Wind-driven estuarine turbidity maxima in Mandovi Estuary,central west coast of India

Systematic studies on the suspended particulate matter (SPM) measured on a seasonal cycle in the Mandovi Estuary, Goa indicate that the average concentrations of SPM at the regular station are ∼20mg/l, 5mg/l, 19mg/l and 5mg/l for June–September, October–January, February–April and May, respectively. SPM exhibits low-to-moderate correlation with rainfall indicating that SPM is also influenced by other processes. Transect stations reveal that the SPM at sea-end stations of the estuary are at least two orders of magnitude greater than those at the river-end during the monsoon. Estuarine turbidity maximum (ETM) of nearly similar magnitude occurs at the same location in two periods, interrupted by a period with very low SPM concentrations. The ETM occurring in June–September is associated with low salinities; its formation is attributed to the interactions between strong southwesterly winds (5.1–5.6ms⁻¹) and wind-induced waves and tidal currents and, dominant easterly river flow at the mouth of the estuary. The ETM occurring in February–April is associated with high salinity and is conspicuous. The strong NW and SW winds (3.2–3.7ms⁻¹) and wind-driven waves and currents seem to have acted effectively at the mouth of the estuary in developing turbidity maximum. The impact of sea breeze appears nearly same as that of trade winds and cannot be underestimated in sediment resuspension and deposition     

Temporal and spatial variability of trace metals in suspended matter of the Mandovi estuary,central west coast of India

Studies on the suspended particulate matter (SPM) in the Mandovi estuary, western India indicate that during the monsoon and pre-monsoon, the SPM increases, and the major and trace metals decrease from stations in the upstream to downstream of the estuary. SPM is consistently low at all stations during the post-monsoon. Trace metals (Cu, Ni, Zn, Cr, and Pb) show strong inter-relationships. They correlate well with Fe and Mn only during the monsoon. The concentrations of Cr, Cu, and Pb are high during the post-monsoon. Enrichment factors and I _geo values of metals indicate that Mn shows significant to strong pollution in all seasons, while Cr, Ni, and Zn during monsoon, and Cr during the post-monsoon show moderate pollution. SPM is controlled by the turbidity maximum, while major and trace metals are governed seasonally by a combination of river discharge, resuspension, spillage of Fe–Mn particulates, and anthropogenic contamination. Incursion of saline waters deep into the river channel during the dry season facilitates aggregation and settling of particulate-borne pollutants close to the discharge area, thereby keeping the estuarine waters free from major contamination.     

Modeling on adsorption–desorption of trace metals to suspended particle matter in the Changjiang Estuary

The uptake and release of trace metals (Cu, Ni, Zn, Cd, and Co) in estuaries are studied using river and sea end-member waters and suspended particulate matter (SPM) collected from the Changjiang Estuary, China. The kinetics of adsorption and desorption were studied in terms of environmental factors (pH, SPM loading, and salinity) and metal concentrations. The uptake of the metals studied onto SPM occurred mostly within 10 h and reached an asymptotic value within 40 h in the Changjiang Estuary. As low pH river water flows into the high pH seawater and the water become more alkaline as it approaches to the seaside of estuary, metals adsorb more on SPM in higher pH water, thus, particulate phase transport of metal become increasingly important in the seaward side of the estuary. The percentage of adsorption recovery and the distribution coefficients for trace metals remained to be relatively invariable and a significant reduction only occurred in very high concentrations of metals (>0.1 mg L⁻¹). The general effect of salinity on metal behavior was to decrease the degree of adsorption of Cu, Zn, Cd, Co, and Ni onto SPM but to increase their adsorption equilibrium pH. The adsorption–desorption kinetics of trace metals were further investigated using Kurbatov adsorption model. The model appears to be most useful for the metals showing the conservative behavior during mixing of river and seawater in the estuary. Our work demonstrates that dissolved concentration of trace metals in estuary can be modeled based on the metal concentration in SPM, pH and salinity using a Kurbatov adsorption model assuming the natural SPM as a simple surfaced molecule.     

