Viscosity of microlite-bearing rhyolitic obsidians: an experimental study

 To investigate the influence of microlites on lava flow rheology, the viscosity of natural microlite-bearing rhyolitic obsidians of calc-alkaline and peralkaline compositions containing 0.1–0.4 wt.% water was measured at volcanologically relevant temperatures (650–950  °C), stresses (10³–10⁵ Pa) and strain rates (10^–5 to 10^–7 s^–1). The glass transition temperatures (T _g ) were determined from scanning calorimetric measurements on the melts for a range of cooling/heating rates. Based on the equivalence of enthalpic (calorimetric) and shear (viscosity) relaxation, we calculated the viscosity of the melt in crystal-bearing samples from the T _g data. The difference between the calculated viscosity of the melt phase and the measured viscosity for the crystal-bearing samples is interpreted to be the physical effect of microlites on the measured viscosity. The effect of <5 vol.% rod-like microlites on the melt rheology is negligible. Microlite-rich and microlite-poor samples from the same lava flow and with identical bulk chemistry show a difference of 0.6 log₁₀ units viscosity (Pa s), interpreted to be due to differences in melt chemistry caused by the presence of microlites. The only major differences between measured and calculated viscosities were for two samples: a calc-alkaline rhyolite with 1 vol.% branching crystals, and a peralkaline rhyolite containing crystal-rich bands with >45 vol.% crystals. For both of these samples a connectivity factor is apparent, with, for the latter, a close packing framework of crystals which is interpreted to influence the apparent viscosity. Received: 14 March 1996 / Accepted: 30 May 1996     

Enigmatic clastogenic rhyolitic volcanism: The Corral de Coquena spatter ring,North Chile

We report on the unusual occurrence of the products of lava fountaining in a Pliocene calc-alkaline rhyolitic monogenetic center from northern Chile. Corral de Coquena is a discontinuous ring of lava located in the moat of La Pacana caldera (23°27' S, 67°23.5' W), part of the Altiplano-Puna Volcanic Complex of the Central Andes. The volcanic structure is composed of a maar-like crater, with an associated pyroclastic (possibly phreatomagmatic) unit, that is overlain by rhyolitic glassy lava ramparts, in which evidence of spatter, agglutinate and clastogenic material is found. Typical explanations for the unusual textures in a rhyolitic lava, such as peralkaline composition, high volatile content, or superheated magma are untenable in this case. We propose that the most likely explanation for this extreme style of rhyolitic volcanism is a combination of moderately high eruption rate and efficient degassing prior to eruption. In the light of reports of several other bodies of fountain-fed silicic magma from the UK, US, and Japan, we propose that Corral de Coquena is a rhyolitic spatter ring superimposed upon a maar-like crater. We further propose that pyroclastic fountaining should be considered an end-member of the spectrum of eruptive styles of calc-alkaline silicic magmas, and that Corral de Coquena is a rare example, preserved because of the hyper-arid climate in the Altiplano-Puna Volcanic Complex.     

Effusive eruption of viscous silicic magma triggered and driven by recharge: a case study of the Cerro Chascon-Runtu Jarita Dome Complex in Southwest Bolivia

