Noble gas and isotope geochemistry in western Canadian Arctic watersheds: tracing groundwater recharge in permafrost terrain

In Canada’s western Arctic, perennial discharge from permafrost watersheds is the surface manifestation of active groundwater flow systems with features including the occurrence of year-round open water and the formation of icings, yet understanding the mechanisms of groundwater recharge and flow in periglacial environments remains enigmatic. Stable isotopes (δ¹⁸O, δD, δ¹³C_DIC), and noble gases have proved useful to study groundwater recharge and flow of groundwater which discharges along rivers in Canada’s western Arctic. In these studies of six catchments, groundwater recharge was determined to be a mix of snowmelt and precipitation. All systems investigated show that groundwater has recharged through organic soils with elevated P_CO2, which suggests that recharge occurs largely during summer when biological activity is high. Noble gas concentrations show that the recharge temperature was between 0 and 5 °C, which when considered in the context of discharge temperatures, suggests that there is no significant imbalance of energy flux into the subsurface. Groundwater circulation times were found to be up to 31 years for non-thermal waters using the ³?H-³He method.     

Assessment of paleo-recharge under the Fennoscandian Ice Sheet and its impact on regional groundwater flow in the northern Baltic Artesian Basin using a numerical model

The study investigates the mechanism of glacial meltwater recharge under the Fennosciandian Ice Sheet during the last glacial maximum (LGM) and its impact on regional groundwater flow in the northern Baltic Artesian Basin (BAB) in Estonia and Latvia. The current hypothesis is that a flow reversal occurred in the BAB due to subglacial recharge during the LGM. This hypothesis is supported by an extensive dataset of geochemical and isotopic measurements in the groundwater of northern Estonia, exhibiting significant depletion in δ¹⁸O with respect to modern precipitation. To verify the consistency of this hypothesis and better understand groundwater flow dynamics during the LGM period, a numerical model is developed for this area. Two cross-sectional models have been created across the northern BAB, in which groundwater flow and the transport of δ¹⁸O have been simulated from the beginning of the LGM to present-day. Several simulations were performed with different subglacial boundary conditions, to investigate the uncertainty related to subglacial recharge of meltwater during the LGM and the subsequent flow reversal in the northern BAB. Several simulations provide a satisfying fit between computed and observed values of δ¹⁸O, which means that the hypothesis of subglacial recharge of meltwater is consistent with δ¹⁸O distribution. The numerical model suggests that preservation of meltwater in northern Estonia is controlled by confining layers and the proximity to the outcrop area of aquifers, located in the Gulf of Finland. The results also suggest that glacial meltwater has been preserved under the Baltic Sea in the Gulf of Riga.     

Sensitivity to long-term climate change of subpermafrost groundwater systems in Svalbard

Deep subpermafrost aquifers are highly climate-dependent, with the permafrost as an aquitard preventing groundwater recharge and discharge. A study from the high-arctic island of Spitsbergen, Svalbard, shows that during a glacial to interglacial phase, both the permafrost and the glacier regime will respond to climatic changes, and a glacier-fed groundwater flow system will vary accordingly. A full glaciation results in the melting of permafrost, and groundwater can flow through pores and fracture systems in the rocks and sediments below the temperate zones of glaciers. These groundwater flow systems will mainly be localized to fjords and valleys and form low-lying terrestrial springs when the relative sea level drops during deglaciation due to glacio-isostatic rise. During an interglaciation, permafrost develops and thickens and the groundwater recharge and discharge areas will thereby be gradually reduced to a minimum reached at the warmest part of an interglaciation. An already frozen spring system cannot reopen before the permafrost melts. Only groundwater springs related to permanently warm-based glacial ice will persist into the next glaciation. During a new glaciation, flow systems that terminated during the previous interglaciation may become revitalized if overridden by warm-based ice causing permafrost thawing.     

