Paleomagnetism of mid-Cretaceous red beds in west-central Kyushu Island, southwest Japan: paleoposition of Cretaceous sedimentary basins along the eastern margin of Asia

A paleomagnetic study was carried out on the mid-Cretaceous sedimentary strata in west-central Kyushu Island, southwest Japan, to elucidate the origin of sedimentary basins along the Asian continental margin in the Cretaceous. We collected paleomagnetic samples from a total of 34 sites of the mid-Cretaceous Goshonoura Group, shallow-marine clastic deposits in west-central Kyushu, and characteristic remanent magnetizations were recognized from 18 horizons of red beds. Thermal demagnetization has revealed that the red beds contain three magnetization components, with low (<240°C), intermediate (240-480°C), and high (480-680°C) unblocking temperatures. The low unblocking temperature component is present-field viscous magnetization, and the intermediate one is interpreted as chemical remanent magnetization carried by maghemite that was presumably formed by post-folding, partial oxidation of detrital magnetite. Rock magnetic and petrographic studies suggest that the high unblocking temperature component resides largely in hematite (martite and pigmentary hematite) and partly in maghemite. Because of the positive fold test, this high temperature component can be regarded as primary, detrital remanent magnetization. The tilt-corrected mean direction of the high temperature component is Dec=65°, Inc=63° with α₉₅=5°, which yields a paleomagnetic pole at 39°N, 186°E and A₉₅=8°. A combination of this pole with those of the Late Cretaceous rocks in southwest Japan defines an apparent polar wander path (APWP), which is featured by a cusp between the Late Cretaceous and the Paleogene. A comparison of this APWP with the coeval paleomagnetic pole from northeast Asia suggests an approximately 50° post-Cretaceous clockwise rotation and 18±8° southward drift with respect to northeast Asia. The southward transport of the Cretaceous basin suggests that the proto-Japanese arc originated north of its present position. We propose that the coast-parallel translation of this landmass was caused by dextral motion of strike-slip faults, which previous geodynamic models interpreted to be sinistral through the Mesozoic. The change in strike-slip motion may have resulted from Mesozoic collision and penetration of exotic terranes, such as the Okhotsk microcontinent, with the northeastern part of Asia.     

New paleomagnetic result from the Ethiopian flood basalts in the Abbay (Blue Nile) and Kessem gorges

New paleomagnetic investigations on the Ethiopian trap series have been undertaken at the Abbay and Kessem gorges in an attempt to better constrain the 30 Ma paleomagnetic pole of Africa. We sampled six thick massive basaltic lava flows, totaling 230 m, from Abbay Gorge and 10 lava flows, 180 m in thickness, from Kessem Gorge. Detailed paleomagnetic analyses disclosed that the carriers of the characteristic remanent magnetization (ChRM) are different in different lava flows. These are mostly titanomagnetites, titanomaghemites, and magnetite minerals with a broad range of coercive force and blocking temperatures. The heating and cooling susceptibility vs. temperature curves, many of which are irreversible, may indicate chemical remagnetization, notably low temperature maghemitization. Only one flow (KS04) with a clear 580°C Curie temperature was apparently unaffected by chemical remagnetization. The ChRM direction of this flow is identical to that in other flows, which suggests that if and when remagnetization occurred, this was shortly after emplacement of the lava flows. All of the flows sampled have normal polarity. However, a reversed component of low to medium coercive force and low to medium unblocking temperature occurs in flow KS01 at Kessem Gorge. The ChRM directions for the 16 sites are D=3.1°, I=5.8° (α₉₅=12.7°). The paleomagnetic pole obtained from these is at λ=83.0°N, φ=193.3°E (A₉₅=9.0°). Comparison with three previous studies of the traps shows remarkable consistency and a number of means are derived and discussed. Two final preferred poles for the traps are at λ=79.0°N, φ=196.9°E (A₉₅=2.8°) when all 112 published flows are used, and λ=78.7°N, φ=209.4°E (A₉₅=3.4°) when only the 76 flows from the four more recently analyzed sections are included. Both are compatible with the recent reference synthetic pole for Africa of Courtillot and Besse [J. Geophys. Res. (2002) in press]. In that sense, the Ethiopian trap pole is not anomalous and does not require more of a non-dipolar contribution than indicated by analyses of the global paleomagnetic data base covering the last few million years.     

