The effects of heating on low-temperature susceptibility and hysteresis properties of basalts

The variation of the low-field susceptibility of basalts down to liquid-nitrogen temperature always falls into one of three types that depend on the composition and grain size of the titanomagnetite grains present. Group 1 basalts contain predominantly unoxidised, multidomain homogeneous titanomagnetites having x 0.3. Group 2 basalts contain predominantly titanomagnetite grains with many exsolved ilmenite lamallae that subdivide the grains so that they act similarly to single domains. Group 3 basalts contain predominantly multidomain magnetite or magnetite-rich titanomagnetite having x 0.15. After repeated heating to 615°C, the group 1 basalts gradually oxidise above 300°C to produce the characteristics of group 2 basalts, owing to the exsolution of ilmenite. On the other hand, both group 2 and 3 basalts are stable to oxidation until at least 500°C. They are therefore the most useful material for palaeointensity studies.     

Secondary remanent magnetization carried by magnetite inclusions in silicates: a comparative study of unremagnetized and remagnetized granites

Magnetic carriers in remagnetized Cretaceous granitic rocks of northeast Japan were studied using paleomagnetism, rock magnetism, optical microscopy and scanning electron microscopy (SEM) by comparison with unremagnetized granitic rocks. The natural remanent magnetization (NRM) of the remagnetized rocks is strong (0.3–1.7 A/m) and shows a northwesterly direction with moderate inclination (NW remanence), whereas the unremagnetized rocks preserve weak NRM (<0.5 A/m) with westerly and shallow direction (W remanence). Although thermal demagnetization shows that both NRMs are carried by magnetite, the remagnetized rocks reveal a higher coercivity with respect to alternating field demagnetization (20 mT相似文献   

Characteristic magnetic properties of titanomagnetites in continental igneous rocks

Curie temperatures, hysteresis, alternating field properties and anhysteretic and ordinary susceptibilities have been used to characterize the titanomagnetites in a large collection of continental granites, diorites, syenites, anorthosites, gabbros, diabases and basalts. Low-Curie-point titanomagnetites or titanomaghemites were found only in basalts. In all shallow and deep-seated intrusive rocks, the predominant magnetic phase was nearly-titanium-free titanomagnetite with a Curie point of 520–580°C. Most felsic plutonic rocks owed their magnetic properties to coarse, discrete titanomagnetites with truly multidomain properties. Many mafic plutonic rocks (anorthosites, gabbros, norites) displayed bimodal magnetic properties, strong-field properties being due to the discrete titanomagnetites and weak-field properties being due to fine magnetite inclusions in deuterically altered silicates. The Lowrie-Fuller test and the anhysteretic induction curve were the most diagnostic tests of this bimodal behaviour. Grain-size variation within a single diabase dike or sill had a strong expression in all magnetic properties, except H_R/H_c and the Lowrie-Fuller test. On the other hand, the Lowrie-Fuller test was a sensitive indicator of changes in “effective” grain size in basalts due to the subdivision of grains by ilmenite lamellae.     

Magnetic properties of basalts and geodynamics of the rift zone in the southern Red Sea

Magnetic properties of young rift basalts in the southern Red Sea are studied in detail. It is found that basalt samples dredged in the rift zone are characterized by a large spread in magnetic parameters. The magnetic properties of the basalts are shown to indicate a complex evolution of the Red Sea rift zone. Titanomagnetite grains of the basalts are mostly affected by single-phase oxidation processes and have preserved paleomagnetic information. However, basalts discovered near the rift axis yield evidence of multiphase oxidation of titanomagnetite grains, which is untypical of young oceanic basalts. These basalts have high Curie points and large values of the natural remanent magnetization and Koenigsberger parameter. The corresponding samples were taken in nontransform zones where rocks have experienced the action of significant tectonic forces and, moreover, anomalous geomagnetic field patterns correlate with the position of these zones. Using the magnetic properties of the basalts, the northern segment of the rift axis is relocated.     

