Geochemical fractionation of manganese in the Riogrande II reservoir, Antioquia, Colombia

The Riogrande II reservoir in Colombia has a total storage capacity of 240 million m³ and lies 2,270 m above sea level. The reservoir is used for power generation, water supply and environmental improvement. Dissolved manganese (Mn) is removed from reservoir water dedicated to domestic use by purification processes. Removal of Mn, however, poses a major challenge to purification processes and warrants the study of ways to naturally reduce dissolved Mn levels in the reservoir. The source of Mn within the reservoir is not well understood, however, presumably arises from sediment mobilization initiated by variation in pH, redox potential (ORP or Eh), dissolved oxygen (O₂) and ionic strength conditions. This study investigated conditions within the reservoir to further understand Mn transfer from the sediment into the water column. O₂, pH, oxidation–reduction potential (ORP or Eh), organic matter content and electric conductivity were measured in water samples and sediment from the reservoir. Sequential extraction (SE) procedures were used to test the specific effects exerted by each of these conditions on Mn mobilization from the sediments. The European Community Bureau of Reference (BCR) sequential extraction procedure was used to quantify metals in sediment (referred to as the BCR extraction below). Statistical analysis of geochemical data from water samples (both water column and sediment pore water) and sediments demonstrated the conditions under which Mn can be released from sediments into the water column. The results indicated a primarily oxic water column and anoxic reducing conditions in the sediment (ORP or Eh ≤ ?80 mV). The pH of water in contact with bottom sediments varied from 7.6 to 6.8. The pH of sedimentary pore water varied from 6.8 to 4.7. The sediments contained significant amounts of organic matter (20 %). Chemical extractions showed that the exchangeable fraction contained over 50 % of the total Mn within sediments. Microscopic analysis using scanning electron microscopy–energy dispersive spectroscopy (SEM–EDS) indicated that Mn does not occur within well-crystallized mineral phases in the Riogrande II sediments. A large proportion of Mn exists instead as material adsorbed onto the surfaces of recently deposited sediment particles. Bacterial oxidation of organic matter may cause the observed anoxic conditions at the bottom of the reservoir. Mineralization of organic matter therefore contributes to reducing conditions within the sediments. Mobilization of Mn from the sediment into the water column may result from reductive dissolution of this fraction. Manganese release by this mechanism diminishes the water quality of the Riogrande II reservoir and warrants further study.     

Silver-Bearing and Associated Minerals in El Zancudo Deposit, Antioquia, Colombia

The occurrence and the chemical compositions of ore minerals (especially the silver‐bearing minerals) and fluid inclusions of the El Zancudo mine in Colombia were investigated in order to analyze the genetic processes of the ore minerals and to examine the genesis of the deposit. The El Zancudo mine is a silver–gold deposit located in the western flank of the Central Cordillera in Antioquia Department. It consists mainly of banded ore veins hosted in greenschist and lesser disseminated ore in porphyritic rocks. The ore deposit is associated with extensive hydrothermally altered zones. The ores from the banded veins contain sphalerite, pyrite, arsenopyrite, galena, Ag‐bearing sulfosalts, Pb‐Sb sulfosalts, and minor chalcopyrite, electrum, and native silver. Electrum is included within sphalerite, pyrite, and arsenopyrite, and is also partially surrounded by pyrite, arsenopyrite, sphalerite, and tetrahedrite. Native silver is present in minor amounts as small grains in contact with Ag‐rich sulfosalts. Silver‐bearing sulfosalts are argentian tetrahedrite–freibergite solid solution, andorite, miargyrite, diaphorite, and owyheeite. Pb‐Sb sulfosalts are bournonite, jamesonite, and boulangerite. Two main crystallization stages are recognized, based on textural relations and mineral assemblages. The first‐stage assemblage includes sphalerite, pyrite, arsenopyrite, galena and electrum. The second stage is divided into two sub‐stages. The first sub‐stage commenced with the deposition and growth of sphalerite, pyrite, and arsenopyrite. These minerals are characterized by compositional growth banding, and seem to have crystallized continuously until the end of the second sub‐stage. Tetrahedrite, Pb‐Cu sulfosalts, Ag‐Sb sulfosalt, and Pb‐Ag‐Sb sulfosalts crystallized from the final part of the first sub‐stage and during the whole second sub‐stage. However, one Pb‐Ag‐Sb sulfosalt, diaphorite, was formed by a retrograde reaction between galena and miargyrite. The minimum and maximum genetic temperatures estimated from the FeS content of sphalerite coexisting with pyrite and the silver content of electrum are 300°C and 420°C, respectively. These estimated genetic temperatures are similar to, but slightly higher than the homogenization temperatures (235–350°C) of primary fluid inclusions in quartz. The presence of muscovite in the altered host rocks and gangue suggest that the pH of the hydrothermal solutions was close to neutral. Most of the sulfosalts in this deposit have previously been attributed as the products of epithermal mineralization. However, El Zancudo can be classified as a xenothermal deposit, in view of the low pressure and high temperature genetic conditions identified in the present study, based on the mineralogy of sulfosalts and the homogenization temperatures of the fluid inclusions.     