Age estimation of the deposition of the cretaceous Upper Sandstones and a later remagnetization event,from Hirna area,SE Ethiopia

Outcrops of the Cretaceous Upper sandstone formation some 375 km to the East of Addis Ababa on the motor Highway to Harar was paleomagnetically investigated. About seventy core samples were collected at various stratigraphic levels from 250–300 meters thick sedimentary formation. After standard sample preparations in the laboratory the resulting specimens were subjected to routine paleomagnetic demagnetization protocol. In the first steps of demagnetizations process the recent and viscous magnetizations were removed by heating until a temperature of level of 300 °C. Further demagnetization of the samples resulted in the isolation of the final magnetization with stable line segments that is directed towards the origin, which is interpreted as Characteristic Remanent Magnetization (ChRM). Rock – magnetic experiments have identified goethite (αFeOOH), hematite (αFe₂O₃), detritial hematite, and magnetite as the magnetic mineral phases carrying the remanence. The ChRM identified resulted in an average value of (D_s = 0.5°, I_s = ?0.7°, α₉₅ = 4.3°, N = 34) for the red sandstones while an average value of (D_s = 335.8°, I_s = ?31.8°, α₉₅ = 4.7°, N = 14) for the limestone intercalations. The former ChRM in the red sandstone is determined to be secondary while the latter ChRM is known to be primary. Comparison of these directional results and their pole equivalents with the African plate Apparent Polar Wander Path curve established by Besse and Courtillot (2003) give ages of between 115–130 Million years for the limestone intercalation and ages of 30 million years for red sandstone unit. These are interpreted respectively as estimates of the age of deposition and a later remagnetization respectively.     

Distortion of the geomagnetic field in volcanic terrains: an experimental study of the Mount Etna stratovolcano

The inclination (I), declination (D) and total intensity (F) of the geomagnetic field were measured on Mount Etna in 1989-1991 at a dozen sites previously sampled for archeomagnetic studies. The purpose of the work was to determine the variations of these parameters at 30 cm above ground level, and how the distortion from the main field can affect the archeomagnetic record of volcanic rocks. Ten measurements were usually performed at each site with a three-component flux-gate magnetometer, whose estimated precision is ±0.2° on direction and ±50 nT on intensity. This was considered sufficient on volcanic areas with highly magnetized rocks and where the geomagnetic gradient may be in excess of 1000 nT/m. Results averaged for each site generally show small variations in intensity (±3% of the total field) and direction (±1.5°). The averaged values of the 12 sites (I=52.6°, D=0.3°, F=44010 nT) are very close to those measured in sedimentary terrain away from the volcano (I=52.9°, D=0.35°, F=44110 nT), themselves consistent with the interpolated IGRF in eastern Sicily. The largest deviations of the geomagnetic direction have been observed on four sites, three of them located on the South flank between 1900 and 700 m elevation. It is suggested that these anomalies are mainly related to dyke swarms which are common within the South Rift Zone of Mount Etna. Our findings show that reliable archeomagnetic results can be obtained from volcanic rocks, provided that lavas of the same eruption are sampled on several sites distributed over the largest possible area.     

New paleomagnetic results from Ceno-Mesozoic volcanic rocks along southern rim of the Tarim Basin,China*

Paleomagnetic samples were collected from four localities located in the southern rim of the Tarim basin. The samples were taken from volcanic rocks erupted between Jurassic and Quaternary. Detailed analysis of all samples has been carried out with progressive thermal demagnetization. A characteristic remanence (ChRM) with higher unblocking temperature has been isolated from all samples. The pole position from the middle Jurassic is at 52.5°N, 187.9°E(dp = 3.7°,dm =6.5°); the directions of the ChRM of Cretaceous correspond to a paleopole at 69.7°N, 211.6°E (dp = 9.8°,dm = 15.9°); the Quaternary pole from the Pulu site is at 79. 9°N, 183.1°E(dp = 1.6°.dm =2.4°). On the basis of these new paleomagnetic data, tectonic evolution of Tarim block is presented.     

