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1.
Impact of treated sewage sludge application on phosphorus release kinetics in some calcareous soils 总被引:1,自引:0,他引:1
Treated sewage sludge contains significant amount of phosphorus and is widely used in agriculture. Kinetics of P release in
soils is a subject of importance in soil and environmental sciences. There are few studies about P release kinetics in treated
sewage sludge amended soils. For this purpose, sludge was mixed with ten soils at a rate equivalent to 100 Mg sludge ha−1, and P desorption was determined by successive extraction using 0.01 M CaCl2 over a period of 65 days at 25 ± 1°C. Phosphorus release rate was rapid at first (until about first 360 h) and then became
slower until equilibrium was approached. Average of P released within 360 h for the unamended and amended soils was about
65 and 73% of the total desorbed P, respectively. Zero-order, first-order, second-order, power function, simplified Elovich
and parabolic diffusion law kinetics models were used to describe P release. First-order, Elovich, power function and parabolic
diffusion models could well describe P release in the unamended and amended soils. Correlation coefficients between P release
rate parameters and selected soil properties showed that in the control soils, calcium carbonate equivalent and Olsen-extractable
P; and in the amended soils, calcium carbonate equivalent, cation exchange capacity, organic matter and Olsen-extractable
P were significantly correlated with P release parameters. The results of this study showed that application of sewage sludge
can change P release characteristics of soils and increase P in runoff. 相似文献
2.
Sewage sludge usually contains significant amount of Zinc (Zn) and is widely used in agricultural lands. A laboratory experiment was performed to determine Zn desorption characteristics in unamended and amended soils with sewage sludge. Ten calcareous soils were amended with 1 % (w/w) sewage sludge. Amended and unamended soils were incubated at field capacity at 25 ± 1 °C for 1 month. After incubation, the kinetics of Zn desorption in amended and unamended soils were determined by successive extraction with DTPA-TEA (diethylenetriaminepentaacetic acid-triethanolamine) in a period of 1–504 h at 25 ± 1 °C. The results of kinetics study showed that extracted Zn and desorption rate constants in the amended soils were significantly (p < 0.01) higher than in the unamended soils. The results showed that Zn desorption increased from 201 to 343 % in amended soil with respect to unamended soils. The amounts of desorbed Zn in the unamended soils ranged from 3.73 to 8.79 mg kg?1, while the amounts of desorbed Zn in amended soils ranged from 11.47 to 17.66 mg kg?1. Desorption kinetics of Zn in two soils conformed fairly well to first-order, parabolic diffusion and power function equations. The results of stepwise regression analysis indicated that calcium carbonate equivalent and clay could be used to estimate Zn desorption characteristics in DTPA-TEA solution in the amended and unamended calcareous soils. It can be concluded that sewage sludge applied to calcareous soils may enhance the source of Zn for the plants. 相似文献
3.
Effect of addition of organic residues on phosphorus release kinetics in some calcareous soils of western Iran 总被引:2,自引:0,他引:2
We investigated the effects on phosphorus (P) release of the addition of potato, wheat, and sunflower residues and fruit compost
to five calcareous soils. Residue was added at the rate of 20 g kg−1. After 2 months of incubation, P values in control and amended soils were used for kinetic studies and fractionated by a
sequential extraction procedure. The relative contribution of available P fraction (KCl-P) increased from 1.4% in control
soils to 1.8%, 1.9%, 2.2%, and 2.3% in soils amended by fruit, wheat, potato, and sunflower residue addition, respectively,
indicating that organic residues increased P in this fraction. In soils amended with different residues, the percentage of
Olsen-P released over 86-h successive extractions with 0.01 M CaCl2 ranged from 57.6% for fruit residue addition (average of five soils) to 60.5% for potato residue addition. The ability of
residues to release P depended on the soil properties, with 21.9 mg kg−1 (average of all residues) released to soil 2 and 77.4 mg kg−1 released to soil 4. Also residues behaved differently, with 31.5 mg kg−1 (average of five soils) released by fruit residues and 40.0 mg kg−1 released by sunflower residues. Release of P was best described by a parabolic diffusion model. The corresponding rate constant
(mg kg−1 h−1/2) for P release for amended soils, defined as the release rate averaged for five soils, was found to decrease in the order:
potato (2.73) > sunflower (2.61) > wheat (2.56) > fruit (2.50). The present study demonstrates that addition of residues improves
P availability of these calcareous soils by increasing extractable P and the release rate and could be an alternative, indigenous
source of P. However, the increase in P availability and the release rate following organic residue application suggests high
potential mobility to water sources. 相似文献
4.