Chronology and palaeoenvironmental implications of the ice‐wedge pseudomorphs and composite‐wedge casts on the Magdalen Islands (eastern Canada)

The Magdalen Islands are a valuable terrestrial record, evidencing the complex glacial and periglacial history of the Gulf of St. Lawrence. Thirteen structures interpreted as ice‐wedge pseudomorphs or composite‐wedge casts were observed at four sites on the southern Magdalen Islands and testify to the former presence of permafrost under periglacial conditions. These features truncate Carboniferous sandstone or Last Glacial Maximum (LGM) glacial and glaciomarine diamicts, both overlain by subtidal or coastal units. Six optically stimulated luminescence (OSL) and four radiocarbon ages were obtained from both host and infilled sedimentary units. These ages provide the first absolute chronological data on these structures, shedding new light on the relationships between glacial and periglacial phases. Our chronostratigraphic data suggest that, after the deglaciation and the emersion of the archipelago, thermal contraction cracks grew during the cold period of the Younger Dryas (11–10 ka; 12.9–11.5 cal. ka BP). The Younger Dryas, which is well documented in the Maritime Provinces of Canada, occurred after a pedogenesis phase associated with the Allerød warm period evidenced by the well‐developed palaeopodzol ubiquitous on the Magdalen Islands.     

Groundwater flow modeling of periods with periglacial and glacial climate conditions for the safety assessment of the proposed high-level nuclear waste repository site at Forsmark,Sweden

The impact of periglacial and glacial climate conditions on groundwater flow in fractured crystalline rock is studied by means of groundwater flow modeling of the Forsmark site, which was recently proposed as a repository site for the disposal of spent high-level nuclear fuel in Sweden. The employed model uses a thermal-hydraulically coupled approach for permafrost modeling and discusses changes in groundwater flow implied by the climate conditions found over northern Europe at different times during the last glacial cycle (Weichselian glaciation). It is concluded that discharge of particles released at repository depth occurs very close to the ice-sheet margin in the absence of permafrost. If permafrost is included, the greater part discharges into taliks in the periglacial area. During a glacial cycle, hydraulic gradients at repository depth reach their maximum values when the ice-sheet margin passes over the site; at this time, also, the interface between fresh and saline waters is distorted the most. The combined effect of advances and retreats during several glaciations has not been studied in the present work; however, the results indicate that hydrochemical conditions at depth in the groundwater flow model are almost restored after a single event of ice-sheet advance and retreat.     

A paleotemperature record derived from dissolved noble gases in groundwater of the Aquia Aquifer (Maryland, USA)

Low ¹⁴C activities in groundwater of the confined part of the Aquia aquifer in southeastern Maryland suggest that most of this water infiltrated at least 30,000 years ago. However, radiocarbon contents of the dissolved inorganic carbon seem to be affected by isotopic exchange, possibly with secondary calcite deposits in the formation, leading to overestimated ¹⁴C ages. Whereas the geochemistry of the Aquia aquifer complicates the application of the widely used ¹⁴C dating method, the accumulation of radiogenic He seems to provide a viable alternative for establishing a chronology. The quasi-linear increase of He concentrations with flow distance observed in the Aquia aquifer can be explained entirely by accumulation of in situ produced radiogenic He. U and Th concentrations in Aquia sand were measured in order to determine the accumulation rate of ⁴He with sufficient confidence to establish a He time scale.Concentrations of dissolved atmospheric noble gases were used to derive mean annual ground temperatures at the time of infiltration. These noble gas temperatures (NGTs) clearly show the presence of water that infiltrated under much cooler conditions than at present. NGTs are correlated with chloride concentrations, corroborating the hypothesis that chloride variations in this aquifer constitute a climate signal. In contrast, the stable isotope ratios δ¹⁸0 and δD do not provide a clear record of past climatic changes in the Aquia aquifer and the correlation between NGTs and stable isotope ratios is weak. The NGT record suggests that mean annual temperatures in this midlatitude coastal site during the last glacial maximum (LGM) were (9.0 ± 0.6) °C colder than during the Holocene. This difference is slightly lower than estimates derived from pollen data for this region, but considerably larger than the rather uniform cooling of about 5°C indicated by noble gas studies in more southern locations of North America. The larger cooling is ascribed to the influence of the Laurentide ice sheet, which at its maximum extension came as close as 250 km to our study site.     

