Eliminierung von Abwasserinhaltsstoffen durch Kombination biochemischer und grenzflächenchemischer Mechanismen

Recent developments and future trends of waste water treatment by combined biochemical and adsorptive elimination steps are presented. Various mechanisms are discussed to explain the enhancement of conventional activated sludge systems by addition of different solid adsorbents. Special emphasis is given to the improvement of elimination capacity and operation stability caused by powdered or granular activated carbons. The results of laboratory experiments as well as large-scale applications suggest that combinations of biological systems with by-product carbonaceous materials are most likely to gain future importance in waste water treatment facilities.     

Zur adsorptiven Eliminierung ausgewählter Pestizide aus wäßrigen Lösungen. Teil 2: Gemischadsorption von 2,4-Dichlorphenol und 8-Hydroxychinolin

Competitive adsorption equilibria were determined for mixtures consisting of the biologically active xenobiotics 2,4-dichlorophenol and 8-hydroxyquinoline. The adsorption data as well as their pH dependence could be adequately represented by using numerical solutions of the IAS theory and the potential theory, respectively. Breakthrough curves for various adsorptive systems are discussed for the compounds under consideration with respect to competition effects.     

Elektrochemische Einschätzung des Oberflächenzustandes von Wasserreinigungskohlen

Electrochemical Characterization of the Surface of Activated Carbon Used in Water Treatment Plants. We tried to measure electrochemically those properties of activated carbons which are important for using them for water purification. A success was achieved with the electrochemical immersion potential U_i which is found to be a function of concentration of functional surface groups on the carbon surface. However, the expected direct proportionality for inert surfaces between BET surface area and amount of charge measured in recharge processes has not been observed.     

Efficiency of Moso Bamboo Charcoal and Activated Carbon for Adsorbing Radioactive Iodine

Preventing radioactive pollution is a troublesome problem but an urgent concern worldwide because radioactive substances cause serious health‐related hazards to human being. The adsorption method has been used for many years to concentrate and remove radioactive pollutants; selecting an adequate adsorbent is the key to the success of an adsorption‐based pollution abatement system. In Taiwan, all nuclear power plants use activated carbon as the adsorbent to treat radiation‐contaminated air emission. The activated carbon is entirely imported; its price and manufacturing technology are entirely controlled by international companies. Taiwan is rich in bamboo, which is one of the raw materials for high‐quality activated carbon. Thus, a less costly activated carbon with the same or even better adsorptive capability as the imported adsorbent can be made from bamboo. The objective of this research is to confirm the adsorptive characteristics and efficiency of the activated carbon made of Taiwan native bamboo for removing ¹³¹I gas from air in the laboratory. The study was conducted using new activated carbon module assembled for treating ¹³¹I‐contaminated air. The laboratory results reveal that the ¹³¹I removal efficiency for a single‐pass module is as high as 70%, and the overall efficiency is 100% for four single‐pass modules operated in series. The bamboo charcoal and bamboo activated carbon have suitable functional groups for adsorbing ¹³¹I and they have greater adsorption capacities than commercial activated carbons. Main mechanism is for trapping of radioiodine on impregnated charcoal, as a result of surface oxidation. When volatile radioiodine is trapped by potassium iodide‐impregnated bamboo charcoal, the iodo‐compound is first adsorbed on the charcoal surface, and then migrates to iodide ion sites where isotope exchange occurs.     

Kurzzeitermittlung der Ablaufqualität von Belebtschlammanlagen anhand der Atmungsaktivität

For checking the quality of the effluent from an activated sludge plant for waste-waters from the sulphite pulp production the respiration of an activated sludge sample in air-saturated water is determined initially without the addition of substrate (ground respiration) and after that with an addition of substrate (methanol, substrate respiration) by means of the Clark-electrode. The measuring device is designed by means of zero displacement in such a way that the difference of the oxygen concentration is indicated by a time relay as the difference quotient. Between the ground respiration and the effluent concentration of BOD₅ exists a significant positive regression, which can be used for controlling the plant. The determination of the substrate respiration serves only for checking with respect to perhaps given inhibition of the conversion of matter by the activated sludge. The determination of the activity of the activated sludge sample takes only 20 min; inclusive of the required determination of the dry matter of sludge, the technique provides a well reproducible measured value for the biochemical conversion in the activated sludge plant within 1… 1.5 h.     