Calibration of magnetic granulometric trends in oceanic basalts

The validity of magnetic granulometric estimates relies heavily on the ability to distinguish ultrafine particles from coarser grains. For example, populations with dominantly superparamagnetic (SP) or multidomain (MD) grains both are characterized by low remanence and coercivity, and distinguishing these endmembers may provide valuable clues to the origin of magnetization in the intervening stable single domain (SD) size range. The natural grain size variations associated with variable cooling rates in submarine lavas provide a rare opportunity for examining progressive changes in average magnetic grain size, from SP–SD mixtures in submarine basaltic glass to SD–MD mixtures in flow interiors. Based on microanalysis and rock magnetic measurements on pillow basalt samples dredged from the flanks of the Mid-Atlantic Ridge (ages <1 Ma to 70 Ma), a model of preferential dissolution with time of the finest-grained titanomagnetites has recently been suggested as the major process contributing to long-term temporal changes in remanent intensity of mid-ocean ridge basalts. We evaluated the local and long-term temporal trends in effective magnetic grain size predicted by this model using hysteresis data from a large number of submarine basalt samples which span a range of ages from 0 to 122 Ma. Specimens were systematically taken along transects perpendicular to the chilled margin of each sample. The large number of data (750 loops) and the inferred progressive change in grain size approaching the chilled margin allow recognition of mixing trends between MD and SD grains and between SD and SP grains on a Day-plot. These trends in hysteresis parameters are crucial to resolving the inherent, but frequently overlooked, ambiguity in inferring grain size from hysteresis parameters. We illustrate that two additional rock magnetic tests (warming of a low-temperature isothermal remanence and hysteresis loop shapes) often used to address these ambiguities are inconclusive, requiring some independent knowledge of whether SP or MD grains are likely to be present. Even with a considerably larger data set the substantial intrasample variability in oceanic basalts precludes recognition of any systematic trend in magnetic grain size with age.     

The ground-state conductivity profile of the core-mantle system of the Earth

The ground state of the core-mantle conductivity system is defined as a step function transition from the constant non-zero conductivity of the core to zero conductivity in the mantle. This ground state is reached by letting the thickness of a transition region Δ → 0, where Δ appears as a parameter in the model conductivity of the system. By a transformation of the equation governing the behavior of the electrostatic potential φ, it is shown that the function V(x) = (1/σ^1/2)(d²σ^1/2/dx²) acts as a potential barrier in the quantum mechanical sense, and that for certain conductivity profiles σ(x), where x is the usual Cartesian coordinate, the electrostatic potential is screened out in regions where σ(x) → 0 as Δ → 0. Consequently, E = −φ also vanishes in these regions. The results generalize to the time-dependent case. Conditions that the conductivity function σ(x) must satisfy to qualify as the ground-state conductivity are defined and an example is provided.     

Results of optical, thermomagnetic and electron microprobe analyses of titanomagnetite grains

This paper presents results of a study of titanomagnetite from specimens of ten different rock units. The rock units comprise trachytes, basalts, ignimbrites, nephelinites, olivine melanephelinites and welded tuffs from Kenya, with ages ranging from recent to Precambrian. The correlations of the stability index with opaque petrology and with thermomagnetic analyses of the titanomagnetite and titanomaghemite bearing specimens appear to be significant. Electron microprobe analyses of the titanomagnetite grains indicate a high percentage of “impurities” in the low stability index specimens and elevation of the Curie point in the high stability index specimens.     

Effect of citrate-bicarbonate-dithionite treatment on fine-grained magnetite and maghemite