A new groundwater radiocarbon correction approach accounting for palaeoclimate conditions during recharge and hydrochemical evolution: The Ledo-Paniselian Aquifer,Belgium

The particular objective of the present work is the development of a new radiocarbon correction approach accounting for palaeoclimate conditions at recharge and hydrochemical evolution. Relevant climate conditions at recharge are atmospheric pCO₂ and infiltration temperatures, influencing C isotope concentrations in recharge waters. The new method is applied to the Ledo-Paniselian Aquifer in Belgium. This is a typical freshening aquifer where recharge takes place through the semi-confining cover of the Bartonian Clay. Besides cation exchange which is the major influencing process for the evolution of groundwater chemistry (particularly in the Bartonian Clay), also mixing with the original porewater solution (fossil seawater) occurs in the aquifer. Recharge temperatures were based on noble gas measurements. Potential infiltration water compositions, for a range of possible pCO₂, temperature and calcite dissolution system conditions, were calculated by means of PHREEQC. Then the sampled groundwaters were modelled starting from these infiltration waters, using the computer code NETPATH and considering a wide range of geochemical processes. Fitting models were selected on the basis of correspondence of calculated δ¹³C with measured δ¹³C. The ¹⁴C modelling resulted in residence times ranging from Holocene to Pleistocene (few hundred years to over 40 ka) and yielded consistent results within the uncertainty estimation. Comparison was made with the δ¹³C and Fontes and Garnier correction models, that do not take climate conditions at recharge into account. To date these are considered as the most representative process-oriented existing models, yet differences in calculated residence times of mostly several thousands of years (up to 19 ka) are revealed with the newly calculated ages being mostly (though not always) younger. Not accounting for climate conditions at recharge (pCO₂ and temperature) is thus producing substantial error on deduced residence times. The derived ¹⁴C model ages are correlated with He concentrations measured in the groundwater of the aquifer. The obtained residence times show a gap between about 14 and 21 ka indicating possible permafrost conditions which inhibited any groundwater recharge.     

Periglacial evidence for a 1.91–1.89 Ga old glacial period at low latitude,Central Sweden

Cryoturbation and slump fold‐like sedimentary structures in ca. 1.9 Ga old dacitic metavolcanic sediments in West Bergslagen, Central Sweden, are recognized as a lowland periglacial environment. This type of environment is comparable with present day tundra in Siberia. Ice‐wedge casts and cryoturbation, together with polygonal frost patterns, are typical geomorphological structures above permafrost in this type of environment. The sedimentary environment could be interpreted as periglacial, broadly comparable to present day tundras. Intensive cryoturbation of the formation and close structural analogy with Quaternary ice‐wedges suggests a cold and humid environment. This discovery is corroborated by a previous report of glacial sediments and structures from NW Australia of ca. 1.8 Ga age. Both occurrences developed at low geographical latitudes, at locations far apart in the Late Palaeoproterozoic supercontinent Columbia. Either suggest the existence of a ca. 100 Ma long epoch of extreme, though possibly intermittent glaciations during the ca. 1.4 Ga long ‘Proterozoic gap’ (～2.2–0.77 Ga) from which no convincing glacial deposits were previously known.     

Insights into palaeorecharge conditions for European deep aquifers

Climatic instability during the late Pleistocene has been reflected in the pattern of groundwater recharge. This report summarizes palaeoclimate knowledge during the late Weichselian in Europe. During this period the majority of northern Europe was covered by thick ice sheets and permafrost, preventing aquifers from recharging. In contrast, southern Europe was generally free of these palaeoclimatic features. Palaeoclimatic information has been combined with isotope data to better understand the palaeorecharge conditions and recharge timing across the European continent. The ¹⁸O and ²H relationship shows latitudinal plus climatic influences. Radiocarbon data show that while southern European aquifers have generally been recharged continuously during the last 40,000 years, northern European aquifers typically show a recharge gap during the Last Glacial Maximum. Areas that underwent continuous recharge during the entire late Pleistocene period can also be distinguished from areas where recharge to aquifers was prevented during the Last Glacial Maximum. Finally, several examples are presented of melt-water recharge or subglacial recharge. The identification of such diversity in the groundwater palaeorecharge in Europe is of great importance for modellers developing management schemes for groundwater resources.     

