Assessment of heavy metal contamination in the surficial sediments from the lower Meghna River estuary,Noakhali coast,Bangladesh

Sediment samples were collected from ten selected sites of the lower Meghna River estuary,and six heavy metals were analyzed with Atomic Absorption Spectrophotometry(AAS)to assess the contamination level and the metals’association with sediment grain size.The current results revealed that the mean concentrations of the studied metals were ranked in descending order of iron(Fe)(1.29×103 mg/kg)>zinc(Zn)(42.41 mg/kg)>lead(Pb)(12.48 mg/kg)>chromium(Cr)(10.59 mg/kg)>copper(Cu)(6.22 mg/kg)>cadmium(Cd)(0.28 mg/kg).The geo-accumulation,contamination,and pollution load indexes suggested that the lower Meghna river estuary was not contaminated by Fe,Zn,Pb,Cr,and Cu.The mean size of the sediment ranged from 28.92 to 126.2 mm,and the Pearson correlation coefficient showed a significant association between Fe and Pb(coefficient of determination,r2=0.836;p<0.05),and no significant correlation was found between individual metals and grain size,indicating no or low influence on the metals distribution.     

Assessment of biopollution in aquatic ecosystems

The introduction of alien species (AS) in marine environments is a factor of disturbance that can be viewed as a pollution agent. Using basic information on abundance and distribution of alien species, we developed an index that classifies AS impacts on native species, communities, habitats and ecosystem functioning. This method can be used to evaluate impact at five different levels of biopollution, fitting within the existing schemes for water quality assessment. Both spatial and temporal comparisons are possible. The assessments may also be used to evaluate management performance where avoidance measures were necessary and assist in preventing further unwanted introductions. Such assessments made for the same areas over time provide opportunities for measuring change in biopollution. We have tested the method using four different well-studied areas within the Baltic Sea (brackish to freshwater environments) for two different times, 20 years apart. Further developments of the scheme may be needed to cover some specific cases and taxonomic groups according to their life history.     

New satellite derived sea ice motion tracks Arctic contamination

Sea ice has been reported to contain contaminants from atmospheric and nearshore sediment resuspension processes. In this study successive passive microwave images from the 85.5 GHz channels on the Special Sensor Microwave Imager (SSM/I) were merged with drifting buoy trajectories from the International Arctic Buoy Program to compute Arctic sea ice motion in the Russian Arctic between 1988 and 1994. Smooth daily motion fields were averaged to prepare monthly maps making it possible to compute the 7-year mean and mean seasonal ice motions as well as principal components of directional variability of sea ice motion for the entire Arctic and surrounding basins. These mean motion vectors are used to simulate the advection of contaminants deposited on or contained within the sea ice and subsequently transported into the Arctic Ocean in order to predict both their mean trajectories and dispersal over time. The 3-year displacement of contaminants from a number of Russian sites and one American site display various behaviours from substantial displacement and dispersal to almost no movement. This computational procedure could be applied to realtime SSM/I and ice buoy data to provide detailed, all-weather, vector motion maps of ice circulation to predict the path and dispersal of any new substance introduced to the sea ice and transported into the Arctic or Antarctic ocean surface.     

Characterization of transboundary POP contamination in aquatic ecosystems of Pearl River delta

During the past two decades, the rapid development of the Pearl River delta leads to substantial accumulation of various toxic organic compounds. This study aims to give a preliminary characterization of the existing state of contamination in this region and to provide insight into the possible fate of persistent organic pollutants (POPs) in this estuary. The available data on POPs in water, river, estuarine sediments, soil, and marine organisms within the Pearl River delta are compiled. It is shown that it may lead to transboundary POP pollution problems at both Hong Kong and Macau Special Administration Regions located at the downstream end of the region. It is noted that the levels of DDTs and HCHs in various environmental media are at alerting levels and that fresh DDT might still be applied illegally within the region. A systematic research is required to determine both the temporal and spatial variations of all POPs in various carrying media of the Pearl River delta as a whole.     

