北山造山带南部晚古生代花岗岩?闪长岩的成因与构造意义

北山造山带位于中亚造山带南部,是中亚造山带的重要组成部分.为了进一步深入认识北山造山带晚古生代的构造?岩浆演化过程,选择北山造山带南部石板墩?白墩子地区的晚古生代花岗岩?闪长岩开展了岩石学、锆石U-Pb定年、Hf同位素、微量元素及岩石地球化学研究.LA-ICP-MS锆石U-Pb年代学研究限定了石板墩花岗岩形成于~304~ 302 Ma,石板墩闪长岩形成于~291 Ma,白墩子石英闪长岩形成于~270 Ma.它们的锆石Hf同位素均呈现较亏损的特征（ε_Hf（t）=-2.0~+15.7）,且由老到新,亏损程度依次增加.岩石学和地球化学特征暗示了亏损地幔来源岩浆在北山造山带晚古生代岩浆活动中的主导作用,亏损地幔来源岩浆与古老地壳部分熔融形成的岩浆以不同比例混合,形成了复杂的岩石组合.因此,晚石炭世?早二叠世花岗岩?闪长岩可能形成于后撤式增生造山作用导致的弧后伸展构造环境.      

兴蒙造山带中段北部晚古生代两期岩浆活动及其构造意义

兴蒙造山带位于中亚造山带东段,长期以来是地质学家研究的焦点区域。内蒙古巴彦乌拉地区位于兴蒙造山带中段北部苏尼特左旗以北,广泛出露晚古生代宝力格组火山—沉积地层和酸性侵入岩体。本文对阿尔善宝拉格附近的宝力格组中性火山岩和侵入其中的花岗斑岩岩墙,及巴彦乌拉苏木南部花岗闪长岩进行了锆石LA-ICP-MS U-Pb定年,定年结果显示,宝力格组火山岩年龄为310.5±0.78 Ma,与巴彦乌拉苏木北部地区火山岩年龄(307.1±6.3Ma,308.9±1.8Ma)一致,证明本区宝力格组地层形成于晚石炭世;花岗闪长岩和花岗斑岩岩墙年龄分别为312.5±0.75 Ma和286.6±0.75 Ma,形成时代分别为晚石炭世和早二叠世;通过区域对比分析认为,兴蒙造山带北部晚古生代存在晚石炭世和早二叠世两期重要的岩浆活动,统计获得峰值年龄分别为318Ma和281Ma。岩石地球化学特征显示,本区晚石炭世宝力格组火山岩具有由低钾拉斑向钙碱性、碱性系列过渡的特征,并以钙碱性和碱性系列为主;早二叠世花岗斑岩为A型花岗岩,具有与邻区锡林浩特及巴彦乌拉—东乌珠穆沁旗带内A型花岗岩类似的地球化学特征;在花岗岩构造判别图中,花岗斑岩落入后造山区域,晚石炭世到早二叠世期间岩浆的形成环境向后造山环境逐渐演化,同时在SiO2和Na2O对K2O相关图解中,K2O含量具有增高变化的趋势,暗示构造环境有向更加稳定的板内环境演变的特征。因此,结合前人地质资料,兴蒙造山带北部晚古生代大量火山岩浆活动可能与二连—贺根山蛇绿混杂带形成有关,晚石炭世时期研究区处于后造山阶段,随着早二叠世大量A型花岗岩、碱性岩浆和双峰式火山岩的形成,该区进入造山后期更广泛的伸展环境。     

东准噶尔北缘乌伦古地区晚二叠世A型花岗质岩墙成因及构造背景

中亚造山带西南缘的东准噶尔地区出露大量晚古生代花岗岩,是揭示该造山带地壳演化的良好对象.在东准噶尔北缘乌伦古西北的阿克吉拉识别出一套走向与区域构造线总体垂直的晚古生代花岗质岩墙,其时代和成因研究对深入理解本区的构造演化具有重要意义.SHRIMP锆石U-Pb测年结果显示其侵位于晚二叠世(266±2 Ma).岩石地球化学组...     