Mineral magnetic properties of soils and parent materials have been interpreted in terms of paleoclimate and rates of soil formation but it is important to understand which minerals contribute to the mineral magnetic signal. Citrate-bicarbonate-dithionite (CBD) treatment has been used to determine the amounts of fine-grained, often pedogenic, ferrimagnetic minerals relative to coarse-grained, often inherited, magnetic minerals. However, questions have been raised about the effect of particle size on the efficacy of CBD in dissolving magnetite and maghemite grains. In this paper we use magnetic susceptibility and its frequency dependence, and the low-temperature behavior of a saturation isothermal remanent magnetization, to track the dissolution of carefully sized magnetite grains. We found that the standard CBD procedure dissolves fine magnetite particles (ca. < 1 μm) but leaves larger particles (ca. > 1 μm) essentially intact. Thin oxidized coatings, presumably maghemite, are also dissolved by the CBD procedure. These results support previous interpretations that the CBD procedure can be used to distinguish between pedogenic and lithogenic magnetic grains, assuming that most pedogenic magnetic grains are sufficiently small (ca. < 1 μm) and most lithogenic magnetic grains are sufficiently large (ca. > 1 μm). These results also show that the standard procedure is too harsh to differentiate between 1 μm grains of magnetite and maghemite. A modified CBD extraction that uses half as much dithionite reduces the magnetic susceptibility of 1 μm magnetite grains by only 10%. This method may be useful in distinguishing between magnetite and maghemite grains in this size range.     

Correlation of magnetic properties with Δ(Sr) of igneous rocks from the northeast Pacific and Gulf of California

The magnetic properties of basalts and diabases recovered under Legs 63 and 64 of the Deep Sea Drilling Project are summarized. They are first correlated with the measured grain sizes of the opaque minerals and the overall alteration states of the rocks, the latter measured by conventional chemical parameters such as water content, total volatiles content, and Fe₂O₃/FeO ratio. It is shown, however, that the decrease in ⁸⁷Sr/⁸⁶Sr upon leaching (Δ(^87/86Sr)) is perhaps the best quantifier of the overall alteration state of the whole rocks as well as of the degree of low-temperature oxidation suffered by the titanomagnetites. It is well correlated with Curie-point variations caused by changes in the Fe³⁺/Fe²⁺ ratio.     

Alteration induced changes of magnetic fabric as exemplified by dykes of the Koolau volcanic range

We studied 93 samples from 8 basaltic dykes of the Koolau volcanic range on the island of Oahu,Hawaii,USA,to determine the influence of hydrothermal alteration on the magnetic fabric as determined by anisotropy of magnetic susceptibility (AMS) measurements. Rock magnetic as well as microscopic investigations show that only ≈25% of the samples have retained their original magnetomineralogical composition of unaltered Ti-poor titanomagnetite. The remaining samples have undergone hydrothermal alteration which transformed the primary magnetic phase into a granular intergrowth of titanomagnetite, titanomaghemite and hematite. In both sample groups,this magnetic phase occurs in coarse (tens of microns),irregularly shaped particles as well as interstitial clusters of smaller (< 5 μm) grains. Our investigations show that hydrothermal alteration does change the bulk susceptibility and the degree of anisotropy but not the directions of principal axes of the AMS ellipsoid which are predominantly corresponding to normal magnetic fabric. The stability of AMS directions, regardless of the degree of alteration, points towards the model of distribution anisotropy as the controlling factor for the observed magnetic fabric.     

Low-temperature oxidation of synthetic Al- and Mg-doped titanomagnetites

Al- and Mg-doped titanomagnetites were synthesized at 1300°C using the gas-mixing technique. A composition, representative of average natural titanomagnetites in ocean floor basalts, was sought.

The samples were ball-milled in acetone to average grain sizes of 0.5 μm and 5 μm and the material was then oxidised, in air, at temperatures below 300°C. This procedure formed titanomaghemite, a cation-deficient titanomagnetite.

Low-temperature oxidation is described as the diffusion of Fe-ions out of the spinel lattice and the process is observed to be distinctly dependent upon grain size.     

Theoretical analysis of thermomagnetic properties, low-temperature hysteresis and domain structure of titanomagnetites

Magnetic hysteresis of coarse-grained titanomagnetites at room temperature is characterised by low coercive force, low relative remanence, and a high ratio of coercivity of remanence to coercive force. These properties are generally interpreted in terms of multidomain structure. At low temperatures, however, ulvöspinel-rich compositions exhibit hysteresis properties similar to those of single-domain assemblages, and on this basis Radhakrishnamurty and Deutsch have proposed an alternative interpretation of the domain structure of titanomagnetites having x 0.3 in terms of a mixture of single-domain and superparamagnetic particles. Low apparent Curie temperatures are attributed to the effects of thermal agitation above the blocking temperature.

