An oil spill-food chain interaction model for coastal waters

An oil spill-food chain interaction model, composed of a multiphase oil spill model (MOSM) and a food chain model, has been developed to assess the probable impacts of oil spills on several key marine organisms (phytoplankton, zooplankton, small fish, large fish and benthic invertebrates). The MOSM predicts oil slick thickness on the water surface; dissolved, emulsified and particulate oil concentrations in the water column; and dissolved and particulate oil concentrations in bed sediments. This model is used to predict the fate of oil spills and transport with respect to specific organic compounds, while the food chain model addresses the uptake of toxicant by marine organisms. The oil spill-food chain interaction model can be used to assess the environmental impacts of oil spills in marine ecosystems. The model is applied to the recent Evoikos-Orapin Global oil spill that occurred in the Singapore Strait.     

Analysis of the reliability of a statistical oil spill response model

A statistical oil spill response model is developed and validated by means of actual oil slick observations reported during the Prestige accident and trajectories of drifter buoys. The model is based on the analysis of a database of hypothetical oil spill scenarios simulated by means of a Lagrangian transport model. To carry out the simulations, a re-analysis database consisting of 44-year hindcast dataset of wind and waves and climatologic daily mean surface currents is used. The number of scenarios required to obtain statistically reliable results is investigated, finding that 200 scenarios provide an optimal balance between the accuracy of the results and the computational effort. The reliability of the model was analyzed by comparing the actual data with the numerical results. The agreement found between actual and numerical data shows that the developed statistical oil spill model is a valuable tool to support spill response planning.     

Scientific management of Mediterranean coastal zone: a hybrid ocean forecasting system for oil spill and search and rescue operations

The oil spill from Prestige tanker showed the importance of scientifically based protocols to minimize the impacts on the environment. In this work, we describe a new forecasting system to predict oil spill trajectories and their potential impacts on the coastal zone. The system is formed of three main interconnected modules that address different capabilities: (1) an operational circulation sub-system that includes nested models at different scales, data collection with near-real time assimilation, new tools for initialization or assimilation based on genetic algorithms and feature-oriented strategic sampling; (2) an oil spill coastal sub-system that allows simulation of the trajectories and fate of spilled oil together with evaluation of coastal zone vulnerability using environmental sensitivity indexes; (3) a risk management sub-system for decision support based on GIS technology. The system is applied to the Mediterranean Sea where surface currents are highly variable in space and time, and interactions between local, sub-basin and basin scale increase the non-linear interactions effects which need to be adequately resolved at each one of the intervening scales. Besides the Mediterranean Sea is a complex reduced scale ocean representing a real scientific and technological challenge for operational oceanography and particularly for oil spill response and search and rescue operations.     

A high-resolution operational forecast system for oil spill response in Belfast Lough

This paper presents a high-resolution operational forecast system for providing support to oil spill response in Belfast Lough. The system comprises an operational oceanographic module coupled to an oil spill forecast module that is integrated in a user-friendly web application. The oceanographic module is based on Delft3D model which uses daily boundary conditions and meteorological forcing obtained from COPERNICUS and from the UK Meteorological Office. Downscaled currents and meteorological forecasts are used to provide short-term oil spill fate and trajectory predictions at local scales. Both components of the system are calibrated and validated with observational data, including ADCP data, sea level, temperature and salinity measurements and drifting buoys released in the study area. The transport model is calibrated using a novel methodology to obtain the model coefficients that optimize the numerical simulations. The results obtained show the good performance of the system and its capability for oil spill forecast.     

Impact of adsorbed petroleum hydrocarbons on marine organisms

Adsorptions of south Louisiana crude oil from seawater by clays, non-clay minerals and sediments were conducted in the laboratory. Effect of sediment-adsorbed and water dispersed crude oil on adult oysters were investigated in aquaria. Hydrocarbons in oyster tissues and surrounding water were identified by gas chromatography. Field specimens from an area of a new oil spill and an area five months after an oil spill were also analysed. Evidence of secondary chemical effect of aged oil in sediments on oyster mortality is presented. Oil coated asbestos surfaces severely reduced recruitment of sedentary larval organisms.     