 The Cerro Chascon-Runtu Jarita Complex is a group of ten Late Pleistocene (∼85 ka) lava domes located in the Andean Central Volcanic Zone of Bolivia. These domes display considerable macroscopic and microscopic evidence of magma mixing. Two groups of domes are defined chemically and geographically. A northern group, the Chascon, consists of four lava bodies of dominantly rhyodacite composition. These bodies contain 43–48% phenocrysts of plagioclase, quartz, sanidine, biotite, and amphibole in a microlite-poor, rhyolitic glass. Rare mafic enclaves and selvages are present. Mineral equilibria yield temperatures from 640 to 750  °C and log ƒO₂ of –16. Geochemical data indicate that the pre-eruption magma chamber was zoned from a dominant volume of 68% to minor amounts of 76% SiO₂. This zonation is best explained by fractional crystallization and some mixing between rhyodacite and more evolved compositions. The mafic enclaves represent magma that intruded but did not chemically interact much with the evolved magmas. A southern group, the Runtu Jarita, is a linear chain of six small domes (<1 km³ total volume) that probably is the surface expression of a dike. The five most northerly domes are composites of dacitic and rhyolitic compositions. The southernmost dome is dominantly rhyolite with rare mafic enclaves. The composite domes have lower flanks of porphyritic dacite with ∼35 vol.% phenocrysts of plagioclase, orthopyroxene, and hornblende in a microlite-rich, rhyodacitic glass. Sieve-textured plagioclase, mixed populations of disequilibrium plagioclase compositions, xenocrystic quartz, and sanidine with ternary composition reaction rims indicate that the dacite is a hybrid. The central cores of the composite domes are rhyolitic and contain up to 48 vol.% phenocrysts of plagioclase, quartz, sanidine, biotite, and amphibole. This is separated from the dacitic flanks by a banded zone of mingled lava. Macroscopic, microscopic, and petrologic evidence suggest scavenging of phenocrysts from the silicic lava. Mineral equilibria yield temperatures of 625–727  °C and log ƒO₂ of –16 for the rhyolite and 926–1000  °C and log ƒO₂ of –9.5 for the dacite. The rhyolite is zoned from 73 to 76% SiO₂, and fractionation within the rhyolite composition produced this variation. Most of the 63–73% SiO₂ compositional range of the lava in this group is the result of mixing between the hybrid dacite and the rhyolite. Eruption of both groups of lavas apparently was triggered by mafic recharge. A paucity of explosive activity suggests that volatile and thermal exchanges between reservoir and recharge magmas were less important than volume increase and the lubricating effects of recharge by mafic magmas. For the Runtu Jarita group, the eruption is best explained by intrusion of a dike of dacite into a chamber of crystal-rich rhyolite close to its solidus. The rhyolite was encapsulated and transported to the surface by the less-viscous dacite magma, which also acted as a lubricant. Simultaneous effusion of the lavas produced the composite domes, and their zonation reflects the subsurface zonation. The role of recharge by hotter, more fluid mafic magma appears to be critical to the eruption of some highly viscous silicic magmas. Received: 23 August 1998 / Accepted: 10 March 1999     

Taupo Volcanic Zone calc-alkaline tephras on the peralkaline Mayor Island volcano, New Zealand: identification and uses as marker horizons

Mayor Island is a peralkaline rhyolitic caldera volcano characterised by numerous, sector-confined pyroclastic deposits, together with lavas forming at least five composite shields. Correlation of sequences between sectors is difficult because of the scarcity of island-wide marker beds. However, eight distal calc-alkaline fall tephras (ca. 7.3 ¹⁴C ka to 64 ka) from Okataina and Taupo volcanic centres in the nearby Taupo Volcanic Zone (TVZ) have been identified on the island. These “foreign” TVZ tephras provide marker planes to correlate activity in different sectors of Mayor Island volcano, and refine an eruptive chronology. At least seventeen pyroclastic eruptions and fourteen lava-producing events (including multiple, shield-forming events) have occurred in the past ca. 64 ka. Age controls provided by the calc-alkaline tephras confirm the extremely local dispersal characteristics of many of the Mayor Island eruptives and show that K/Ar ages as young as 25–33 ka on obsidians with 4.2–4.4% K₂O are reliable.     

Volcanological aspects of peralkaline silicic welded ash-flow tuffs

Peralkaline silicic welded ash-flow tuffs differ characteristically in a number of properties from most calc-alkaline welded tuffs, due to their generally lower viscosity and higher temperatures. For example, individual cooling units are relatively small (less than 30 m thick, less than 5 km³ in volume); rocks can be thoroughly welded and crystallized to feldspar, quartz, and mafic minerals; several primary deformational structures (e.g. lineations, stretching of pumice, folds, ramp structures) indicate late stage laminar creep, resulting from the low yield strength of the nearly homogeneous glass of very low viscosity. Theoretical considerations also suggest that peralkaline melts are of low viscosity and high temperature, as inferred from,e.g., their chemical composition (high iron- and alkali-, and low alumina-concentrations). The low viscosity may also be due to trapping of volatiles. Absence or paucity of OH-bearing phenocryst phases, paucity of pyroclastic rocks, other than ash flow tuffs, formed from highly explosive eruptions, and apparently high crystallization temperatures, indicate that peralkaline silicic magmas are comparatively dry. The common occurrence of peralkaline ash-flow tuffs may be due to an increased water content of the magmas, resulting also in amphibole phenocrysts in some welded tuffs, or to specific volcanotectonic conditions. Ash flows of peralkaline composition move as particularly dense particulate flows. This type of flowage and the very rapid welding of the low viscosity glass lead to a high degree of homogenization of the fine glass shards. This in turn inhibits complete degassing of the collapsing ash flow. Semiclosed systems result where gas overpressures can develop and where volatiles play an important role by fluxing crystallization and transporting dissolved matter. Several types of vesicles can form under these conditions: (a) Spherical vesicles within collapsed ash and pumice particles formed after deposition of the ash flow. (b) Round or irregular vesicles transsecting pyroclastic particles, vesicle sheets, and large cavities, several m in diameter, may form in a largely homogenized ash-flow tuff beneath tightly welded layers. (c) Lensoid cavities formed during granophyric crystallization of large pumice particles. Small ash particles of peralkaline composition may assume spherical shapes due to their low viscosity and in some cases, expansion of bubbles. They form during transport and are preserved under low load pressure in the top part of cooling units. Globule lavas and most froth flows are interpreted as welded ash-flow tuffs, some of their unusual features being due to their peralkaline composition.     

