Sub‐arctic Holocene climatic and oceanographic variability in Stjernsund,northern Norway: evidence from benthic foraminifera and stable isotopes

A high‐resolution record, covering 9.3–0.2 ka BP, from the sub‐arctic Stjernsund (70°N) was studied for benthic foraminiferal faunas and stable isotopes, revealing three informally named main phases during the Holocene. The Early‐ to Mid‐Holocene (9.3–5.0 ka BP) was characterized by the strong influence of the North Atlantic Current (NAC), which prevented the reflection of the Holocene Climatic Optimum (HCO) in the bottom‐water temperature. During the Mid‐Holocene Transition (5.0–2.5 ka BP), a turnover of benthic foraminiferal faunas occurred, Atlantic Water species decreased while Arctic‐Polar species increased, and the oxygen isotope record showed larger fluctuations. Those variations correspond to a period of global climate change, to spatially more heterogeneous benthic foraminiferal faunas in the Nordic Seas region, and to regionally diverging terrestrial temperatures. The Cool Late Holocene (2.5–0.2 ka BP) was characterized by increased abundances of Arctic‐Polar species and a steady cooling trend reflected in the oxygen isotopes. In this period, our record differs considerably from those on the SW Barents Sea shelf and locations farther south. Therefore, we argue that regional atmospheric cooling triggered the late Holocene cooling trend. Several cold episodes centred at ～8.3, ～7.8, ～6.5, ～4.9, ～3.9 and ～3.3 ka BP were identified from the benthic foraminiferal faunas and the δ¹⁸O record, which correlated with marine and atmospherically driven proxy records. This suggests that short‐term cold events may result from reduced heat advection via the NAC or from colder air temperatures.     

Palaeoceanographic changes in the northern Barents Sea during the last 16 000 years – new constraints on the last deglaciation of the Svalbard–Barents Sea Ice Sheet

The sediment core NP05‐71GC, retrieved from 360 m water depth south of Kvitøya, northwestern Barents Sea, was investigated for the distribution of benthic and planktic foraminifera, stable isotopes and sedimentological parameters to reconstruct palaeoceanographic changes and the growth and retreat of the Svalbard–Barents Sea Ice Sheet during the last ～16 000 years. The purpose is to gain better insight into the timing and variability of ocean circulation, climatic changes and ice‐sheet behaviour during the deglaciation and the Holocene. The results show that glaciomarine sedimentation commenced c. 16 000 a BP, indicating that the ice sheet had retreated from its maximum position at the shelf edge around Svalbard before that time. A strong subsurface influx of Atlantic‐derived bottom water occurred from 14 600 a BP during the Bølling and Allerød interstadials and lasted until the onset of the Younger Dryas cooling. In the Younger Dryas cold interval, the sea surface was covered by near‐permanent sea ice. The early Holocene, 11 700–11 000 a BP, was influenced by meltwater, followed by a strong inflow of highly saline and chilled Atlantic Water until c. 8600 a BP. From 8600 to 7600 a BP, faunal and isotopic evidence indicates cooling and a weaker flow of the Atlantic Water followed by a stronger influence of Atlantic Water until c. 6000 a BP. Thereafter, the environment generally deteriorated. Our results imply that (i) the deglaciation occurred earlier in this area than previously thought, and (ii) the Younger Dryas ice sheet was smaller than indicated by previous reconstructions.     