Determination of masonry building fundamental frequencies in five Slovenian towns by microtremor excitation and implications for seismic risk assessment

Site effects studies using microtremor free-field measurements were performed recently in five Slovenian towns characterized by increased seismic hazard to determine resonance frequency of soft sediments. In this study, microtremor investigations were extended to the measurements inside buildings to determine their fundamental frequencies and to assess the possible occurrence of soil-structure resonance. Measurements were performed in 66 buildings, and by spectral analysis, it was possible to determine reliably fundamental frequencies (longitudinal and transverse) for 58 buildings. Residential masonry houses with two or three floors prevail, but some buildings of up to six-floor height were also surveyed. Microtremor measurements have proved to be an effective tool for assessment of fundamental frequencies of buildings. Such experimental approach is very valuable, as analytical seismic evaluation of an existing building is usually very difficult. Statistical analysis of the fundamental frequency versus number of floors (height) was performed to generalize identification of potential soil-structure resonance. The difference in average fundamental frequency is very clear between buildings with two and three floors. The average value of both horizontal components for two-floor buildings is 9.11?±?1.94?Hz, and for three-floor buildings, 7.03?±?1.46?Hz. On the other hand, the difference in frequencies between three- and four-floor buildings (average for later is 6.52?±?0.80?Hz) is very small. The average fundamental frequencies for five- and six-floor buildings are lower, 4.62?±?0.64?Hz and 5.30?±?0.70?Hz, respectively, with no statistically significant difference between both types. Most Slovenian towns are located in shallow sedimentary basins where the free-field soft covers frequencies are in the range 2?C20?Hz. On the other hand, houses with two and three floors represent the large majority of the building stock. To assess the possible occurrence of soil-structure resonance in general, an average fundamental frequency?±?one standard deviation interval is obtained for these two building heights, which gives the range 5.6?C11.1?Hz. The free-field data show that this frequency range occupies from 22?% of the surveyed area in the Kobarid basin to up to 59?% in the Bovec basin and is in between for other three basins. This leads to the conclusion that the possible occurrence of soil-structure resonance is a serious issue for typical geological situations, in which towns are located.     

The monitoring and prediction of mining subsidence in the Amaga,Angelopolis, Venecia and Bolombolo Regions,Antioquia, Colombia