拉萨地块中部晚白垩世火山岩Ar-Ar年代学和古地磁研究结果及其构造意义

为进一步确定拉萨地块白垩纪-古近纪的古地理位置,我们对青藏高原拉萨地块措勤地区林子宗火山岩18个采点进行了古地磁研究.结果表明高温(高场)特征剩磁分量主要为亚铁磁性的磁铁矿所携带,特征剩磁分量在95%置信水平下通过了褶皱检验. 倾斜校正后采点平均的特征剩磁方向为D/I=16.2°/17.7°, α95=5.6°,对应古地磁极位置为63.1°N,224.6°E,A95=5.1°. 另一方面,Ar-Ar年代学结果表明采样剖面的林子宗火山岩形成年龄为~99-93 Ma, 与拉萨地块林周盆地的林子宗群火山岩的形成年龄存在较大差异.由此我们得到晚白垩世拉萨地块中部措勤地区的古纬度为8.5°±6.9°N,与林周盆地古近纪林子宗群典中组和年波组所揭示出的古纬度相当,进一步表明亚洲大陆最南缘的拉萨地块在晚白垩世-古近世期间位于北半球~10°N的低纬度地区.结合最新的特提斯海相地层古地磁结果,晚白垩世-古近世拉萨地块的古地理位置限定了印度与欧亚大陆的初始碰撞时间不晚于60.5 Ma;~93 Ma以来,拉萨地块和单一刚性欧亚大陆之间存在~1900 km的构造缩短.     

New Cambrian paleomagnetic pole for Yangtze Block

A total of 120 samples from 12 sites were collected from two flanks of a fold. Stepwise thermal demagnetization has successfully revealed characteristic magnetization components from the rocks in each case. A well-defined component determined from red fine-grained sandstone is clustered in the northeasterly direction with shallow upward inclination (D = 29.3°,I= -19.2°,k = 283.7, α₉₅ = 7.3°. tilt-corrected). The pole position (39.5°N, 247.3°E,dp = 4.0°,dm = 7.6°) derived from this component is close to the Permian pole for the Yangtze Block, indicating that the red fine-grained sandstone has been overprinted. The red mudstone reveals two characteristic components Component A with lower unblocking temperature, characterized by northerly declination and moderate to steep inclination corresponds to a pole position overlay with the present North Pole. Component B (D = 129.1°,I=-23.6°,k = 44.6, α₉₅ = 7.8°, tilt-corrected) with higher unblocking temperature, passes fold test, and yields a pole position (39.5°S, 185.l°E,dp = 4.4°,dm = 8.3°) different from the other poles for the Yangtze Block. It is therefore suggested that component B was probably a primary magnetization and the Yangtze Block was situated at low latitudes in the Southern Hemisphere in the Middle Cambrian.     

Inversion of magnetic measurements of the CHAMP satellite over the Pannonian Basin

The Pannonian Basin is a deep intra-continental basin that formed as part of the Alpine orogeny. In order to study the nature of the crustal basement we used the long-wavelength magnetic anomalies acquired by the CHAMP satellite. The anomalies were distributed in a spherical shell, some 107,927 data recorded between January 1 and December 31 of 2008. They covered the Pannonian Basin and its vicinity. These anomaly data were interpolated into a spherical grid of 0.5° × 0.5°, at the elevation of 324 km by the Gaussian weight function. The vertical gradient of these total magnetic anomalies was also computed and mapped to the surface of a sphere at 324 km elevation. The former spherical anomaly data at 425 km altitude continued downward to 324 km. To interpret these data at the elevation of 324 km we used an inversion method. A polygonal prism forward model was used for the inversion. The minimum problem was solved numerically by the Simplex and Simulated annealing methods; a L₂ norm in the case of Gaussian distribution parameters and a L₁ norm was used in the case of Laplace distribution parameters. We interpret that the magnetic anomaly was produced by several sources and the effect of the sable magnetization of the exsolution of hemo-ilmenite minerals in the upper crustal metamorphic rocks.     