Sea-level estimates during the last deglaciation based on δO and accelerator mass spectrometry C ages measured in Globigerina bulloides

Coupled measurements of δ¹⁸O and accelerator mass spectrometry (AMS) ¹⁴C in a particular species of planktonic foraminifera may be used to calculate sea-level estimates for the last deglaciation. Of critical importance for this type of study is a knowledge of the seasonality of foraminiferal growth, which can be provided by δ¹⁸O measurements of modern shells (core tops, plankton tows). Isotopic (δ¹⁸O, AMS-¹⁴C dating) and faunal records (transfer function sea surface temperature) were obtained from two cores in the North Atlantic at about 37°N. The locations were chosen to obtain high sedimentation rate records removed from the major ice-melt discharge areas of the last deglaciation. Based upon Globigerina bulloides data, four δ¹⁸O-based sea-level estimates were calculated: −67 ± 7 m at 12,200 yr B.P. and −24 ± 8 m at about 8200 yr B.P. for core SU 81-18; −83 ± 10 m at 12,200 yr B.P. and −13 ± 11 m at about 8500 yr B.P. for core SU 81-14. Using a second working hypothesis concerning the seasonability of G. bulloides growth, it is suggested that the sea-level rose by about 40 m during the millennium which followed 14,500 yr B.P.     

Differential response at the seafloor during Palaeocene and Eocene ocean warming events at Walvis Ridge,Atlantic Ocean (ODP Site 1262)

The Latest Danian Event (LDE, c. 62.1 Ma) is an early Palaeogene hyperthermal or transient (<200 ka) ocean warming event. We present the first deep‐sea benthic foraminiferal faunal record to study deep‐sea biotic changes together with new benthic (Nuttallides truempyi) stable isotope data from Walvis Ridge Site 1262 (Atlantic Ocean) to evaluate whether the LDE was controlled by similar processes as the minor early Eocene hyperthermals. The spacing of the double negative δ¹³C and δ¹⁸O excursion and the slope of the δ¹⁸O–δ¹³C regression are comparable, strongly suggesting a similar orbital control and pacing of eccentricity maxima as well as a rather homogeneous carbon pool. However, in contrast to early Eocene hyperthermals, the LDE exhibits a remarkable stability of the benthic foraminiferal fauna. This lack of benthic response could be related to the absence of threshold‐related circulation changes or better pre‐adaptation to elevated deep‐sea temperatures, as the LDE was superimposed on a cooling trend, in contrast to early Eocene warming.     

Late Pleistocene-Holocene benthic foraminiferal distribution in the southwestern Barents Sea: Paleoenvironmental implications

A benthic foraminiferal stratigraphy from the southwestern Barents Sea indicates that foraminifera were reworked and deposited in tills during the last glaciation. The deglaciation occurred in three main steps: (1) Presence of an Elphidium excavatum dominated assemblage > 13,300–12,000 B.P. (2), Nonion barleeanum dominated assemblage 12,000–10,000 B.P., and (3) establishment of a fauna similar to the modern one at 10,000 B.P. The transition from step 1 to step 2 indicates that the deglacial warming/incipient intrusion of Atlantic water was delayed in the southwestern Barents Sea compared with the western margin of the Norwegian shelf by approximately 1,000 years. Corrosive bottom water that formed during the last deglaciation causing carbonate dissolution may be due to poor ventilation or increased biogenic production accompanying the inferred oceanographic changes.     

Holocene paleoceanography of the northern Barents Sea and variations of the northward heat transport by the Atlantic Ocean