Amaga, Angelopolis, Venecia and Bolombolo are small towns located in Antioquia, in the Central Cordillera of the Colombian Andes. Mining has been practised in this region for a period of at least 100 years. This mining has mainly been small-scale, poorly mechanised and restricted to shallow room and pillar workings. Recently, the semi-mechanisation of some mines has enabled coal to be extracted using longwall mining methods. However, this has resulted in subsidence that has caused severe damage to structures, residential property, and agricultural land, and also induced landslides. In the British Isles, there are several reliable methods that can be used to predict the likelihood and magnitude of mining subsidence. The British Coal Corporation and the University of Nottingham have developed one such method, the “Subsidence With Influence Function Technique (SWIFT).” Based on mining subsidence observations undertaken in the coalfields of Britain over a period of approximately 50 years. The SWIFT program was used to predict the magnitude of subsidence, above a longwall panel, at the Industrial Hullera mine in Colombia. The results were then compared with subsidence profiles obtained from precise levelling and field monitoring. In each case, the SWIFT program overestimated the magnitude of mining subsidence by 0.17–0.20 m. However, the morphology of the subsidence profile, area-of-influence and location of maximum subsidence were similar. This overestimation of the predicted subsidence was attributed to the occurrence of strong, igneous rocks, such as rhyolite sills, in the Colombian coal measures. These strong, competent horizons act as cantilever beams during subsidence, causing bed separation and therefore reducing the magnitude of subsidence. In spite of these differences, mining subsidence can be predicted with a reasonable degree of accuracy and precision using the SWIFT technique, provided the software is calibrated and used in conjunction with local expertise.     

Analysis of circular tunnels due to seismic P-wave propagation,with emphasis on unreinforced concrete liners

A set of closed-form expressions to calculate tunnel liner forces due to compressional seismic P-wave propagation is presented. The results are compared against a state-of-practice method that considers only shear S-waves, and verified against dynamic numerical analyses. Under the realistic assumption of full-slip conditions at the liner-rock mass interface, it is shown that P-waves can lead to significantly higher axial hoop forces compared to S-waves, and can be critical for tunnels bored through areas of irregular topography/geological stratigraphy. The findings are of particular interest for the analysis of unreinforced concrete tunnel liners, where earthquake effects can be a governing factor.     

Dynamic characterisation and seismic assessment of medieval masonry towers

The paper investigates the dynamic characterisation, the numerical model tuning and the seismic risk assessment of two monumental masonry towers located in Italy: the Capua Cathedral bell tower and the Aversa Cathedral bell tower. Full-scale ambient vibration tests under environmental loads are performed. The modal identification is carried out using techniques of modal extraction in the frequency domain. The refined 3D finite element model (FEM) is calibrated using the in situ investigation survey. The FEM tuning is carried out by varying the mechanical parameters and accounting for the restraint offered by the neighbouring buildings and the role of soil–structure interaction. The assessment of the seismic performance of the bell towers is carried out through a nonlinear static procedure based on the multi-modal pushover analysis and the capacity spectrum method. Through the discussion of the case studies, the paper shows that the modal identification is a reliable technique that can be used in situ for assessing the dynamic behaviour of monumental buildings. By utilising the tuned FEM of the towers, the theoretical fundamental frequencies are determined, which coincide with the previously determined experimental frequencies. The results from seismic performance assessment through a pushover analysis confirm that the masonry towers in this study are particularly vulnerable to strong damage even when subjected to seismic events of moderate intensity.     

Dynamic characterisation and seismic assessment of medieval masonry towers

The paper investigates the dynamic characterisation, the numerical model tuning and the seismic risk assessment of two monumental masonry towers located in Italy: the Capua Cathedral bell tower and the Aversa Cathedral bell tower. Full-scale ambient vibration tests under environmental loads are performed. The modal identification is carried out using techniques of modal extraction in the frequency domain. The refined 3D finite element model (FEM) is calibrated using the in situ investigation survey. The FEM tuning is carried out by varying the mechanical parameters and accounting for the restraint offered by the neighbouring buildings and the role of soil–structure interaction. The assessment of the seismic performance of the bell towers is carried out through a nonlinear static procedure based on the multi-modal pushover analysis and the capacity spectrum method. Through the discussion of the case studies, the paper shows that the modal identification is a reliable technique that can be used in situ for assessing the dynamic behaviour of monumental buildings. By utilising the tuned FEM of the towers, the theoretical fundamental frequencies are determined, which coincide with the previously determined experimental frequencies. The results from seismic performance assessment through a pushover analysis confirm that the masonry towers in this study are particularly vulnerable to strong damage even when subjected to seismic events of moderate intensity.