Wind and freshwater influence over hydrocarbon dispersal on Patos Lagoon, Brazil

The two-dimensional barotropic, hydrodynamic and transport model MOHID is applied to the Patos Lagoon system using a nested modelling approach to reproduce both the lagoon and estuary hydrodynamics. A new Lagrangian oil spill model is presented and used to simulate a hypothetical oil spill in the estuary. Hydrodynamic fields are validated and used to force the oil model. Results show that the hydrodynamics of this system is mainly controlled by the wind and freshwater discharge. The dispersion, concentration and thickness evolution of the oil in the first day after the spill is determined by the equilibrium between these two factors. The freshwater discharge is the major factor controlling the oil dispersion for discharges greater than 5000 m3 while the wind assumes control for lower discharge amounts. The results presented are a first step toward a coastal management tool for the Patos Lagoon.     

Effects of an oil spill on benthic community production and respiration on subtropical intertidal sandflats

This study determined effects of an oil spill on subtropical benthic community production and respiration by monitoring CO₂ fluxes in benthic chambers on intertidal sandflats during emersion before and after an accidental spill. The oil spill decreased sediment chlorophyll a concentrations, altered benthic macrofaunal community, and affected ecological functioning by suppressing or even stopping microalgal production, increasing bacterial respiration, and causing a shift from an autotrophic system to a heterotrophic system. Effects of the oil spill on the macrofauna were more severe than on benthic microalgae, and affected sedentary infauna more than motile epifauna. Despite the oil spill’s impact on the benthic community and carbon metabolism, the affected area appeared to return to normal in about 23 days. Our results suggest that the prompt response of benthic metabolism to exposure to petroleum hydrocarbons can serve as a useful indicator of the impact of an oil spill.     

The environmental and biotic impact of the oil spill in Kerch Strait in November 2007

The effect of an emergency oil spill in Kerch Strait in November 2007 on the environment and biota in the southern Sea of Azov is analyzed based on the material of integrated expedition studies carried out by the Southern Scientific Center, RAS, before and after shipwrecks and during monitoring within a year after the emergency.     

Impacts of a fuel oil spill on seagrass meadows in a subtropical port, Gladstone, Australia--the value of long-term marine habitat monitoring in high risk areas

We used an established seagrass monitoring programme to examine the short and longer-term impacts of an oil spill event on intertidal seagrass meadows. Results for potentially impacted seagrass areas were compared with existing monitoring data and with control seagrass meadows located outside of the oil spill area. Seagrass meadows were not significantly affected by the oil spill. Declines in seagrass biomass and area 1month post-spill were consistent between control and impact meadows. Eight months post-spill, seagrass density and area increased to be within historical ranges. The declines in seagrass meadows were likely attributable to natural seasonal variation and a combination of climatic and anthropogenic impacts. The lack of impact from the oil spill was due to several mitigating factors rather than a lack of toxic effects to seagrasses. The study demonstrates the value of long-term monitoring of critical habitats in high risk areas to effectively assess impacts.     