Foraminiferal assemblages were studied in northern Barents Sea core ASV 880 along with oxygen and carbon isotope measurements in planktonic (N. pachyderma sin.) and benthic (E clavatum) species. AMS C‐14 measurements performed on molluscs Yoldiella spp. show that this core provides a detailed and undisturbed record of Holocene climatic changes over the last 10000 calendar years. Surface and deep waters were very cold (<0°C) at the beginning of the Holocene. C. reniforme dominated the highly diverse benthic foraminiferal assemblage. From 10 to 7.8 cal. ka BP, a warming trend culminated in a temperature optimum, which developed between 7.8 and 6.8 cal. ka BP. During this optimum, the input of Atlantic water to the Barents Sea reached its maximum. The Atlantic water mass invaded the whole Franz Victoria Trough and was present from subsurface to the bottom. No bottom water, which would form through rejection of brine during winter, was present at the core depth (388 m). The water stratification was therefore greatly reduced as compared to the present. An increase in percentage of I. helenae/norcrossi points to long seasonal ice‐free conditions. The temperature optimum ended rather abruptly, with the return of cold polar waters into the trough within a few centuries. This was accompanied by a dramatic reduction of the abundance of C. reniforme. During the upper Holocene, the more opportunistic species E. clavatum became progressively dominant and the water column was more stratified. Deep water in Franz Victoria Trough contained a significant amount of cold Barents Sea bottom water as it does today, while subsurface water warmed progressively until about 3.7 cal. ka BP and reached temperatures similar to those of today. These long‐term climatic changes were cut by several cold events of short duration, in particular one in the middle of the temperature optimum and another, which coincides most probably with the 8.2 ka BP cold event. Both long‐ and short‐term climatic changes in the Barents Sea are associated with changes in the flow of Atlantic waters and the oceanic conveyor belt.     

Holocene hydrological reconstructions from stable isotopes and paleolimnology, Cordillera Real, Bolivia

Multiproxy analyses of sediment cores from Lago Taypi Chaka Kkota (LTCK) Cordillera Real, Bolivia, provide a record of drier conditions following late Pleistocene deglaciation culminating in pronounced aridity between 6.2 and 2.3 ka B.P. Today LTCK is a glacial-fed lake that is relatively insensitive to changes in P–E because it is largely buffered from dry season draw-down through the year-round supply of glacial meltwater. This was not the case during the middle to late Holocene when glaciers were absent from the watershed. Lake-water δ¹⁸O values inferred from δ¹⁸O analysis of sediment cellulose range from −12.9 to −5.3‰ and average −8.7‰ between 6.2 and 2.3 ka B.P. Modern lake-water δ¹⁸O from LTCK averages −14.8‰ which is compatible with the δ¹⁸O_lw value of −14.3‰ for the surface sediment cellulose. Analyses of δ¹⁸O from modern surface waters in 23 lakes that span the range from glacial-fed to closed basin vary from −16.6 to −2.5‰. This approximates the magnitude of the down-core shift in δ¹⁸O_lw values in LTCK during the middle to late Holocene from −12.9 to −5.3‰. Strong paleohydrologic change during the middle Holocene is also evident in diatom assemblages that consist of shallow-water, non-glacial periphytic taxa and bulk organic δ¹³C and δ¹⁵N that show increases likely resulting from degradation of lacustrine organic matter periodically exposed to subaerial conditions. Neoglaciation began after 2.3 ka B.P. as indicated by changes in the composition of the sediments, lower δ¹⁸O values, and a return to diatom assemblages characteristic of the glacial sediments that formed during the Late Pleistocene. Collectively, these data indicate that the past 2.3 ka B.P. have been the wettest interval during the Holocene. Millennial-scale shifts in the paleohydrologic record of LTCK during the early to middle Holocene conform to other regional paleoclimatic time-series, including Lake Titicaca and Nevado Sajama, and may be driven by insolation and resultant changes in atmospheric circulation and moisture supply. In contrast, an apparent 1200-year lag in the onset of wetter conditions at LTCK (2.3 ka B.P.) compared to Lake Titicaca (3.5 ka B.P.) provides evidence for variable sub-regional hydrologic response to climate change during the middle to late Holocene.     

