铁法盆地西部矿区16^#煤聚积环境背景及聚煤特征

铁法盆地西部矿区１６＾＃煤是在冲积扇前网结河－湖缘三角液－湖泊环境组合背景上大面积泥炭沼泽化而形成的。聚煤环境有湖缘三角洲平原泥炭沼泽，湖滨泥炭沼泽、冲积扇前湿地泥炭沼泽和网结河湿地泥炭沼泽。其中，湖滨和湖缘三角洲平原泥炭治泽垂向叠加地段构成北部富煤带的主体，冲积庐前湿地泥炭沼泽形成了南部富煤带的主体。     

我国贫营养泥炭沉积的物质组成、理化特性及水化学环境分析

泥炭藓是贫营养泥炭类型中的建群植物，由于生态水环境主要靠大气降水补给，少受其他水源的污染，可自然反映古降水、古湿度的情况，所以是古气候研究最理想的纤维素同位素测试材料之一。因此，弄清我国贫营养泥炭沉积的物质组成及水化学环境特征，具有重要意义。笔根据多年来的国内外野外调查，结合收集到的资料，以东北大小兴安岭山地的泥炭辞贫营养泥炭地为基础，与美国、加拿大以及俄罗斯等国家的同类泥炭地相比较，对我国贫营养泥炭沉积的物质组成、理化特性及水化学环境做了系统的分析研究，并就此讨论了湿地保护中的一些实际问题，以及相应的对策。     

长白山圆池的泥炭沼泽及生态旅游

长白山圆也周围分布着各种类型的泥炭沼泽，衍生着由低位泥炭向中位泥炭、高位泥炭的发育过程，是进行科学研究和地学旅游的风景胜地。本文从生态学的意义上提出了在保护中开发和在开发中保护的建议。     

华北山西组D^2煤层煤相特征及泥炭沼泽的发展规律

通过煤相研究，揭示了形成Ｄ＾２煤层的成煤泥炭沼泽，首先起源于平塑，大同和霍西等地的水域泥炭沼泽化，在垂向扩展和水平扩展过程中，若干孤立的源地泥岩沼泽联结成片，形成巨大的泥炭沼泽体之发展演化规律，及从北往南，山前湖泊泥炭沼泽（湖沼）、溢水洼地泥炭沼泽（浅沼）、泻湖海湾泥炭沼泽（盐沼）和滨海平原泥炭沼泽之分布特征。     

泥炭沼泽有机地球化学研究进展

近几十年来，国内外泥炭沼泽地球化学研究取得了一系列重要进展，特别是在脂类化合物和稳定同位素等方面。泥炭沼泽是一个良好的地质档案，泥炭纤维素碳、氢和氧同位素组成和比值是环境变化的综合参数，沉积脂类化合物含有反映有机质母源先质的骨架结构，这些标志物高分辨率地记录了全新世以来古气候、古植被和古环境的演变信息，在当今全球变化研究中占有相当重要的地位。本文综述了泥炭沼泽地球化学研究进展，侧重于泥炭沼泽脂类化合物和稳定同位素等标志物的地球化学研究现状和发展趋势；侧重论述了研究技术的发展、定性说明到定量分析的过渡、研究精度的提高及存在的问题，分析了这些分子标志物与植被演替、气候变迁和环境变化间的对应关系，指出了我国在该方面的薄弱之处以及需加强的领域。     

南华北晚石炭世风暴事件及其对聚煤作用的影响

应用煤地质学和沉积学相结合的理论和方法，揭示了南华北晚石炭世地层中存在的异地煤。根据煤层顶、底板和煤层本身的特征以及煤层在区域上分布的特点，可以看出，这些异地煤的形成，是由于热带－亚热带频繁的风暴作用侵蚀滨海泥炭沼泽的结果。强烈的风暴作用，不仅通过风暴上升流侵蚀改造泥炭层，而且还通过风暴回流将部分泥炭物质搬运到浅海环境再沉积，从而在泥炭沼泽内和浅海海底两种场所形成两种不同类型的异地煤。     