Zum Umweltverhalten von Fluortensiden. Teil 3: Reinigung der industriellen Abwässer

Four fluorotensides which are used mainly industrially are investigated with respect to their removability from waters. Since, in general, fluorotensides are difficult to remove or not at all removable biochemically, the effects of chemical or physicochemical treatment processes are tested. As the results represented in pictures and tables show, different modes of behaviour can be recognized with respect to the respective purification effect for the investigated fluorotensides, partly among them. Flocculation with Al- and Fe-salts as well as chlorination and ozonization show only partial effects. But all the investigated fluorotensides can be adsorptively eliminated by means of powder or granular active charcoal and adsorbent resin Wofatit EA₆₀.     

安哥拉红砂现场试坑浸水试验研究

为准确评价安哥拉红砂场地的自重湿陷特征,开展现场试坑浸水试验,对地表及不同深度地层变形、水分入渗规律和浸水前后标贯击数进行监测与研究,并对现场试验与室内试验结果差异性进行探讨。结果表明：浸水后红砂地基表现为持续抬升,变形曲线可分为陡升、缓升、不稳定和趋于稳定4个阶段;深度8 m以上红砂地层为湿陷沉降变形,累计沉降量为5.6 mm,远小于室内试验计算的自重湿陷沉降量137 mm;红砂竖向渗透速率和水平渗透速率均较大,浸水和停水后红砂含水率变化较快,红砂持水性较差,浸水过程中红砂地层的饱和度小于80%,为非饱和渗透;浸水后红砂地层标贯击数显著降低,具有显著的软化特性。红砂较大的渗透系数和较差的持水性导致红砂很难达到饱和状态,是自重湿陷沉降量实测值远小于计算值的因素之一,一般工程建设中建议可不考虑红砂地基的湿陷特性,而将其按软化特性进行设计。研究结果不仅可指导红砂场地未来工程建设,还可为其他砂土湿陷性评价提供借鉴。     

Gesetzmäßigkeiten des Sauerstoffaustausches zwischen Gewässer und Atmosphäre im Flußmündungsgebiet

Meteorological conditions, biochemical processes in water bodies and anthropogenic pressure of a region are the main factors to determine the atmosphere water-body gas exchange. Research on oxygen outflows in the Dnjepr estuary region has shown that though gas exchange with atmosphere permanently exists its intensity varies throughout a day, vegetation period, year. The process of evasion is the most active in the flood plain pools of the river. Oxygen exchange between the atmosphere and a river is to be determined with physical characteristics of water outflow and with the anthropogenic influence. Oxygen absorption from the atmosphere is dominating for the liman water area in spite of differences between its parts. The obtained results have shown that gas exchange between river estuary pools and the atmosphere is of great importance for the oxygen balance of these pools.     

Determining hydraulic resistance in gravel‐bed rivers from the dynamics of their water surfaces

Traditionally, approaches to account for the effect of the boundary roughness of a gravel‐bed river have used a grain‐size index of the bed surface as a surrogate for hydraulic resistance. The use of a single grain‐size does not take into account the spatial heterogeneity in the bed surface and how this heterogeneity imparts resistance on the flow, nor the way in which this relationship changes with variables such as flow stage. A new technique to remotely quantify hydraulic resistance is proposed. It is based on measuring the dynamics of a river's water surface and relating this to the actual hydraulic resistance created by a rough sediment boundary. The water surface dynamics are measured using a new acoustic technique, grazing angle sound propagation (GRASP). This proposed method to measure hydraulic resistance is based on a greater degree of physical reasoning, and this is discussed in the letter. By measuring acoustically the temporal dynamics of turbulent water surfaces over a water‐worked gravel bed in a laboratory flume, a dependency is demonstrated between the temporal variation in the reflected acoustic pressure and measured hydraulic resistance. It is shown that the standard deviation in acoustic pressure decreases with increasing hydraulic resistance. This is shown to apply for a range of relative submergences and bed slopes that are typical of gravel‐bed rivers. This remote sensing technique is both rapid and inexpensive, and has the potential to be applied to natural river channels and to other environmental turbulent flows, such as overland flows. A whole new class of low‐cost, remote and non‐intrusive instruments could be developed as a result and used in a wide range of hydraulic and hydrological applications. Copyright © 2006 John Wiley & Sons, Ltd.     

