Identification and significance of a late Pleistocene tephra in Canterbury district,South Island,New Zealand

A rhyolitic ash 4 to 8 cm thick is well preserved within a thick loess unit in a coastal section 2 km long near Teviotdale, Canterbury district, South Island, New Zealand. The ash (informally named Tiromoana ash) contains fresh glass shards which give a fission-track age of 20,300 ± 7100 yr B.P. The only possible source for such a tephra with this age range is from Taupo Volcanic Zone (TVZ), North Island, some 550 km north of Teviotdale. Within the time span ca. 15,000 to 42,000 yr B.P. five widespread and voluminous rhyolitic tephras (viz. Rerewhakaaitu Ash, Rotoehu Ash, Kawakawa Tephra, Omataroa Tephra, and Mangaone Tephra) were erupted from TVZ. On the basis of the fission-track age, ferromagnesian mineralogy, and electron-microprobe analyses of glass shards and titanomagnetites from Tiromoana ash and the five possible correlatives listed above, Tiromoana ash is correlated with Kawakawa Tephra (dated by ¹⁴C at ca. 20,000 yr B.P.). This is the only known occurrence to date of Kawakawa Tephra in the South Island. Its preservation is attributed to special site conditions (low precipitation and minimal sheet erosion) leeward of a prominent terrace. The identification of the ash at Teviotdale as Kawakawa Tephra supports recently revised age assignments for the upper loess sheet in Canterbury. Moreover, it implies that loess enclosing Kawakawa Tephra in nonglaciated districts of southern North Island and Taupo Volcanic Zone is a correlative.     

A terrestrial record of Last Interglacial climate preserved by voluminous debris avalanche inundation in Taranaki,New Zealand

At Airedale Reef, western North Island, New Zealand, a ca. 4 m thick volcanogenic debris avalanche deposit has facilitated the preservation of an enveloping sequence of peats with interbedded andesitic tephras spanning marine isotope (MIS) 5. The sequence closely overlies a wave‐cut terrace correlated to MIS 5e and, in turn, is overlain by andic beds with tephra interbeds including the Rotoehu and Kawakawa tephras deposited during early MIS 3 and mid‐MIS 2, respectively. Pollen analysis of the organic sequence shows a coherent pattern of fluctuating climate for the Last Interglacial–Last Glacial transition that corresponds with marine isotope stratigraphy and supports the contention that orbital variations were a primary factor in late Quaternary southern mid‐latitude climate change. A five‐stage subdivision of MIS 5 is clearly recognised, with marine isotope substage (MISS) 5b drier than MISS 5d, and the cooling transition from 5a to MIS 4 also may have been comparatively dry and characterised by natural fire, perhaps associated with volcanism. Several other examples of volcanic impact on vegetation and the landscape are evident. The Airedale Reef sequence exhibits strong similarities with fragmentary MIS 5 pollen records preserved elsewhere in New Zealand and enables the proxy record of southern mid‐latitude climatic variability during the Last Interglacial–Glacial cycle to be extended. Copyright © 2004 John Wiley & Sons, Ltd.     

Onshore–offshore correlation of Pleistocene rhyolitic eruptions from New Zealand: implications for TVZ eruptive history and paleoenvironmental construction