浅钻技术在若尔盖地区泥炭调查中的应用

泥炭是一种具有多种用途的宝贵自然资源,泥炭中的有机碳储量是研究全球碳库变化及碳循环过程的重要参数。由于泥炭多分布于沼泽中,且泥炭松软含水量大的特性,对于泥炭深度的调查、获取用于测试泥炭原状样品的质量不高,导致泥炭碳储量评价仍存在不确定性和偏差。笔者等在典型泥炭形成地若尔盖沼泽湿地地区,开展了浅钻泥炭调查取样工作,通过在泥炭斑块边缘及中心两种不同沼泽湿地地层开展的试验,验证了轻便钻机在难进入的沼泽湿地的适应性,配套的振动冲击工艺可高质量的获得无扰动的泥炭样品,同时查明了泥炭层的厚度。通过试验初步探索了采用轻便钻机配套振动冲击钻进工艺进行泥炭调查取样的有效性。浅层取样钻探作为泥炭调查取样的一种直接有效的技术手段,可以有效地提高泥炭调查效率和精度,为准确评价泥炭储量数据提供可靠的钻探技术服务支撑。     

浅钻技术在若尔盖地区泥炭调查中的应用

泥炭是一种具有多种用途的宝贵自然资源,泥炭中的有机碳储量是研究全球碳库变化及碳循环过程的重要参数。由于泥炭多分布于沼泽中,且泥炭松软含水量大的特性,对于泥炭深度的调查、获取用于测试泥炭原状样品的质量不高,导致泥炭碳储量评价仍存在不确定性和偏差。笔者等在典型泥炭形成地若尔盖沼泽湿地地区,开展了浅钻泥炭调查取样工作,通过在泥炭斑块边缘及中心两种不同沼泽湿地地层开展的试验,验证了轻便钻机在难进入的沼泽湿地的适应性,配套的振动冲击工艺可高质量的获得无扰动的泥炭样品,同时查明了泥炭层的厚度。通过试验初步探索了采用轻便钻机配套振动冲击钻进工艺进行泥炭调查取样的有效性。浅层取样钻探作为泥炭调查取样的一种直接有效的技术手段,可以有效地提高泥炭调查效率和精度,为准确评价泥炭储量数据提供可靠的钻探技术服务支撑。     

泥炭沉积与气候变化的泥炭记录

气候变化是影响全球泥炭沼泽分布和演化的最重要的因子之一,而泥炭地由于自身的特点成为过去气候变化的良好地质档案。在介绍泥炭沉积过程及不同类型的泥炭沼泽的发育特点基础上,从过去气候变化的常用泥炭记录和泥炭地碳记录等方面总结了国际上针对泥炭地反演气候变化研究的若干重要进展,重点剖析了泥炭腐殖化度、植物残体、有壳变形虫、生物标志化合物、同位素和孢粉等泥炭地过去气候变化重建的代用指标的适用范围和优缺点,同时也分析了泥炭地碳累积和碳循环等热点研究问题。最后从泥炭地作为过去气候变化的记录档案、泥炭地对现在气候变化的响应与反馈及在泥炭地进行现场气候变化监测与实验等方面对泥炭地与气候变化研究进行了展望。     

贵州浅表泥炭地层^14C年代测定

汇总贵州地区浅埋和裸露泥炭地层的１４Ｃ年代数据；通过解析三个典型剖面的１４Ｃ年代测定结果，探讨１４Ｃ时间标尺的可信程度；认为贵州晚第四纪泥炭地层发育的时间特点是：黔西北高原自４万年以来，黔中高原自２万年以来一直有泥炭积累，其中以全新世中期发育的泥炭分布最为广泛。     

论江苏若干矿产资源开发利用的新方向

江苏泥炭大多数为低有机质分解较强的低位泥炭，适于制作肥料或制成腐肥使用；江苏硅质原料丰富，一种以硅为主的化肥——硅肥正日益显示其重要性；湖泊淤泥具有颗粒微细、含砂量少、可塑性高、结合力强、干燥敏感性好和收缩率较大等特点，是生产空心砖的最佳原料；高家边组泥页岩和坟头组底部细粉砂质泥岩及泥质粉砂岩是良好的陶粒原料、砖瓦、陶瓷建材以及水泥用粘土质原料；利用矿泉水与茶的结合能够生产出高、中、低多效应的复合型新产品。上述尚未被利用或利用程度不够的矿产资源有着广泛的开发利用前景。     