New paleomagnetic results from Ceno-Mesozoic volcanic rocks along southern rim of the Tarim Basin,China*

Paleomagnetic samples were collected from four localities located in the southern rim of the Tarim basin. The samples were taken from volcanic rocks erupted between Jurassic and Quaternary. Detailed analysis of all samples has been carried out with progressive thermal demagnetization. A characteristic remanence (ChRM) with higher unblocking temperature has been isolated from all samples. The pole position from the middle Jurassic is at 52.5°N, 187.9°E(dp = 3.7°,dm =6.5°); the directions of the ChRM of Cretaceous correspond to a paleopole at 69.7°N, 211.6°E (dp = 9.8°,dm = 15.9°); the Quaternary pole from the Pulu site is at 79. 9°N, 183.1°E(dp = 1.6°.dm =2.4°). On the basis of these new paleomagnetic data, tectonic evolution of Tarim block is presented.

     

Origin and evolution of two contrasting thermal groundwaters (CO2-rich and alkaline) in the Jungwon area,South Korea: Hydrochemical and isotopic evidence

In the Jungwon area, South Korea, two contrasting types of deep thermal groundwater (around 20–33 °C) occur together in granite. Compared to shallow groundwater and surface water, thermal groundwaters have significantly lower δ¹⁸O and δD values (> 1‰ lower in δ¹⁸O) and negligible tritium content (mostly < 2 TU), suggesting a relatively high age of these waters (at least pre-thermonuclear period) and relatively long subsurface circulation. However, the hydrochemical evolution yielded two distinct water types. CO₂-rich water (P_CO2 = 0.1 to 2 atm) is characterized by lower pH (5.7–6.4) and higher TDS content (up to 3300 mg/L), whereas alkaline water (P_CO2 = 10^− 4.1–10^− 4.6 atm) has higher pH (9.1–9.5) and lower TDS (< 254 mg/L). Carbon isotope data indicate that the CO₂-rich water is influenced by a local supply of deep CO₂ (potentially, magmatic), which enhanced dissolution of silicate minerals in surrounding rocks and resulted in elevated concentrations of Ca²⁺, Na⁺, Mg²⁺, K⁺, HCO₃⁻ and silica under lower pH conditions. In contrast, the evolution of the alkaline water was characterized by a lesser degree of water–rock (granite) interaction under the negligible inflow of CO₂. The application of chemical thermometers indicates that the alkaline water represents partially equilibrated waters coming from a geothermal reservoir with a temperature of about 40 °C, while the immature characteristics of the CO₂-rich water resulted from the input of CO₂ in Na–HCO₃ waters and subsequent rock leaching.     

Paleomagnetism of gabbros of the Early Proterozoic Blachford Lake Intrusive Suite and the Easter Island dyke,Great Slave Lake,NWT: Possible evidence for the earliest continental drift

The Caribou Lake gabbro, part of the Blachford Lake Intrusive Suite accurately dated at –2186±10 mA, has a predominantNW–/SE+ magnetization with a mean, irrespective of sign, ofD=119°,I=50°, ₉₅=5° and a palaeopole 14°N, 064°W,A ₉₅=5°; it has not proved possible to determine if the magnetization is primary. The Easter Island dyke, less well-dated in the range –2200 to –2500 Ma, has a predominantWNW+ magnetization, whose mean, when corrected for an 8° tilt, isD=288°,I=46°, ₉₅=5 and palaeopole is 32°S, 2°W,A ₉₅=5°; the magnetization is probably primary. A vertical magnetization (D), not significantly different from the present field, occurs sporadically in both units and is considered to be Late Phanerozoic in age. Palaeopoles from the Caribou Lake gabbro and the Easter Island dyke, together with those already known from Early Proterozoic intrusives of the Archaean Slave Structural Province, roughly define a swath (the Slave Track) which maps the motion of the Slave Province relative to the geomagnetic axis during this interval. The corresponding array of palaeopoles (the Superior Track) from the Superior Structural Province does not fall in the same place. Hence it would appear that Slave and Superior were not in their present relative positions in the Early Proterozoic in disagreement with arguments that have been made for a fixed supercontinent during much of the Proterozoic. Mid-Proterozoic paleomagnetic signatures indicate that Slave and Superior had assumed their present relative position by about –1750 mA. These Early Proterozoic relative motions are the earliest for which there is palaeomagnetic evidence.Earth Physics Branch Contribution No. 1111.     

