NWA 13943(CK5型)碳质球粒陨石的矿物岩石学和稳定同位素组成研究

CK型陨石是一类高度氧化的碳质球粒陨石, 金属/磁铁矿的比值接近零. 与其它类型的碳质球粒陨石(岩石类型: 1-3)不同, 大多数CK型陨石在母体上经历了强烈的热变质过程(550--1270K), 以4-6型为主. 多项证据表明, CK和CV3型陨石具有成因联系. 但是, 两者在岩相结构和化学组成方面仍存在微小差异. 因此, 精细地区分和比较两者的地球化学特征对于验证CK-CV单一母体假说非常重要. Northwest Africa (NWA) 13943是一块新发现的陨石, 经历过较强烈的热变质作用. 利用扫描电子显微镜和电子探针, 确定了NWA 13943的岩石类型. 并运用质谱分析技术, 重点测定了NWA 13943陨石的全岩氧同位素和铬同位素组成. 综合岩石结构、矿物化学成分、氧同位素异常(△¹⁷O,△代表同位素分馏值)和铬同位素异常(ε⁵⁴Cr, ε表示样品中的同位素比值与标样中的同位素比值的相对偏差的10⁴倍),CK和CV型陨石的母体可能形成于原行星盘中两个相似但不同的化学源区.     

球粒陨石难熔包体中贵金属的矿物岩石学分析:对太阳星云演化的启示

球粒陨石中的富钙富铝难熔包体(Ca,Al-rich Inclusion,CAI)是太阳系最早形成的物体,保留了太阳星云早期的原始信息,但深入研究发现许多难熔包体具有复杂的演化历史,包括部分熔融和后期变质作用等.针对难熔包体中更为难熔、化学性质更为稳定的贵金属颗粒进行天体化学研究,选取CV群碳质球粒陨石NWA 2140,对其CAI中的贵金属颗粒进行岩石学观察及化学成分测定.根据得到的成分分析结果,能大致推出包体经历过的热力学历程,辨识出两类贵金属合金颗粒,这两类贵金属分别为早期冷凝产物和原生金属的后期蚀变产物.     

行星际尘中低原子序元素的丰度分析

本文根据二颗行星际尘的质谱(1～32a.m.u)和EDS谱,分析了它们的低原子序元素的丰度.结果表明,它们与相应的太阳系元素丰度值相近,是碳质球粒型宇宙尘,可能保留有较多大用系形成初期的信息。     

X-Wind模式下对宁强碳质球粒陨石光学特征的重新认识

宁强碳质球粒陨石非偏振光、偏正光、反射光下的矿物、组构的光学特征中蕴藏着丰富的有关太阳星云演化初期不挥发组分吸积时的动力、温度、压力、介质信息．在宁强陨石双面抛光片中,矿物组构混杂堆积的构造反映了太阳星云吸积盘上极弱的机械动力环境和近物源吸积作用;外形不规则,边缘参差的矿物集合体和矿物碎片应该是抛落时碰撞破碎的球粒,这些球粒形成于X-Wind模式中的X-区,并被双极喷流抛落到太阳星云的不同部位;在透射光下,从宁强陨石中首次发现存在有玻璃、结晶、及气相包裹体,它们可以反映出太阳星云演化过程中的物质成分、热力学、动力学信息,应该引起重视．实验观察中还发现同一个球粒中锯齿状缝合线连接的橄榄石栅条和橄榄石颗粒．诸多现象需要理论物理、天体物理观察和天体化学实验的科学家共同努力去探讨.X-Wind模式中许多细节有待天体化学实验去检验、补充和完善．     

小行星与彗星—近地小行星,主带小行星和彗星之间相互关系探讨

小行星和彗星都是太阳系中的小天体,而近地小行星又是小行星中特殊的一类。近年来对近地小行星的观测和研究已全面开展,这已成为当今太阳系研究的前沿领域之一。本文初步探讨太阳系中不同小天体之间的关系:1.小行星与短周期彗星之间的关系;2.近地小行星与主带小行星和短周期彗星之间的关系。最近的观测研究表明某些小行星可能是由彗星演变来的,而某些近地小行星可能来源于主带小行星和死亡的彗核。     