     

Methodology and applications for the benefit cost analysis of the seismic risk reduction in building portfolios at broadscale

This article presents a methodology for an estimate of the benefit cost ratio of the seismic risk reduction in buildings portfolio at broadscale, for a world region, allowing comparing the results obtained for the countries belonging to that region. This methodology encompasses (1) the generation of a set of random seismic events and the evaluation of the spectral accelerations at the buildings location; (2) the estimation of the buildings built area, the economic value, as well as the classification in structural typologies; (3) the development of vulnerability curves for each typology; (4) the estimation of the annual average loss of the buildings portfolio in the current conditions as well as in the case of a hypothetical structural intervention. The benefit cost ratio is estimated as the difference between the estimates of the present value of these two annual average losses, divided by the retrofitting costs. This methodology has been applied to the portfolio of public schools of 14 countries of Latin America and the Caribbean, for evaluating the feasibility of the seismic risk reduction at a national scale.     

地震危险性、地震危害性和地震易损性

做好城市防震减灾工作 ,关键是对未来可能遭遇地震灾害定量化预测。本文论述地震灾害定量化的三要素 :地震危险性 ,地震危害性和地震易损性 ,它们概念完全不同 ,且很容易混淆 ,但又存在因与果的关系。本文还简要介绍厦门市地震科技工作者开展的“闽南地区综合防震减灾示范工程”。     

Assessment of seismic risk scenarios for Bucharest,Romania

In this paper, seismic risk scenarios for Bucharest, the capital city of Romania, are proposed and assessed. Bucharest has one of the highest seismic risk levels in Europe, and this is due to a combination of relatively high seismic hazard and a building stock built mainly before the devastating Vrancea 1977 earthquake. In this study, the seismic risk of Bucharest is assessed using the most recent information regarding the characteristics of the residential building stock. The ground motion amplitudes are evaluated starting from random fields obtained by coupling a ground motion model derived for the Vrancea intermediate-depth seismic source with a spatial correlation model. The seismic risk evaluation method applied in this study is based on the well-known macroseismic method. For several structural typologies, the vulnerability parameters are evaluated based on a damage survey performed on 18,000 buildings in Bucharest after the March 1977 earthquake. Subsequently, the risk metrics are compared with those from other studies in the literature that apply a different risk assessment methodology in order to gain a better view of the uncertainties associated with a seismic risk study at city level. Finally, the impact of several Vrancea intermediate-depth earthquake scenarios is evaluated and the results show that the earthquake which has the closest epicenter to Bucharest appears to be the most damaging.     

Assessment of seismic risk scenarios for Bucharest,Romania

In this paper, seismic risk scenarios for Bucharest, the capital city of Romania, are proposed and assessed. Bucharest has one of the highest seismic risk levels in Europe, and this is due to a combination of relatively high seismic hazard and a building stock built mainly before the devastating Vrancea 1977 earthquake. In this study, the seismic risk of Bucharest is assessed using the most recent information regarding the characteristics of the residential building stock. The ground motion amplitudes are evaluated starting from random fields obtained by coupling a ground motion model derived for the Vrancea intermediate-depth seismic source with a spatial correlation model. The seismic risk evaluation method applied in this study is based on the well-known macroseismic method. For several structural typologies, the vulnerability parameters are evaluated based on a damage survey performed on 18,000 buildings in Bucharest after the March 1977 earthquake. Subsequently, the risk metrics are compared with those from other studies in the literature that apply a different risk assessment methodology in order to gain a better view of the uncertainties associated with a seismic risk study at city level. Finally, the impact of several Vrancea intermediate-depth earthquake scenarios is evaluated and the results show that the earthquake which has the closest epicenter to Bucharest appears to be the most damaging.

     