Silicic phreatomagmatism in the Snake River Plain: the Deadeye Member

Non-welded rhyolitic pyroclastic units in the central Snake River Plain are interbedded with the much better exposed, large-volume ‘Snake-River type’ rheomorphic welded rhyolitic ignimbrites and rhyolite lavas. We document one such unit to investigate why it is so different from the interbedded welded ignimbrites. The newly recognised Deadeye Member of southern Idaho is a soil-bounded eruption-unit that comprises ashfall layers and a 4-m-thick ignimbrite that extends for >35 km. The ignimbrite is non-welded, lithic-clast poor and varies from massive to diffuse low-angle cross-bedded. It contains abundant angular clasts of non-vesicular black glass, and upper parts contain accretionary lapilli. The ashfall layers above it contain coated ash pellets and ash clumps, which record moist aggregation of fine ash. The magmas of the Deadeye eruption were closely similar in composition and temperature to those that generated the intensely welded rheomorphic ignimbrites of the central Snake River Plain. We infer that the marked contrast in physical appearance of the Deadeye ignimbrite compared to the other, more typical Snake-River-type welded ignimbrites was the result of emplacement at relatively low temperatures during an eruption in a lacustrine environment. Magmatic volatile-driven fragmentation of the rhyolitic magma was influenced by interaction with lake water that also led to cooling. The Deadeye Member is the first-recorded example of explosive silicic phreatomagmatism in the central Snake River Plain.     

Composition of widespread volcanic glass in deep-sea sediments of the Southern Pacific Ocean: an Antarctic source inferred

Widespread Plio-Pleistocene (2.43-0.06 Ma) tephra zones recognised in deep-sea cores from high latitudes (>60°) in the Southern Pacific Ocean were thought to have originated from calc-alkaline rhyolitic eruptions in New Zealand, some 5000 km distant. Electron microprobe analyses of the glasses reveal a wide diversity of alkalic felsic compositions, as well as minor components of basic and intermediate glasses, incompatible with a New Zealand Neogene source but similar to contemporaneous eruptives from the Antarctic region. Most tephra zones are trachytic; seven zones are peralkaline rhyolite. The rhyolitic zones represent a deep-sea record of widespread silicic eruptions from continental Antarctica, possibly Marie Byrd Land. The extent of these rhyolitic zones suggest a greater frequency of large explosive eruptions in Antarctica than previously documented. The coarse grain size of some of the shards (up to 3 mm), their great distance from the closest sources (>1600 km for some cores), and the presence of nonvolcanic ice-rafted debris indicate some of the glasses, especially the more basic compositions, may have been ice-rafted, contrary to previous suggestions of a fallout origin.     