The phosphorus (P) resources worldwide are limited, and the prices of commercial P fertilizer continue to increase. Therefore, the use of P containing wastes is important for P recycling in agriculture. The P fractionation methods have been widely applied to characterize the effect of land use practice on soil P dynamics. Information about effect of organic manures on available P and inorganic P (Pi) fractions in calcareous soils of Chaharmahal va Bakhtiari province is limited. The objectives of this research were to study the effect of municipal compost (MC) on available P and Pi forms in five calcareous soils. Municipal compost was applied at the rates of 0, 0.5, 1.0, 1.5 and 2.0% (w/w). Samples were incubated at 25?±?1°C and 20% moisture content for 150?days. At the end of incubation, available P in MC-treated soils was extracted by Olsen, AB-DTPA and 0.01?M CaCl2 methods. Also, phosphorus was fractionated chemically into labile P (LP), non-occluded P(NP), re-adsorbed P (RP), occluded P (OP), calcium phosphates (CaP) and residual P. The results showed that there was a linear increase in soil available P with MC application. There was a significant positive relationship between Olsen-P, AB-DTPA-P and 0.01?M CaCl2-P, and MC additions with slopes ranged from 0.471 to 0.583, 0.032 to 0.106, and 0.033 to 0.081, respectively. The increase in soil test P (STP) from MC additions was not related to the initial STP of the soils. A sharp increase in LP, NP and CaP and decrease in residual P concentration occurred in all soils with MC application. It can be concluded that MC applied to calcareous soils may enhance P nutrition of plants. Furthermore, applied P partitioning into the relatively available forms means the potential erosion losses of P to streams and other bodies of water. 相似文献
5.
6.
Phosphorus desorption kinetics in two calcareous soils amended with P fertilizer and organic matter 总被引:2,自引:1,他引:1
We studied the effects of poultry manure and pistachio compost with and without phosphorus fertilizer on the kinetics of phosphorus
desorption in two calcareous soils of Kerman and Koohbanan farms in the southeastern of Iran. For this purpose mono potassium
phosphate, at rates of 0, and 100 parts per million of phosphorus, and air-dried manure, at rates of 0 and 4% were mixed with
the soils. The soils were incubated at 24–25°C and near field capacity for 90 days in the greenhouse. Afterwards, the desorption
of P was studied by the successive extraction with 0.5 M NaHCO3. The results of this research indicated that application of OM and fertilizer P combined increased P recovery in each of
the extraction time, adding poultry manure and 100 mg phosphorus together to the soils, increased P desorption more than pistachio
compost in the soils. The phosphorus desorption rate was initially rapid and then became slower until equilibrium was approached.
Kinetic data were best described by power function and simple Elovich equations. Subsequent to these equations, parabolic
diffusion equation was also well fitted the time-dependent P desorption data. 相似文献
7.