On different time scales of suspended matter dynamics in the Weser estuary

Long-term observations in the Weser estuary (Germany) between 1983 and 1997 provide insight into the response of the estuarine turbidity maximum (ETM) under a wide range of conditions. In this estuary the turbidity zone is closely tied to the mixing zone, and the positions of the ETM and the mixing zone vary with runoff. The intratidal suspended particulate matter (SPM) concentrations vary due to deposition during slack water periods, subsequent resubsequent and depletion of temporarily-formed and spatially-limited deposits during the following ebb or flood, and subsequent transport by tidal currents. The corresponding time history of SPM concentrations is remarkably constant over the years. Spring tide SPM concentrations can be twice the neap tide concentrations or even larger. A hysteresis in SPM levels between the falling and rising spring-neap cycle is attributed to enhanced resuspension by the stronger spring tidal currents. There is evidence that the ETM is pushed up-estuary during times of higher mean water levels due to storms. During river floods the ETM is flushed towards the outer estuary. If river floods and their decreasing parts occur during times of relatively high mean water levels, the ETM seems to be maintained in the outer estuary. If river floods and their decreasing parts occur during times of relatively low mean water levels, the ETM seems to loose inventory and may need up to half a year of non-event conditions to gain its former magnitude. During this time seasonal effects may be involved. Analyses of storm events and river floods have revealed that the conditions in the seaward boundary region play an equally important role for the SPM dynamics as those arising from the river.     

Seasonal and tidal monthly patterns of particulate matter dynamics in the Columbia River estuary

We investigated seasonal and tidal-monthly, suspended particulate matter (SPM) dynamics in the Columbia River estuary from May to December 1997 using acoustic backscatter (ABS) and velocity data from four long-term Acoustic Doppler Profiler (ADP) moorings in or near the estuarine turbidity maximum (ETM). ABS profiles were calibrated and converted to total SPM profiles using pumped SPM samples and optical backscatter (OBS) data obtained during three seasonal cruises. Four characteristic settling velocity (W _s) classes were defined from Owen Tube samples collected during the cruises. An inverse analysis, in the form of a non-negative least squares minimization, was used to determine the contribution of the four,W _s-classes to each, total SPM profile. The outputs from the inverse analyses were 6–8 mo time-series ofW _s-specific SPM concentration and transport profiles at each mooring. The profiles extended from the free surface to 1.8–2.7 m from the bed, with 0.25–0.50 m resolution. These time series, along with Owen Tube results and disaggregated size data, were used to investigate SPM dynamics. Three non-dimensional parameters were defined to investigate how river flow and tidal forcing affect particle trapping: Rouse numberP (balance between vertical mixing and settling) trapping efficiencyE (ratio of maximum SPM concentration in the estuary to fluvial source concentration), and advection numberA (ratio of height of maximum SPM concentration to friction velocity). The most effective particle trapping (maximum values ofE) occurs on low-flow neap tides. The location of the ETM and the maximal trapping migrated seasonally in a manner consistent with the increase in salinity intrusion length after the spring freshet. Maximum advection (high values ofA) occurred during highly stratified neap tides.     

A variable turbidity maximum in the Kennebec estuary, Maine

A turbidity maximum has been observed in the Kennebec estuary during mode rate and low flow conditions near the upstream limit of salinity intrusion. Hydrographic, ADCP, and transmissometer data were collected at different river flow levels and seasons during 1995–1998. The location of the tip of the salt intrusion changes dramatically and during high runoff may be flushed from the channel of the estuary along with the accumulated particles in the turbidity maximum. It is hypothesized that the estuarine turbidity maximum (ETM) was absent 18% of the time with occurrences in all seasons during 1993–1999 based on river flow volumes from the Kennebec and Androscoggin Rivers throughout the study period. When the flow is moderate and low, which occurred 73% of the time on average, a region of high turbidity can be found as far as 40 km upstream of the mouth. Suspended particulate loads are low in the ETM, on the order of tens of mg l⁻¹ and may vary with the length of time that the ETM has been present.     