有机质含量及组分对泥炭土物理力学性质影响

富含有机物质是泥炭土工程性质不良的主要原因。不同有机质含量及组分的泥炭土,其物理力学性质差异很大。为明确有机质含量的影响,对数十组不同有机质含量无定形泥炭土试样进行一系列室内试验,系统分析了物理、变形、强度及渗透性随有机质含量的变化规律;为比较有机质组分不同导致的工程性质差异,将以上无定形泥炭土物理力学指标与纤维泥炭土试验数据进行系统分析。结果表明:无定形泥炭土基本物理力学指标与有机质含量间有一定的线性关系,其中,初始孔隙比（e₀）、天然含水率（w₀）、液塑限（w_L、w_p）、黏聚力（c）随有机质含量增加线性增大,比重（G_s）、固结系数（C_v）和内摩擦角（φ）随有机质含量增大而减小。相较无定形泥炭土,纤维泥炭土比重小、含水率大、孔隙比大。抗剪强度方面,无定形泥炭土黏聚力随有机质含量增大而增大,较纤维泥炭土略高;内摩擦角随有机质含量增大而有下降趋势,约为纤维泥炭土的1/5～1/14。渗透性方面,无定形泥炭土的初始渗透系数（k_v0）及渗透指数（C_k）随有机质含量增大而减小,且普遍小于纤维泥炭土。     

The association of uranium with organic matter in Holocene peat: An experimental leaching study

Uraniferous peat was sampled from surface layers of a Holocene U deposit in northeastern Washington State. Dried, sized, and homogenized peat that contained5980 ±307 ppm U was subjected to a variety of leaching conditions to determine the nature and strength of U-organic bonding in recently accumulated organic matter. The results complement previous experimental studies of U uptake on peat and suggest some natural or anthropogenic disturbances that are favorable for remobilizing U. The fraction of U leached in 24 h experiments at 25°C ranged from 0 to 95%. The most effective leach solutions contained anions capable of forming stable dissolved complexes with uranyl (UO₂⁺²) cation. These included H₂SO₄ (pH= 1.5) and concentrated (0.01M) solutions of sodium bicarbonate-carbonate (pH= 7.0–10.0), or sodium pyrophosphate (pH= 10). Effective leaching by carbonate and pyrophosphate in the absence of added oxidant, and the insignificant effect of added oxidant (as pressurized O₂) strongly suggest that U is initially fixed on organic matter as an oxidized U(VI) species. Uranium is more strongly bound than some other polyvalent cations, based on its resistance to exchange in the presence of large excesses of dissolved Ca²⁺ and Cu²⁺. Measurements of the rate of U leaching indicate faster rates in acid solution compared to carbonate solution, and are consisten with simultaneous attack of sites with different affinities for U. Sulfuric acid appears a good choice for commercial extraction of U from mined peat.In situ disturbances such as overliming of peat soils, addition of fertilizers containing pyrophosphate, or incursions of natural carbonate-rich waters could produce significant remobilization of U, and possibly compromise the quality of local domestic water supplies.     

城市污水处理厂污泥利用现状及潜在环境问题

根据国家环保总局要求,在2010年前全国主要城市的污水处理率要达到70%,这将使我国的水环境得到明显改善,另一方面也带来了污泥的处置和利用问题.污泥是一种优质的有机肥料,有选择地控制使用,既可满足作物生长对养分的需要,又可培育土壤.符合污泥固废“减量化”和“资源化”的处置要求.     

Formation Environment of Main Brown Coal Seam in Xi-2 Minefield of Shengli Coalfield Based on Coal Ash Phase Analysis

The formation environment of the main coal seam in Shengli coal mine is analyzed, and the effect of coal ash parameters on the coal-forming environment is mainly discussed according to gray component parameters combined with other coal quality test analysis data. Results show that the hydrodynamic conditions of the main coal during coal accumulation have a general pattern of strong northeast and weak southwest, and lakeside swamp is generally in the retrograde process from south to north. The No.5 coal seam is a water entry cycle, and the No.5_lower coal is a water withdrawal cycle. The No.6 thick coal seam is formed in the peat swamp environment where the water is shallow and the groundwater activity is weak. The input of terrestrial debris material was most abundant in the formation period of No.5_lower coal, followed by No.5 coal, and that in No.6 coal is the least. Vertically, the peat swamp environment changed from weak reduction to weak oxidation to strong reducing environment. The ash yield was low to high to low from bottom to top. The organic sulfur is the main type of sulfur in the main coal seam. The weaker the hydrodynamic condition, the higher the organic sulfur content in the reduction environment, while lower organic sulfur content in the oxidation environment. The peat swamp water of No.5_lower coal is medium alkaline, and the peat swamp water of No.5 and No. 6 coals is weakly alkaline or acidic.     