The aim of this study was to evaluate the release kinetics, speciation, and fractionation of boron (B) in some calcareous soils of western Iran. Ten surface soil samples were incubated with 100 mg B kg?1 for a week at field capacity moisture. After air drying of samples, the trend of B release was experimented using sequential extraction with 10 mM CaCl2. B speciation in soil solution was calculated for the first and the last steps of extraction by the visual MINTEQ program. The distribution of B among five fractions including exchangeable (F1), specially adsorbed (F2), bound by Fe–Mn oxides (F3), organically bound (F4) and residual (F5), was determined in control and spiked soils. The results indicated that the release rates were initially rapid followed by a slower reaction and the main proportion of the added B was extracted by CaCl2. The release kinetics of B was described well with Elovich, parabolic diffusion, power function, and first-order equations. The speciation results revealed that the uncharged boric acid (H3BO 3 0 ) was the dominant species in soil solutions. In control soils, B concentration in different fractions decreased in the following order: F5 > F1 > F2 > F3 > F4. In spiked soils, however, the largest and the smallest fractions were exchangeable and residual, respectively. This implies that B transformation from soluble to less mobile and non-labile forms is not a rapid process and requires more than a week. The significant relationship observed between kinetic parameters of power and parabolic equations and organically bound B fraction and OM content indicated that organic matter played an important role in B adsorption and release in calcareous soils. 相似文献
8.
Evaluation of phosphorus leaching from contaminated calcareous soils due to the application of sheep manure and ethylenediamine tetraacetic acid 总被引:1,自引:0,他引:1
Organic amendment application to heavy metal contaminated soils may contribute to leaching of phosphorus (P). The objectives
of this study were to determine the influence of sheep manure and ethylenediamine tetraacetic acid (EDTA) on the P leaching
from a wide range of calcareous contaminated soils. Glass tubes, 4.9 cm diameter, and 40 cm long, were packed with contaminated
soil. The resulting 20 cm long column of soils had bulk density of 1.3–1.4 g cm−3. The columns were leached with distilled water, 0.01 M EDTA, 0.01 M CaCl2 or sheep manure extract (SME) solutions. The breakthrough curves for P were different and the amounts of P leached varied
considerably between different soils and leaching solutions. The amounts leached with SME were less than the amount added
through the SME, indicating that some P was retained by the soil, mainly due to preliminary sorption of organic ligands on
to the soil with the creation of new sorbing surfaces. The amount leached with EDTA solution varied from 9.9 to 46.3% of the
extractable P when 15 pore volumes had passed through the column. Low amounts of P were leached by 0.01 M CaCl2, which is likely to be due to the high concentration of soluble Ca used in the solution. Thus, among leaching solutions the
application of EDTA and SME on contaminated calcareous soils might enhance the mobility of P and large amounts of P will be
leached, leading to contamination of ground and surface waters. 相似文献
9.
方沸石属小孔沸石,既是天然矿物,又可人工合成。在Na2O-Al2O3-SiO2-H2O水热体系,方沸石结构稳定,其生成受热力学因素控制,多种含SiO2、Al2O3组分的原料均可合成方沸石,且易于实现。方沸石通过离子替代可形成多种方沸石-白榴石系列矿物,离子交换反应存在2种形式,与交换离子尺寸相关。在农业上,负载有K、N等营养元素的方沸石兼具土壤调理和养分缓释/控释功能,是一种新型生态型肥料;在废水处理方面,方沸石可吸附多种金属离子,并对放射性元素封存有独特效果;在石油化工领域,方沸石限于对特定小分子的催化氧化作用。从绿色生态角度考虑,水热处理固体废弃物并用于有害离子处理、利用富钾岩石在制取钾盐的同时制备方沸石并用作土壤调理剂及新型缓释肥料是此类矿物资源综合利用的有效途径。 相似文献
10.
11.
Mohsen Jalali 《Environmental Geology》2007,53(2):365-374
Phosphorus (P) application in excess of plant requirement may result in contamination of drinking water and eutrophication
of surface water bodies. The phosphorous buffer capacity (PBC) of soil is important in plant nutrition and is an important
soil property in the determination of the P release potential of soils. Phosphorus sorption greatly affects both plant nutrition
and environmental pollution. For better and accurate P fertilizer recommendations, it is necessary to quantify P sorption.