Groundwater flow system as an archive of palaeotemperature: Noble gas, radiocarbon, stable isotope and geochemical study in the Pannonian Basin, Hungary

To establish the increase in temperature and the time span of the transition between the Late Glacial Maximum (LGM) and the Holocene, the noble gas content, ¹⁸O, ²H, ¹³C δ values, ³H and ¹⁴C activity and chemistry were studied in a groundwater flow system in Quaternary sediments in Hungary. The study area is a sub-basin of the Pannonian Basin, where the C isotope ratios are not influenced by carbonate reactions along the flow path, because the only water-rock interaction is ion exchange. The δ¹⁸O and δ²H values indicate a cold infiltration period, followed by warming, and, finally, warm temperature conditions. The noble gas data show that the average infiltration temperature was 3.3 °C in the cold, 12.9 °C in the warm, and intermediate in the transitional stage. Using the noble gas temperatures, geochemical batch modelling was performed to simulate the chemical processes. Based on the geochemical model, δ¹³C and ¹⁴C₀ (initial radiocarbon activity) in the recharging water were calculated. Transport modelling was used to simulate the distribution of chemical components, δ¹⁸O, δ²H and ¹⁴C₀, along the flow path. It was found that the main processes determining the chemical composition of the groundwater were dissolution/precipitation of calcite and dolomite during infiltration near the surface, and ion exchange along the flow path. In the recharge area the δ¹³C and ¹⁴C₀ were controlled by dissolution and precipitation of carbonate minerals, C speciation, and fractionation processes. All these processes were influenced by the recharge temperature. NGTs calculated from the dissolved noble gas concentrations showed an average of 3.3 °C for cold, and 12.9 °C for warm infiltration, i.e. for the LGM and for the Holocene. The temperature difference was thus 9.1 ± 0.8 °C, which is one of the largest degree of warming detected by noble gases so far. The alkalinity indicates that carbonate reactions were unimportant along the flow path. Owing to the temperature dependence of the equilibrium constants, temperature conditions during infiltration have to be taken into consideration in radiocarbon age calculation. Dispersive transport along the flow path modified the chemical and isotopic composition of infiltrated water. The contribution of the old pore water, which was free of the ¹⁴C isotope, resulted in uncertainties in radiocarbon age determination. It was concluded that determination of the radiocarbon age or mean residence time requires detailed knowledge of the hydraulic conditions of groundwater.     

Hydrochemical trends,palaeorecharge and groundwater ages in the fissured Chalk aquifer of the London and Berkshire Basins,UK

The hydrochemical, radiochemical, stable isotope, ¹⁴C and dissolved noble gas composition of groundwaters has been determined along two profiles across the confined, fissured Chalk aquifer of the London Basin of southern England, and for selected sites in the adjacent Berkshire Basin. During downgradient flow in the London Basin aquifer, the groundwater chemistry is modified by water–rock interactions: congruent and incongruent reaction of the carbonate lithology resulting in enhanced Mg/Ca and Sr/Ca ratios and ¹³C contents with increased residence times; redox and ion exchange reactions; and towards the centre of the Basin, mixing with a residual saline connate water stored in the Chalk matrix. There is evidence from anomalous water chemistries for a component of vertical leakage from overlying Tertiary beds into the confined aquifer as a result of historical dewatering of the aquifer. Dissolved noble gas contents indicate the climate was up to 4.5°C cooler than at present during recharge of the waters now found in the centres of both Basins; stable isotope (²H and ¹⁸O) depletions correspond to this recharge temperature change. For evolved waters having δ¹³C > −8‰ PDB a negative linear correlation is demonstrated between derived recharge temperatures and δ¹³C values, which is interpreted as mixing between relatively warm, light isotopic, fracture-borne waters and cooler stored waters of the matrix having a ¹³C signature more or less equilibrated with the Chalk. From geochemical (¹⁴C, ⁴He) age estimates, the abstracted water is interpreted as being either of wholly Holocene/post-Devensian glacial origin, or an admixture of Holocene and Late Pleistocene pre-glacial (cold stage interstadial) recharge. Devensian pleniglacial stage waters of the Last Glacial Maximum are not represented.     