敦煌地块南部古生代花岗岩地球化学、锆石U-Pb定年及Hf同位素特征研究

敦煌地块出露有大量古生代花岗岩,对这些花岗岩的研究可以更深入的了解敦煌地块的构造演化及其地球动力学意义。本文对敦煌地块南部的安盆沟复式花岗岩体和小草湖花岗岩体进行了岩相学、地球化学、锆石U-Pb年代学和Hf同位素的研究。研究结果表明:(1)安盆沟岩体岩石组合为正长花岗岩-花岗岩,其中正长花岗岩侵位于早古生代(431Ma),花岗岩侵位于泥盆纪(~360Ma)和石炭纪(~340Ma);小草湖岩体主要为似斑状花岗岩,侵位时代为石炭纪(340Ma)。(2)安盆沟早古生代正长花岗岩的ε_(Hf)(t)为-11.7到-6.3,tDM2为1.8~2.2Ga,而晚古生代花岗岩的ε_(Hf)(t)为-12.3到-5.5,tDM2为1.7~2.1Ga,二者Hf同位素特征相似,推测源岩均为古元古代-中元古代时期的含泥质成分的(变)砂质岩。小草湖似斑状花岗岩为加厚下地壳部分熔融成因的埃达克质岩石,ε_(Hf)(t)变化于-16.7至-4.9,tDM2变化于1.8~2.4Ga之间,源岩为古元古代古老地壳物质。两个岩体的部分源岩可能与Columbia超大陆的汇聚和裂解有关。(3)安盆沟正长花岗岩、花岗岩和小草湖似斑状花岗岩的残留相分别为麻粒岩、角闪岩和麻粒岩-角闪榴辉岩,反映了形成深度和变质级别的不同。(4)敦煌地块内的早古生代造山活动结束时间明显晚于中央造山带,并且早古生代造山活动以及早-晚古生代花岗岩与北侧的天山-北山造山带存在时空上的对应关系,敦煌地块可能在古生代期间卷入了中亚造山带的造山活动中。     

黑龙江多宝山古生代海盆闭合的岩石学证据

综合研究黑龙江多宝山地区古生代沉积地层、生物化石,通过分析侵入岩岩石地球化学及其锆石U--Pb 同位素测年资料,表明该地区早奥陶世至晚泥盆世早期为海相沉积地层,晚泥盆世晚期为海陆交互相沉积地层,早石炭世为陆相河湖沉积地层。多宝山海盆东南侧出露一套年龄为( 300 ± 3 ～ 357 ± 4) Ma 的花岗岩,其中正长、二长花岗质糜棱岩为后造山花岗岩,碱长花岗岩为造山后A 型花岗岩。表明多宝山海盆于晚泥盆世开始闭合,至早石炭世为陆相河湖沉积,晚石炭世-早二叠世为抬升剥蚀阶段。表现为多宝山地区于早石炭世开始造山,晚石炭世晚期或延至早二叠世发生造山后伸展作用。     

东昆仑造山带西段早古生代花岗岩锆石LA-ICP-MS年龄、岩石地球化学特征及地质意义

笔者等对东昆仑造山带西段克其克孜苏花岗岩开展岩石学、岩石地球化学及LA-ICP-MS锆石U-Pb年代学研究,探讨岩体的形成时代、成因及地质意义.研究表明,克其克孜苏花岗岩中的锆石U-Pb加权平均年龄为442.3±4.4 Ma(MSWD=2.7),为晚奥陶世—早志留世,是区域上新解体出的早古生代花岗岩.花岗岩SiO2含量...     

内蒙古维拉斯托矿床花岗岩类SHRIMP年代学及Hf同位素研究

维拉斯托铜多金属矿床地处中亚造山带和大兴安岭造山带的叠加复合部位,该矿床花岗岩类锆石SHRIMP U-Pb测年结果显示为(298.0±2.5)Ma、(308.3±4.2)Ma、(313.9±3.4)Ma和(320.5±4.1)Ma,表明该矿区花岗岩类的成岩时代为晚石炭世。岩石地球化学特征表明它们为岩浆弧活动的产物。除花岗闪长岩样品锆石的εHf(t)为-4.1～+4.08外,其他3件黑云母花岗岩、黑云母二长花岗岩、石英闪长岩样品锆石ε_Hf(t)为正值,为+0.4～+9.9,锆石Hf模式年龄的峰值与古亚洲洋发育的时间较为一致,暗示矿区花岗岩类源区物质主要为俯冲的古亚洲洋壳以及少量前寒武纪地壳。矿区花岗岩类系统研究为探讨晚古生代兴蒙造山带的演化过程提供了基础资料,为该铜多金属矿床的成因研究提供了新的证据。     