行星科学与深空探测（二）--行星科学研究的国际现状和发展趋势

根据太阳系行星物质的主要性态和大小,人们通常将其分成行星（包括类地行星和类木行星）、卫星、小行星、彗星和流星体。类地行星包括水星、金星、地球和火星;类木行星包括木星、土星、天王星和海王星;质量较大的小行星和卫星的内部结构与类地行星相似,质量较小的小行星和卫星以及流星体主要由岩石和金属组成;彗星是含有太阳系形成时期物质且没有经过太多物理和化学演化的冰态小天体。     

中国陨石发展现状与假陨石泛滥（上）

落后的起步 陨石是外层空间给人类的珍贵礼物,是研究地外物质与太阳系的珍贵科学标本,对于移民太空、延续人类生命的终极目标可谓意义重大。欧美等国很早已有系统的研究,我国天体化学与陨石研究的开端始自1976年吉林陨石雨,“嫦娥之父”欧阳自远院士堪称奠基之人。     

行星科学与深空探测（三）——太阳系小天体研究和行星深空探测的国际现状与发展趋势

小行星与慧星研究 小行星和彗星是45亿年前太阳系形成时遗留的原始残骸,包含着太阳系早期的物理和化学信息,对研究太阳系起源和行星系统形成具有重要科学意义,同时精密确定其轨道动力学演化又是目前空间环境和地球安全方面的重要现实需求。     

银河系化学元素的丰度特征和合成图像(Ⅱ):太阳系原始同位素丰度异常及其解释

太阳系原始同位素组成是研究太阳系起源和演化的基础。评述了太阳星云的原始放射性核素丰度特征及解释此丰度特征的分子云自增丰模型、AGB星污染模型和散裂反应模型。陨石包体中前太阳矿物颗粒的同位素组成异常表明,前太阳颗粒中低密度石墨、X型碳硅石可能来源于超新星爆发,而AGB星或红巨星被认为是尖晶石和碳硅石的最可能的恒星来源。太阳系中比较特殊的氖和氙的同位素组成异常也与超新星爆发密切相关。     

不可忽视的小行星

在太阳系里,有许多沿着椭圆轨道绕太阳运行而且不易挥发出气体和尘埃的小天体,这就是人们常说的小行星。据估计,太阳系中小行星数以几十万计,小行星的体积大小不一,最大的直径有1000千米左右,最小的只有鹅卵石大小。由于它们的质量很小,一般不会发生像地球沧海桑田那样的变化过程,因此保留了太阳系初期的原始状况,这对于研究太阳系的起源与演化有     

A plausible link between the asteroid 21 Lutetia and CH carbonaceous chondrites

A crucial topic in planetology research is establishing links between primitive meteorites and their parent asteroids. In this study, we investigate the feasibility of a connection between asteroids similar to 21 Lutetia, encountered by the Rosetta mission in July 2010, and the CH3 carbonaceous chondrite Pecora Escarpment 91467 (PCA 91467). Several spectra of this meteorite were acquired in the ultraviolet to near‐infrared (0.3–2.2 μm) and in the midinfrared to thermal infrared (2.5–30.0 μm or 4000 to ~333 cm⁻¹), and they are compared here to spectra from the asteroid 21 Lutetia. There are several similarities in absorption bands and overall spectral behavior between this CH3 meteorite and 21 Lutetia. Considering also that the bulk density of Lutetia is similar to that of CH chondrites, we suggest that this asteroid could be similar, or related to, the parent body of these meteorites, if not the parent body itself. However, the apparent surface diversity of Lutetia pointed out in previous studies indicates that it could simultaneously be related to other types of chondrites. Future discovery of additional unweathered CH chondrites could provide deeper insight in the possible connection between this family of metal‐rich carbonaceous chondrites and 21 Lutetia or other featureless, possibly hydrated high‐albedo asteroids.     