We have examined theoretically the effects of thermal agitation on the low- and high-field thermomagnetic curves and find that observed Curie temperatures in general represent an intrinsic property of the magnetic mineral present, rather than reflecting thermal agitation. The high coercive force and relative remanence at low temperatures for titanomagnetites having x > 0.5 can be explained on the basis of the interaction of domain walls with crystal defects when the large increases in magnetocrystalline anisotropy and magnetostriction with decreasing temperature are taken into account. We discuss the evidence for the existence of domain walls in coarse-grained ulvöspinel-rich titanomagnetites and conclude that multidomain structure is well established.

It is also shown that fine titanomagnetite grains may have more than one blocking temperature. In any temperature interval for which superparamagnetic grains are present they will disproportionately influence susceptibility and low-field hysteresis.     

Low temperature magnetic properties of basalts containing near ~TM30 titanomagnetite

The paper is devoted to studying the mineral composition and magnetic properties, mainly at the cryogenic temperatures, of the Middle–Late Devonian basalts from North Timan. The magnetic minerals in these basalts are dominated by intermediate-composition titanomagnetites (TM25–TM30) which demonstrate unusual magnetic properties in a wide temperature range. At room temperature, a low coercive force coexists with relatively high M_rs/M_s ratios. At cryogenic temperatures, the dependences of magnetic susceptibility on the temperature and frequency of the applied field are characteristic of this titanomagnetite composition, whereas the remanent saturation magnetization acquired at 2 K is destroyed at significantly lower temperatures compared to the synthetic analogs. The obtained results again highlight the necessity of studying the low-temperature properties of titanomagnetite samples with a controlled composition and grain size.     

Magmatic and phreatomagmatic volcanic activity at Mt. Takahe, West Antarctica, based on tephra layers in the Byrd ice core and field observations at Mt. Takahe

The morphology, grain size characteristics and composition of ash particles in 30 ka to 150 ka tephra layers from the Byrd ice core were examined to characterize the eruptions which produced them and to test the suggestion that they were erupted from Mt. Takahe, a shield volcano in Marie Byrd Land, West Antarctica. Volcanic deposits at Mt. Takahe were examined for evidence of recent activity which could correlate with the tephra layers in the ice core.Coarse- and fine-ash layers have been recognized in the Byrd ice core. The coarse-ash layers have a higher mass concentration than the fine-ash layers and are characterized by fresh glass shards > 50 μm diameter, many containing elongate pipe vesicles. The fine-ash layers have a lower mass concentration and contain a greater variety of particles, typically < 20 μm diameter. Many of these particles are aggregate grains composed of glass and crystal fragments showing S and Cl surface alteration. The grain-size distributions of the coarse and fine-ash layers overlap, in part because of the aggregate nature of grains in the fine-ash layers. The coarse-ash layers are interpreted as having formed by magmatic eruption whereas the fine-ash layers are believed to be hydrovolcanic in origin.Mt. Takahe is the favored source for the tephra because: (a) chemical analyses of samples from the volcano are distinctive, being peralkaline trachyte, and similar in composition to the analyzed tephra; (b) Mt. Takahe is a young volcano (< 0.3 Ma); (c) pyroclastic deposits on Mt. Takahe indicate styles of eruption similar to that inferred for the ice core tephra; and (d) Mt. Takahe is only about 350 km from the calculated site of tephra deposition.A speculative eruptive history for Mt. Takahe is established by combining observations from Mt. Takahe and the Byrd ice core tephra. Initial eruptions at Mt. Takahe were subglacial and then graded into alternating subaerial and subglacial activity. The tephra suggest alternating subaerial magmatic and hydrovolcanic eruptions from 30 to 20 ka B.P., followed by a sustained period of hydrovolcanic eruptions from 20 to 14 ka B.P., which peaked at 18 ka B.P.     