Taupo Volcanic Zone (TVZ), in the North Island, New Zealand, is arguably the most active Quaternary rhyolitic system in the world. Numerous and widespread rhyolitic tephra layers, sourced from the TVZ, form valuable chronostratigraphic markers in onshore and offshore sedimentary sequences. In deep-sea cores from Ocean Drilling Program (ODP) Leg 181 Sites 1125, 1124, 1123 and 1122, located east of New Zealand, ca 100 tephra beds are recognised post-dating the Plio-Pleistocene boundary at 1.81 Ma. These tephras have been dated by a combination of magnetostratigraphy, orbitally tuned stable-isotope data and isothermal plateau fission track ages. The widespread occurrence of ash offshore to the east of New Zealand is favoured by the small size of New Zealand, the explosivity of the mainly plinian and ignimbritic eruptions and the prevailing westerly wind field.Although some tephras can be directly attributed to known TVZ eruptions, there are many more tephras represented within ODP-cores that have yet to be recognised in near-source on-land sequences. This is due to proximal source area erosion and/or deep burial as well as the adverse effect of vapour phase alteration and devitrification within near-source welded ignimbrites. Despite these difficulties, a number of key deep-sea tephras can be reliably correlated to equivalent-aged tephra exposed in uplifted marine back-arc successions of Wanganui Basin where an excellent chronology has been developed based on magnetostratigraphy, orbitally calibrated sedimentary cycles and isothermal plateau fission track ages on tephra. Significant Pleistocene tephra markers include: the Kawakawa, Omataroa, Rangitawa/Onepuhi, Kaukatea, Kidnappers-B, Potaka, Unit D/Ahuroa, Ongatiti, Rewa, Sub-Rewa, Pakihikura, Ototoka and Table Flat Tephras. Six other tephra layers are correlated between ODP-core sites but have yet to be recognised within onshore records.The identification of Pleistocene TVZ-sourced tephras within the ODP record, and their correlation to Wanganui Basin and other onshore sites is a significant advance as it provides: (1) an even more detailed history of the TVZ than can be currently achieved from the near-source record, (2) a high-resolution tephrochronologic framework for future onshore-offshore paleoenvironmental reconstructions, and (3) well-dated tephra beds correlated from the offshore ODP sites with astronomically tuned timescales provide an opportunity to critically evaluate the chronostratigraphic framework for onshore Plio-Pleistocene sedimentary sequences (e.g. Wanganui Basin, cf. Naish et al. [1998. Quaternary Science Reviews 17 695–710].     

Late Quaternary volcanism in New Zealand: Towards an integrated record using distal airfall tephras in lakes and bogs

Studies on distal airfall tephra layers preserved in lake sediments and peats in northern New Zealand have documented the stratigraphic, chronologic, and compositional relationships of 46 eruptives, aged c. 17000–700yr BP, which originated from six North Island volcanic centres: Taupo (9 tephras), Okataina (8), Maroa (1) (rhyolitic); Mayor Island (2) (peralkaline); Tongariro (11), Egmont (15) (andesitic). Sources were distinguished by mineralogy and composition, field relations, and ¹⁴C chronology. All known rhyolitic tephra-producing eruptions from Taupo, Okataina, and Maroa volcanoes since c. 17000yr BP are represented, but only a small proportion of the known tephras erupted from Tongariro, Egmont, or Mayor Island volcanoes is recorded. The distal tephras from these latter volcanic centres may thus reflect atypically powerful (or oblique) eruptions, or dispersal by strong winds. An improved record of volcanism for the Tongariro, Egmont, and Mayor Island centres might be obtainable from suitable lakes or bogs more proximal to them.     

Dissolution and depletion of ferromagnesian minerals from Holocene tephra layers in an acid bog,New Zealand,and implications for tephra correlation

This study examines the depletion of ferromagnesian silicate minerals from a sequence of thin, distal, mainly rhyolitic tephra layers of Holocene age preserved in an acid peat bog (Kopouatai), North Island, New Zealand. The rate of such depletion has been fast, as indicated by the complete loss of biotite from one tephra layer (Kaharoa Tephra), in which it is normally dominant, in only ca. 770 yr. Chemical dissolution is advocated as the likely cause for the depletion, with amphiboles and other mineral grains commonly showing etch pits, microcaves, and other characteristic surface solution features. Theoretical thermodynamic and kinetic models show a marked increase in the rate of dissolution of all ferromagnesian minerals under conditions of low pH (< 4), but that where silica concentrations in solution are high the relative proportions of minerals remaining are unaffected. However, where concentrations of dissolved silica are low, as in most bog environments, the relative proportions of ferromagnesian minerals are affected as well as absolute amounts being decreased. Amphiboles are depleted relative to pyroxenes, consistent with kinetic studies. The results show that the identification and correlation of tephras on the basis of relative abundances of ferromagnesian minerals alone may be unreliable, and emphasise the need to use multiple criteria in such studies.     