Tidal-induced inorganic carbon dynamics in the Strait of Gibraltar

This study presents the distribution of dissolved inorganic carbon (DIC) along the Strait of Gibraltar, its tidal-induced variability, as well as the inorganic carbon exchange between the Atlantic Ocean and Mediterranean Sea. During November 2003, water column samples were collected at nine stations to measure total alkalinity (TA), pH, and dissolved oxygen (DO) for the spatial characterization of the carbonate system. At the same time, anchored samplings were carried out, above the Camarinal Sill and in the Eastern Section of the Strait, in order to assess the tidal mixing effects for oxygen and DIC distribution on the water column. Three distinct water masses can be discerned in this area: the Surface Atlantic Water (SAW), the Mediterranean Water (MW), and the less abundant North Atlantic Central Water (NACW). The observations show an increase in the DIC and a decrease in oxygen concentration with depth, related to the different physico-chemical features of each water mass. The results show the high time-dependence of the vertical distribution of DIC with the interface oscillation, affected by the intense mixing processes taking place in the Strait. Intense mixing episodes over the Camarinal Sill are responsible for an increase in the DIC concentrations in the upper layer of the Eastern Section of the Strait. Higher DIC concentrations in the Mediterranean than in the Atlantic waters are responsible for a net DIC transport of 1.47×10¹² mol C yr⁻¹ to the Atlantic Ocean. Nevertheless, the net exchange is highly sensitive to the interface definition, as well as to the estimate of water volume transport used.     

The Tsesis oil spill impact on the pelagic ecosystem

On 26 October, 1977, the tanker Tsesis grounded in the Swedish archipelago, 65 km south of Stockholm (northern Baltic proper, 59°N, 18°E). The Tsesis carried 17575 t of No. 5 fuel oil. The total spill was estimated as being somewhat more than 1000 t, of which about 600–700 t were recovered, thus leaving about 300 t in the environment. The spill occurred only about 5 km east of the Askö Laboratory, a marine ecological station, which made a relatively fast sampling response possible. The effects on the pelagic ecosystem were studied for 1 month following the spill. Severe effects were recorded only in the immediate vicinity of the wreck where zooplankton biomass declined substantially during the first few days after the spill. Within 5 days the zooplankton biomass was re-established. Oil contamination of zooplankton was recorded for over 3 weeks. It is suggested that an increased phytoplankton biomass and primary production in the impacted area was due to decreased zooplankton grazing rates. Increased bacterial numbers and the oil degradation pattern indicated a rapid bacterial degradation of hydrocarbons in the water column. Sediment traps positioned in the area demonstrated the importance of sedimentation as a pathway for removal of oil from the water column. During the second week after the spill, 0.7% of sedimented material was petroleum hydrocarbons. Using sediment trap data, a total sedimentation of 30–60 t of oil was estimated in the impacted area (42 km²). This corresponds to 10–15% of the unrecovered oil.     

Impacts of a fuel oil spill on seagrass meadows in a subtropical port,Gladstone, Australia – The value of long-term marine habitat monitoring in high risk areas

We used an established seagrass monitoring programme to examine the short and longer-term impacts of an oil spill event on intertidal seagrass meadows. Results for potentially impacted seagrass areas were compared with existing monitoring data and with control seagrass meadows located outside of the oil spill area.Seagrass meadows were not significantly affected by the oil spill. Declines in seagrass biomass and area 1 month post-spill were consistent between control and impact meadows. Eight months post-spill, seagrass density and area increased to be within historical ranges. The declines in seagrass meadows were likely attributable to natural seasonal variation and a combination of climatic and anthropogenic impacts. The lack of impact from the oil spill was due to several mitigating factors rather than a lack of toxic effects to seagrasses. The study demonstrates the value of long-term monitoring of critical habitats in high risk areas to effectively assess impacts.     

An evaluation of marine bird population trends following the Exxon Valdez oil spill, Prince William Sound, Alaska