12,000-Year, preliminary results of the stable nitrogen and carbon isotope record from the Empakai Crater lake sediments, Northern Tanzania

The stable isotope compositions of organic carbon and nitrogen, the contents of organic carbon and nitrogen and C/N ratios for two cores recovered from the Empakai Crater at water depths of 11 and 20 m are used to document climatic changes in northern Tanzania. Eight ¹⁴C AMS dates determined on total organic matter (OM) indicate that the sedimentation rate in this lake is about 30 cm/ka for the late Pleistocene to early Holocene period. There are differences in the δ¹³C values of organic carbon between the two cores, which may be a result of differences in location from the present shoreline and of different water depths. In the deeper-water core the δ¹³C values show a general downcore decrease to the base of the core with a sharp change to lower values of about 4‰ at a depth of 100 cm (8.7 ka). The general trend of downcore decrease in ¹³C values can be attributed either to a systematic decrease in the relative proportion of C₄ type of OM, owing to an increase in precipitation and change in vegetation cover from grassland to forest, or to utilization of isotopically enriched carbon during photosynthesis. The δ¹⁵N values show a general downcore increase with again a sharp change of about 5‰ to lower values at about 8.7 ka. A sharp change of about 5‰ and 4‰ to more depleted values at a depth of 100 cm of both ¹⁵N and ¹³C, respectively, suggests either hiatus or abrupt change in climatic condition from wetter conditions to drier conditions. There is enhanced preservation of OM in the lake as depicted by high mean values of organic carbon and nitrogen at both sites.     

Lower Eocene carbonate-cemented “chimney” structures (Varna, Bulgaria) — Control of seepage rates on their formation and stable isotopic signature

The genesis of Lower Eocene calcite-cemented columns, “pisoid”-covered structures and horizontal interbeds, clustered in dispersed outcrops in the Pobiti Kamani area (Varna, Bulgaria) is related to fossil processes of hydrocarbon migration. Field observations, petrography and stable isotope geochemistry of the cemented structures and associated early-diagenetic veins, revealed that varying seepage rates of a single, warm hydrocarbon-bearing fluid, probably ascending along active faults, controlled the type of structure formed and its geochemical signature. Slow seepage allowed methane to oxidize within the sediment under ambient seafloor conditions (δ¹⁸O = − 1 ± 0.5‰ V-PDB), explaining columns' depleted δ¹³C ratios of − 43‰. Increasing seepage rates caused methane to emanate into the water column (δ¹³C = − 8‰) and raised precipitation temperatures (δ¹⁸O = − 8‰). Calcite-cemented conduits formed and upward migrating fluids also affected interbed cementation. Even higher-energy fluid flow and temperatures likely controlled the formation of “pisoids”, whereby sediment was whirled up and cemented.     

Depositional environments and chronology of Late Weichselian glaciation and deglaciation in the central North Sea

Graham, A.G.C., Lonergan, L. & Stoker, M.S. 2010: Depositional environments and chronology of Late Weichselian glaciation and deglaciation in the central North Sea. Boreas, Vol. 39, pp. 471–491. 10.1111/j.1502‐3885.2010.00144.x. ISSN 0300‐9483. Geological constraints on ice‐sheet deglaciation are essential for improving the modelling of ice masses and understanding their potential for future change. Here, we present a detailed interpretation of depositional environments from a new 30‐m‐long borehole in the central North Sea, with the aim of improving constraints on the history of the marine Late Pleistocene British–Fennoscandian Ice Sheet. Seven units characterize a sequence of compacted and distorted glaciomarine diamictons, which are overlain by interbedded glaciomarine diamictons and soft, bedded to homogeneous marine muds. Through correlation of borehole and 2D/3D seismic observations, we identify three palaeoregimes. These are: a period of advance and ice‐sheet overriding; a phase of deglaciation; and a phase of postglacial glaciomarine‐to‐marine sedimentation. Deformed subglacial sediments correlate with a buried suite of streamlined subglacial bedforms, and indicate overriding by the SE–NW‐flowing Witch Ground ice stream. AMS ¹⁴C dating confirms ice‐stream activity and extensive glaciation of the North Sea during the Last Glacial Maximum, between c. 30 and 16.2 ¹⁴C ka BP. Sediments overlying the ice‐compacted deposits have been reworked, but can be used to constrain initial deglaciation to no later than 16.2 ¹⁴C ka BP. A re‐advance of British ice during the last deglaciation, dated at 13.9 ¹⁴C ka BP, delivered ice‐proximal deposits to the core site and deposited glaciomarine sediments rapidly during the subsequent retreat. A transition to more temperate marine conditions is clear in lithostratigraphic and seismic records, marked by a regionally pervasive iceberg‐ploughmarked erosion surface. The iceberg discharges that formed this horizon are dated to between 13.9 and 12 ¹⁴C ka BP, and may correspond to oscillating ice‐sheet margins during final, dynamic ice‐sheet decay.     