Middle to late Pleistocene record of explosive volcanic eruptions in marine sediments offshore Kamchatka (Meiji Rise,NW Pacific)

This paper presents the first detailed study of a late Pleistocene marine tephra sequence from the NW Pacific, downwind from the Kamchatka volcanic arc. Sediment core SO201-2-40, located on the Meiji Rise ~400 km offshore the peninsula, includes 25 tephras deposited within the last 215 ka. Volcanic glass from the tephras was characterized using single-shard electron microprobe analysis and laser ablation inductively coupled mass spectrometry. The age of tephras was derived from a new age model based on paleomagnetic and paleoclimate studies. Geochemical correlation of distal tephras to Kamchatkan pyroclastic deposits allowed the identification of tephras from the Karymsky, Gorely, Opala and Shiveluch eruptive centers. Three of these tephras were also correlated to other marine and terrestrial sites and hence are identified as the best markers for the north-west Pacific region. These are an early Holocene tephra from the Karymsky caldera (~8.7 ka) and two tephras falling into the Marine Isotope Stage (MIS) 6 glacial time: an MIS 6.4 tephra from Shiveluch (~141 ka) and the MIS 6.5 Rauchua tephra (~175 ka) from Karymsky. The data presented in this study can be used in paleovolcanological and paleoceanographic reconstructions.     

Dating late Quaternary events by the combined U‐Pb LA‐ICP‐MS and (U‐Th)/He dating of zircon: A case study on Omachi Tephra suite (central Japan)

Dating of young (<1 Ma) geological events has long been a challenge for geochronologists. Combining (U‐Th)/He with U‐Pb or U‐Th‐disequilibrium dating methods offers a unique dating tool that can address this important period. We present a new methodology that combines U‐Pb LA‐ICP‐MS and (U‐Th)/He dating of zircon and use it to date two Pleistocene marker tephras (A1Pm and DPm) from the Omachi Tephra suite (Japan). A1Pm and DPm yield U‐Pb ages in the range of 350–850 and ~140–630 ka, respectively, documenting protracted periods of zircon crystallisation (100's of k.y.) prior to eruption. (U‐Th)/He ages constrain the eruption ages of the A1Pm and DPm tephras to 375 ± 13 and 97.1 ± 7.3 ka, respectively, and are in agreement with published estimates. This study demonstrates the potential of combined zircon U‐Pb LA‐ICP‐MS and (U‐Th)/He dating to constrain magmatic and eruption events in the critical ~100 ka–1 Ma interval.     

New age estimates and climatostratigraphic correlations for the Borrobol and Penifiler Tephras: evidence from Abernethy Forest,Scotland

The emerging tephrostratigraphy of NW Europe spanning the last termination (ca. 15–9 ka) provides the potential for synchronizing marine, ice‐core and terrestrial records, but is currently compromised by stratigraphic complications, geochemical ambiguity and imprecise age estimates for some layers. Here we present new tephrostratigraphic, radiocarbon and chironomid‐based palaeotemperature data from Abernethy Forest, Scotland, that refine the ages and stratigraphic positions of the Borrobol and Penifiler tephras. The Borrobol Tephra (14.14–13.95 cal ka BP) was deposited in a relatively warm period equated with Greenland Interstadial sub‐stage GI‐1e. The younger Penifiler Tephra (14.09–13.65 cal ka BP) is closely associated with a cold oscillation equated with GI‐1d. We also present evidence for a previously undescribed tephra layer that has a major‐element chemical signature identical to the Vedde Ash. It is associated with the warming trend at the end of the Younger Dryas, and dates between 11.79 and 11.20 cal ka BP. Copyright © 2011 John Wiley & Sons, Ltd.     

The Late Holocene tephra record of the central Mediterranean Sea: Mapping occurrences and new potential isochrons for the 4.4–2.0 ka time interval

Five cores from the southern Tyrrhenian and Ionian seas were studied for their tephra and cryptotephra content in the 4.4–2.0 ka time interval. The chronological framework for each core was obtained by accelerator mass spectrometry ¹⁴C dating, the occurrence of distinct marker tephra and stratigraphic correlation with adjacent records. Tephrochronology allowed us to correlate the analyzed deposits with tephra markers associated with Somma-Vesuvius (79 ad ), Ischia Island (Cretaio), Mt Etna (FG, FL and FS) and Campi Flegrei (Astroni-Agnano Monte Spina) events. For the first time in the marine setting, a large single glass data set is provided for the Late Holocene Etnean marker beds including the FS tephra (ca. 4.3 ka). Moreover, unknown deposits from Lipari (ca. 2.2–2.0 ka) and Vulcano (3.6–3.3 ka) are also recognized at more distal sites than previously reported. These results contribute to improve the high-resolution tephrostratigraphic framework of the central Mediterranean Sea. They also provide new insights into the chemical composition and dispersal pattern of tephras that can be used as inter-archive tools for regional and ‘local’ stratigraphic correlations and for addressing paleoclimate research.     