Deterministic assessment of seismic risk in Constantine city,Northeast Algeria

Northern Algeria has experienced many destructive earthquakes throughout its history. The largest recent events occurred in El Asnam on October 10, 1980 (moment magnitude; Mw = 7.3), in Constantine on October 27, 1985 (surface-wave magnitude; Ms = 6.0), and in Zemmouri–Boumerdes on May 21, 2003 (Mw = 6.8). Because of the high population density and industrialization in these regions, the earthquakes had disastrous consequences and hence highlighted the vulnerability of Algeria to seismic events. To reduce seismic risk in Constantine, the capital city of East Algeria, we present a seismic risk scenario for this city, focusing on the vulnerability of the key historic areas of Coudia, Bellevue–Ciloc, and the Old City. This scenario allows us to assess the maximum ground acceleration using empirical attenuation laws, based on the following considerations: (a) the 1985 Constantine seismic event as an earthquake reference; (b) site effects related to regional geology; (c) damage to buildings, and (d) seismic vulnerability. This study shows the map of peak ground acceleration taking into account the effects of site lithology (Avib). We observe the strongest vibrations along the two rivers “Boumerzoug and Rhumel” and also, we note that the EC8 gives a good estimate acceleration in the image of the three studied areas (Bellevue–Ciloc, Coudia, and Old Town). By correlating with the geology, we observe an acceleration of 0.13 g in the neritic limestone of the rock (Old Town) something that fits with the value obtained 0.14 g (PGA) without taking into consideration the lithology. Moreover, according to the Algerian Earthquake Engineering Code (2003) (RPA), the Wilaya of Constantine is classified in the zone IIa (medium seismicity) with an acceleration data of 0.25 g. This study integrates geographic information system (GIS) data into risk models.     

Deterministic assessment of seismic risk in Constantine city,Northeast Algeria

Northern Algeria has experienced many destructive earthquakes throughout its history. The largest recent events occurred in El Asnam on October 10, 1980 (moment magnitude; Mw = 7.3), in Constantine on October 27, 1985 (surface-wave magnitude; Ms = 6.0), and in Zemmouri–Boumerdes on May 21, 2003 (Mw = 6.8). Because of the high population density and industrialization in these regions, the earthquakes had disastrous consequences and hence highlighted the vulnerability of Algeria to seismic events. To reduce seismic risk in Constantine, the capital city of East Algeria, we present a seismic risk scenario for this city, focusing on the vulnerability of the key historic areas of Coudia, Bellevue–Ciloc, and the Old City. This scenario allows us to assess the maximum ground acceleration using empirical attenuation laws, based on the following considerations: (a) the 1985 Constantine seismic event as an earthquake reference; (b) site effects related to regional geology; (c) damage to buildings, and (d) seismic vulnerability. This study shows the map of peak ground acceleration taking into account the effects of site lithology (Avib). We observe the strongest vibrations along the two rivers “Boumerzoug and Rhumel” and also, we note that the EC8 gives a good estimate acceleration in the image of the three studied areas (Bellevue–Ciloc, Coudia, and Old Town). By correlating with the geology, we observe an acceleration of 0.13 g in the neritic limestone of the rock (Old Town) something that fits with the value obtained 0.14 g (PGA) without taking into consideration the lithology. Moreover, according to the Algerian Earthquake Engineering Code (2003) (RPA), the Wilaya of Constantine is classified in the zone IIa (medium seismicity) with an acceleration data of 0.25 g. This study integrates geographic information system (GIS) data into risk models.

     

Mapping seismic risk: the current crisis

The seismic risks to which populations are exposed should be estimated reliably for mitigation and preparation of response to disastrous earthquakes. Three parameters need to be known: Population numbers, properties of the built environment, and the seismic hazard. If we focus on large cities, we can say that at least one of these is known satisfactorily, namely the population, but not the other two. In the developing world, the numbers of buildings in a city are known only approximately, their distribution into building types (resistance to shaking) has to be assumed, and the distribution of types throughout the city is unknown. Recent verification of the world seismic hazard map has shown that it is grossly misleading: Instrumental measurements of accelerations due to six earthquakes were about three times larger, on average, than the maximum likely accelerations shown on the map; the macroseismic intensities reported for the last 60 earthquakes with M ≥ 7.5 were all significantly larger than expected, based on the hazard map (by 2.3 intensity units for the 12 deadliest earthquakes); and calculations of losses of life based on the hazard map underestimate the losses sustained in the 12 recent earthquakes with more than 1,000 fatalities by two to three orders of magnitude. This means that the seismic risk in most of the approximately 1,000 large cities at risk in the developing world is unknown. To remedy this intolerable situation, models for the built environment in cities need to be constructed, using cost-effective analyses of satellite images, and worst case scenario estimates of the losses in case of the nearest maximum credible earthquake.     