西准噶尔成矿带晚古生代花岗岩类岩浆活动及其构造意义

中亚造山带是晚古生代地壳显著生长与大规模成矿的重要地区。本文采集了中亚造山带西部的西准噶尔成矿带哈图-别鲁阿嘎希及其附近地区11个岩体共33件花岗岩类样品,对其开展了岩石地球化学与同位素示踪等研究,厘定了该地区晚古生代岩浆活动的特点与大地构造环境,并与哈萨克斯坦境内的巴尔喀什成矿带晚古生代岩浆活动进行了对比。研究表明,哈图地区晚石炭世花岗岩类主要为后碰撞伸展构造环境的A型花岗岩类,别鲁阿嘎希等地区存在洋内俯冲与岛弧环境的埃达克岩,显示了西准噶尔晚古生代构造环境时空变化的复杂性。该地区花岗岩类εNd(t)值较高(+4.62~+7.53)、εSr(t)值为(-57.61~+18.21),具有中亚造山带花岗岩类的共同特征,为古生代增生的新生陆壳,其源区与亏损地幔组分具有亲缘关系,这与巴尔喀什成矿带东段的花岗岩类具有一致性。花岗岩的~(206)Pb/~(204)Pb、~(207)Pb/~(204)Pb和~(208)Pb/~(204)Pb比值范围分别为18.2776~19.1677、15.5260~15.5796和38.2080~39.0821,为造山带花岗岩类。     

阿拉善地块南缘古生代花岗岩类研究进展

阿拉善地块处于华北克拉通,塔里木克拉通和祁连造山带的交汇处,其南缘古生代花岗岩广泛分布。结合近年来阿拉善南缘古生代花岗岩研究成果,从锆石U-Pb年代学和地球化学等方面进行分析总结,认为阿拉善南缘早古生代花岗岩主要受控于祁连造山带的构造演化,其岩浆活动可分为两期,中奥陶世—早志留世和中志留世—早泥盆世,前者处于俯冲环境,后者为后碰撞伸展环境;晚古生代花岗岩仅零星出露于龙首山地区,岩石地球化学特征与宗乃山—沙拉扎山构造带花岗岩相似,与中亚造山带的构造演化相关。并对目前研究中存在的问题和未来研究的方向提出了建议。     

新疆中天山古生代侵入岩浆序列及构造演化

新疆中天山构造岩浆带是中亚造山带的重要组成部分,广泛分布着古生代花岗质侵入体。本研究重点对中天山南缘巴音布鲁克及巴伦台地区的花岗质侵入体进行了LA-ICP-MS锆石U-Pb测年,并获得了岩体侵位年龄由老到新分别为463±3Ma(石英闪长岩)、437±5Ma(石英闪长岩)、424±3Ma(二长花岗岩)、383±4Ma(二长花岗岩)、356±3Ma(二长花岗岩)和303±5Ma(正长花岗岩)。综合区域地质分析认为,中天山古生代侵入岩浆活动可分为四个构造岩浆演化阶段:(1)晚寒武世—晚奥陶世阶段,Terskey洋盆和南天山洋盆自新元古代打开形成广阔洋盆,Terskey洋盆在晚寒武世开始初次俯冲,于晚奥陶世洋盆闭合,南天山洋盆于早奥陶世初次俯冲,具有自西向东、由早到晚的俯冲特点;(2)早志留世—中泥盆世阶段,南天山洋盆持续向北俯冲,该阶段北天山洋开始向南侧俯冲,在伊犁地块北缘形成了弧岩浆;(3)晚泥盆世—早石炭世阶段,南天山洋盆闭合于晚泥盆世末期,在早石炭世中晚期进入残余洋盆演化阶段;(4)晚石炭世—早二叠世阶段,该阶段为后碰撞伸展环境,区域上为陆内演化阶段。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。