Effects of alumina refinery wastewater and signature metal constituents at the upper thermal tolerance of: 2. The early life stages of the coral Acropora tenuis

The success of early life history transitions of the coral Acropora tenuis were used as endpoints to evaluate thermal stress and the effects of wastewater discharged to a tropical marine environment. The studies assessed the effects of: (i) temperature; (ii) three signature metals of the wastewater, aluminium (Al), vanadium (V) and gallium (Ga); and (iii) the wastewater (at 27 °C and 32 °C) on fertilisation and larval metamorphosis. The median inhibition temperatures for fertilisation and metamorphosis were 32.8 °C and 33.0 °C, respectively. Fertilisation IC₅₀s for Al, V and Ga were 2997, 2884 and 3430 μg L⁻¹, respectively. Metamorphosis IC₅₀s for Al, V and Ga were 1945, 675 and 3566 μg L⁻¹, respectively. The wastewater only affected fertilisation and metamorphosis at moderate concentrations (IC₅₀s = 63% and 67%, v/v, respectively, at 27 °C), posing a low risk to this species in the field. The effects of wastewater and temperature on fertilisation and metamorphosis were additive.     

Intrusion of ultramafic magmatic bodies into the continental crust: Numerical simulation

Intrusions of ultramafic bodies into the lower density continental crust are documented for a large variety of tectonic settings spanning continental shields, rift systems, collision orogens and magmatic arcs. The intriguing point is that these intrusive bodies have a density higher by 300-500 kg m⁻³ than host rocks. Resolving this paradox requires an understanding of the emplacement mechanism. We have employed finite differences and marker-in-cell techniques to carry out a 2D modeling study of intrusion of partly crystallized ultramafic magma from sublithospheric depth to the crust through a pre-existing magmatic channel. By systematically varying the model parameters we document variations in intrusion dynamics and geometry that range from funnel- and finger-shaped bodies (pipes, dikes) to deep seated balloon-shaped intrusions and flattened shallow magmatic sills. Emplacement of ultramafic bodies in the crust lasts from a few kyr to several hundreds kyr depending mainly on the viscosity of the intruding, partly crystallized magma. The positive buoyancy of the sublithospheric magma compared to the overriding, colder mantle lithosphere drives intrusion while the crustal rheology controls the final location and the shape of the ultramafic body. Relatively cold elasto-plastic crust (T_Moho = 400 °C) promotes a strong upward propagation of magma due to the significant decrease of plastic strength of the crust with decreasing confining pressure. Emplacement in this case is controlled by crustal faulting and subsequent block displacements. Warmer crust (T_Moho = 600 °C) triggers lateral spreading of magma above the Moho, with emplacement being accommodated by coeval viscous deformation of the lower crust and fault tectonics in the upper crust. Strong effects of magma emplacement on surface topography are also documented. Emplacement of high-density, ultramafic magma into low-density rocks is a stable mechanism for a wide range of model parameters that match geological settings in which partially molten mafic-ultramafic rocks are generated below the lithosphere. We expect this process to be particularly active beneath subduction-related magmatic arcs where huge volumes of partially molten rocks produced from hydrous cold plume activity accumulate below the overriding lithosphere.     

Paleomagnetism of the Djebel Reouina Namurian Formation (Tindouf Basin,Algeria)

The paleomagnetic study of the Namurian of Reouina (28.9°N, 08.0°W) revealed the existence of two magnetization components, either juxtaposed or superimposed, besides a viscous component. The high blocking temperature component, carried by hematite, has a mean direction defined by D = 126.9° and I = 10.8°. It provides a Namurian paleomagnetic pole located at 28.4°S and 56.9°E (K = 642, A ₉₅=1.7°). The second component is carried at least in part, by grains with blocking temperatures lower than 550°C. Though well defined, it consists of two superimposed components, the high unblocking temperature component with a likely Permian overprint.     