Magnetic domain observations of nucleation processes in natural pyrrhotite and titanomagnetite

Magnetic domain patterns have been observed on particles of natural pyrrhotite and titanomagnetite undergoing hysteresis. These observations indicate that hysteresis properties are governed by two distinct mechanisms: (1) wall-pinning and (2) nucleation of reverse domains. Particles which are dominated by wall-pinning spontaneously nucleate reverse domains in saturation remanence (J_rs). The coercivity of such grains is determined by the presence of potential wells encountered by the wall in its traverse across the grain. However, many pseudosingle-domain particles (PSD) between 5 and 30 μm in diameter do not nucleate reverse domains in J_rs, but remain as saturated single-domains. These particles require a reverse field H_n to nucleate domain walls. When H_n is sufficiently large, the nucleating field controls magnetization reversal by driving the wall across the particle in a single Barkhausen jump, and the muscopic coercivity is nucleation-dominated.

The proportion P (w=0) of particles of a given size d which fail to nucleate walls in J_rs is found to be given by A exp(−Bd^1/2), where A and B are experimentally determined constants. The nucleation field H_n in pyrrhotite is observed to increase with decreasing grain size, exceeding 500 Oe in 5 μm particles.

The difficulty with which reverse domains are nucleated subsequent to saturation may thus provide a mechanism for achieving the high values of J_rs/J_s and coercive force observed in fine, pseudosingle-domain particles.     

The microstructure and domain structure of multiphase oxidized titanomagnetites

An estimation of the domain state of 15 natural and synthetic samples containing both homogeneous and multiphase oxidized titanomagnetites was made by means of J_rs/J_s and H_cr/H_c ratios, the Lowrie-Fuller criterion, the thermomagnetic criterion, F criterion and the Preisach diagram. The J_rs/J_s and H_cr/H_c ratios and the Lowrie-Fuller criterion are shown to be not sufficiently informative for a determination of the domain state. In the case where the lamellae thickness became thinner than 0.1 μm, titanomagnetite grains demonstrate multidomain behaviour independent of the size of the interlamellar regions (cells). If the lamellae become thicker than 0.1 μm the domain state depends on the size of the cells. Single-domain behaviour is obtained for a cell size less than 1 × 1 μm; in agreement with the results of others, larger cells have multidomain properties.     

Complete remagnetization of some Permian dykes from western Norway induced during burial/uplift

Stable paleomagnetic directions in four basaltic dykes and in some associated Caledonian metamorphic rocks define high-latitude, Mesozoic paleomagnetic pole positions which are not compatible with the K---Ar age of 250 My determined for the dykes. A monotonic increase of 40% occurs in the potassium content of samples taken across a dyke 32 cm wide. This is accompanied by only a 1–2% variation in the K---Ar age of the samples, suggesting the absence of any significant level of initial argon. Titanomagnetite grains having bulk compositions around x = 0.6 have suffered extensive low-temperature alteration, forming assemblages of ferri-rutile granules in a matrix of pure magnetite. The complete remagnetisation of both the dykes and the associated country rocks is probably an expression of a VRM acquired at elevated temperatures (150–500°C) at the emplacement depth of the dykes. A stable remanent magnetisation was locked-in during uplift of the area, probably related to the Kimmerian basin development in the adjacent North Sea and the epeirogenic uplift of western Fennoscandia.     