Small rock‐slope failures conditioned by Holocene permafrost degradation: a new approach and conceptual model based on Schmidt‐hammer exposure‐age dating,Jotunheimen, southern Norway

Rock‐slope failures (RSFs) constitute significant natural hazards, but the geophysical processes that control their timing are poorly understood. However, robust chronologies can provide valuable information on the environmental controls on RSF occurrence: information that can inform models of RSF activity in response to climatic forcing. This study uses Schmidt‐hammer exposure‐age dating (SHD) of boulder deposits to construct a detailed regional Holocene chronology of the frequency and magnitude of small rock‐slope failures (SRSFs) in Jotunheimen, Norway. By focusing on the depositional fans of SRSFs (≤10³ m³), rather than on the corresponding features of massive RSFs (~10⁸ m³), 92 single‐event RSFs are targeted for chronology building. A weighted SHD age–frequency distribution and probability density function analysis indicated four centennial‐ to millennial‐scale periods of enhanced SRSF frequency, with a dominant mode at ~4.5 ka. Using change detection and discreet Meyer wavelet analysis, in combination with existing permafrost depth models, we propose that enhanced SRSF activity was primarily controlled by permafrost degradation. Long‐term relative change in permafrost depth provides a compelling explanation for the high‐magnitude departures from the SRSF background rate and accounts for: (i) the timing of peak SRSF frequency; (ii) the significant lag (~2.2 ka) between the Holocene Thermal Maximum and the SRSF frequency peak; and (iii) the marked decline in frequency in the late‐Holocene. This interpretation is supported by geomorphological evidence, as the spatial distribution of SRSFs is strongly correlated with the aspect‐dependent lower altitudinal limit of mountain permafrost in cliff faces. Results are indicative of a causal relationship between episodes of relatively warm climate, permafrost degradation and the transition to a seasonal‐freezing climatic regime. This study highlights permafrost degradation as a conditioning factor for cliff collapse, and hence the importance of paraperiglacial processes; a result with implications for slope instability in glacial and periglacial environments under global warming scenarios.     

Inactive and relict rock glaciers of the Deboullie Lakes Ecological Reserve,northern Maine,USA

Lobate talus slopes in the Deboullie Lakes Ecological Reserve (DLER) of northern Maine exhibit parabolic profiles characteristic of inactive and relict talus‐derived rock glaciers. Vegetated rock glacier surfaces suggest that the landforms are no longer active, and lobes comprising two DLER rock glaciers document periods of past growth. Observations of perennial subsurface ice are supported by datalogger temperature measurements, indicating that sporadic permafrost exists throughout the DLER. We compare the DLER rock glaciers, along with similar features elsewhere in New England and adjacent Québec, to the modern alpine permafrost distribution. Results indicate that a mean annual temperature cooling of ～6°C is required to promote active rock glacier growth. Ages of plant remains recovered from the basal sediments of a local pond constrain deglaciation to before 11 320 ¹⁴C a BP, and core stratigraphy and organic content reveal that a periglacial environment persisted during the early postglacial era. Thus, we hypothesise that the DLER rock glaciers were active during Lateglacial time despite the lack of glacier activity in the region. We take this to suggest that north‐eastern US rock glaciers formed in response to mean annual temperatures skewed towards the frigid winters of the Younger Dryas chronozone. Copyright © 2009 John Wiley & Sons, Ltd.     