Physical properties of the 1980 Mount St. Helens cryptodome magma

 Physical properties of cryptodome and remelted samples of the Mount St. Helens grey dacite have been measured in the laboratory. The viscosity of cryptodome dacite measured by parallel–plate viscometry ranges from 10.82 to 9.94 log₁₀ η (Pa s) (T=900–982  °C), and shrinkage effects were dilatometrically observed at T>900  °C. The viscosity of remelted dacite samples measured by the micropenetration method is 10.60–9.25 log₁₀ η (Pa s) (T=736–802  °C) and viscosities measured by rotational viscometry are 3.22–1.66 log₁₀ η (Pa s) (T=1298–1594  °C). Comparison of the measured viscosity of cryptodome dacitic samples with the calculated viscosity of corresponding water-bearing melt demonstrates significant deviations between measured and calculated values. This difference reflects a combination of the effect of crystals and vesicles on the viscosity of dacite as well as the insufficient experimental basis for the calculation of crystal-bearing vesicular melt viscosities at low temperature. Assuming that the cryptodome magma of the 18 May 1980 Mount St. Helens eruption was residing at 900  °C with a phenocryst content of 30 vol.%, a vesicularity of 36 vol.% and a bulk water content of 0.6 wt.%, we estimate the magma viscosity to be 10^10.8 Pa s. Received: 25 August 1996 / Accepted: 19 July 1997     

Rhyolite magma degassing: an experimental study of melt vesiculation

 The vesiculation of a peralkaline rhyolite melt (initially containing ∼0.14 wt.% H₂O) has been investigated at temperatures above the rheological glass transition (T _g≈530  °C) by (a) in situ optical observation of individual bubble growth or dissolution and (b) dilatometric measurements of the volume expansion due to vesiculation. The activation energy of the timescale for bubble growth equals the activation energy of viscous flow at relatively low temperatures (650–790  °C), but decreases and tends towards the value for water diffusion at high temperatures (790–925  °C). The time dependence of volume expansion follows the Avrami equation ΔV (t)∼{1–exp [–(t/τ_av) ⁿ ]} with the exponent n=2–2.5. The induction time of nucleation and the characteristic timescale (τ_av) in the Avrami equation have the same activation energy, again equal to the activation energy of viscous flow, which means that in viscous melts (Peclet number <1) the vesiculation (volume expansion), the bubble growth process, and, possibly, the nucleation of vesicles, are controlled by the relaxation of viscous stresses. One of the potential volcanological consequences of such behavior is the existence of a significant time lag between the attainment of a super-saturated state in volatile-bearing rhyolitic magmas and the onset of their expansion. Received: March 20, 1995 / Accepted: October 24, 1995     

Bubble growth in rhyolitic melts: experimental and numerical investigation

 Bubble growth controlled by mass transfer of water from hydrated rhyolitic melts at high pressures and temperatures was studied experimentally and simulated numerically. Rhyolitic melts were hydrated at 150 MPa, 780–850  °C to uniform water content of 5.5–5.3 wt%. The pressure was then dropped and held constant at 15–145 MPa. Upon the drop bubbles nucleated and were allowed to grow for various periods of time before final, rapid quenching of the samples. The size and number density of bubbles in the quenched glasses were recorded. Where number densities were low and run duration short, bubble sizes were in accord with the growth model of Scriven (1959) for solitary bubbles. However, most results did not fit this simple model because of interaction between neighboring bubbles. Hence, the growth model of Proussevitch et al. (1993), which accounts for finite separation between bubbles, was further developed and used to simulate bubble growth. The good agreement between experimental data, numerical simulation, and analytical solutions enables accurate and reliable examination of bubble growth from a limited volume of supersaturated melt. At modest supersaturations bubble growth in hydrated silicic melts (3–6 wt% water, viscosity 10⁴–10⁶ Pa·s) is diffusion controlled. Water diffusion is fast enough to maintain steady-state concentration gradient in the melt. Viscous resistance is important only at the very early stage of growth (t<1 s). Under the above conditions growth is nearly parabolic, R²=2Dtρ_m(C₀–C_f)/ρ_g until the bubble approaches its final size. In melts with low water content, viscosity is higher and maintains pressure gradients in the melt. Growth may be delayed for longer times, comparable to time scales of melt ascent during eruptions. At high levels of supersaturation, advection of hydrated melt towards the growing bubble becomes significant. Our results indicate that equilibrium degassing is a good approximation for modeling vesiculation in melts with high water concentrations (C₀>3 wt%) in the region above the nucleation level. When the melt accelerates and water content decreases, equilibrium can no longer be maintained between bubbles and melt. Supersaturation develops in melt pockets away from bubbles and new bubbles may nucleate. Further acceleration and increase in viscosity cause buildup of internal pressure in the bubbles and may eventually lead to fragmentation of the melt. Received: 19 June 1995 / Accepted: 27 December 1995     

Shallow and deep reservoirs involved in magma supply of the 1944 eruption of Vesuvius