Extraterrestrial organic compounds and cyanide in the CM2 carbonaceous chondrites Aguas Zarcas and Murchison

Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.     

Spectroscopy of K-complex asteroids: Parent bodies of carbonaceous meteorites?

This is the first focused study of non-Eos K asteroids. We have observed a total of 30 K-complex objects (12 K-2 Sk- and 13 Xk-type asteroids (from the Bus taxonomy), plus 3 K-candidates from previous work) and we present an analysis of their spectral properties from 0.4 to 2.5 μm. We targeted these asteroids because their previous observations are spectrally similar enough to suggest a possible compositional relationship. All objects have exhibited spectral redness in the visible wavelengths and minor absorptions near 1 micron. If, as suggested, K-complex asteroids (including K, Xk, and Sk) are the parent bodies of carbonaceous meteorites, knowledge of K-asteroid properties and distribution is essential to our understanding of the cosmochemical importance of some of the most primitive meteorite materials in our collection. This paper presents initial results of our analysis of telescopic data, with supporting analysis of laboratory measurements of meteorite analogs. Our results indicate that K-complex asteroids are distinct from other main belt asteroid types (S, B, C, F, and G). They do not appear to be a subset of these other types. K asteroids nearly span the range of band center positions and geometric albedos exhibited by the carbonaceous chondrites (CO, CM, CV, CH, CK, CR, and CI). We find that B-, C-, F- and G-type asteroids tend to be darker than meteorites, and can have band centers longer than any of the chondrites measured here. This could indicate that K-complex asteroids are better spectral analogues for the majority of our carbonaceous meteorites than the traditional B-, C-, F- and G-matches suggested in the literature. This paper present first results of our ongoing survey to determine K-type mineralogy, meteorite linkages, and significance to the geology of the asteroid regions.     

Clay mineral‐organic matter relationships in the early solar system

Abstract— As the solar system formed, it inherited and perpetuated a rich organic chemistry, the molecular products of which are preserved in ancient extraterrestrial objects such as carbonaceous chondrites. These organic‐rich meteorites provide a valuable and tangible record of the chemical steps taken towards the origin of life in the early solar system. Chondritic organic matter is present in the inorganic meteorite matrix which, in the CM and CI chondrites, contains evidence of alteration by liquid water on the parent asteroid. An unanswered and fundamental question is to what extent did the organic matter and inorganic products of aqueous alteration interact or display interdependence? We have used an organic labelling technique to reveal that the meteoritic organic matter is strongly associated with clay minerals. This association suggests that clay minerals may have had an important trapping and possibly catalytic role in chemical evolution in the early solar system prior to the origin of life on the early Earth.     

Reflectance spectroscopy of insoluble organic matter (IOM) and carbonaceous meteorites

Insoluble organic matter (IOM) is the major organic component of chondritic meteorites and may be akin to organic materials from comets and interplanetary dust particles (IDPs). Reflectance spectra of IOM in the range 0.35–25 μm are presented as a tool for interpreting organic chemistry from remote measurements of asteroids, comets, IDPs, and other planetary bodies. Absorptions in the IOM spectra were strongly related to elemental H/C (atom) ratio. The aliphatic 3.4 μm absorption in IOM spectra increased linearly in strength with increasing H/C for H/C > 0.4, but was absent at lower H/C values. When meteorite spectra from the Reflectance Experiment Laboratory (RELAB) spectral catalog (n = 85) were reanalyzed at 3.4 μm, this detection limit (H/C > 0.4) persisted. Aromatic absorption features seen in IOM spectra were not observed in the meteorite spectra due to overlapping absorptions. However, the 3.4 μm aliphatic absorption strength for the bulk meteorites was correlated with both H/C of the meteorite's IOM and bulk C (wt%). Gaussian modeling of the 3 μm region provided an additional estimate of bulk C for the meteorites, along with bulk H (wt%), which is related to phyllosilicate abundance. These relationships lay the foundation for determining organic and phyllosilicate abundances from reflectance spectra. Both the full IOM spectra and the spectral parameters discussed here will aid in the interpretation of data from asteroid missions (e.g., OSIRIS‐REx, Hayabusa2), and may be able to place unknown spectral samples within the context of the meteorite collection.     