Carbon isotope chemostratigraphy of a Precambrian/Cambrian boundary section in the Three Gorge area, South China: Prominent global-scale isotope excursions just before the Cambrian Explosion

Carbon isotope chemostratigraphy has been used for worldwide correlation of Precambrian/Cambrian (Pc/C) boundary sections, and has elucidated significant change of the carbon cycle during the rapid diversification of skeletal metazoa (i.e. the Cambrian Explosion). Nevertheless, the standard δ¹³C curve of the Early Cambrian has been poorly established mainly due to the lack of a continuous stratigraphic record. Here we report high-resolution δ¹³C chemostratigraphy of a drill core sample across the Pc/C boundary in the Three Gorge area, South China. This section extends from an uppermost Ediacaran dolostone (Dengying Fm.), through a lowermost Early Cambrian muddy limestone (Yanjiahe Fm.) to a middle Early Cambrian calcareous black shale (Shuijingtuo Fm.). As a result, we have identified two positive and two negative isotope excursions within this interval. Near the Pc/C boundary, the δ¹³C_carb increases moderately from 0 to + 2‰ (positive excursion 1: P1), and then drops dramatically down to − 7‰ (negative excursion 1: N1). Subsequently, the δ¹³C_carb increases continuously up to about + 5‰ at the upper part of the Nemakit–Daldynian stage. After this positive excursion, δ¹³C_carb sharply decreases down to about − 9‰ (N2) just below the basal Tommotian unconformity. These continuous patterns of the δ¹³C shift are irrespective of lithotype, suggesting a primary origin of the record. Moreover, the obtained δ¹³C profile, except for the sharp excursion N2, is comparable to records of other sections within and outside of the Yangtze Platform. Hence, we conclude that the general feature of our δ¹³C profile best represents the global change in seawater chemistry. The minimum δ¹³C of the N1 (− 7‰) is slightly lower than carbon input from the mantle, thus implying an enhanced flux of ¹³C-depleted carbon just across the Pc/C boundary. Hence, the ocean at that time probably became anoxic, which may have affected the survival of sessile or benthic Ediacaran biota. The subsequent δ¹³C rise up to + 5‰ (P2) indicates an increase of primary productivity or an enhanced rate of organic carbon burial, which should have resulted in lowering pCO₂ and following global cooling. This scenario accounts for the cause of the global-scale sea-level fall at the base of the Tommotian stage. The subsequent, very short-term, and exceptionally low δ¹³C (− 9‰) in N2 could have been associated with the release of methane from gas hydrates due to the sea-level fall. The inferred dramatic environmental changes (i.e., ocean anoxia, increasing productivity, global cooling and subsequent sea-level fall with methane release) appear to coincide with or occur just before the Cambrian Explosion. This may indicate synchronism between the environmental changes and rapid diversification of skeletal metazoa.     

Molecular and carbon isotopic analysis of individual biological markers: evidence for sources of organic matter and paleoenvironmental conditions in the Upper Ordovician Maquoketa Group, Illinois Basin, U.S.A.