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.     

Oceanic and Hydrologic Influences on Flow and Water Properties in the St. Jones River Estuary,Delaware

Influences of tides, freshwater discharge, and winds on water properties in the St. Jones River estuary (USA), a Delaware National Estuarine Research Reserve, were investigated using multiyear records of sea level, salinity, and turbidity, supplemented by a current profiler time series in 2007. Results demonstrate that instantaneous properties fluctuate with semidiurnal tides and resonant overtides, whereas tidal mean variations are forced by seasonal freshwater inflow and offshore winds. Mean sea level and salinity are highest in summer and vary with seasonal water temperature and rainfall, whereas sea level variability and turbidity are highest in winter on account of storm effects. Salinity and discharge modeling suggest that much (43–65%) of the freshwater resident in the estuary is derived from non-point sources below the head of tide. This diffuse freshwater inflow produces a seaward surface slope and weak mean current, which temporarily reverses under the influence of storm–wind setup within Delaware Bay.     

Suspended particulate matter and dynamics of the Mfolozi estuary,Kwazulu-Natal: Implications for environmental management

 The Mfolozi Estuary on the KwaZulu-Natal coast of South Africa is the most turbid estuary in Natal due to poor catchment management, leading to large quantities of suspended particulate matter (SPM) entering the estuary from the Mfolozi River. This paper quantities some of the solute and sediment dynamics in the Mfolozi Estuary where the main documented environmental concern is the periodic input of SPM from the Mfolozi Estuary to the St. Lucia system, causing reduction of light penetration and endangering biological productivity in this important nature reserve. Synoptic water level results have allowed reach mean bed shear stresses and velocities to be calculated for an observed neap tidal cycle. Results indicate that ebb velocities dominate the sediment transport processes in the estuary when fluvial input in the Mfolozi River is of the order of 15–20 m³ s^–1. Observed and predicted flood tide velocities are too low (<0.35 m s^–1) to suspend and transport significant amounts of SPM. Observed results indicate that although the SPM load entering the estuary is dominantly from the Mfolozi River, the Msunduzi River flow plays a major role in the composition of the estuary's salinity and velocity fields. It is calculated that the Mfolozi Estuary would fill with sediment in 1.3 years if it was cut off from the sea. The major fluvial flood events help maintain the estuary by periodically pushing sediment seawards (spit progrades seawards 5 m yr^–1) and scouring and maintaining the main flow channel in the estuary. During low fluvial flow conditions, tidal flow velocities will become the dominant control on sediment transport in the estuary. Interchange of SPM between the St. Lucia and Mfolozi estuaries under present conditions is complicated by the strong transverse velocity shear between the two systems at their combined mouth. This is creating a salinity-maintained axial convergence front that suppresses mixing of solutes and SPM between the systems for up to 10 h of the tidal cycle during observed conditions. Received: 22 May 1995 · Accepted: 31 July 1995     

Fine sediment transport and accumulations at the mouth of the Seine estuary (France)

A comprehensive study of fine sediment transport in the macrotidal Seine estuary has been conducted, including observations of suspended particulate matter (SPM), surficial sediment, and bathymetric data, as well as use of a three dimensional mathematical model. Tide, river regime, wind, and wave forcings are accounted. The simulated turbidity maximum (TM) is described in terms of concentration and location according to tidal amplitude and the discharge of the Seine River. The TM is mainly generated by tidal pumping, but can be concentrated or stretched by the salinity front. The computed deposition patterns depend on the TM location and are seasonally dependent. The agreement with observations is reasonable, although resuspension by waves may be overestimated. Although wave resuspension is likely to increase the TM mass, it generally occurs simultaneously with westerly winds that induce a transverse circulation at the mouth of the estuary and then disperse the suspended material. The resulting effect is an output of material related to wind and wave events, more than to high river discharge. The mass of the computed TM remains stable over 6 months and independent of the river regime, depending mainly on the spring tide amplitude. Computed fluxes at different cross-sections of the lower estuary show the shift to the TM according to the river flow and point out the rapidity of the TM adjustment to any change of river discharge. The time for renewing the TM by riverine particles has been estimated to be one year.     