Late Quaternary Paleoclimatic Change in the Ulleung Basin, East Sea, Korea

Paleoclimatic changes in the late Quaternary sediments deposited in the East Sea were analyzed by studying diatoms. A total of 95 species belonging to 47 genera were identified from the Core02GHP-02 of the Ulleung Basin in the East Sea, Korea. In the Core 02GHP-02, U-Oki(169–181 cm; 9.3 ka), AT(464–465.5 cm; 22 ka) and U–Ym(556–559 cm; 33 ka) tephra layers were recognized. The chronological divisions of 02GHP-02 may be correlated with the climatic changes from the glacial interval(730–620 cm; MIS3), to interstadial(620–500 cm; MIS3), to the last glacial maximum(500–390 cm; MIS 2), to the deglaciation(390–290 cm; MIS 2), to the late glacial(290–190 cm; MIS 1), and to the Holocene(190–10 cm; MIS 1). It is speculated that diatoms were rarely found during the glacial interval when the 02GHP-02 core was deposited; during the interstadial(MIS 3) and deglaciation, a mixture of warm-water and cold-water species were found. In particular, Fragilariopsis doliolus seems to have appeared in the East Sea after 8 ka BP. In the lower layers of the Holocene deposits, cold-water species such as Neodenticula seminae were frequently found, while in the upper layers, warm-water species such as Hemidiscus cuneiformis were found in relatively large abundance. Therefore, the findings indicate that the climate became warmer during the transition from the lower layer to the upper layer of the Holocene deposits.     

Three new distal tephras in sediments spanning the Last Glacial–Interglacial Transition in Scotland

Three new microtephras are reported from a number of lake sites from the Inner Hebrides and Scottish mainland. One occurs stratigrapically in the middle of Greenland Interstadial 1 (GI‐1) and has been named the Penifiler Tephra. It is rhyolitic and possesses a geochemical signature that is very similar to that of the Borrobol Tephra, which also occurs in three of the sequences reported here, but which lies close to the lower boundary of GI‐1. The second occurs stratigraphically in the early Holocene below the Saksunarvatn Ash and is named the Ashik Tephra. This tephra is geochemically bimodal, with a rhyolitic component comparable to the An Druim Tephra that occurs later in the Holocene, and a basaltic component which is similar to the Saksunarvatn Ash. A third tephra occurs stratigraphically above the Saksunarvatn Ash and is provisionally named the Breakish Tephra. The consistent inter‐site correlation demonstrated for these new tephras at several sites enhances the regional tephrostratigraphic framework, and increases the potential for correlating palaeoenvironmental events during GI‐1 and the early Holocene. However, the occurrence of multiple tephras with similar geochemistry in close stratigraphic and temporal proximity has implications for the rigour with which tephrostratigraphic investigations must be performed. Copyright © 2006 John Wiley & Sons, Ltd.     

A multiple-approach radiometric age estimate for the Rotoiti and Earthquake Flat eruptions,New Zealand,with implications for the MIS 4/3 boundary