Variations in the carbon isotopic composition (δ¹³C) of pristane, phytane, n-heptadecane (n-C₁₇), C₂₉ ααα 20R sterane, and aryl isoprenoids provide evidence for a diverse community of algal and bacterial organisms in organic matter of the Upper Ordovician Maquoketa Group of the Illinois Basin. Carbon isotopic compositions of pristane and phytane from the Maquoketa are positively covariant (r = 0.964), suggesting that these compounds were derived from a common source inferred to be primary producers (algae) from the oxygenated photic zone. A variation of 3‰ in δ¹³C values (−31 to −34‰) for pristane and phytane indicates that primary producers utilized variable sources of inorganic carbon. Average isotopic compositions of n-C₁₇ (−32‰) and C₂₉ ααα 20R sterane (−31‰) are enriched in ¹³C relative to pristane and phytane (−33‰) suggesting that these compounds were derived from a subordinate group of primary producers, most likely eukaryotic algae. In addition, a substantial enrichment of ¹³C in aryl isoprenoids (−14 to −18‰) and the identification of tetramethylbenzene in pyrolytic products of Maquoketa kerogen indicate a contribution from photosynthetic green sulfur bacteria to the organic matter. The presence of anaerobic, photosynthetic green sulfur bacteria in organic matter of the Maquoketa indicates that anoxic conditions extended into the photic zone.The δ¹³C of n-alkanes and the identification of an unusual suite of straight-chain n-alkylarenes in the m/z 133 fragmentograms of Ordovician rocks rich in Gloeocapsomorpha prisca (G. prisca) indicate that G. prisca did not contribute to the organic matter of the Maquoketa Group.     

The origin of dolomite associated with salt diapirs in central Tunisia: Preliminary investigations of field relationships and geochemistry

Black and white dolomite crystals (mm to cm width) of different isotopic composition are associated with Triassic diapirism in central Tunisia, as well as with evaporite minerals and clays. The white dolomites occur mostly in the Jabal Hadifa diapir near the contact with Cretaceous limestones, whereas the smaller black dolomites occur in the Jabal Hamra diapir. The former dolomite has a narrow range of δ¹⁸O and δ¹³C values (− 3.83‰ to − 6.60‰ VPDB for δ¹⁸O; − 2.11‰ to − 2.83‰ VPDB for δ¹³C), whereas the latter dolomite has a wider range and more depleted values (− 4.92‰ to − 9.97‰ for δ¹⁸O; − 0.55‰ to − 6.08‰ for δ¹³C). However, the ⁸⁷Sr / ⁸⁶Sr ratios of most of the samples are near Triassic seawater values. Dolomite formation is due to at least two different fluids. The main fluid originated from deeper hydrothermal or basinal sources related to the Triassic saliferous rocks and ascended through faults during the diapiric intrusion. The second, less important fluid source is related to meteoric water originating from Cretaceous rocks.     

Origin of methane in high-arsenic groundwater of Taiwan – Evidence from stable isotope analyses and radiocarbon dating

Groundwaters in the confined aquifers of the Chianan and Ilan coastal plains of Taiwan are rich in dissolved methane (CH₄). Serious endemic “blackfoot disease”, which occurred in the Chianan plain, especially during AD1950-1970, has been demonstrated to have arisen from drinking highly reducing groundwater with abnormal arsenic and humic substance levels. In order to explore the origin of CH₄ and its hydrological implications, stable carbon isotope ratios (δ¹³C) and radiocarbon (¹⁴C) ages of exsolved CH₄, dissolved inorganic carbon (DIC), and sedimentary biogenic sediments from a total of 34 newly completed water wells at 16 sites were determined. The main results obtained are as follows: (1) The δ¹³C_CH4 (−65‰ to −75‰) values indicate that, except for one thermogenic sample (δ¹³C_CH4=38.2‰) from the Ilan plain, all CH₄ samples analyzed were produced via microbially mediated CO₂ reduction. Many δ¹³C_DIC values are considerably greater than −10‰ and even up to 10‰ due to Rayleigh enrichment during CO₂ reduction. (2) Almost all the ¹⁴C ages of CH₄ samples from the shallow aquifer (I) (<60 m depth) are greater than the ¹⁴C ages of coexisting DIC and sediments, suggesting the presence of CH₄ from underlying aquifers. (3) The ¹⁴C ages of coexisting CH₄, DIC and sediments from aquifer (II) of the Chianan plain are essentially equal, reflecting in-situ generation of CH₄ and DIC from decomposition of sedimentary organic matter and sluggishness of the groundwater flow. On the other hand, both CH₄ and DIC from each individual well of the relatively deep aquifers (III) and (IV) in the Chianan plain are remarkably younger than the deposition of their coexisting sediments, indicating that current groundwaters entered these two aquifers much later than the deposition of aquifer sediments. (4) Each CH₄ sample collected from the Ilan plain is older than coexisting DIC, which in turn is distinctly older than the deposition of respective aquifer sediments, demonstrating the presence of much older CO₂ and CH₄ from underlying strata.     