Untersuchungen zur Bestimmung und zum Vorkommen des Thiocyanats im Wasserkörper der westlichen Ostsee

For the gas-chromatographic determination of thiocyanate in waters two enrichment processes were used: 1) the evaporation of the water sample on the water bath and 2) the adsorptive enrichment on Wofatit EA 60. As the example of the investigation of water samples from the Baltic Sea has shown, the less selective process 1 gave higher results of measurements than the adsorptive method 2. As compared with the GDR's coastal region of the Baltic (0.4 … 5.2 μg/l), the SCN^? concentrations (1986) in the western offshore region (0.1 … 2.1 μg/l) are considerably lower. With increasing depth and growing salt content the SCN^? concentration in the Baltic decreases. Anthropogenic influences, such as the input of residual products of sewage works effluents, can be inferred from the relatively increased SCN^? concentrations in the coastal region.     

Simulation von Variablen der Fließgewässerqualität mittels Mehrfachregressionen

There are investigated the variables O₂, BOD₅, seston, NO₃-N, NH₄-N and o-PO₄ from at least five-year series of five stations along a river section of 50 km. After exclusion of a linear trend and substraction of the individual monthly mean values from the monthly mean of many years in order to eliminate the effect of the annual variation as well as testing for normal distribution, first the correlation coefficients of the variables to the flow rate Q and the temperatures of air and water are determined, which show directional changes just in the longitudinal profile of the river. The same holds for the correlation of the variables between the measuring points. From this the model structure is derived, according to which the concentration at one measuring station can be simulated by multiple regression to Q and T at the same level as well as the concentration at the upper level. The results are discussed in detail and evaluated with respect to their inclusion in longterm management models of water quantity management.     

Schwermetallbestimmung in Klärwerksschlämmen mittels Röntgenfluoreszenzanalyse

The X-ray fluorescence analysis is an important means for the determination of the heavy metal concentrations in sewage sludges and for the evaluation of their usability in agriculture. Analysis devices from the GDR were used for that. For the investigations there was used as the zero sample a sludge which was not loaded with heavy metals, homogeneous and constantly dried at 105 °C. The drying bed sludge samples were treated with different heavy metal solutions with different concentrations. Preparation of samples, measuring conditions and general spectra are described. The measuring results of tests up to 100 g heavy metal in 1 kg dry substance are critically evaluated. The analysis of a sewer sludge sample takes only about ten minutes. There are determined: Cr, Ni, Cu, Zn, Mo, Cd, Hg and Pb.     

Zur akuten Toxizität von Trichlorfon gegenüber ausgewählten Wasserorganismen

Two different formulations of Trichlorfon were examined for their acute toxicity in laboratory tests. Cyprinus carpio L., Salmo gairdneri Rich. and the fish food organisms Cyclops spec., Diaptomus spec. and Chironomus spec. were used as test objects. The differences in toxicity between crystalline and technical Trichlorfon were not very large. The recorded lethal concentrations are summarized in graphical representations and tables. After exposure for several hours to lower concentrations of active constituents, the toxicant-damaged fishes regained their original activity of life during a subsequent phase of recovery Tests of fish food organisms with 100 … 200 μg/l Trichlorfon led to death within 48 hours. Also on chironomid larvae Trichlorfon has a lethal effect at 0.2 mg/l within 48 hours. Toxicity is increased by the hardness constituents of the water. As experiments conducted with Crustacea have shown, growth is inhibited only at a certain concentration in the body.     

Gewässergütebewertung und Bewertung von Abwasserfahnen in Rhein und Main auf der Basis mikrobieller Enzymaktivitäten

Quality Mapping of Surface Water and Assessment of Treated and Untreated Waste-water Inputs into the Rhine and Main River Based on Microbial Enzyme Activities Microbial enzyme activities are used for an extension of the traditional quality mapping of surface water. In the following study, the enzymatic parameters were proved and validated on samples from various creeks and rivers in Baden-Württemberg and on samples gathered from the Rhine and Main Rivers (Germany). The test parameters should also be used for the control and the preservation of the capacity of the biological self-purification, which is the only natural and essential process in drinking-water conditioning of surface water. Main subject of the surveys was the development of criteria for an assessment of the measured enzymatical inhibition effects. Therefore, classes of inhibition and indices of inhibition are defined.     