Indicators of sediment and biotic mercury contamination in a southern New England estuary

Total mercury (Hg) and methylmercury (MeHg) were analyzed in near surface sediments (0-2 cm) and biota (zooplankton, macro-invertebrates, finfish) collected from Narragansett Bay (Rhode Island/Massachusetts, USA) and adjacent embayments and tidal rivers. Spatial patterns in sediment contamination were governed by the high affinity of Hg for total organic carbon (TOC). Sediment MeHg and percent MeHg were also inversely related to summer bottom water dissolved oxygen (DO) concentrations, presumably due to the increased activity of methylating bacteria. For biota, Hg accumulation was influenced by inter-specific habitat preferences and trophic structure, and sediments with high TOC and percent silt-clay composition limited mercury bioavailability. Moreover, hypoxic bottom water limited Hg bioaccumulation, which is possibly mediated by a reduction in biotic foraging, and thus, dietary uptake of mercury. Finally, most biota demonstrated a significant positive relationship between tissue and TOC-normalized sediment Hg, but relationships were much weaker or absent for sediment MeHg. These results have important implications for the utility of estuarine biota as subjects for mercury monitoring programs.     

Effects of heavy metal contamination on the macrobenthic fauna in estuaries: the case of the Seine estuary

Heavy metal contamination levels are generally higher in estuaries than in the open sea. Some estuaries, the Seine estuary for example, have particularly high pollution levels of metals, yet continue to support a very high benthic biomass and remain quite productive. Measurements of sediment contamination are highly variable due to diverse chemical analysis methods, sediments origin and sources of contaminants found in the estuaries. Salinity appears to be the principal factor controlling contaminant distribution in the sediment and the overlying and/or interstitial waters; it also affects the bioavailability of contaminants in estuarine sediments. Of course, the response to contaminants varies greatly among species and assemblages. Trace metals explain only a small part of the variation in benthic community structure. Some species, such as the shrimp Crangon crangon, appears vulnerable to metal pollution, while other species, such as Scrobicularia plana, are able to tolerate quite high levels of cadmium in their tissue. This paper demonstrates the wide variability of benthic responses to contamination, which is probably due to the high spatio-temporal heterogeneity of the estuary. To reduce the problems due the heterogeneity and variability observed to date in the available results, it will be necessary to encourage integrated estuarine studies, in which sedimentologists, chemists, and biologists work together on the same campaigns at the same sites.     

Transboundary aspect of assessing the impact of NPPs under construction on aquatic ecosystems: Case study of the Baltiiskaya NPP

The environmental feasibility assessment of the construction and operation of nuclear power stations in near-border areas must take into account the requirements of the international and European environmental legislation. For the study on environment feasibility assessment of the Baltic NPP to meet the international standards, the following steps were taken: the content and the application practice of UNECE Convention on Environmental Impact Assessment in a Transboundary Context (Espoo) to NPP substantiation were analyzed and compared with the Russian procedure of environmental impact assessment (EIA); water quality standards for water bodies used for fishery and the approaches to assessing the damage to aquatic bioresources in Russia, Lithuania (EU), and Belarus were compared. A transboundary network for monitoring aquatic ecosystems was developed in the zone of potential influence of the Baltic NPP, and a permanent mathematical model was developed and used to forecast the effect of the anticipated water discharge from the station on the hydrodynamic, chemical, and temperature regime of the Neman R., whose results were used to forecast the impact of water intake and discharge facilities of the Baltic NPP on the food base and migration character of ichthyofauna.     

Assessment of bottom sediment contamination in acidified Karelian lakes

The physicochemical, toxicological, and teratological properties of bottom sediments in Karelian lakes (Vuontelenjarvi, Suojarvi, Venderskoe, and Chuchjarvi) and Kondopoga Bay of Lake Onega are studied. Bioassay results testify to a high toxicity of bottom sediments in heavily acidified lakes (with the water pH of 5.5 and lower).     

The amphipod Orchomenella pinguis – A potential bioindicator for contamination in the Arctic

Indigenous organisms can be used as bioindicators for effects of contaminants, but no such bioindicator has been established for Arctic areas. Orchomenella pinguis is a benthic amphipod, ubiquitous in the Arctic and can be found in high numbers. We collected O. pinguis at sites with different contamination levels. Population characteristics (body length distribution, average dry weight and amphipod organic content) were related to sediment contaminant concentrations, in order to identify suitable endpoints for using this species as a bioindicator. We show that O. pinguis was prevalent in both clean and contaminated areas, easy to sample and that its population characteristics could be linked to both contamination and sediment organic content. We suggest that O. pinguis is a suitable bioindicator for the Arctic, but that endpoints such as reproductive effects and phenotypic and genotypic responses are needed together with population characteristics to assess impacts of contamination.     