Comparison of microbial gases from the Middle America Trench and Scripps Submarine Canyon: implications for the origin of natural gas

Chemical and isotopic compositions have been measured on 62 microbial gases from Tertiary hemipelagic sediments in the Middle America Trench off Guatemala and from decaying kelp and surf grass currently accumulating in Scripps Submarine Canyon off southern California. Gases from the Middle America Trench have been generated primarily by the reduction of carbon dioxide; methane δ¹³C varies from −84‰ to −39‰, methane δD varies from −208‰ to −145‰, and carbon dioxide δ¹³ C varies from −27‰ to +28‰. Gases from Scripps Submarine Canyon have been generated primarily by acetate dissimilation; methane δ¹³ C varies from −63‰ to −43‰, methane δD varies from −331‰ to −280‰, and carbon dioxide δ¹³C varies from −17‰ to +3‰.Methane δ¹³C values as heavy as −40‰ appear to be uncommon for gases produced by carbon dioxide reduction and, in the Middle America Trench, are associated with unusually positive carbon dioxide δ¹³C values. However, based on the 25‰ intramolecular fractionation between acetate car☐yl carbon and methyl carbon estimated from the Scripps Submarine Canyon data, methane produced by acetate dissimilation may commonly have heavy δ¹³C values. The δD of methane derived from acetate is more negative than natural methanes from other origins. Microbial methane δD values appear to be controlled primarily by interstitial water δD and by the relative proportions of methane derived from carbon dioxide and acetate.The chemical and isotopic compositions of microbial gas and thermogenic gas overlap, making it difficult to determine the origins of many commercial natural gases from methane δ¹³C and C₂₊ hydrocarbon concentrations alone. Measurements of methane δD and carbon dioxide δ¹³C can provide useful additional information, and together with ethane δ¹³C data, help identify gases with mixed microbial and thermogenic origins.     

The structure of Termination II (penultimate deglaciation and Eemian) in the North Atlantic

A study of the 140–100 ka interval in core T90-9P from the North Atlantic (45° N, 25° W), based on analysis of oxygen and carbon isotope records from planktonic and benthonic foraminifera, and from the bulk sediment fine fraction facilitates a detailed paleoceanographic reconstruction of the penultimate deglaciation (Termination II), and of the Eemian interglacial (δ¹⁸O stage 5e). The first step of Termination II was characterised by low productivity and a mixed water column, which was a remnant of glacial conditions. A 3 ka period of relatively stable conditions, with a stratified water column (‘Termination II pause’), occurred half-way through Termination II, and preceeded a second and more rapid climatic shift. The end of the deglaciation (Eemian maximum, i.e. isotopic event 5.53) initiated the establishment of strong, seasonal, water column stratification. North Atlantic Deep Water (NADW) production remained low during the complete glacial–interglacial transition. After the Eemian maximum, NADW prodution was restored, and bottom waters remained quite stable during the course of the Eemian, while surface waters gradually cooled in the second half of the stage. A short surface water cooling event accompanied by a reduced seasonal water column stratification and nutrient instability occurred at approximately 117 ka BP.     