The Aguas Zarcas (CM2) meteorite: New insights into early solar system organic chemistry

To date, the CM2 class of carbonaceous chondrites has provided the most detailed view of organic synthesis in the early solar system. Organic‐rich chondrites actually observed falling to Earth (“Falls”), for example, the Murchison meteorite in 1969, are even more rare. The April 23, 2019 fall of the Aguas Zarcas meteorite is therefore the most significant CM2 fall since Murchison. Samples collected immediately following the fall provide the rare opportunity to analyze its bulk mineralogy and organic inventory relatively free of terrestrial contamination. According to the Meteoritical Bulletin, Aguas Zarcas (“AZ” or “Zarcas”) is dominated by serpentine, similar to other CM2 chondrites. Likewise, our initial analyses of AZ were meant to give a broad view of its soluble organic inventory relative to other carbonaceous chondrites. We observe that while it is rich in hydrocarbons, carboxylic acids, dicarboxylic acids, sugar alcohols, and sugar acids, some of these classes may be of lesser abundance than in the more well known carbonaceous chondrites such as Murchison. Compared generally with other CM2 meteorites, the most significant finding is the absence, or relatively low levels, of three otherwise common constituents: ammonia, amino, acids, and amines. Overall, this meteorite adds to the building database of prebiotic compounds available to the ancient Earth.     

Comparison of FT‐IR spectra of bulk and acid insoluble organic matter in chondritic meteorites: An implication for missing carbon during demineralization

Past studies of the various separable carbonaceous fractions have been unable to account for all of C in primitive chondrites. In particular, up to 20–50% of the C is lost during acid leaching of bulk samples even after the C in carbonates and soluble organic matter is accounted for. To try to better characterize the nature of this “missing C,” we have compared the bulk infrared (IR) absorption spectra of a number of primitive chondrites with those of their previously reported insoluble organic matter (IOM). The aliphatic C–H stretching bands, in particular, allow us to compare the molecular structures of bulk C with that of IOM. The spectral differences between bulk C and IOM reflect “missing C” phases that were lost during acid leaching, although we cannot completely exclude the possibility that the OM was modified after demineralization. Comparing IR spectra of bulk meteorite powder and IOM suggests that the missing C varies in its molecular structure, and that mildly thermally metamorphosed type 3 chondrites tend to be richer in an aliphatic fraction with lower CH₂/CH₃ ratios, relative to IOM, compared to aqueously altered carbonaceous chondrites (CI/CM/CR). The missing C is most likely released from acid‐labile functional groups, such as esters, acetals, and amides, during demineralization, although it cannot be ruled out that some fraction of the missing C is in small grains that are difficult to recover from suspension, or in water‐soluble compounds trapped in phyllosilicates.     

Infrared transmission spectra from 2.5 to 25 μm of various meteorite classes

Infrared transmission spectra from 53 meteorites in the spectral range from 2.5 to 25 μm were measured to permit comparisons with data of astronomical objects that are potential meteorite sources. Data were taken for 14 carbonaceous chondrites, 5 LL ordinary chondrites, 6 L ordinary chondrites, 10 H ordinary chondrites, 1 enstatite chondrite, 4 aubrites, 3 eucrites, 4 howardites, 1 diogenite, 1 mesosiderite, 2 nakhlites, 1 shergottite, and the anomalous achondrite Angra dos Reis. The CO and CV carbonaceous chondrites have spectra similar to each other, with 10-μm features characteristic of olivine. The CM carbonaceous chondrites have distinctive 10-μm features that are attributed to layer lattice silicates. Members of both the CI and CR classes have spectra distinct from those of other carbonaceous chondrites. The LL, L, and H ordinary chondrites have spectra that match those of olivine and pyroxene mixtures. The enstatite chondrites and enstatite achondrites (aubrites) all exhibit spectra diagnostic of the pyroxene enstatite. The angrite, howardites, aucrites, nakhlites, shergottite, and diogenite all have similar spectra also dominated by pyroxene. The single mesosiderite examined had a spectrum distinct from all the other meteorites.     

