc is a prime example of a fault-zone weakening process. Because of its velocity-strengthening behavior, talc may play a role in stabilizing slip at depth in subduction zones and in the creeping faults of central and northern California that are associated with ophiolitic rocks.     

Pollen analyses from a 50 000‐yr rodent midden series in the southern Atacama Desert (25° 30′ S)

Precipitation in northern Chile is controlled by two great wind belts—the southern westerlies over the southern Atacama and points south (> 24° S) and the tropical easterlies over the northern and central Atacama Desert (16–24° S). At the intersection of these summer and winter rainfall regimes, respectively, is a Mars‐like landscape consisting of expansive surfaces devoid of vegetation (i.e. absolute desert) except in canyons that originate high enough to experience runoff once every few years. Pollen assemblages from 39 fossil rodent middens in one of these canyons, Quebrada del Chaco (25° 30′ S), were used to infer the history of vegetation and precipitation at three elevations (2670–2800 m; 3100–3200 m; 3450–3500 m) over the past 50 000 years. When compared to modern conditions and fossil records to the north and south, the pollen evidence indicates more winter precipitation at > 52, 40–33, 24–17 k cal. yr BP, more precipitation in both seasons at 17–14 k cal. yr BP, and more summer precipitation from 14–11 k cal. yr BP. Younger middens are scarce at Quebrada del Chaco, and the few Holocene samples indicate hyperarid conditions comparable to today. The only exception is a pollen assemblage that indicates a brief but significant interlude of increased winter precipitation in the last millennium. Copyright © 2005 John Wiley & Sons, Ltd.     

Regional soil-gas helium distribution of the Ely and Delta 1° × 2° quadrangles, Basin and Range Province

A reconnaissance soil-gas helium survey was made in the Ely, Nevada and Delta, Utah 1° × 2° quadrangles in the Basin and Range Province. Helium concentrations in 510 samples ranged from −147 to 441 ppb He with respect to ambient air. The median helium value for the study area was 36 ppb. Concentrations of more than 100 ppb He and less than −20 ppb He occur more commonly in the Ely quadrangle and are especially numerous in the western one-half of this quadrangle. Interpretation of the data reveals that the helium concentrations reflect the rock type, particularly the silicic volcanic occurrences, and the geological structure of the area created by crustal extension. The regional soil-gas helium distribution is important information to consider when interpreting anomalies from detailed surveys.     

Mechanism of chalcopyrite formation from iron monosulphides in aqueous solutions (< 100°C, pH 2–4.5)

In low-temperature aqueous solutions (< 100°C, pH 2–4.5), chalcopyrite (CuFeS₂) does not form through direct precipitation from solution. The pathway is exclusively via precursor iron sulphides and dissolved Cu salts. The reaction of dissolved Cu (II) salts with natural hexagonal pyrrhotite (Fe_0.9S) is diffusion controlled. The initial stage has an apparent activation energy of 11.4 ± 1.8 kJ mol⁻¹ and the rate (in units of mol dm⁻³s⁻¹ cm⁻²) is independent of the solid reactant surface area. The reaction proceeds through a series of metastable Cu-Fe-sulphide intermediaries. These phases form a series of ephemeral layers penetrating into the pyrrhotite surface. The first phase formed has the stoichiometry Cu_0.1Fe_0.9S. No Fe is released into the solution during its formation and this, together with the extremely low apparent activation energy and the stoichiometry, suggest that it is formed by stuffing of electron holes in the pyrrhotite structure with Cu ions. The transformation from the hexagonal close-packed arrangement of the pyrrhotite structure to the essentially cubic packing in chalcopyrite proceeds through a series of intermediaries, approximating in composition to members of the cubanite group. The rate of formation of these phases is controlled by the coupled diffusion of Fe (II), Fe (III), Cu (I) and Cu (II) species through the surface reaction zone, although the process as a whole can be approximated by steady-state diffusion of total Cu into a semi-infinite medium. Experiments with metastable precursor iron monosulphide phases, including amorphous FeS and synthetic mackinawite indicate similar reaction pathways.

The results suggest that chalcopyrite formation in low-temperature natural systems may be significantly constrained by kinetic factors. Chalcopyrite is, at least, a diagenetic mineral since its formation requires the prior formation of iron sulphides. However, at ambient temperatures its formation is probably limited to very early diagenesis.     

Macrobioerosion and Microbioerosion in Marine Molluscan Shells from Holocene and Modern Beaches (39°−40°S, South of Buenos Aires Province, Argentina)

The marine sediments of the area of Verde Peninsula-Jabali Island(39°28′S/62°19′W-40°28′S/62°11′W) Holocene in age(3-2 ky),and modern beaches contain a significant amount of bioeroded mollusc shells.Fifteen sites were analyzed,in which 20.11%of the mollusc shells(2168 valves) presented bioerosion traces,in 54 species(30 bivalves and 24 gastropods).Fourteen ichnogenera were reported:Entobia,Maeandropoiydora,Iramena,Caulostrepsis,Pennatichnus,Pinaceocladichnus,Trypanites,and Gastrochaenolites(Domichnia),Gnathichnus and Radulichnus(Pascichnia),Finichnus and Centrichnus(Fixichnia),Oichnus(Praedicnia)(macrobioerosion),y Semidendrina(microbioerosion),the latter is first reported in mollusc shells in Argentina.Eleven ichnospecies were identified Finichnus peristroma,Maeandropoiydora sulcans,Gnathichnus pentax,Pinaceocladichnus onubensis,Caulostrepsis taeniola,Centrichnus eccentricus,Radulichnus inopinatus,Oichnus simplex,Oichnus paraboloides,Oichnus gradatus,and Gastrochaenolites torpedo(lithic remains).The dominant ichnogenera in the Holocene deposits are Iramena,Entobia and Oichnus.The same ichnogenera are constant with different abundance in the modern beaches,and increasing representation of Pinaceocladichnus and Pennatichnus.The dominant ichnofacies in the Holocene deposits is Trypanites,revealing a benthonic marine community composed of cheilostome bryzoans,clionaid sponges,predator gastropods,regular echinoids,polychaete annelids,bivalves,thallophytas and fungi.Generally,the area was described as a sublittoral,low-energy,stable environment with high rate of oxygenation,and sandy bottoms,with rocky bottoms at Villalonga locality.     