A multi-tracer approach to delineate groundwater dynamics in the Rio Actopan Basin,Veracruz State,Mexico

Geochemistry and environmental tracers were used to understand groundwater resources, recharge processes, and potential sources of contamination in the Rio Actopan Basin, Veracruz State, Mexico. Total dissolved solids are lower in wells and springs located in the basin uplands compared with those closer to the coast, likely associated with rock/water interaction. Geochemical results also indicate some saltwater intrusion near the coast and increased nitrate near urban centers. Stable isotopes show that precipitation is the source of recharge to the groundwater system. Interestingly, some high-elevation springs are more isotopically enriched than average annual precipitation at higher elevations, indicating preferential recharge during the drier but cooler winter months when evapotranspiration is reduced. In contrast, groundwater below 1,200 m elevation is more isotopically depleted than average precipitation, indicating recharge occurring at much higher elevation than the sampling site. Relatively cool recharge temperatures, derived from noble gas measurements at four sites (11–20 °C), also suggest higher elevation recharge. Environmental tracers indicate that groundwater residence time in the basin ranges from 12,000 years to modern. While this large range shows varying groundwater flowpaths and travel times, ages using different tracer methods (¹⁴C, ³H/³He, CFCs) were generally consistent. Comparing multiple tracers such as CFC-12 with CFC-113 indicates piston-flow to some discharge points, yet binary mixing of young and older groundwater at other points. In summary, groundwater within the Rio Actopan Basin watershed is relatively young (Holocene) and the majority of recharge occurs in the basin uplands and moves towards the coast.     

Review: Groundwater in Alaska (USA)

Groundwater in the US state of Alaska is critical to both humans and ecosystems. Interactions among physiography, ecology, geology, and current and past climate have largely determined the location and properties of aquifers as well as the timing and magnitude of fluxes to, from, and within the groundwater system. The climate ranges from maritime in the southern portion of the state to continental in the Interior, and arctic on the North Slope. During the Quaternary period, topography and rock type have combined with glacial and periglacial processes to develop the unconsolidated alluvial aquifers of Alaska and have resulted in highly heterogeneous hydrofacies. In addition, the long persistence of frozen ground, whether seasonal or permanent, greatly affects the distribution of aquifer recharge and discharge. Because of high runoff, a high proportion of groundwater use, and highly variable permeability controlled in part by permafrost and seasonally frozen ground, understanding groundwater/surface-water interactions and the effects of climate change is critical for understanding groundwater availability and the movement of natural and anthropogenic contaminants.     

Dating groundwater in the Bohemian Cretaceous Basin: Understanding tracer variations in the subsurface

The northern section of the Bohemian Cretaceous Basin has been the site of intensive U exploitation with harmful impacts on groundwater quality. The understanding of groundwater flow and age distribution is crucial for the prediction of the future dispersion and impact of the contamination. State of the art tracer methods (³H, ³He, ⁴He, ⁸⁵Kr, ³⁹Ar and ¹⁴C) were, therefore, used to obtain insights to ageing and mixing processes of groundwater along a north–south flow line in the centre of the two most important aquifers of Cenomanian and middle Turonian age. Dating of groundwater is particularly complex in this area as: (i) groundwater in the Cenomanian aquifer is locally affected by fluxes of geogenic and biogenic gases (e.g. CO₂, CH₄, He) and by fossil brines in basement rocks rich in Cl and SO₄; (ii) a thick unsaturated zone overlays the Turonian aquifer; (iii) a periglacial climate and permafrost conditions prevailed during the Last Glacial Maximum (LGM), and iv) the wells are mostly screened over large depth intervals.Large disagreements in ⁸⁵Kr and ³H/³He ages indicate that processes other than ageing have affected the tracer data in the Turonian aquifer. Mixing with older waters (>50 a) was confirmed by ³⁹Ar activities. An inverse modelling approach, which included time lags for tracer transport throughout the unsaturated zone and degassing of ³He, was used to estimate the age of groundwater. Best fits between model and field results were obtained for mean residence times varying from modern up to a few hundred years. The presence of modern water in this aquifer is correlated with the occurrence of elevated pollution (e.g. nitrates).An increase of reactive geochemical indicators (e.g. Na) and radiogenic ⁴He, and a decrease in ¹⁴C along the flow direction confirmed groundwater ageing in the deeper confined Cenomanian aquifer. Radiocarbon ages varied from a few hundred years to more than 20 ka. Initial ¹⁴C activity for radiocarbon dating was calibrated by means of ³⁹Ar measurements. The ¹⁴C age of a sample recharged during the LGM was further confirmed by depleted stable isotope signatures and near freezing point noble gas temperature. Radiogenic ⁴He accumulated in groundwater with concentrations increasing linearly with ¹⁴C ages. This enabled the use of ⁴He to validate the dating range of ¹⁴C and extend it to other parts of this aquifer. In the proximity of faults, ³⁹Ar in excess of modern concentrations and ¹⁴C dead CO₂ sources, elevated ³He/⁴He ratios and volcanic activity in Oligocene to Quaternary demonstrate the influence of gas of deeper origin and impeded the application of ⁴He, ³⁹Ar and ¹⁴C for groundwater dating.     