Assessing the spatial variability of the ~3 μm OH/H2O absorption feature in CM2 carbonaceous chondrites

H₂O and OH are readily detected in hydrated minerals in CM chondrites via reflectance spectroscopy due to their characteristic vibration absorptions at infrared wavelengths. Previous spectroscopic work on bulk powdered CM chondrites has shown that spectral parameters, like the wavelength position of the “3 μm absorption feature,” vary systematically with the extent to which the samples have been aqueously altered. However, it is yet unclear how these spectral features may vary across an intact meteorite chip when measured at spatial scales smaller than that of the individual components of the meteorite. Here, we explore the spatial variability of this spectral feature and others on intact CM2 chips which, unlike powders, retain their petrologic and textural characteristics. We also model the modal mineralogy of the bulk meteorite powders and correlate this with key spectral features, demonstrating that microscope Fourier transform infrared spectroscopic mapping provides a powerful, rapid, and non-destructive technique for assessing compositional diversity and variations in water–rock interactions in chondritic planetary materials. In all CM2 chondrites studied here, we find that variations in the position, shape, and strength of the 3 μm absorption feature reveal a single chondrite can exhibit as much spectral variation as the entire suite of CM2 chondrites. The observed variations in the position and shape of the 3 μm feature within individual CM2 chondrite chips suggest a range of alteration products (e.g., Mg-rich to Fe-rich phyllosilicates) are present and record sub-mm scale variations in the amount and/or chemistry of the altering fluids. The samples having experienced the most progressive aqueous alteration show the least amount of variability in features like the 3 μm absorption band minimum position, whereas the least altered samples exhibit the most variability. We also find that the bulk spectral signatures in the least altered samples appear to be biased toward the spectral signatures of clasts versus matrix. By extension, asteroid reflectance spectra exhibiting 3 μm absorption features consistent with those measured here may be interpreted in a similar framework in which the spectrum of what may appear to be the least altered asteroids represents an average that belies the true diversity of mineralogy and chemistry of the body.     

Prebiotic carbon in clays from Orgueil and Ivuna (CI), and Tagish Lake (C2 ungrouped) meteorites

Abstract— Transmission electron microscopic (TEM) and electron energy‐loss spectroscopic (EELS) study of the Ivuna and Orgueil (CI), and Tagish Lake (C2 ungrouped) carbonaceous chondrite meteorites shows two types of C‐clay assemblages. The first is coarser‐grained (to 1 μm) clay flakes that show an intense O K edge from the silicate together with a prominent C K edge, but without discrete C particles. Nitrogen is common in some clay flakes. Individual Orgueil and Tagish Lake meteorite clay flakes contain up to 6 and 8 at% C, respectively. The C K‐edge spectra from the clays show fine structure revealing aromatic, aliphatic, carboxylic, and carbonate C. The EELS data shows that this C is intercalated with the clay flakes. The second C‐clay association occurs as poorly crystalline to amorphous material occurring as nanometer aggregates of C, clay, and Fe‐O‐rich material. Some aggregates are dominated by carbonaceous particles that are structurally and chemically similar to the acid insoluble organic matter. The C K‐edge shape from this C resembles that of amorphous C, but lacking the distinct peaks corresponding to aliphatic, carboxylic, and carbonate C groups. Nanodiamonds are locally abundant in some carbonaceous particles. The abundance of C in the clays suggest that molecular speciation in the carbonaceous chondrites is partly determined by the effects of aqueous processing on the meteorite parent bodies, and that clays played an important role. This intricate C‐clay association lends credence to the proposal that minerals were important in the prebiotic chemical evolution of the early solar system.