This study was conducted to investigate available P and P sorption by calcareous soils in a semi-arid region of Hamadan, western
Iran. The soil samples were mainly from cultivated land. Olsen’s biocarbonate extractable P (Olsen P) varied among soils and
ranged from 10 to 80 mg kg−1 with a mean of 36 mg kg−1. Half of the soils had an Olsen P > 40 mg kg−1 and >70% of them had a concentration >20 mg kg−1, whereas the critical concentration for most crops is <15 mg P kg−1. Greater average Olsen P in soils occurred under garlic (56 mg kg−1) and potato (44 kg kg−1) fields than in dry-land wheat farming (24 mg kg−1), pasture (30 mg kg−1), and wheat (24 mg P kg−1) fields. A marked increase in fertilizer P rates applied to agricultural soils has caused P to be accumulated in the surface
soil. Phosphate sorption curves were well fitted to the Freundlich equation. The standard P requirement (SPR) of soils, defined
as the amount of P sorbed at an equilibrium concentration of 0.2 mg l−1 ranged from 4 to 102 mg kg−1. Phosphorus buffer capacity was relatively high and varied from 16 to 123 l kg−1 with an average of 58 l kg−1. In areas of intensive crop production, continual P applications as P fertilizer and farmyard manure have been used at levels
exceeding crop requirements. Surface soil accumulations of P are high enough that loss of P in surface runoff and a high risk
for P transfer into groundwater have become priority management concerns. 相似文献
12.
The aim of this study was to evaluate total mercury concentration and its lithogenic and exogenic fractions in some calcareous soils of western Iran, where water contamination and bioaccumulation of mercury have been reported in the bottomland’s reservoir. In particular, we investigated soil physico-chemical properties and weathering conditions related to lithogenic and exogenic fractions of mercury for two groups of calcareous soils with a known comparative pedological evolution and weathering condition that was evident in the presence or absence of underlying layers of accumulated clay. Our results showed that the total mercury content of the studied soils ranged from 45.40 to 830.36 with a mean of 486.81 μg kg?1. Furthermore, calculation of mercury fractions revealed that lithogenic and exogenic fractions vary slightly according to the three reference elements (Fe, U and Nb) used in the calculations for the two groups of studied soils. The results also illustrated that most of the mercury content is of exogenic origin; therefore, total mercury variations are closely related to the content of exogenic mercury, while the lithogenic fraction exhibited no relationship with total mercury concentration. Moreover, application of the weathering indexes of Parker and the CaO/ZrO2 molar ratio supported the dependence of lithogenic mercury accumulation on weathering intensity in the studied calcareous soils. However, the significance of this relationship is stronger for more weathered calcareous soils; in such cases, fine-particle fractions are more developed, which encourages carrier phases such as organic materials and iron oxyhydroxides to become involved in more efficient fixation of mercury. Nevertheless, the formation of underlying layers of accumulated clay, i.e. argillic horizons, may restrain fixation of exogenic mercury by limiting its atmospheric input. 相似文献
13.
This paper is concerned with a farmer's decision on the timing of nitrogen fertilizer application. Analytical models are developed to determine the necessary conditions for the optimal timing of the application of nitrogen fertilizer. The models, coupled with an estimated cotton yield function, are used to assess a farmer's decision on the optimal application timing of nitrogen fertilizer in cotton production. The empirical results explain various observed application timings of nitrogen fertilizer being used in cotton production in Mississippi, USA, and provide an estimate of the cost to a farmer when he or she must comply with a restriction on the timing of the application of nitrogen fertilizer.The views expressed are those of the authors, and do not necessarily represent the policies of the US Department of Agriculture or the views of other US Department of Agriculture staff members 相似文献
14.
15.
天然胶结钙质土是广泛分布于热带及亚热带海洋中由生物碎屑经碳酸钙胶结或固结而形成的碳酸盐岩类。其独特的工程性质常常给岩土工程设计与施工带来麻烦,也正因此引起了研究者的兴趣并对其开展了较为全面的试验研究工作。针对天然胶结钙质土、人工胶结钙质土的室内试验以及人工胶结钙质土试样的制备等3方面取得的研究进展进行总结回顾,汇总了胶结钙质土的基本应力-应变行为以及围压、初始密度及胶结度等主要参数的影响规律,指出了研究中尚存在的问题,并对胶结钙质土的进一步的研究工作进行了展望。该工作必将对此领域的研究具有借鉴和指导意义。 相似文献
16.