Distribution and fractionation of rare earth elements and Yttrium in suspended and bottom sediments of the Kali estuary,western India

Concentrations of rare earth elements (REE) and yttrium (Y), and major metals (Al, Fe and Mn) were measured in suspended particulate matter (SPM) and bottom sediments of the Kali estuary, western India, for their distribution and fractionation. The contents of SPM and metals in it were more uniform along the longitudinal transect during the monsoon. During the post- and pre-monsoons, low SPM in the upper/middle estuary coincided with high Fe and Mn and total REE (∑REE). But in the lower estuary SPM and its ∑REE content increased seaward, while Fe and Mn decreased. The Y/Ho ratios decreased seaward during the monsoon but increased during the post-monsoon. Sm/Nd ratios were more uniform along the transect during monsoon but decreased marginally seaward in other seasons. The Post-Archean Average Australian Shale (PAAS)-normalized REE patterns exhibited middle REE and heavy REE enrichment with positive Ce (\({\text{Ce}}/{\text{Ce}}^{*}\)), Eu (\({\text{Eu}}/{\text{Eu}}^{*}\)) and Y anomalies. The \({\text{Ce}}/{\text{Ce}}^{*}\) increased but \({\text{Eu}}/{\text{Eu}}^{*}\) decreased marginally seaward. The fine-grained sediments showed higher ∑REE and lower Y/Ho ratios than in coarse-grained sediments. The PAAS-normalized REE patterns of sediment were similar to that of SPM. The results revealed two processes, colloidal flocculation and coagulation of metals in the low-salinity zone and an estuarine turbidity maximum in the high salinity zone. Rare earths and yttrium (REY) in SPM and sediments primarily reflected the source rock composition than that of chemical weathering. Apart from physico-chemical processes, the mineralogy and grain size of sediments controlled the distribution and fractionation of REY in the estuary.     

Suspended Sediment Transport in the Freshwater Reach of the Hudson River Estuary in Eastern New York

Deposition of Hudson River sediment into New York Harbor interferes with navigation lanes and requires continuous dredging. Sediment dynamics at the Hudson estuary turbidity maximum (ETM) have received considerable study, but delivery of sediment to the ETM through the freshwater reach of the estuary has received relatively little attention and few direct measurements. An acoustic Doppler current profiler was positioned at the approximate limit of continuous freshwater to develop a 4-year time series of water velocity, discharge, suspended sediment concentration, and suspended sediment discharge. This data set was compared with suspended sediment discharge data collected during the same period at two sites just above the Hudson head-of-tide (the Federal Dam at Troy) that together represent the single largest source of sediment entering the estuary. The mean annual suspended sediment–discharge from the freshwater reach of the estuary was 737,000 metric tons. Unexpectedly, the total suspended sediment discharge at the study site in November and December slightly exceeded that observed during March and April, the months during which rain and snowmelt typically result in the largest sediment discharge to the estuary. Suspended sediment discharge at the study site exceeded that from the Federal Dam, even though the intervening reach appears to store significant amounts of sediment, suggesting that 30–40% of sediment discharge observed at the study site is derived from tributaries to the estuary between the Federal Dam and study site. A simple model of sediment entering and passing through the freshwater reach on a timescale of weeks appears reasonable during normal hydrologic conditions in adjoining watersheds; however, this simple model may dramatically overestimate sediment delivery during extreme tributary high flows, especially those at the end of, or after, the “flushing season” (October through April). Previous estimates of annual or seasonal sediment delivery from tributaries and the Federal Dam to the ETM and harbor may be high for those years with extreme tributary high-flow events.     