We examined post-spill trends (1989-1998) of marine bird populations in Prince William Sound (PWS) following the Exxon Valdez oil spill (EVOS) to evaluate recovery of injured taxa. Two criteria were employed. First, we examined population trends of injured taxa only in the oiled area of PWS using regression models. Second, we examined population trends of injured taxa in the oiled area relative to the unoiled area using homogeneity of the slopes tests. We considered a population recovering if there was a positive trend using either criteria. We considered a population not recovering if there was no trend using either criteria or a negative trend in the oiled area. A significant negative trend in the oiled area relative to the unoiled area was considered a continuing and increasing effect. Most taxa for which injury was previously demonstrated were not recovering and some taxa showed evidence of increasing effects nine years after the oil spill. Four taxa (loons Gavia spp, Harlequin Duck Histrionicus histrionicus, Bufflehead Bucephala spp, and North-western Crow Corvus caurinus) showed weak to very weak evidence of recovery. None of these taxa showed positive trends in both winter and summer. Nine taxa (grebes Podiceps spp, cormorants Phalacrocorax spp, Black Oystercatcher Haematopus bachmani, Mew Gull Larus canus, Glaucous-winged Gull Larus glaucescens, terns Sterna spp, murres Uria spp, Pigeon Guillemot Cepphus columba, and murrelets Brachyramphus spp) showed no evidence of recovery during summer or winter. Four taxa (scoters Melanitta spp, mergansers Mergus spp, goldeneyes Bucephala spp, and Black-legged Kittiwaka Rissa tridactyla) showed evidence of continuing, increasing effects. We showed evidence of slow recovery, lack of recovery, and divergent population trends in many taxa which utilize shoreline and nearshore habitats where oil is likely to persist. Potential lingering spill effects and natural variability appear to be acting in concert in delaying recovery of many PWS bird populations.     

Temporal and geographical trends in the genotoxic effects of marine sediments after accidental oil spill on the blood cells of striped beakperch (Oplegnathus fasciatus)

To determine the impact of genetic toxicity caused by the Hebei Spirit oil spill on December 7, 2007, we measured DNA damage in the blood cells of striped beakperch in vitro after exposure to extracts from sediments in the Taean area. The objective of this study was to investigate temporal changes of toxic effects caused by residual PAHs in the sediments up to 18 months after an oil spill. In conclusion, DNA damage had reduced over this 18-month period; that is, the sediments recovered quickly from the oil pollution. In addition, statistically significant correlations between PAHs and DNA damage were observed. Because the comet assay is sensitive to DNA damage induced by genotoxic substances from the polluted sediments, the comet assay can be considered a useful tool as a biomarker in investigating genetic toxicity in environmental monitoring and elucidating the recovery of oil pollution after oil spill as well.     

Different dynamics and routes of modern pollen transport in the northern and southern parts of the South China Sea

The pollen distribution patterns of surface marine sediments indicated that the mechanisms of pollen transportation, the routes of pollen dispersal and their source areas are distinctively different between the northern and southern parts of the South China Sea. The maximum loadings of most palynomorphs which usually adapted to wind transport and flotation (e.g. pine pollen and spores) occur in the northern part, adjacent to the convergence of the Taiwan Strait and Bashi Strait rather than the estuaries of big rivers, suggesting that the transport of N-E winter monsoon and monsoon-forced current is primarily responsible for pollen distribution in this area. The pollen source area should be quite large, including probably not only the south of mainland and adjacent islands but also the southeastern part of China. There is another group of pollen, smaller and denser such asQuercus and tropical-subtropical forms, which is clustered close to the continent and islands. Such a pattern is a result of fluvial transport and the pollen might come from the adjacent areas. In the southern part, however, the pollen concentrations are much lower, and decrease with distance from the shore or the depth of water, implying the effects of fluvial and offshore current transport and also the relatively local pollen source area, e.g. Borneo     

Enhancing the management response to oil spills in the Tuscany Archipelago through operational modelling

A new approach towards the management of oil pollution accidents in marine sensitive areas is presented in this work. A set of nested models in a downscaling philosophy was implemented, externally forced by existing regional operational products. The 3D hydrodynamics, turbulence and the oil transport/weathering models are all linked in the same system, sharing the same code, exchanging information in real time and improving its ability to correctly reproduce the spill. A wind-generated wave model is also implemented using the same downscaling philosophy. Observations from several sources validated the numerical components of the system. The results obtained highlight the good performance of the system and its ability to be applied for oil spill forecasts in the region. The success of the methodology described in this paper was underline during the Costa Concordia accident, where a high resolution domain was rapidly created and deployed inside the system covering the accident site.     