Stable isotope and geochemical evidence of formation pore fluid evolution during diagenesis of Tertiary sandstones and mudrocks of the Niger Delta

Petrological data provide evidence that framboidal pyrite, Fe-carbonates and kaolinite are the major diagenetic minerals developed during burial diagenesis in the Tertiary Niger Delta sandstones and associated mudrocks. The pyrite sulphur, carbonate carbon and oxygen and kaolinite oxygen and hydrogen isotope compositions have been determined. These data (pyrite, δ³⁴S = −24.8 to 21.0‰; “siderite”, δ¹³C(PDB) = −14.7 to +5.0‰, δ¹⁸O(PDB) = −19.1 to −0.6‰; Fe-calcite, δ¹³C(PDB) = +17.5 to 17.9‰, δ¹⁸O(PDB) = −8.3 to −8.0‰; kaolinite, δ¹⁸O(SMOW) = +14.7 to 17.5‰, δD (SMOW) = −86 to −43‰) have been used to interpret the isotopic compositions of the precipitating pore fluids and/or the temperatures of mineral formation. The interpretation of these results indicate that in the deltaic depositional setting the syndepositional pore waters had a significant but variable marine influence that favoured the early formation of pyrite. Subsequently the subsurface influence of meteoric waters, showing varying degrees of modification involving organic and/or water-rock reactions, played an increasingly significant role in the development of later diagenetic cements in the sediments when abundant authigenic carbonates and kaolinites were formed.     

Variations of stable isotopes with depth in regolith calcite cements in the Broken Hill region, Australia: Palaeoclimate evolution signal?

Twenty two samples of calcretes from seven depth-profiles in the Menindee catchment, Broken Hill region, Australia were analysed for their inorganic and organic carbon contents and inorganic carbon and oxygen isotopes. The organic carbon content is very low (from 0.06 to 0.31 wt.%) while inorganic carbon (carbonate) is up to 3.9 wt.%. Both δ¹³C and δ¹⁸O become more positive closer to the surface. Carbon isotopes vary from − 8.5‰ to −5.5‰ PDB. Oxygen isotopes vary from − 6‰ to − 1.8‰ V-PDB. Depth-related δ¹³C and δ¹⁸O variations correlate over at least 15 km and show no significant variation along the flow path. δ¹³C values increase by 3‰ and δ¹⁸O values increase by 4‰ with decreasing depth in a 1.40 m thick soil profile. The variation is interpreted to indicate an increasingly elevated air temperature, greater water stress and subsequently an aridification of the area through time. The Broken Hill calcrete data confirm that climatic evolution can be deduced from isotopic series and be applied successfully to the Broken Hill region.     

Glacial/interglacial sea surface temperature changes in the Southwest Pacific ocean over the past 360 ka

The phase relationship between climate parameters during terminations gives insight into deglaciation mechanisms. By combining foraminiferal Mg/Ca and alkenone thermometers with planktonic and benthic foraminiferal δ¹⁸O, we determined the phase relationship between local sea surface temperature (SST) and global seawater δ¹⁸O changes in the Coral Sea in the Southwestern Pacific over the last 360 ka. The onset of the SST warming preceded the seawater δ¹⁸O change by several ka for Termination I, II and III. During Termination I, the SST warming started at 20 ka BP, earlier than atmospheric CO₂ rise suggesting that the greenhouse effect was not the main trigger of this early warming. Compilation of ¹⁴C-dated SST records from the whole Pacific during Termination I reveals that the onset of the warming is generally earlier in the Southern and the tropical Pacific than in the North Pacific. This spatio-temporal warming pattern suggests linkage between the southern ocean and tropical Pacific. The early tropical warming could provide heat and moisture to the northern high latitudes, modifying radiative balance and precipitation over ice sheets at the onset of deglaciation.