New Early Cretaceous paleomagnetic results from Qilian orogenic belt and its tectonic implications

Lower Cretaceous red sedimentary rocks from the depositional basin of East Qilian fold belt have been collected for a paleomagnetic study. Stepwise thermal demagnetization reveals two or three components of magnetization from dark red sandstones. Low-temperature magnetic component is consistent with the present Earth Field direction in geographic coordinates. High-temperature magnetic components are mainly carried by hematite. The mean pole of 19 sites for high-temperature magnetic components after tilt-correction is λ=62.2°N, φ=193.4°E, A95=3.2°, and it passes fold tests at 99% confidence level and reversal tests at 95% confidence level. The paleopole is insignificantly different from that of Halim et al. (1998) from the same sampling area at the 95% confidence level. Compared with paleomagnetic results for North China, South China, and Eurasia, our results suggest that no significant relative latitudinal displacement has taken place between Lanzhou region and these blocks since Cretaceous time. Remarkably, the pole of Lanzhou shows a 20° clockwise rotation with respect to those of North China, South China, and Eurasia. Geological information indicates that the crustal shortening in the western part of Qilian is greater than that in eastern part. In this case, the clockwise rotation of sampling area was related to India/Eurasia collision, and this collision resulted in a left-lateral strike-slip motion of the Altun fault in north Tibetan Plateau after the Cretaceous.     

Effects of low tide rainfall on the erodibility of intertidal cohesive sediments

Low tide rainfall may represent an important but little studied process affecting sediment fluxes on intertidal mudflats. In this study, we simulated rainfall events on an intertidal mudflat (median grain size=18.4 μm) of low slope (1 in 300) then quantified effects on sediment erodibility. Treatments consisted of a high (4.1 mm min⁻¹ for 6 min) and low (0.36 mm min⁻¹ for 60 min) rain intensity, chosen to match naturally occurring events and experiments were conducted seasonally (May and August) to encompass variations in ambient sediment stability. Changes in bed elevation due to rainfall were estimated using marked rods and sediment erodibility parameters (mass of sediment eroded at a flow velocity of 0.3 m s⁻¹ (ME-30, g m⁻²) and critical erosion velocity (U_crit, m s⁻¹)) were determined in annular flumes (bed area=0.17 m²). Ambient/control sediment erodibility in May (ME-30=211 g m⁻², U_crit=0.18 m s⁻¹) was higher than in August (ME-30=30 g m⁻², U_crit=0.26 m s⁻¹) and was correlated with changes in biological activity. In May, surface sediment was influenced by high densities of the bioturbating snail Hydrobia ulvae (1736 ind. m⁻²) and low biomass of the sediment stabilising microphytobenthos (5.7 μg chlorophyll a cm⁻²). In contrast, in August H. ulvae densities were low (52 ind. m⁻²) and microphytobenthic biomass higher (9.2 μg chlorophyll a cm⁻²). The high rain treatment caused a decrease in bed elevation of between 1.5 mm (May) and 4.4 mm (August) and significantly reduced sediment organic content and microphytobenthic biomass. Rainfall increased sediment erodibility; compared to ambient sediments ME-30 increased by a factor of 1.4× in May and 8.8× in August and caused a 10–30% decline in U_crit. The seasonal difference in treatment effect was due to the change in ambient sediment stability. The low rain treatment in August had no effect on bed elevation, microphytobenthic biomass or sediment erodibility. In May, the same treatment caused a reduction in bed elevation (0.5 mm) and microphytobenthic biomass but counter-intuitively, a decrease in sediment erodibility (ME-30 was reduced by 40%, U_crit increased by 5%) compared to controls. We attribute this result to removal by rainfall of easily eroded surface flocs and biogenic roughness which resulted in an underlying sediment with a smoother surface and greater resistant to erosion. Results suggest that high intensity rain events may destabilise intertidal sediments making them more susceptible to erosion by returning tidal currents and that the sediment eroded during such events may represent a considerable fraction (up to 25%) of the seasonal variation in shore elevation. The impact of natural rain events are likely to vary considerably due to variations in droplet size, intensity and duration and the interaction with ambient sediment stability.     