考虑地震危险性的倾倒变形边坡风险定量分析

风险分析与评估是解决边坡固有不确定性的重要工具,但同时考虑外在荷载和内在岩土力学参数的不确定性,对边坡进行系统定量风险分析的研究较少.以西藏扎拉水电站厂后倾倒变形边坡为例,基于场地地震峰值加速度概率密度函数和不同地震峰值加速度下边坡失稳概率拟合函数,采用数值积分计算了边坡在设计基准期的失稳概率,并采用离散元方法对边坡失...     

Data concerning seismic risk evaluation in Romania

In this paper some results are presented of the researches performed in two main directions: (1) the geologic hazard assessment in the extra-Carpathian territory and (2) the estimation of the degree of exposure of the population to this hazard. For the evaluation of the geologic hazard, data regarding the seismic history of the extra-Carpathian territory (only the intermediate depth Vrancea earthquakes were analyzed) and the recent geodynamical processes which can be triggered or amplified by seismic vibrations, were used. These data published in two previous papers, have been reevaluated and are present in a unitary form, allowing for the separation into zones with different degrees of geological hazard in the analyzed territory. The data regarding the number, space distribution, and density of the population has made it possible to estimate the number of people living in each zone.Paper presented at the 21st General Assembly of the European Seismological Commission held in Sofia, 1988.     

Applying the HAZUS-MH software tool to assess seismic risk in downtown Ottawa,Canada

The aim of this paper is to present earthquake loss estimations for a portion of downtown Ottawa, Canada, using the HAZUS-MH (Hazards United States Multi-Hazard) software tool. The assessment is performed for a scenario earthquake of moment magnitude 6.5, at an epicentral distance of 15 km, occurring during business hours. A level 2 HAZUS-MH analysis was performed where the building inventory, microzonation studies, and site-specific ground motion hazard maps (2% exceedence probability in 50 years) were all improved based on local information. All collected data were assembled into a set of standard geodatabases that are compatible with the HAZUS-MH software using a GIS-specific procedure. The results indicate that the greatest losses are expected in unreinforced masonry buildings and commercial buildings. Sensitivity studies show that soil classes, the vulnerability of schools, and the spatial scale of loss estimations are also important factors to take into account.     

Earthquake risk assessment for the building inventory of Muscat,Sultanate of Oman

Little Andaman, the fourth largest island in the Andaman group of islands of India, was severely affected by the December 26, 2004, Indian Ocean tsunami generated by massive earthquake of moment magnitude 9.3 Mw which devastated the Andaman and Nicobar group of islands causing heavy damage to life and property. Due to hostile terrain conditions not much information was available on the extent of inundation and run-up along the island except for Hut Bay region. In order to study the vulnerability of the island to tsunami hazard, the inundation in the island due to the 2004 tsunami was studied using TUNAMI N2 numerical model and ENVISAT ASAR datasets. The extent of inundation derived from the SAR imagery was compared using the RTK-GPS field survey points collected in the Hut Bay regions immediately after the 2004 tsunami. The extent of inundation obtained from SAR images for the entire island was compared with inundation obtained from model. It was observed that the inundation obtained from the model matched well with inundation extent from SAR imagery for nearshore regions, while for low-lying areas and creeks large deviations were observed. In the absence of field datasets, the inundation derived from SAR imagery would be effective in providing ground data to validate the numerical models which can then be run for multiple scenarios for disaster mitigation and planning operation in areas that have hostile terrain conditions.     

Earthquake vulnerability and seismic risk assessment of urban areas in high seismic regions: application to Chania City,Crete Island,Greece

The earthquake vulnerability and the seismic risk assessment for the urban center of Chania in the island of Crete is approached through the development of a GIS-based application that takes into consideration the structural and geological domain of the region. Considering a localized model, the various structural and geomorphologic attributes of the region were assigned specific weights of significance that allowed the creation of a modular application that was tested for the city of Chania, and it was verified based on the recent seismic activity of the area. The proposed risk map and model can become a significant tool for confronting crises resulting from future earthquake incidences.