Assessment of the typology and the trophic status of two Mediterranean lake ecosystems in Northwestern Greece

The objective of this study is the assessment of the typology and the trophic relevant water quality parameters in two Mediterranean lakes (Lake Ziros and Lake Kastoria) under the view of the WFD. Lake types were identified based on characteristics specified in Annex II of the WFD, while trophic indexes (OECD, TSI Carlson) were used in order to assess their trophic status. A modified TSI index appropriate for warmer lakes was also applied. According to our results, Lake Kastoria is classified as eutrophic lake with a tendency to hypertrophication while Lake Ziros is a mesotrophic ecosystem with clear signals of eutrophication. Both ecosystems are considered “at risk” of not fulfilling the WFD environmental objectives due to the existence of certain anthropogenic pressures.     

Apparent discrepancy in contamination history of a sub-tropical estuary evaluated through 210Pb profile and chronostratigraphical markers

Zn and Cd concentrations, stable lead isotopes and ²¹⁰Pb-derived chronology were determined in a sediment core sampled at Sepetiba Bay (South-eastern Brazil). During the last decades, the bay’s watershed has been modified by the increase of industrial activities and human interventions. In particular, Zn and Cd ore treatment plants were built near the coast in 1960 and 1970, respectively, and water has been diverted from the adjacent Paraíba do Sul River watershed since 1950. The core collected at shallow depth near the industrial area exhibits four successive events: (i) at 50 cm depth, a change in the ²⁰⁶Pb/²⁰⁷Pb ratio from about 1.162 to more than 1.18 might be the result of the São Francisco Channel opening and water diversion from Paraíba do Sul river; (ii) at 40 cm depth, Zn concentration starts to increase (up to 0.8 mg g⁻¹) (iii) above 30 cm depth, relatively high Cd concentrations (up to 1.6 μg g⁻¹) are observed and (iv) at 16 cm depth, change in unsupported ²¹⁰Pb slope is probably related to a waste dam built to prevent strong metal contamination in the bay. Sediment accumulation rates evaluated by Zn and Cd profiles used as time-markers are higher than those calculated from ²¹⁰Pb-based chronology models. Using the constant initial concentration (CIC) model both events are supposed to date back to about 1884 and 1902, respectively, while using the constant rate of supply (CRS) model it shifts to about 1925 and 1935. Such discrepancies are probably assigned to the fact that these models do not take into account site-specific local sedimentation dynamics. In the study area, particles deposition seems to be controlled by enrichment with unsupported ²¹⁰Pb transported by runoff from a mangrove flat bank. Chronology derived from a model that assumes an exponential increase of the initial ²¹⁰Pb activity fits well with the estimated rates obtained from historical events.     

Assessment of heavy metal contamination of roadside soils in Southwest China

Topsoil (0–20 cm) samples were collected from the edge of roads to the locations about 200 m off the roads along the four roads with different transportation periods in October 2005. Total concentrations of As, Cd, Cr, Cu, Ni, Pb and Zn were determined using the inductively coupled plasma atomic absorption spectrometry in order to assess and compare road transportation pollution. Results showed that with the exception of As, Cu and Pb, the average concentrations of heavy metals were generally, higher than the regional elemental background values. Most soil samples were moderately or highly polluted by Cd or Ni, but the contamination index (P _i ) values for As, Pb and Zn were lower than other heavy metals in all sites. Among the four roads, heavy metal pollution was heavier for Dali Road due to longer transportation periods, while low or no contamination could be observed for the other roads. However, the integrated contamination index (P _c ) values showed a generally low contamination or no contamination level for all soil samples in this region, followed by the order of Dali Road > Dabao Highway > Road 320 > Sixiao Highway. The same pollution source of these heavy metals was found using factor analysis.     