Solubility of silica polymorphs in electrolyte solutions, I. Activity coefficient of aqueous silica from 25° to 250°C, Pitzer''s parameterisation

Within the framework of Pitzer's specific interaction model, interaction parameters for aqueous silica in concentrated electrolyte solutions have been derived from Marshall and co-authors amorphous silica solubility measurements. The values, at 25°C, of the Pitzer interaction parameter (λ_SiO2(aq)−i) determined in this study are the following: 0.092 (i = Na⁺), 0.032 (K⁺), 0.165 (Li⁺), 0.292 (Ca²⁺, Mg²⁺), −0.139 (SO₄²⁻), and −0.009 (NO₃⁻). A set of polynomial equations has been derived which can be used to calculate λ_SiO2(aq)−i for these ions at any temperature up to 250°C. A linear relationship between the aqueous silica-ion interaction parameters (λ_SiO2(aq)−i) and the surface electrostatic field (Z_i/r_e,i) of ions was obtained. This empirical equation can be used to estimate, in first approximation, λ_SiO2(aq)−i if no measurements are available. From this parameterisation, the calculated activity coefficient of aqueous silica is 2.52 at 25°C and 1.45 at 250°C in 5 m NaCl solution. At lower concentrations, e.g. 2 m NaCl, the activity coefficient of silica is 1.45 at 25°C and 1.2 at 250°C. Hence, in practice, it is necessary to take into account the activity coefficient of aqueous silica (λ_SiO2(aq)≠1) in hydrothermal solutions and basinal brines where the ionic strength exceeds 1. A comparison of measured [Marshall, W.L., Chen, C.-T.A., 1982. Amorphous silica solubilities, V. Prediction of solubility behaviour in aqueous mixed electrolyte solutions to 300°C. Geochim. Cosmochim. Acta 46, 289–291.] and computed amorphous silica solubility, using this parameterisation, shows a good agreement. Because the effect of individual ions on silicate and silica polymorph solubilities are additive, the present study has permitted to derive Pitzer interaction parameters that allow a precise computation of γ_SiO2(aq) in the Na---K---Ca---Mg---Cl---SO₄---HCO₃---SiO₂---H₂O system, over a large range of salt concentrations and up to temperatures of 250°C.     

Differential Late Paleozoic active margin evolution in South-Central Chile (37°S–40°S) – the Lanalhue Fault Zone

The N–S oriented Coastal Cordillera of South Central Chile shows marked lithological contrasts along strike at 38°S. Here, the sinistral NW–SE-striking Lanalhue Fault Zone (nomen novum) juxtaposes Permo-Carboniferous magmatic arc granitoids and associated, frontally accreted metasediments (Eastern Series) in the northeast with a Late Carboniferous to Triassic basal-accretionary forearc wedge complex (Western Series) in the southwest. The fault is interpreted as an initially ductile deformation zone with divergent character, located in the eastern flank of the basally growing, upwarping, and exhuming Western Series. It was later transformed and reactivated as a semiductile to brittle sinistral transform fault. Rb–Sr data and fluid inclusion studies of late-stage fault-related mineralizations revealed Early Permian ages between 280 and 270 Ma for fault activity, with subsequent minor erosion. Regionally, crystallization of arc intrusives and related metamorphism occurred between 306 and 286 Ma, preceded by early increments of convergence-related deformation. Basal Western Series accretion started at >290 Ma and lasted to 250 Ma. North of the Lanalhue fault, Late Paleozoic magmatic arc granitoids are nearly 100 km closer to the present day Andean trench than further south. We hypothesize that this marked difference in paleo-forearc width is due to an Early Permian period of subduction erosion north of 38°S, contrasting with ongoing accretion further south, which kinematically triggered the evolution of the Lanalhue Fault Zone. Permo-Triassic margin segmentation was due to differential forearc accretion and denudation characteristics, and is now expressed in contrasting lithologies and metamorphic signatures in todays Andean forearc region north and south of the Lanalhue Fault Zone.     

Convergence structures of the Peru trench between 10°S and 14°S

High resolution seafloor studies of the Peru Trench between 10°S and 14°S with the GLORIA long-range side-scan sonar system show that the Nazca plate is broken by numerous normal faults as it bends into the trench. These bending-induced faults strike subparallel to the trench axis and overprint and cut across spreading fabric structures of the plate. They commonly form grabens having widths and spacings of 3–5 km and extend for as much as 100 km along strike. Vertical displacements are generally 200 m or more by the time they reach the trench axis. Turbidite deposits are found in the trench north of 11.5°S. Both turbidite and pelagic sediments are folded and temporarily accreted to the base of the overriding plate along the length of the trench axis. They are apparently subsequently implaced in the grabens by slumping and subducted with the Nazca plate. The Mendaña Fracture Zone, which intersects the trench between 9°40′S and 10°35′S, appears to be the locus of a seaward propagating rift that is forming in response to subduction-induced extensional stresses in the Nazca plate.