Variability of the mixing zones and estuarine turbidity maxima in the Elbe and Weser estuaries

The neighboring coastal plain estuaries of the Elbe and Weser Rivers in Northern Germany exhibit pronounced estuarine turbidity maxima (ETM). Common features and differences between the longitudinal distributions of salinity and suspended particulate matter (SPM) in both estuaries are compared as well as the mechanisms effecting them. Monthly transects of the near surface SPM indicate that the long-term variability of salinity and the ETM is mainly influenced by the freshwater runoff. The variability is reduced to certain characteristic patterns by application of Empirical Orthogonal Functions analysis. The coefficients of these patterns are then correlated to runoff and the resulting functional regressions are used for the construction of a statistical model for the distribution of salinity and SPM along the estuaries; for SPM this has not been successful.     

A particle conveyor belt process in the Columbia River estuary: Evidence from chlorophyll<Emphasis Type="Italic">a</Emphasis> and particulate organic carbon

Using both the photosynthetically active chlorophylla (chla) content of the organic carbon fraction of suspended particulate matter (chla/POC) and the percentage of photosynthetically, active chla in fluorometrically measured chla plus pheophytina (% chla), we determined that under specified hydrodynamic conditions, neap-spring tidal differentiation in particle dynamics could be observed in the Columbia River estuary. During summer time neap tides, when river discharge was moderate, bottom chla/POC remained relatively unchanged from riverine chla/POC over the full 0–30 psu salinity range, suggesting a benign trapping environment. During summertime spring tides, bottom chla/POC decreased at mid range salinities indicating resuspension of chla-poor POC during flood-ebb transitions. Bottom % chla during neap tides tended to average higher than that during spring tides, suggesting that neap particles were more recently hydrodynamically trapped than those on the spring tides. Such differentiation supported the possibility of operation of a particle conveyor belt process, a process in which low-amplitude neap tides favor selective particle trapping in estuarine turbidity maxima (ETM)., while high-amplitude spring tides favor particle resuspension from the ETM. Untrapped river-derived particles at the surface would continue through the estuary to the coastal ocean on the neap tide; during spring tide some particles eroded from the ETM would combine with unsettled riverine particles in transit toward the ocean. Because in tensified biogeochemical activity is associated with ETM, these neap-spring differences may be critical to maintenance and renewal of populations and processes in the estuary. Very high river discharge (15, 000 m³ s⁻¹) tended to overwhelm neap-spring differences, and significant oceanic input during very low river discharge (5,000 m³ s⁻¹) tended to do the same in the estuarine channel most exposed to ocean input. During heavy springtime phytoplankton blooms, development of a thick bottom fluff layer rich in chla also appeared to negate neapspring differentiation because spring tides apparently acted to resuspend the same rich bottom material that was laid down during neap tides. When photosynthetic assimilation numbers [μgC (μgchl,a)⁻¹h⁻¹] were measured across, the full salinity range, no neap-spring differences and no river discharge effects occurred, indicating that within our suite of measurements the compositional distinction of suspended particulate material was mainly a function of chla/POC, and to a lesser extent % chla. Even though these measurements suggest the existence of a conveyor belt process, proof of actual operation of this phenomenon requires scalar flux measurements of chla properties in and out of the ETM on both neap and spring tides.     