Assessment of the historical trace metal contamination of sediments in the Elizabeth River, Virginia

Two sediment cores (Southern Branch, PC-1, and Western Branch, WB-2) were taken from the highly industrialized Elizabeth River, Virginia. The concentrations of trace metals cadmium, cobalt, chromium, copper, nickel, lead and zinc, major elements iron, manganese and aluminum, organic carbon content and the specific surface area of the sediments were determined in each of the cores. Down-core variations in metals varied significantly in each core with maximum contamination events occurring at different times in different portions of the river. In PC-1, maximum metal concentrations were seen after the appearance of (137)Cs. In contrast, the highest levels in WB-2 occurred well before the appearance of (137)Cs. Although stricter environmental regulations have caused a decrease in metal concentrations since the 1980s, the concentrations in the surface sediments of many trace metals were elevated to levels 2-5 times higher than the levels at the bottom of the cores in both the Southern and Western Branches of the river.     

Anthropogenic Processes in Continental Waters of Arctic Regions and Criteria for Their Assessment

Development features of anthropogenic processes in continental waters in the Arctic Basin, including eutrophication, acidification, and toxic pollution, are characterized. The major changes in the ecosystems and the formation periods of hazardous situations are demonstrated. Criteria are suggested for the diagnostics of unfavorable processes and the need of more stringent water quality standards is substantiated.     

Assessment of organotin contamination in marine sediments and biota from the Gulf and adjacent region

Butyltin species were measured in sediments from coastal locations in the Gulf and Gulf of Oman. Both butyltin and phenyltin species were measured in biota samples from four countries in this region. With tributyltin (TBT) concentrations up to 60 ngSng(-1), some sediments could be classified as contaminated (i.e. TBT>1.3 ngSng(-1)), namely Dukhan (Qatar), the BAPCO industrial complex and Askar (Bahrain), and Hilf and the Raysut Port Area (Oman). Higher concentrations of total butyltins were found in oysters relative to fish, but ranging from 6.5 to 488 ngSng(-1) dry weight they are nonetheless relatively low. Diphenyltin and triphenyltin were found in some fish and bivalves from the Gulf, but not in biota from the Gulf of Oman. The environmental levels of organotin species are comparatively low by global standards and pose no immediate public health problems.     

Assessment of metal contamination in surface sediments from Zhelin Bay,the South China Sea

Metals and biogenic elements were analyzed from surface sediments collected from Zhelin Bay in the South China Sea in December 2008. The high concentrations of TOC, TN and BSi indicate the high nutrient level and diatom productivity in Zhelin Bay. The concentrations of metals were generally far lower than the effects-range-low (ERL) values that define pollutant levels. Enrichment factors (EF) and geoaccumulation indices (I_geo) suggest there are pollution levels of Cd, Cu and Zn at some stations. As, Cu, and Pb are potentially biotoxic in some stations. Correlation and principal component analyses indicate that most of the metals primarily originate from natural sources, and from maricultural activities as well. Mariculture contributes considerable Cd and Cu contamination. As and Pb comes primarily from combustion of gasoline and diesel fuel by ships.     

Assessment of tributyltin contamination in a shipyard area using a mussel transplantation approach

Mussels (Mytilus galloprovincialis) were transplanted to seven stations around a large shipyard for 126 days to evaluate tributyltin (TBT) contamination. Although the application of TBT-based paints to ships is totally banned in Korea, butyltin compounds were found to accumulate in mussels following transplantation. Concentrations of TBT and total butyltins in transplanted mussels near the shipyard were in the range of 40–350 ng Sn/g and 74–530 ng Sn/g on a dry weight basis, respectively. Obviously, low TBT concentrations (6.0–53 ng Sn/g dw) were determined in mussels at four stations outside the shipyard. A negative gradient of TBT concentrations and TBT portion to total butyltin concentrations were found in both the surface water and transplanted mussels according to distance from the shipyard. In addition, TBT concentrations in surface water and transplanted mussels showed significant correlation (r² = 0.71; p < 0.001). These results indicate that the shipyard still releases fresh TBT into surrounding waters even after TBT regulation in Korea, and mussel transplantation is useful in evaluating TBT contamination in shipyard area.