Residence time of Chalk groundwaters in the Paris Basin and the North German Basin: a geochemical approach

The comparative geochemical and isotopic study of confined and unconfined Chalk groundwaters of the Paris Basin and the N German Basin proves a significant chemical evolution during groundwater flow from the recharge zones to the deep confined aquifer. Different time dependent geochemical parameters have been tested as dating tools: Cation ratios (Sr²⁺/Ca²⁺, Mg²⁺/Ca²⁺), N–NO⁻₃, noble gas contents as paleotemperature indicators (Ne, Ar, Kr, Xe), radiogenic He, ¹³C, ¹⁴C, ¹⁸O, ²H, ³H. Cation ratios and ¹³C show the importance of incongruent dissolution processes in the Chalk aquifer. Water–rock interactions were taken into account in a multi-step dissolution model to determine radiocarbon groundwater ages. The oldest waters in the confined part of the Paris basin Chalk with maximum ¹⁴C ages of 14,000 a B.P. contain pleistocene recharge components as can be shown by a stable isotope depletion and noble gas temperatures significantly lower than in recent groundwaters. Chalk waters at the Lägerdorf site in Northern Germany show a distinct stratification with respect to residence times and hydrochemistry.     

Periglacial wedges and the late Pleistocene environment of Wyoming's intermontane basins

Nonsorted polygons in the uppermost 2 to 3 m beneath Pleistocene surfaces indicate permafrost at 1340 m and higher elevations in the intermontane and piedmont plains of Wyoming during the Wisconsin, and perhaps earlier, glacial maxima. The polygons, as much as 10 m in diameter, are delineated by wedges that vary in depths, range from narrow to moderately flared forms, and deform host materials. The wedges have silty fine-to-medium sand matrices (largely eolian) with pebbles or clasts from hosts of gravel or bedrock. Some wedges may reflect seasonal cracking in a periglacial active zone, but most are either permafrost sand-wedge relics or, less commonly, ice-wedge casts. Alternative explanations are rejected largely because similar features are apparently lacking in the lower and warmer plains from eastern Colorado southward. The wedges suggest an arid, windy, periglacial environment whose mean-annual temperatures are conservatively estimated as some 10° to 13°C colder than those at present. Although late Wisconsin-early Holocene floral and faunal evidence indicates lowered montane biotic zones, the eolian and periglacial features indicate a lack of extensive forest cover on the basin floors. In conjunction with vertebrate-fossil associations of grazing and tundra animals, the wedges may provide a parallel line of evidence for a former periglacial steppe, or “steppe-tundra”, in the Wyoming basins.     

东北末次冰期的古环境

近年,在东北区含有猛犸象、披毛犀动物群的顾乡屯组中测得了一批C¹⁴年龄数据。例如,在典型地点哈尔滨顾乡屯地下10-13米处年龄大于40,000年;在哈尔滨荒山、榆树周家油坊和永吉江南窝堡等剖面中上部为2-3万年,向下不同深度处年龄大于40,000年。又如肇源三站出土的完整松花江猛犸象(Mammuthus sungari Chou et. Chang)(骨架为21,200士600年。在安图明月镇产“安图人”及其化石群的洞穴堆积中为26,560土550-35,370士1800年。在永吉大绥河坝址为17,140士270年。在扎赉诺尔东露天矿上部为11,280土200年,下部巨型猛犸象骨架为33,450士2000年。