K. Urushibara-Yoshino 《Environmental Geology》1996,28(3):154-160
The properties of soils on previously dated sand dunes from Robe to Naracoorte in South Australia were examined. In these
areas younger sand dunes are composed of fresh sand, but older sand dunes are composed of calcarenited sand. The soils on
the sand dunes developed successionally by the age of sand dunes. The soil properties of these sand dunes differ depending
on the ages of the sand dunes. The properties of sand particles in soils are as follows:
(1) On the sand dunes of 4300 years B.P., A/C profile developed (Rendzina). On the sand dunes older than 125 000 years B.P.
and on the plateau of Tertiary limestone, soil profiles of A1/AB/B/C on the sand dunes of 83 000 years B.P. and A1/A3/B1/B2/C (Terra rossa) are well developed.
(2) Within the sand of A/C horizons of the sand dunes with the age of 4300 year B.P., the calcite grain content is about 64%,
and the quartz content is about 35%. Within the B horizons of soils on the dunes from 83 000 years B.P. to 347 000 years B.P.,
the calcite grain content is only 1–2%; however, the quartz grain content is about 92%. In the B2 horizons of soils on the dune of 690 000 years B.P. and on the Tertiary plateau, there are some calcite grains but the quartz
grain content is about 96%.
(3) The average size of quartz grains in the soils on the sand dunes from 4300 B.P. to 347 000 years B.P. is generally smaller,
but the average size of quartz on the sand dunes of 690 000 year B.P. becomes larger and the grains are well rounded. On the
Tertiary limestone plateau, the average quartz size becomes again smaller, and the grains are more rounded.
(4) Fet in B2 horizon of the soil profiles increases clearly corresponding to the age. Iron activity expressed by Feo/Fed also shows a close relation to the chronological sequence. The B horizon of the soil profiles shows a drastic decrease of
Feo/Fed according to the age. Iron crystalinity, (Fed-Feo)/Fet, has a tendency for a positive relation with increasing age.
Received: 1 June 1995 · Accepted: 4 December 1995 相似文献
17.
Salar Rezapour 《Environmental Earth Sciences》2014,71(5):2199-2210
Monitoring general variability of soil attributes is a fundamental requirement from the point of view of understanding and predicting how ecosystems yield. In order to monitor impact of different land use types on the combination of morphological, clay mineralogical and physicochemical characterizes, 42 soil samples (0–30 cm) were described and analyzed. Soil samples belonging to Cambisols and Vertisols reference soil groups collected from three neighboring land use types included cropland (under long-term continuous cultivation), grassland, and forestland. The soils were characterized by high pH (mean of 7.1–7.5) and calcium carbonate equivalent (CCE) (mean of 35–97 g kg?1) in the three land use types. The weakening in soil structure, hardening of consistency, and lighting of soil color occurred for the cropland under comparable condition with grassland and forest. Changes in land use types produced a remarkable change in the XRD patterns of clay minerals containing illite and smectite due the dynamic and removal of potassium. Continuous cultivation resulted in an increase in sand content up to 35 % while silt and clay content decreased up to 22 and 18 %, respectively, as compared to the adjoining grassland and forest mainly as a result of the difference of dynamic alterational and erosional process in the different land use. Long-term cultivation caused a negative and degradative aspects on soil heath as is manifested by the increasing in soil pH (a rise of 0.3–0.46 unit), electrical conductivity (EC) (a rise of 1.78–5.5 times), sodium absorption ration (SAR) (a rise of 10–51 %), exchangeable sodium percentage (ESP) (a rise of 3–46 %), and the decrease in soil organic C (a drop of 12–41 %), along with soil fertility attributes. Overall, the general distribution of soil organic C, total N, available P and K, cation exchange capacity (CEC), and exchangeable cations (Ca, Mg, and K) followed the order: forestland > grassland > cropland. The general distribution of EC, SAR, ESP, and exchangeable Na, however, followed the order: cropland > grassland > forestland. Soil quality index (SQI), calculated based on some physicochemical properties, specified that cultivation led to a negative effect in SQI for both Cambisols (a drop of 10–17 %) and Vertisols (a drop of 17 %) as compared to those of under grassland and forestland. 相似文献
18.