 During the 1944 eruption of Vesuvius a sudden change occurred in the dynamics of the eruptive events, linked to variations in magma composition. K-phonotephritic magmas were erupted during the effusive phase and the first lava fountain, whereas the emission of strongly porphyritic K-tephrites took place during the more intense fountain. Melt inclusion compositions (major and volatile elements) highlight that the magmas feeding the eruption underwent differentiation at different pressures. The K-tephritic volatile-rich melts (up to 3 wt.% H₂O, 3000 ppm CO₂, and 0.55 wt.% Cl) evolved to reach K-phonotephritic compositions by crystallization of diopside and forsteritic olivine at total fluid pressure higher than 300 MPa. These magmas fed a very shallow reservoir. The low-pressure differentiation of the volatile-poor K-phonotephritic magmas (H₂O<1 wt.%) involved mixing, open-system degassing, and crystallization of leucite, salite, and plagioclase. The eruption was triggered by intrusion of a volatile-rich magma batch that rose from a depth of 11–22 km into the shallow magma chamber. The first phase of the eruption represents the partial emptying of the shallow reservoir, the top of which is within the volcanic edifice. The newly arrived magma mixed with that resident in the shallow reservoir and forced the transition from the effusive to the lava fountain phase of the eruption. Received: 14 September 1998 / Accepted: 10 January 1999     

Modelling the dynamics and thermodynamics of volcanic degassing

 The rates of passive degassing from volcanoes are investigated by modelling the convective overturn of dense degassed and less dense gas-rich magmas in a vertical conduit linking a shallow degassing zone with a deep magma chamber. Laboratory experiments are used to constrain our theoretical model of the overturn rate and to elaborate on the model of this process presented by Kazahaya et al. (1994). We also introduce the effects of a CO₂–saturated deep chamber and adiabatic cooling of ascending magma. We find that overturn occurs by concentric flow of the magmas along the conduit, although the details of the flow depend on the magmas' viscosity ratio. Where convective overturn limits the supply of gas-rich magma, then the gas emission rate is proportional to the flow rate of the overturning magmas (proportional to the density difference driving convection, the conduit radius to the fourth power, and inversely proportional to the degassed magma viscosity) and the mass fraction of water that is degassed. Efficient degassing enhances the density difference but increases the magma viscosity, and this dampens convection. Two degassing volcanoes were modelled. At Stromboli, assuming a 2 km deep, 30% crystalline basaltic chamber, containing 0.5 wt.% dissolved water, the ∼700 kg s^–1 magmatic water flux can be modelled with a 4–10 m radius conduit, degassing 20–100% of the available water and all of the 1 to 4 vol.% CO₂ chamber gas. At Mount St. Helens in June 1980, assuming a 7 km deep, 39% crystalline dacitic chamber, containing 4.6 wt.% dissolved water, the ∼500 kg s^–1 magmatic water flux can be modelled with a 22–60 m radius conduit, degassing ∼2–90% of the available water and all of the 0.1 to 3 vol.% CO₂ chamber gas. The range of these results is consistent with previous models and observations. Convection driven by degassing provides a plausible mechanism for transferring volatiles from deep magma chambers to the atmosphere, and it can explain the gas fluxes measured at many persistently active volcanoes. Received: 26 September 1997 / Accepted: 11 July 1998     

Spherulites and thundereggs from pitchstones of the Deccan Traps: geology,petrochemistry, and emplacement environments

Spherulites and thundereggs are rounded, typically spherical, polycrystalline objects found in glassy silicic rocks. Spherulites are dominantly made up of radiating microscopic fibers of alkali feldspar and a silica mineral (commonly quartz). They form due to heterogeneous nucleation in highly supercooled rhyolitic melts or by devitrification of glass. Associated features are lithophysae (“stone bubbles”), which have an exterior (sometimes concentric shells) of fine quartz and feldspar, and internal cavities left by escaping gas; when filled by secondary silica, these are termed thundereggs. Here, we describe four distinct occurrences of spherulites and thundereggs, in pitchstones (mostly rhyolitic, some trachytic) of the Deccan Traps, India. The thundereggs at one locality were previously misidentified as rhyolitic lava bombs and products of pyroclastic extrusive activity. We have characterized the thundereggs petrographically and geochemically and have determined low contents of magmatic water (0.21–0.38 wt.%) in them using Fourier transform infrared spectroscopy. We consider that the spherulite-bearing outcrops at one of the localities are of lava flows, but the other three represent subvolcanic intrusions. Based on the structural disposition of the Deccan sheet intrusions studied here and considerations of regional geology, we suggest that they are cone sheets emplaced from a plutonic center now submerged beneath the Arabian Sea.     