Pyroclastic fall deposits of the paired Rotoiti and Earthquake Flat eruptions from the Taupo Volcanic Zone (New Zealand) combine to form a widespread isochronous horizon over much of northern New Zealand and the southwest Pacific. This horizon is important for correlating climatic and environmental changes during the Last Glacial period, but has been the subject of numerous disparate age estimates between 35.1±2.8 and 71±6 ka (all errors are 1 s.d.), obtained by a variety of techniques. A potassium–argon (K–Ar) age of 64±4 ka was previously determined on bracketing lavas at Mayor Island volcano, offshore from the Taupo Volcanic Zone. We present a new, more-precise ⁴⁰Ar/³⁹Ar age determination on a lava flow on Mayor Island, that shortly post-dates the Rotoiti/Earthquake Flat fall deposits, of 58.5±1.1 ka. This value, coupled with existing ages from underlying lavas, yield a new estimate for the age of the combined eruptions of 61.0±1.4 ka, which is consistent with U–Th disequilibrium model-age data for zircons from the Rotoiti deposits. Direct ⁴⁰Ar/³⁹Ar age determinations of plagioclase and biotite from the Rotoiti and Earthquake Flat eruption products yield variable values between 49.6±2.8 and 125.3±10.0 ka, with the scatter attributed to low radiogenic Ar yields, and/or alteration, and/or inheritance of xenocrystic material with inherited Ar. Rotoiti/Earthquake Flat fall deposits occur in New Zealand in association with palynological indicators of mild climate, attributed to Marine Isotope Stage (MIS) 3 and thus used to suggest an age that is post-59 ka. The natures of the criteria used to define the MIS 4/3 boundary in the Northern and Southern hemispheres, however, imply that the new 61 ka age for the Rotoiti/Earthquake Flat eruption deposits will provide the inverse, namely, a more accurate isochronous marker for correlating diverse changes across the MIS 4/3 boundary in the southwest Pacific.     

Late Quaternary tephrostratigraphy,Ahklun Mountains,SW Alaska

Radiocarbon‐dated sediment cores from six lakes in the Ahklun Mountains, south‐western Alaska, were used to interpolate the ages of late Quaternary tephra beds ranging in age from 25.4 to 0.4 ka. The lakes are located downwind of the Aleutian Arc and Alaska Peninsula volcanoes in the northern Bristol Bay area between 159° and 161°W at around 60°N. Sedimentation‐rate age models for each lake were based on a published spline‐fit procedure that uses Monte Carlo simulation to determine age model uncertainty. In all, 62 ¹⁴C ages were used to construct the six age models, including 23 ages presented here for the first time. The age model from Lone Spruce Pond is based on 18 ages, and is currently the best‐resolved Holocene age model available from the region, with an average 2σ age uncertainty of about ± 109 years over the past 14.5 ka. The sedimentary sequence from Lone Spruce Pond contains seven tephra beds, more than previously found in any other lake in the area. Of the 26 radiocarbon‐dated tephra beds at the six lakes and from a soil pit, seven are correlated between two or more sites based on their ages. The major‐element geochemistry of glass shards from most of these tephra beds supports the age‐based correlations. The remaining tephra beds appear to be present at only one site based on their unique geochemistry or age. The 5.8 ka tephra is similar to the widespread Aniakchak tephra [3.7 ± 0.2 (1σ) ka], but can be distinguished conclusively based on its trace‐element geochemistry. The 3.1 and 0.4 ka tephras have glass major‐ and trace‐element geochemical compositions indistinguishable from prominent Aniakchak tephra, and might represent redeposited beds. Only two tephra beds are found in all lakes: the Aniakchak tephra (3.7 ± 0.2 ka) and Tephra B (6.1 ± 0.3 ka). The tephra beds can be used as chronostratigraphic markers for other sedimentary sequences in the region, including cores from Cascade and Sunday lakes, which were previously undated and were analyzed in this study to correlate with the new regional tephrostratigraphy. Copyright © 2012 John Wiley & Sons, Ltd.     

Geochemistry,dispersal, volumes and chronology of Holocene silicic tephra layers from the Katla volcanic system,Iceland

At least 12 silicic tephra layers (SILK tephras) erupted between ca. 6600 and ca. 1675 yr BP from the Katla volcanic system, have been identified in southern Iceland. In addition to providing significant new knowledge on the Holocene volcanism of the Katla system which typically produces basaltic tephra, the SILK tephras form distinct and precise isochronous marker horizons in a climatically sensitive location close to both the atmospheric and marine polar fronts. With one exception the SILK tephras have a narrow compositional range, with SiO₂ between 63 and 67%. Geochemically they are indistinguishable from ocean transported pumice found on beaches in the North Atlantic region, although they differ significantly from the silicic component of the North Atlantic Ash Zone One (NAAZO). Volumes of airborne SILK tephra range from 0.05 to 0.3 km³. We present new isopach maps of the six largest layers and demonstrate that they originate within the Katla caldera. The apparently stable magma system conditions that produced the SILK tephras may have been established as a consequence of the eruption of the silicic component of NAAZO (ca. 10.3 ka) and disrupted by another large‐scale event, the tenth century ad Eldgjá eruption (ca. 1 ka). Despite the current long repose, silicic activity of this type may occur again in the future, presenting hitherto unknown hazards. Copyright © 2001 John Wiley & Sons, Ltd.     

