Persistence of a Groundwater Contaminant Plume after Hydraulic Source Containment at a Chlorinated‐Solvent Contaminated Site

The objective of this study was to characterize the behavior of a groundwater contaminant (trichloroethene, TCE) plume after implementation of a source‐containment operation at a site in Arizona. The plume resides in a quasi‐three‐layer system comprising a sand/gravel unit bounded on the top and bottom by relatively thick silty clayey layers. The system was monitored for 60 months beginning at start‐up in 2007 to measure the change in contaminant concentrations within the plume, the change in plume area, the mass of the contaminant removed, and the integrated contaminant mass discharge (CMD). The concentrations of TCE in groundwater pumped from the plume extraction wells have declined significantly over the course of operation, as have concentrations for groundwater sampled from 40 monitoring wells located within the plume. The total CMD associated with operation of the plume extraction wells peaked at 0.23 kg/d, decreased significantly within 1 year, and thereafter began an asymptotic decline to a current value of approximately 0.03 kg/d. Despite an 87% reduction in contaminant mass and a comparable 87% reduction in CMD for the plume, the spatial area encompassed by the plume has decreased by only approximately 50%. This is much less than would be anticipated based on ideal flushing and mass‐removal behavior. Simulations produced with a simplified three‐dimensional (3D) numerical model matched reasonably well to the measured data. The results of the study suggest that permeability heterogeneity, back diffusion, hydraulic factors associated with the specific well field system, and residual discharge from the source zone are all contributing to the observed persistence of the plume, as well as the asymptotic behavior currently observed for mass removal and for the reduction in CMD.     

CDSN网月带VLP地震数据解调

中国数字地震台网自１９８６年１０月起，记录了大量的超长周围地震数据，这些ＶＬＰ地震数据以网月带记录形式存放。网月带中，数据格式有ＡＣＳⅡ码、ＢＣＤ码和二进制数据３种形式。本文提出了ＣＤＳＮ网月带ＶＬＰ地震数据的解调方法，分析了网月带的数据结构，输出ＶＬＰ地震数据文件。     

Magnetic and Ionospheric Effects of a Meteoroid Plume

This paper is concerned with the study of the possibility of products of a meteoroid explosion in the atmosphere (meteoroid plume) to reach ionospheric altitudes. It has been shown that, in the case of meter-sized or larger space bodies entering the atmosphere, the plume is able to reach the lower ionosphere. The plume can be one of the sources of the formation of nacreous and noctilucent clouds. The aerosols ejected by the plume to lower ionospheric altitudes can lead to the formation of dust plasma, significantly changing the electrodynamic properties of the medium. The motion of the plume with a velocity of ~1 km/s is accompanied by the generation of a ballistic shock with a radius of 1–10 km. The relative excess pressure in the shock front can cause relative disturbances in the electron content at the altitudes of D, E, and F1 layers by ~10–100%. The geomagnetic effect of the plume and ballistic shock can reach ~1–10 nT.     

Pyrite Oxidation Halts Migration of a Phosphorus Plume

We have established a monitoring record of phosphate (PO₄³⁻) migration in the Long Point, ON campground septic system plume that now spans 26 years. Previously, at year 16 (2006), a P plume 16 m in length was documented and provided a good fit with an analytical advection dispersion model when a P migration velocity of 0.8 m/yr was used (retardation factor of 37) and when P behaved in an otherwise conservative manner (sorption only). However, between years 16 and 26 (2016), the P plume length expanded by only 2 m (0.2 m/yr) and increased in depth by only 0.5 m. The zone of abrupt P depletion at depth occurs close to the zone where SO₄²⁻ concentrations increase in response to NO₃⁻ oxidation of pyrite. Scanning electron microscope images of sand grains from the nose of the P plume reveal abundant authigenic mineral coatings of considerable thickness (∼5 to 20 μm), with Fe as the dominant cation and containing 1 to 3 wt % P. This evidence suggests that P is now being attenuated along a reaction front that coincides with the zone where pyrite oxidation is occurring. P migration may now be controlled by the rate of migration of the pyrite oxidation front and this is several times slower than the previously indicated rate in the shallower, sorption-controlled portion of the plume. Monitoring at Long Point has demonstrated the danger of embracing an overly simplistic conceptual model when attempting to predict wastewater P migration in groundwater and also highlights the unique insight provided by a long-term monitoring record.     