Interaction of oil and mineral fines on shorelines: review and assessment

The interaction of fine mineral particles with stranded oil in an aqueous medium reduces the adhesion of the oil to solid surfaces, such as sediments or bedrock. The net result is the formation of stable, micron-sized, oil droplets that disperse into the water column. In turn, the increase in surface area makes the oil more available for biodegradation. This interaction, referred to as oil–mineral aggregate (OMA) formation, can explain how oiled shorelines are cleaned naturally in the absence of wave action in very sheltered coastal environments. OMA formation also plays an important role in the efficacy of shoreline treatment techniques, such as physical mixing and sediment relocation that move oiled sediments into the zone of wave action to promote the interaction between oil and mineral fines. Successful application of these shoreline treatment options has been demonstrated at two spill events (the Tampa Bay response in Florida and the Sea Empress operation in Wales) and at a controlled oil spill experiment in the field (the 1997 Svalbard ITOSS program). Sediment relocation harnesses the hydraulic action of waves so that the processes of fine-particle interaction and physical abrasion usually occur in tandem on open coasts. There has been no evidence of significant detrimental side-effects of residual oil in pelagic or benthic environments associated with the use of these treatment options to enhance rates of dispersion and oil biodegradation.     

Backward probabilistic model of groundwater contamination in non-uniform and transient flow

Backward location and travel time probabilities, which provide information about the former location of contamination in an aquifer, can be used to identify unknown contamination sources. Backward location probability describes the possible upgradient positions of contamination at a known time in the past, and backward travel time probability describes the time required for contamination to travel from a known upgradient location to an observation point. These probabilities are related to adjoint states of resident concentration, and their governing equation is the adjoint of a forward contaminant transport model. Using adjoint theory to obtain the appropriate governing equation, we extend the backward probability model for conservative solutes to more general non-uniform and transient flow fields. In particular, we address three important extensions, spatially-varying porosity, transient flow and temporally-varying porosity, and internal distributed sources and sinks of solute and water. For the first time we learn that forward and backward location and travel time probabilities are not necessarily equivalent to adjoint states, but are related to them. The extensions are illustrated using a vertically-integrated groundwater model, creating transient flow by a step change in pumping and using areal recharge as an internal distributed source. Both the movement and spread of probabilities are affected. With internal sources of water, there are two interpretations of backward probability, depending on whether or not the source of water is also a source of solute. The results demonstrate how the backward probability model can be applied to other, perhaps more important, non-uniform and transient flow conditions, with time- and space-varying water storage, such as time-varying pumping or unsaturated (or saturated–unsaturated) flow and transport with spatially- and temporally-varying moisture content.     

Estimating and quantifying oil contamination on the shoreline

A wide range of parameters can be used to describe the degree of oil contamination on the shoreline following a spill. This study compares five parameters, obtained by visual estimates and systematic ground mapping on a gravel beach at an experimental spill site. For shoreline cleanup decisions the most relevant parameter involves the measurement of the area of surface oil cover and calculation of the volume of contaminated sediments. Accurate estimates of the volume of oil on the shore require sampling and measurements of the concentrations of oil in the sediments. The reliability of aerial or ground estimates of the oil distribution on a gravel beach decreases with time as the colour of the surface oil changes to blend with the local sediments.     

盘锦地区地下水位映震效能分析

盘锦地区深井水位观测始于上世纪七八十年代,观测资料连续可靠,在辽宁省及邻区发生的中强地震前有很好的前兆信息。通过研究盘锦地区深井水位的多年动态,分析典型震例,并利用基于GIS的地震分析预报系统等,探讨了水位变化和油田开采的关系,总结了盘锦地区地下水位的映震效能。