Late Quaternary tephra layers around Raoul and Macauley Islands,Kermadec Arc: implications for volcanic sources,explosive volcanism and tephrochronology

A suite of deep‐sea cores were collected along transects up to 100 km across the fore‐arc and back‐arc regions of the predominantly submarine Kermadec arc near Raoul and Macauley islands, southwest Pacific. The cores reveal a macroscopic tephra record extending back >50 ka. This is a significant addition to the dated record of volcanism, previously restricted to fragmented late Holocene records exposed on the two islands. The 27 macroscopic tephra layers display a wide compositional diversity in glass (～50–78 wt% SiO₂). Many tephra layers comprise silicic shards with a subordinate mafic shard population. This could arise from magma mingling and may reflect mafic triggering of the silicic eruptions. Broadly, the glass compositions can be distinguished on diverging high‐K and low‐K trends, most likely arising from different source volcanoes. This distinction is also reflected in the tephra records exposed on Raoul (low‐K) and Macauley (high‐K) islands, the likely source areas. Heterogeneous tephra comprising shards of both high‐ and low‐K affinity, silicic and mafic compositions, and more homogeneous tephra with subordinate outlier shard compositions, are best explained by post‐depositional mixing of separate eruption deposits or contemporaneous eruptions. Evidently, the slow sedimentation rates of the calcareous oozes (～10¹–10² mm ka^?1) were insufficient to adequately separate and preserve closely spaced eruption deposits. This exemplifies the difficulty in assessing eruption frequencies and magmatic trends, and erecting a tephrostratigraphy, using geochemical fingerprinting in such environments. Despite these difficulties, the ca. 5.7 ka Sandy Bay Tephra erupted from Macauley Island can be correlated over a distance of >100 km, extending east and west of the island, showing that the mostly submerged volcanoes are capable of wide tephra dispersal. Hence there is potential for developing chronostratigraphies for the southwest Pacific beyond the region covered by the extensive rhyolite marker beds from the Taupo Volcanic Zone. Copyright © 2011 John Wiley & Sons, Ltd.     

First cosmogenic 10Be constraints on LGM glaciation on New Zealand's North Island: Park Valley,Tararua Range

We report the first direct ages for late Quaternary glaciation on the North Island of New Zealand. Mt Ruapehu, the volcanic massif in the North Island's centre, is currently glaciated and probably sustained glaciers throughout the late Quaternary, yet no numeric ages have been reported for glacial advances anywhere on the North Island. Here, we describe cosmogenic ¹⁰Be ages of the surface layers of a glacially transported boulder and glacially polished bedrock from the Tararua Range, part of the axial ranges of the North Island. Results indicate that a limited valley glaciation occurred, culminating in recession at the end of the last glacial coldest period (LGCP, ca. 18 ka). This provides an initial age for deglaciation on the North Island during the last glacial–interglacial transition (LGIT). It appears that glaciation occurred in response to an equilibrium‐line altitude (ELA) lowering of ～1400 m below the present‐day mean summer freezing level. Ages for glaciation in the Tararua Range correspond closely to exposure ages for the last glacial maximum (LGM) from the lateral moraines of Cascade Valley in the South Island, and in Cobb Valley, in northern South Island. The corollary is that glaciation in the Tararua Range coincided with the phase of maximum cooling during MIS 2, prior to the Antarctic Cold Reversal (ACR), during the LGCP. Copyright © 2008 John Wiley & Sons, Ltd.     

North European last glacial–interglacial transition (LGIT; 15–9 ka) tephrochronology: extended limits and new events