Plume rise and spread in a linearly stratified environment

We present analyses of plume rise into a linearly stratified environment, either with or without a uniform horizontal flow. In the case of a still ambient, we collate results on plume spreading height and volume flux, enabling the speed of the spreading intrusion in the buoyancy-inertia regime to be expressed in terms of the fundamental parameters of plume buoyancy flux and ambient buoyancy frequency. A theoretical expression for the final volume flux emanating from the plume-rise region, in terms of maximum rise height, is also derived. Hence it is shown that the ratio of the intrusion radius to the maximum rise height is a simple function of ambient buoyancy frequency and time. In the case of a wind, we analyse the theoretical model for a rising plume to obtain predictions for the downwind volume flux, and subsequent lateral spread, in the limits of strong and weak wind. We identify a regime of very weak wind, which may be modelled as a passive advection of plume flow in the still case as a first approximation. Numerical solutions of a general model are presented which show that it predicts a peak in entrainment, and hence volume-flux growth, in the case of intermediate wind strength. We verify the crosswind model predictions of lateral spread, upwind penetration and entrainment by comparison with large-eddy simulations.     

Rapid Cleanup of a Perchlorate Plume from Fireworks

Perchlorate was detected in a municipal wellfield in Evart, Michigan in April 2015. Perchlorate concentrations were detected initially in six of the City's wells at concentrations ranging up to 20 μg/L. An investigation to identify the source determined that the perchlorate was from fireworks launched during the annual 4th of July show held at the fairgrounds located upgradient from the wellfield. The use of approximately 600 kg of fireworks during the annual display resulted in an annual loading of approximately 4 kg of perchlorate to groundwater. An aggressive groundwater extraction system began operation in June 2016 to restore water quality in the affected aquifer, and the 2016 fireworks display was relocated to a location outside the capture zone of the water supply wells. Within 18 months average perchlorate concentrations in the water supply wells had been reduced to about 0.6 μg/L. The extraction system continued to operate through the end of 2019, by which time the average perchlorate concentrations in the water supply wells were reduced to 0.2 μg/L. In 2019, approximately 0.4 kg of perchlorate were removed from the aquifer, about one-half of the amount removed in 2018, reflecting the slow leaching of perchlorate of fireworks residuals from vadose zone soils.     

西南天山地区长时间尺度重力场变化特征

利用西南天山地区2007至2016年共20期流动重力观测资料,分析该地区一年、两年尺度和累积重力变化特征,探讨区域构造活动、地震孕育发生与重力场变化特征的关系。结果表明:西南天山地区迈丹断裂带、柯坪塔格断裂带等大型断裂带影响该区域的重力场分布,使该地区较多出现NEE向的重力梯度分布特征。塔里木盆地和西南天山重力变化有明显的差异性,2个不同的构造块体在重力分布上呈现相对反向变化,塔里木盆地和西南天山地区的重力变化界线不在塔里木盆地边缘的山前地带,而较多出现在柯坪推覆体中北缘地带。西南天山地区的地震大部分发生在重力正值变化区域的零线附近,震中及附近地区重力异常分布与构造特征有较好的一致性。在活动断裂带附近同时出现重力变化零线以及与断裂走向一致的重力变化高梯度带,可作为中短期前兆异常。     

Oxygen and Ethene Biostimulation for a Persistent Dilute Vinyl Chloride Plume

Contamination of groundwater with chlorinated ethenes is common and represents a threat to drinking water sources. Standard anaerobic bioremediation methods for the highly chlorinated ethenes PCE and TCE are not always effective in promoting complete degradation. In these cases, the target contaminants are degraded to the daughter products DCE and/or vinyl chloride. This creates an additional health risk, as vinyl chloride is even more toxic and carcinogenic than its precursors. New treatment modalities are needed to deal with this widespread environmental problem. We describe successful bioremediation of a large, migrating, dilute vinyl chloride plume in Massachusetts with an aerobic biostimulation treatment approach utilizing both oxygen and ethene. Initial microcosm studies showed that adding ethene under aerobic conditions stimulated the rapid degradation of VC in site groundwater. Deployment of a full‐scale treatment system resulted in plume migration cutoff and nearly complete elimination of above‐standard VC concentrations.