Magnetic properties of sediments in the Bay of Bengal and the Andaman Sea: impact of rapid North Atlantic Ocean climatic events on the strength of the Indian monsoon

The results of a high-resolution mineral magnetic study combined with major element geochemistry analysis, oxygen isotopes and ¹⁴C AMS stratigraphy are reported for deep-sea gravity cores MD77-169 and MD77-180 located in the Andaman Sea and the Bay of Bengal, respectively. Core MD77-169 covers the last 280 kyr and core MD77-180 covers the last 160 kyr. In both cores, rock magnetic parameters indicate that the magnetic assemblage is dominated by pseudo-single domain titanomagnetite grains, with grain-size variations following a strong 23 kyr periodicity. Smaller magnetic grain sizes are observed during periods characterized by a strong summer monsoon. In addition, in core MD77-180, we observe a correlation between magnetic grain size and a chemical index of alteration. This suggests that these magnetic grain-size changes are related to chemical weathering driven by summer monsoon rainfall. A comparison of the GISP2 ice core isotopic record and the magnetic grain-size record of the Bay of Bengal shows that rapid temperature variations documented in the ice core (Dansgaard–Oeschger cycles and Heinrich events), during the last glacial period are also present in the magnetic grain-size record. Heinrich events and cold stadial events are characterized by relatively large magnetic grain sizes. Furthermore, Heinrich events are characterized by lower values of the chemical index of alteration implying a lower degree of chemical weathering related to significantly drier conditions on the continent. We suggest that rapid cold events of the North Atlantic (Heinrich events) during the last glacial stages are characterized by a weaker summer monsoon rainfall over the Himalaya via an atmospheric teleconnection.     

Surface exposure dating of young basalts (1–200 ka) in the San Francisco volcanic field (Arizona,USA) using cosmogenic 3He and 21Ne

K–Ar ages of young basalts (<500 ka) are often higher than the actual eruption age, due to low potassium contents and the frequent presence of excess Ar in olivine and pyroxene phenocrysts. Geological studies in the San Francisco and Uinkaret volcanic fields in Arizona have documented the presence of excess ⁴⁰Ar and have concluded that K–Ar ages of young basalts in these fields tend to be inaccurate. This new study in the San Francisco volcanic field presents ³He_c and ²¹Ne_c ages yielded by olivine and pyroxene collected from three Pleistocene basalt flows – the South Sheba (∼190 ka), SP (∼70 ka), and Doney Mountain (∼67 ka) lava flows, – and from one Holocene basalt, the Bonito Lava Flow (∼1.4 ka) at Sunset Crater. These data indicate that, in two of three cases, ⁴⁰Ar/³⁹Ar and K–Ar ages of the young basalts agree well with cosmic-ray surface exposure ages of the same lava flow, thus suggesting that excess ⁴⁰Ar is not always a problem in young basalt flows in the San Francisco volcanic field. The exposure age of the Bonito lava flow agrees within uncertainty with dendrochronological and archeological age determinations. K–Ar and cosmogenic ³He and ²¹Ne ages from the SP flow are in agreement and much older than the OSL age (5.5–6 ka) reported for this lava flow. Furthermore, if the non-cosmogenic ages are assumed to be accurate, the subsequent calculated production rates at South Sheba and SP flow sample sites agree well with values in the literature.     

Variation of magnetic directions within pillow basalts

Relative directions of magnetization have been measured within individual pillow basalts collected from the Atlantic Ocean and Caribbean Sea. The angle between the magnetic directions was determined and is referred to as the directional difference. Although one pillow contained a directional difference of 44°, the remaining ten pillows had differences less than 14°. The maximum orientation and measurement error was 7°. Dispersion on the scale found in these fine-grained pillow basalts would not appreciably affect the magnetic anomaly pattern on the sea floor. We detected no reversals of magnetization despite the sometimes large and variable low-temperature oxidation. Comparison of directions within homogeneous segments of the pillow, viscous remanent magnetization (VRM) acquisition experiments, and alternating field (AF) demagnetization indicate a large portion of the dispersion was due to the acquisition of a viscous component in the larger grained, less oxidized portion of the pillows. Evidence from one variably weathered pillow suggests that extreme low-temperature oxidation may lead to the acquisition of a secondary component with high coercivities (20–80 mT). We could not determine whether this was a chemical remanent magnetization (CRM) or a VRM acquired by single domain grains near the superparamagnetic threshold. Hysteresis properties confirmed by microscopic examination indicated that the magnetic grain size in all the pillows was at least as small as pseudo-single domain.