Anomalous gold contents in brown coals and peat in the south-eastern region of the Western-Siberian platform

One hundred twenty-two samples of Jurassic and Paleogene brown coals and 1254 peat samples from the south-eastern region of the Western-Siberian platform were analyzed for gold by the neutron-activation method. Mean content of Au in Jurassic coals is 30 ± 8 ppb, in Paleogene coals is 10.6 ± 4.8 ppb, and in peat is 6 ± 1.4 ppb. Concentrations of gold as high as 4.4 ppm were found in coal ash and 0.48 ppm in the peat ash. Coal beds with anomalous gold contents were found at Western-Siberian platform for the first time.Negative correlation between gold and ash yield in coals and peat and highest gold concentrations were found in low-ash and ultra-low-ash coals and peat. Primarily this is due to gold's association with organic matter.For the investigation of mode of occurrence of Au in peat the bitumen, water-soluble and high-hydrolyzed substances, humic acids, cellulose and lignin were extracted from it. It was determined that in peat about 95% of gold is combined with organic matter. Forty to sixty percent of Au is contained in humic acids and the same content is in lignin. Bitumens, water-soluble and high-hydrolyzed substances contain no more than 1% of general gold quantity in peat.The conditions of accumulation of high gold concentrations were considered. The authors suggest that Au accumulation in peat and brown coals and the connection between anomalous gold concentrations and organic matter in low-ash coals and peat can explain a biogenic–sorption mechanism of Au accumulation. The sources of formation of Au high concentration were various Au–Sb, Au–Ag Au–As–Sb deposits that are abundant in the Southern and South-Eastern peripheries of the coal basin.     

Lead contamination of fluvial sediments in an eroding blanket peat catchment

Over the last few years there has been growing concern over the mobilisation of anthropogenically derived, atmospherically deposited Pb from upland blanket peat soils to receiving surface waters. The near-surface layer of blanket peat soils of the Peak District, southern Pennines, UK, is severely contaminated with high concentrations of Pb. Erosion of peat soils in this upland area may be releasing large quantities of previously deposited Pb into the fluvial system. Samples of fluvial sediments (suspended, floodplain, streamside fan, trash-line and channel bed) were collected from a severely eroding blanket peat catchment in the Peak District in order to investigate Pb contamination of fluvial sediments, to determine the mechanism for fluvial Pb transport and to determine if erosion of contaminated peat soils in the catchment is releasing Pb into the fluvial system. Concentrations of Pb associated with fluvial sediments are considerably higher than those in the catchment geology, but not as high as those in peat soils in the catchment. Intra- and inter-storm variability in the Pb content of suspended sediments can be explained by differences in organic matter content of these sediments and differences in erosion processes operating within the catchment. High Pb concentrations are associated with suspended sediments that have a high organic matter content. The results of this study suggest that organic matter is the principle vector for sediment-associated Pb in the fluvial system. Erosion of contaminated peat soils in the Peak District is releasing Pb into the fluvial system. The extent to which this is a problem in other peatland environments is an area requiring further research.     

Salt Marshes on Substrate Enriched in Organic Matter: The Case of Ombrogenic Atlantic Salt Marshes

Ombrogenic Atlantic salt marshes are defined as areas of halophytic, terrestrial vegetation which are periodically flooded by the tide and have a predominant underlying organic substrate comprising of wood and/or Sphagnum peat that formed under freshwater conditions. The objective of this study was to determine to what extent salt marsh plant ecology and, specifically, vegetation composition and zonation relate to this underlying substrate of organic matter (peat). A vegetation survey was carried out on nine salt marshes, three on peat substrate and two on sand, mud and sand/mud, respectively. In parallel, key edaphic variables were measured including pH, conductivity, organic content, moisture content and nutrients: ammonium, nitrate and phosphorus. Salt marshes on peat substrate are distinct. Ammonium content was twice the maximum reported in other salt marsh studies, while the vegetation composition of salt marshes on peat substrate was significantly different from that of other salt marshes. Salt marshes on peat substrate were found to be higher in species diversity and richness and characterised by a predominantly forb and rush community. However, some common salt marsh species, such as Atriplex portulacoides and Spartina anglica were absent from salt marshes on peat. Ordination analysis revealed that zonation was primarily associated with conductivity on peat substrates. In contrast, moisture plays a greater role in zonation within non-peat salt marshes. The findings confirm that the high organic matter content of ombrogenic Atlantic salt marshes is associated with distinct vegetation composition.