The enormous Chillos Valley Lahar: an ash-flow-generated debris flow from Cotopaxi Volcano, Ecuador

 The Chillos Valley Lahar (CVL), the largest Holocene debris flow in area and volume as yet recognized in the northern Andes, formed on Cotopaxi volcano's north and northeast slopes and descended river systems that took it 326 km north–northwest to the Pacific Ocean and 130+ km east into the Amazon basin. In the Chillos Valley, 40 km downstream from the volcano, depths of 80–160 m and valley cross sections up to 337 000 m² are observed, implying peak flow discharges of 2.6–6.0 million m³/s. The overall volume of the CVL is estimated to be ≈3.8 km³. The CVL was generated approximately 4500 years BP by a rhyolitic ash flow that followed a small sector collapse on the north and northeast sides of Cotopaxi, which melted part of the volcano's icecap and transformed rapidly into the debris flow. The ash flow and resulting CVL have identical components, except for foreign fragments picked up along the flow path. Juvenile materials, including vitric ash, crystals, and pumice, comprise 80–90% of the lahar's deposit, whereas rhyolitic, dacitic, and andesitic lithics make up the remainder. The sand-size fraction and the 2- to 10-mm fraction together dominate the deposit, constituting ≈63 and ≈15 wt.% of the matrix, respectively, whereas the silt-size fraction averages less than ≈10 wt.% and the clay-size fraction less than 0.5 wt.%. Along the 326-km runout, these particle-size fractions vary little, as does the sorting coefficient (average=2.6). There is no tendency toward grading or improved sorting. Limited bulking is recognized. The CVL was an enormous non-cohesive debris flow, notable for its ash-flow origin and immense volume and peak discharge which gave it characteristics and a behavior akin to large cohesive mudflows. Significantly, then, ash-flow-generated debris flows can also achieve large volumes and cover great areas; thus, they can conceivably affect large populated regions far from their source. Especially dangerous, therefore, are snow-clad volcanoes with recent silicic ash-flow histories such as those found in the Andes and Alaska. Received: 28 April 1997 / Accepted: 19 August 1997     

A study of melt inclusions at Vulcano (Aeolian Islands, Italy): insights on the primitive magmas and on the volcanic feeding system

 This work presents the results of a microthermometric and EPMA-SIMS study of melt inclusions in phenocrysts of rocks of the shoshonitic eruptive complex of Vulcano (Aeolian Islands, Italy). Different primitive magmas related to two different evolutionary series, an older one (50–25 ka) and a younger one (15 ka to 1890 A.D.), were identified as melt inclusions in olivine Fo_88–91 crystals. Both are characterized by high Ca/Al ratio and present very similar Rb/Sr, B/Be and patterns of trace elements, with Nb and Ti anomalies typical of a subduction zone. The two basalts present the same temperature of crystallization (1180±20  °C) and similar volatile abundances. The H₂O, S and Cl contents are relatively high, whereas magmatic CO₂ concentrations are very low, probably due to CO₂ loss before low-pressure crystallization and entrapment of melt inclusions. The mineral chemistry of the basaltic assemblages and the high Ca/Al ratio of melt inclusions indicate an origin from a depleted, metasomatized clinopyroxene-rich peridotitic mantle. The younger primitive melt is characterized with respect to the older one by higher K₂O and incompatible element abundances, by lower Zr/Nb and La/Nb, and by higher Ba/Rb and LREE enrichment. A different degree of partial melting of the same source can explain the chemical differences between the two magmas. However, some anomalies in Sr, Rb and K contents suggest either a slightly different source for the two magmas or differing extents of crustal contamination. Low-pressure degassing and cooling of the basaltic magmas produce shoshonitic liquids. The melt inclusions indicate evolutionary paths via fractional crystallization, leading to trachytic compositions during the older activity and to rhyolitic compositions during the recent one. The bulk-rock compositions record a more complex history than do the melt inclusions, due to the syneruptive mixing processes commonly affecting the magmas erupted at Vulcano. The composition and temperature data on melt inclusions suggest that in the older period of activity several shallow magmatic reservoirs existed; in the younger one a relatively homogeneous feeding system is active. The shallow magmatic reservoir feeding the recent eruptive activity probably has a vertical configuration, with basaltic magma in the deeper zones and differentiated magmas in shallower, low-volume, dike-like reservoirs. Received: 11 March 1998 / Accepted: 14 July 1998     