Hydrography and circulation of the Chubut River estuary (Argentina)

The hydrography and circulation of the Chubut River were investigated under exceptionally low river discharge. The frontal zone formed by the entrance of the tide in the estuary may be observed as far as 4.5 km from the mouth, showing that the salt intrusion due to tidal effects reaches further inland than during normal river discharge. Based on the classification of Hansen and Rattray (1966), the estuary corresponds to Type 1 with some vertical stratification observed on the seaward side of the frontal zone. A lateral salinity gradient was found, which was not the result of Coriolis force. The general morphology of the estuary and the consequent secondary circulation due to meanders and interchannel bars may explain the lateral variation. Wind effect is a major component of the circulation and mixing of this shallow estuary.     

Groundwater-dependent ecology of the shoreline of the subtropical Lake St Lucia estuary

The ecology of the St Lucia estuary in South Africa is of unique international importance. During droughts the estuary experiences high salinities, with values above that of seawater. Ion-poor groundwater flowing into the estuary from prominent sand aquifers along its eastern shoreline forms low-salinity habitats for salt-sensitive biota. During droughts, plants and animals can take refuge in the groundwater discharge zone until the condition in the estuary regains tolerable salinity. Simulations of the groundwater discharge indicate that the flow can persist during droughts over at least a decade, and be of great important for the resilience of the estuary. Anthropogenic activities have reduced the river inflow and made the St Lucia estuary more sensitive to droughts. The groundwater has thereby become increasingly important for the estuary’s ecology. Protection of the groundwater discharge along the shoreline itself and actions to increase the groundwater recharge are therefore important management tasks.     

Flow and sediment dynamics in migrating salinity intrusions: Fraser River estuary, Canada

The salinity intrusion in the Fraser estuary, Canada, migrates landward during the rising tide and is flushed downstream on the falling tide. Suspended sediment concentrations are higher during unstratified flows than during stratified conditions. Mixing between the upper layer and the salinity intrusion is restricted by a strong density interface on the rising tide but enhanced mixing occurs across a weak salinity gradient on the falling tide. A weakly-developed estuarine turbidity maximum (ETM) and positive internal waves occur at the tip of the salinity intrusion as it migrates seaward. Spectral analyses of optical backscatter probe time series indicate that sediment movement from the upper layer is restricted by the density interface on the rising tide. During the falling tide, sediment mixing is enhanced by internal waves at the surface of the ETM. Internal waves generated at the density interface have a higher frequency during the rising tide than the falling tide.     

Composition of estuarine colloidal material: major and trace elements

Colloidal-sized material from the Patuxent River estuary, Maryland, was analyzed for more than 30 elements by instrumental neutron activation analysis. Sample data from stations ranging in salinity from 0.04 g/kg to 12 g/kg indicate that the winter colloidal material is dominated upstream by poorly crystallized clay minerals and iron oxide, but above a salinity of 10 g/kg, it consists primarily of carbonaceous material. Winter colloidal material decreases non-conservatively seaward from 29 to 0.6 mg/l. The summer colloidal material, however, is carbon-rich throughout the estuary and the amount of colloidal material in the upper water column does not change appreciably with increasing salinity. Many trace elements (Cs, Hf, Rb, Se, Th, V and the REE) covary with Al and probably are associated with the clay component. Other elements (As, Ba, Sb, Se, U and Zn) are considerably enriched relative to Al and may covary with the organic component. The results suggest that the freshwater winter colloidal system is a product of continental weathering processes, whereas the summer colloidal material is derived primarily from estuarine biological processes.     

Aggregation of montmorillonite and organic matter in aqueous media containing artificial seawater

Background  

The dispersion-aggregation behaviors of suspended colloids in rivers and estuaries are affected by the compositions of suspended materials (i.e., clay minerals vs. organic macromolecules) and salinity. Laboratory experiments were conducted to investigate the dispersion and aggregation mechanisms of suspended particles under simulated river and estuarine conditions. The average hydrodynamic diameters of suspended particles (representing degree of aggregation) and zeta potential (representing the electrokinetic properties of suspended colloids and aggregates) were determined for systems containing suspended montmorillonite, humic acid, and/or chitin at the circumneutral pH over a range of salinity (0 – 7.2 psu).