海原断裂带刺儿沟古地震剖面炭屑~(14)C年龄及其意义

在青藏高原东北缘海原断裂带刺儿沟古地震剖面上不仅保存了地震活动的崩积楔遗迹,还发现多层炭屑以及与人类活动有关的铁渣、陶片等遗物,文中运用14C测年法和经红外释光照射后的绿光释光测年法(Post-IR OSL)分别对剖面上的炭屑、烘烤黏土、沉积物等样品进行年龄测定和比对,获得了各炭屑层和人类活动遗迹的年代。测定的人类活动遗迹年代与海原周缘历史记载的强震发生时间序列比对结果表明,刺儿沟人类活动遗迹的形成可能与历史地震无关,过去以炭屑年代作为地层年代来限定古地震发生的时代,建立的古地震事件时序的结果可能不正确,上述工作为进一步研究海原断裂带的强震复发规律和海原地区考古提供了重要的基础资料     

Atomabsorptionsspektrometrische Metallbestimmung in natürlichen Gewässern und Abwässern

With the aid of the Soviet atomic-absorption two-channel spectrometer “Saturn” successful attempts were made to improve the sensitivity of the heavy-metal determination after the previous two-step separation and concentration technique. Compared with other combustible gases, the propane/nitrogen-oxide flame is preferred. Because of the possibility of the direct determination of the heavy metals in the water samples the duration of analyses could be reduced by fifty per cent. Besides the heavy-metal analytics, a rapid-determination technique for calcium and magnesium was developed. The results of the different determination techniques and the ranges of measurement are given in several tables.     

4D signal enhancement using singular-value decomposition: application to mapping oil–water contact movement across the Nelson Field

A new method for time‐lapse signal separation and enhancement using singular‐value decomposition is presented. Singular‐value decomposition is used to separate a 4D signal into its constituent parts: common geology, time‐lapse response and noise. Synthetic tests which demonstrate the advantages of the singular‐value decomposition technique over traditional differencing methods are also presented. This signal separation and enhancement technique is used to map out both the original and moved oil–water contacts across the Nelson Field. The singular‐value decomposition technique allows the oil–water contact to be mapped across regions which would have been missed using traditional differencing methods. In particular, areas toward the edges of the field are highlighted by the technique. The oil–water contact is observed to move upwards across the field, with the largest movements being associated, as anticipated, with natural production. The results obtained are broadly consistent with those predicted by the reservoir simulator model. Singular‐value decomposition is demonstrated to be a useful tool for enhancing the time‐lapse signal and for gaining confidence in areas where traditional differencing fails.     

Wirkung der Chlorung auf die Abläufe einer Großkläranlage und ihres Vorfluters

To protect a water for the purpose of local recreation – inclusive of bathing – the effluent of an upstream clarification plant was chlorinated. Due to poorly controlled dosing, residual chlorine quantities exceeding the permissible level entered the receiving stream, its biocenosis having been considerably endangered. Detrimental effects on the chemical composition are graphically represented by the measured results for some waters – partly criteria of quality. There is explained that the self-purification capacity of the water decreased by about 30 % and that the hydrobiological species composition of periphyton was reduced by about 80 %. Finally, advice is given concerning the prevention of such damages to waters.     

Die gaschromatographische Bestimmung von Diethylentriaminpentaessigsäure in Oberflächenwasser

Gaschromatographic Determination of Diethylenetriaminepentaacetic Acid in Surface Water. A method for the determination of diethylenetriaminepentaacetic acid (DTPA) is reported. The determination is based on the preconcentration on a strong base anion exchange resin, esterification with n-propanol and following gaschromatographic separation using a N-selective detector. The sensitivity of the method, including enrichment, is 1 μg/L in river water. The identity of DTPA in river water was proved by mass spectrography. The method can be used also for the quantitative determination of nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), cyclohexanediaminetetraacetic acid (CDTA) and ethyleneglycolbis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid (EGTA). The method was used to examine river water. An investigation along the river Rhine, taking grab samples from January and february 1992 showed that DTPA was present in some sampling places in similiar concentrations as NTA and EDTA.