Simulating bubble number density of rhyolitic pumices from Plinian eruptions: constraints from fast decompression experiments

Decompression experiments of a crystal-free rhyolitic liquid with ≈ 6.6 wt. % H₂O were carried out at a pressure range from 250 MPa to 30–75 MPa in order to characterize effects of magma ascent rate and temperature on bubble nucleation kinetics, especially on the bubble number density (BND, the number of bubbles produced per unit volume of liquid). A first series of experiments at 800°C and fast decompression rates (10–90 MPa/s) produced huge BNDs (≈ 2 × 10¹⁴ m⁻³ at 10 MPa/s ; ≈ 2 × 10¹⁵ m⁻³ at 90 MPa/s), comparable to those in natural silicic pumices from Plinian eruptions (10¹⁵–10¹⁶ m⁻³). A second series of experiments at 700°C and 1 MPa/s produced BNDs (≈ 9×10¹² m⁻³) close to those observed at 800°C and 1 MPa/s (≈ 6 × 10¹² m⁻³), showing that temperature has an insignificant effect on BNDs at a given decompression rate. Our study strengthens the theory that the BNDs are good markers of the decompression rate of magmas in volcanic conduits, irrespective of temperature. Huge number densities of small bubbles in natural silicic pumices from Plinian eruptions imply that a major nucleation event occurs just below the fragmentation level, at which the decompression rate of ascending magmas is a maximum (≥ 1 MPa/s).     

Distribution of Ca in highly fractionated peralkaline magmas

Many peralkaline rhyolites and granites contain less than 0.15 wt.% CaO. In contrast, strongly fractionated peralkaline nepheline syenites and phonolites usually contain greater than 0.5 wt.% CaO. Consideration of known distributions of Ca between crystals and liquid in conjunction with crystal fractionation does not provide an adequate explanation of the contrasting levels of Ca depletion observed. Examination of the suites of late-crystallizing accessory phases in peralkaline rocks suggests that Ca is more soluble in undersaturated magmas than in over-saturated magmas. Activities for CaO in silicic and phonolitic rocks are calculated and the latter have higher CaO activities than the former and this may manifest itself in the different suites of accessory phases and levels of Ca depletion noted in natural rocks.     

Variation of volatile concentration in a magma system of Satsuma-Iwojima volcano deduced from melt inclusion analyses

Chemical analyses of 30 melt inclusions from Satsuma-Iwojima volcano, Japan, were carried out to investigate volatile evolution in a magma chamber beneath the volcano from about 6300 yr BP to the present. Large variations in volatile concentrations of melts were observed. (1) Water concentration of rhyolitic melts decreases with time; 3–4.6 wt.% at the time of latest caldera-forming eruption of Takeshima pyroclastic flow deposit (ca. 6300 yr BP), 3 wt.% for small pyroclastic flow (ca. 1300 yr BP) of Iwodake, post-caldera rhyolitic dome, and 0.7–1.4 wt.% for submarine lava eruption (Showa-Iwojima) in 1934. (2) Rhyolitic melts of the Takeshima and Iwodake eruptions contained CO₂ of less than 40 ppm, while the Showa-Iwojima melt has higher CO₂ concentration of up to 140 ppm. (3) Water and CO₂ concentrations of basaltic to andesitic melt of Inamuradake, a post-caldera basaltic scoria cone, are 1.2–2.8 wt.% and ≤290 ppm, respectively.Volatile evolution in the magma chamber is interpreted as follows: (1) the rhyolitic magma at the time of the latest caldera-forming eruption (ca. 6300 yr BP) was gas-saturated due to pressure variation in the magma chamber because the large variation in water concentration of the melt was attributed to exsolution of volatile in the magma prior to the eruption. Iwodake eruption (ca. 1300 yr BP) was caused by a remnant of the caldera-forming rhyolitic magma, suggested from the similarity of major element composition between these magmas. (2) Volatile composition of the Showa-Iwojima rhyolitic melt agrees with that of magmatic gases presently discharging from a summit of Iwodake, indicating the low pressure degassing condition. (3) The degassing of the magma chamber by magma convection in a conduit of Iwodake during non-eruptive but active degassing period for longer than 800 years decreased water concentration of the rhyolitic magma. (4) Geological and petrological observations indicate that a stratified magma chamber, which consists of a lower basaltic layer and an upper rhyolitic layer, might have existed during the post-caldera stage. Addition of CO₂ from the underlying basaltic magma to the upper gas-undersaturated (degassed) rhyolitic magma increased CO₂ concentration of the rhyolitic magma.     