Transfer pathways of phosphorus (P) from soil to surface waters are the subject of much current research because of concerns about eutrophication. However, P transfer via groundwater discharge has received little attention. Temporal P changes at eight Carboniferous limestone karst springs from two catchments in western Ireland are examined. The eight springs were sampled fortnightly between June and October 1999 and thereafter monthly until February 2000. Each sample was analysed for total P (TP), total dissolved P (TDP) and dissolved reactive P (DRP). Total P exhibited some hydrological response at all springs (e.g. increase from 45 to 107 µg l–1) reflecting significant changes in particulate P (PP) (e.g. increase from 7 to 44 µg l–1) and dissolved organic P (DOP) (e.g. increase from 0 to 27 µg l–1), with DRP displaying greatest temporal stability. Greatest response to rainfall events occurred after the first major autumnal rains in September 1999, when there appeared to be dislodging of loosely bound PP and DOP, which was transported to groundwater. This response to the first autumnal rains probably reflects the hydrological switch where the catchments change from a soil moisture deficit to a soil moisture surplus situation. Daily autosampling demonstrated TP concentrations of up to 1,814 µg l–1 due to local pollution, highlighting the need to adopt storm event driven sampling rather than discrete sampling in karstic springs. Identification and management of springs in karst areas, with associated point recharge via swallow holes, presents an urgent and demanding challenge. 相似文献
19.
Phosphorus retention in calcareous soils and the effect of organic matter on its mobility 总被引:7,自引:0,他引:7
Ray von Wandruszka 《Geochemical transactions》2006,7(1):6-8
A survey of the interactions between phosphorus (P) species and the components of calcareous soils shows that both surface
reactions and precipitation take place, especially in the presence of calcite and limestone. The principal products of these
reactions are dicalcium phosphate and octacalcium phosphate, which may interconvert after formation. The role of calcium carbonate
in P retention by calcareous soils is, however, significant only at relatively high P concentrations – non-carbonate clays
play a more important part at lower concentrations. In the presence of iron oxide particles, occlusion of P frequently occurs
in these bodies, especially with forms of the element that are pedogenic in origin. Progressive mineralization and immobilization,
often biological in nature, are generally observed when P is added as a fertilizer. 相似文献
20.
生物质炭对于土壤中不同形态氮库的含量影响已有较多研究,但对西南喀斯特区石灰性土壤氮素形态,尤其是控制氮素形态的转化过程研究较为缺乏。本研究设置土壤中添加1%(C1)和3%(C2)蔗渣生物质炭2个用量水平,并以不施用蔗渣生物质炭作为对照(CK),共3个处理,通过15NH4NO3和NH415NO3成对标记技术,结合MCMC氮素转化模型研究了不同用量的蔗渣生物质炭对石灰性土壤氮转化过程的短期影响,为该地区蔗渣资源化利用和土壤氮保持提供理论支撑。结果表明,与CK相比,添加蔗渣生物质炭能够快速提高土壤pH和有机碳含量。添加生物质炭并没有显著改变土壤氮的矿化、铵态氮(NH+4氮(NO-3物同化和异养硝化速率,但NH+4随生物质炭用量的增加而提高,以添加量最高的C2处理最大。添加生物质炭同样提高了土壤NH+4速率,但C1和C2处理的土壤NH+4放速率并无显著性差异。与CK和C1处理相比,施用高量蔗渣生物质炭通过抑制自养硝化速率而显著降低了硝态氮净产生速率。这些结果表明,施用高量蔗渣生物质炭于石灰性土壤中可快速实现对NH+4,降低自养硝化速率,减少NO-3,从而降低了其损耗和淋失风险。 相似文献