High‐precision correlation of palaeoclimatic and palaeoenvironmental records is crucial for testing hypotheses of synchronous change. Although radiocarbon is the traditional method for dating late Quaternary sedimentary sequences, particularly during the last glacial–interglacial transition (LGIT; 15–9 ka), there are inherent problems with the method, particularly during periods of climate change which are often accompanied by major perturbations in atmospheric radiocarbon content. An alternative method is the use of tephras that act as time‐parallel marker horizons. Within Europe, numerous volcanic centres are known to have erupted during the LGIT, providing considerable potential for high‐precision correlation independent of past radiocarbon fluctuations. Here we report the first identification of the Vedde Ash and Askja Tephra in Ireland, significantly extending the known provenance of these events. We have also identified two new horizons (the Roddans Port Tephras A and B) and tentatively recognise an additional horizon from Vallensgård Mose (Denmark) that provide crucial additional chronological control for the LGIT. Two phases of the Laacher See Tephra (LST) are reported, the lower Laacher See Tephra (LLST) and probably the C2 phase of the Middle Laacher See Tephra (MLST‐C2) indicating a more northeasterly distribution of this fan than reported previously. Copyright © 2006 John Wiley & Sons, Ltd.     

Non‐synchronous deposition of North Atlantic Ash Zone II in Greenland ice cores,and North Atlantic and Norwegian Sea sediments: an example of complex glacial‐stage tephra transport

Tephra provides regional chronostratigraphical marker horizons that can link different climate archives with highly needed accuracy and precision. The results presented in this work exemplify, however, that the intermittent storage of tephra in ice sheets and during its subsequent iceberg transport, especially during glacial stages, constitutes a potential source of serious error for the application of tephrochronology to Nordic Seas and North Atlantic sediment archives. The peak shard concentration of the rhyolitic component of the North Atlantic Ash Zone II (NAAZ‐II) tephra complex, often used to correlate marine and ice core records in Marine Isotope Stage (MIS) 3, is shown to lag the eruption event by ca. 100–400 years in some North Atlantic and Norwegian Sea cores. While still allowing for a correlation of archives on millennial timescales, this time delay in deposition is a major obstacle when addressing the lead–lag relationship on short timescales (years to centuries). A precise and accurate determination of lead–lag relationships between archives recording different parts of the climate system is crucial in order to test hypotheses about the processes leading to abrupt climate change and to evaluate results from climate models. Copyright © 2011 John Wiley & Sons, Ltd.     

A terrestrial palynological record for the last two glacial cycles from southwestern New Zealand

A pollen profile from Okarito Pakihi Bog in south Westland, New Zealand extending from near present back to Marine Isotope Stage (MIS) 6 provides a continuous record of vegetation and climate change for the past two glacial cycles. Independent chronological control was obtained by AMS radiocarbon dating of organic sediments in the upper part of the sequence and OSL dating of inorganic silts in the lower part, with a unique tie point provided by the ca 26.5 cal ka Kawakawa Tephra. As was probably a common occurrence in this region, the basin developed as a moraine-dammed proglacial lake and remained lacustrine until the early Holocene, when a peat bog developed. Survival of the depositional site through subsequent multiple ice advances, unusual in a glaciated landscape, was probably assisted by lateral displacement of the basin relative to its source area, across the Alpine Fault.There is good correspondence between inferred periods of substantial treeline depression in the pollen profile and the record for ice advance in this region. More cooling events are evident in the pollen record, however, presumably due to the fragmentary nature of glacial geomorphology. The pollen record also shows broad consistency with the MIS record and hence with the Milankovitch orbital forcing model, but with some departures, including an early onset to the last glacial maximum (LGM). Several sub-Milankovitch scale events are also evident, including a mid-LGM warming and Lateglacial reversals during both the last and the penultimate deglaciation.     

Tephrochronology of the Toluca Basin,central Mexico

The major element glass geochemistry of 10 Late Pleistocene and Holocene tephras found in the Toluca Basin in the Trans-Mexican Volcanic Belt is reported for the first time, as a key step towards establishing a tephrochronology for the region. The context for this tephrochronology is provided by a review of Late Quaternary volcanism of the basin. New tephra samples were collected from reference profiles around the basin in order to establish major element glass geochemical data for tephras described in previous publications, but not previously analysed. In addition, cores were taken from the basin floor to extend the known spatial distribution of the tephra layers and establish correlations with the lacustrine record. Improved chronological control has been provided by seven new AMS and conventional radiocarbon dates on the major tephras. Geochemical data are presented for 10 tephras ranging in age from ca. 25,000 BP (Lower Toluca Pumice) to about 8500 BP (Tres Cruces Tephra). Based on geochemical data, it is possible to correlate between sites within the Toluca Basin and between the Toluca Basin and the Basin of Mexico. The basis for a tephrochronological framework has been established.