New multibeam mapping and geochemistry of the 30°–35° S sector,and overview,of southern Kermadec arc volcanism

New multibeam mapping and whole-rock geochemistry establish the first order definition of the modern submarine Kermadec arc between 30° and 35° S. Twenty-two volcanoes with basal diameters > 5 km are newly discovered or fully-mapped for the first time; Giggenbach, Macauley, Havre, Haungaroa, Kuiwai, Ngatoroirangi, Sonne, Kibblewhite and Yokosuka. For each large volcano, edifice morphology and structure, surficial deposits, lava fields, distribution of sector collapses, and lava compositions are determined. Macauley and Havre are large silicic intra-oceanic caldera complexes. For both, concentric ridges on the outer flanks are interpreted as recording mega-bedforms associated with pyroclastic density flows and edifice foundering. Other stratovolcanoes reveal complex histories, with repeated cycles of tectonically controlled construction and sector collapse, extensive basaltic flow fields, and the development of summit craters and/or small nested calderas.Combined with existing data for the southernmost arc segment, we provide an overview of the spatial distribution and magmatic heterogeneity along ∼780 km of the Kermadec arc at 30°–36°30′ S. Coincident changes in arc elevation and lava composition define three volcano–tectonic segments. A central deeper segment at 32°20′–34°10′ S has basement elevations of > 3200 m water-depth, and relatively simple stratovolcanoes dominated by low-K series, basalt–basaltic andesite. In contrast, the adjoining arc segments have higher basement elevations (typically < 2500 m water-depth), multi-vent volcanic centres including caldera complexes, and erupt sub-equal proportions of dacite and basalt–basaltic andesite. The association of silicic magmas with higher basement elevations (and hence thicker crust), coupled with significant inter- and intra-volcano heterogeneity of the silicic lavas, but not the mafic lavas, is interpreted as evidence for dehydration melting of the sub-arc crust. Conversely, the crust beneath the deeper arc segments is thinner, initially cooler, and has not yet reached the thermal requirements for anatexis. Silicic calderas with diameters > 3 km coincide with the shallower arc segments. The dominant mode of large caldera formation is interpreted as mass-discharge pyroclastic eruption with syn-eruptive collapse. Hence, the shallower arc segments are characterized by both the generation of volatile-enriched magmas from crustal melting and a reduced hydrostatic load, allowing magma vesiculation and fragmentation to initiate and sustain pyroclastic eruptions. Proposed initiation parameters for submarine pyroclastic eruptions are water-depths < 1000 m, magmas with 5–6 wt.% water and > 70 wt.% SiO₂, and a high discharge rate.     

Measurement and implication of "effective" viscosity for rhyolite flow emplacement

Hazardous explosive activity may sporadically accompany the extrusion of silicic lava domes. Modelling of the emplacement of silicic domes is therefore an important task for volcanic hazard assessment. Such modelling has been hampered by a lack of a sufficiently accurate rheological database for silicic lavas with crystals and vesicles. In the present study, the parallel-plate viscometry method was applied to determine the shear viscosity of five natural rhyolitic samples from a vertical section through the Ben Lomond lava dome, Taupo Volcanic Centre, New Zealand. Rheological measurements were performed at volcanologically relevant temperatures (780-950°C) and strain rates (10^-5-10^-7 s^-1). Although these samples are in the metastable state, viscosity determinations, melt composition, as well as water and crystal contents of samples were demonstrably stable during experiments. For samples containing up to 5 vol.% microlites, the composition of the melt, rather than the physical effect of suspended crystals, had greater influence on the effective viscosity of the silicic magma. Samples with 10 vol.% microlites and containing a flow banding defined by microlites show no significant orientational effects on apparent viscosity. The rheological measurements were used together with a simple cooling model to construct thermal and viscosity profiles revealing conditions during the emplacement of the Ben Lomond lava dome.