Palaeomagnetism of the Börzsöny Mountains (Hungary)

Summary Mean directions of magnetization (29 normal and 31 reversed) were recorded for 60 magmatic localities of middle Miocene age from the Börzsöny Mountains (Hungary). The overall mean direction of RM, irrespective of polarity, isD=0,9°;I=59,8°; withk=8,3 and ₉₅=6,8°. The coordinates of the corresponding geomagnetic north pole are =82,7°, A=193,8 with p=7,7° and m=10,2°.     

Paleomagnetism of ordovician lamprophyres from Taylor Valley,Victoria Land,Antarctica

Paleomagnetic study of specimens from four lamprophyric dykes on the Kukri Hills, Taylor Valley (77.64°S, 163.35°E) has yielded a primary mean direction of magnetization ofD=222.6 andI=+0.6 with ₉₅=10.9° after AF cleaning. The magnetization of five other dykes and of the amphibolitic basement was either unstable or not fully reliable.The corresponding pole position lies at 9.3°S and 26.7°E and confirms the previous results from Lower Ordovician rocks from distant areas of East Antarctica.A Lower Ordovician mean pole position recalculated from valid data lies at 17°S, 21°E.     

Paleomagnetic study of some Cretaceous and tertiary rocks on Hispaniola

Summary A reconnaissance paleomagnetic study of Hispaniola shows that three igneous units in the Dominican Republic possess meaningful directions of magnetism. A Late Cretaceous tonalite, an Eocene pyroxene diorite and a Miocene andesite porphyry have been investigated. The rock material studied is fresh, and has not been affected by secondary oxidation except in the case of the andesite which is occasionally weathered and reveals some hydrothermal alteration. Alternating field and thermal demagnetization result in removal of viscous remanence in some samples, while others reveal a good stability of NRM and little change in direction. The results disclose directions of magnetization substantially different from that of the present earth's field in Hispaniola and from those obtained from contemporaneous rocks of North America. They yield paleomagnetic poles at 23.1° N, 144.9° W for the Cretaceous tonalite and at 17.4° N, 138.0° W for the Eocene diorite, the positions of which are not significantly different from each other, suggesting no change of geomagnetic field direction during the two epochs. These poles have generally similar positions to those obtained from Late Cretaceous rocks on Jamaica and Puerto Rico. The Miocene data fall into two groups, one having a direction corresponding to a pole closely coinciding with the Miocene North American pole and the other giving a paleomagnetic pole at 68.3° N, 151.9° W coinciding with the Miocene pole for Jamaica. Paleotectonic interpretation of the results suggests that like other Greater Antilles, Hispaniola has been subject to large anticlockwise rotation since Late Cretaceous.     

Numerical modeling of a long-term in situ chemical osmosis experiment in the Pierre Shale,South Dakota

We have numerically modeled evolving fluid pressures and concentrations from a nine-year in situ osmosis experiment in the Pierre Shale, South Dakota. These data were obtained and recently interpreted by one of us (C.E.N.) as indicating a potentially significant role for chemical osmosis in media like the Pierre Shale. That analysis considered only the final pressure differentials among boreholes that were assumed to represent osmotic equilibrium. For this study, the system evolution was modeled using a recently developed transient model for membrane transport. The model simulates hydraulically and chemically driven fluid and solute transport. The results yield an estimate of the thickness of the water film between the clay platelets b of 40 Å, which corresponds to an osmotic efficiency σ of 0.21 for the ambient pore water salinity of 3.5 g/l TDS. These values largely confirm the results of the earlier equilibrium analysis. However, the new model analysis provides additional constraints suggesting that intrinsic permeability k = 1.4 × 10⁻¹⁹ m², specific storage S_s = 1.7 × 10⁻⁵ m⁻¹, and diffusion coefficient D* = 6 × 10⁻¹¹ m²/s. The k value is larger than certain independent estimates which range from 10⁻²¹ to 10⁻²⁰; it may indicate opening of microcracks during the experiments. The fact that the complex transient pressure and concentration behavior for the individual wells could be reproduced quite accurately, and the inferred parameter values appear to be realistic for the Pierre Shale, suggests that the new model is a useful tool for modeling transient coupled flows in groundwater systems.