九龙江口海域中磷的化学形态分布

根据１９８７年３月至１９８８年１２月笔者在九龙江口、厦门西海域的调查研究资料，着重讨论颗粒态磷（ＰＰ）、溶解态无机磷（ＤＩＰ）、溶解态有机磷（ＤＯＰ）、总磷（ＴＰ）等各种形态磷的含量分布、季节变化，及其与叶绿素（Ｃｈｌ．ａ）、总悬浮物量（ＴＳＭ）等其他要素的关系。     

The chemical distribution characteristics of variant form phosphorus in the seawater of the South China Sea

According to two cruises investigation information in summer and winter during 1998 and1999, the phosphorous concentration distribution and changes of summer and winter were discussed pri-marily in the South China Sea. The results show that the phosphate concentration of surface seawater insummer is distinctly lower than that in winter, averaging 0.04 μmol/dm3 in summer and 0.35 μmol/dm3 in winter. The organic phosphorous concentration of surface seawater in summer is higher than thatin winter, averaging 0.12μmol/dm3 in summer and 0.04 μmol/dm3 in winter respectively. The season-al changes of total phosphorus are similar to phosphate, averaging 0.22 μmol/dm3 in summer and 0.61μmol/dm3 in winter respectively. In vertical direction, phosphate, TDP and TP content are the lowestin upper 50 m water column, and increase in linearity rapidly with water depth, increasing slowly under500 m, reach to maximum about 1 000 m, then decrease slightly with water depth increasing. The ver-tical distribution is typical in summer, and there is small dispersed for phosphorus concentration for thesame depth of different stations. However, in winter there is a large disperse for phosphate, TDP andTP, specifically for phosphate at 200 m at which the concentration is maximum. This result indicatesthat there are large differences in hydrology and biology conditions that affect largely the chemical envi-ronment of the South China Sea. The organic phosphorus is the predominant in surface seawater of theSouth China Sea, but the inorganic phosphorus is the predominant in layers below depth of 150 m. Theorganic phosphorus concentration in deep water usually decreases with water depth increasing. The or-ganic phosphorus in summer is remarkably more than that in winter because of the strong biology activi-ties in summer.     

Sedimentation settings and evolution history of the Kuril Basin (Sea of Okhotsk) in the Cenozoic

A study of the rocks from the Cenozoic sedimentary cover of the Kuril Basin slopes revealed two sedimentation stages in this area: the Late Oligocene-Early Miocene and Late Miocene-Pleistocene, which are separated by erosion in the Middle Miocene. They are characterized by dominant siliceous and terrigenous sediments, respectively. The former largely accumulated in neritic settings, while the latter were deposited in the bathyal zone under a strong influence of explosive volcanism. The change in the sedimentation regime probably occurred in the Middle-Late Miocene during the formation of the slopes of the present-day Kuril Basin. The rocks constituting crustal blocks with a granite-metamorphic layer served as a source of terrigenous material for the Cenozoic sedimentary cover, which indicates the sialic nature of the underlying basement.     

南海海域海水中各形态磷的化学分布特征

根据1998年7月和1999年1月两个航次的调查资料,对南海水体中磷的含量分布以及夏、冬季变化规律进行了探讨.结果表明,南海表层水体中磷酸盐夏季含量明显低于冬季,夏季平均含量为0.004μmol/dm3,而冬季为0.35 μmol/dm3;有机磷含量夏季高于冬季,含量分别为0.12,0.04 μmol/dm3;总磷含量的季节变化与无机磷酸盐类似,夏、冬季含量分别为0.22,0.61 μmol/dm3.在垂向分布上表层50 m水柱中PO₄3--P,总溶解态磷和总磷含量最小,随水深增加基本上呈线性快速增加,至500 m增加减缓,1 000 m左右为最大含量,然后随着水深略有下降.在夏季垂直分布比较典型,不同站位在一水深的含量离散性小,而冬季PO₄3--P,总溶解态磷和总磷的垂直分布则显得离散性大,尤其是PO₄3--P分布在200 m左右出现最大值,说明当年冬季南海各区域存在着较大水文、生物差异,很大的影响了化学环境的变化.在南海表层水中通常以有机磷占优势,在150 m深处以下的水中则以无机磷为主.深水中溶解的有机磷含量一般随水深减少.夏季的有机磷明显高于冬季,表明夏季的生物作用强烈.     

冲绳海槽浮岩中岩浆包裹体岩石化学成分特征

系统地分析了冲绳海槽酸性浮岸中玻璃质岩浆包裹体的岩石化学成分，探讨了包裹体的岩石化学成分特征及其在岩浆起源及结晶演化过程中的指示意义，并结合前期及前人工作讨论了冲绳海槽不同岩石类型之间的成因联系及演化关系。结果表明，斑晶结晶时岩浆熔体为钙碱性英安质或流纹质岩浆，是来自地幔的拉斑玄武质岩浆充分结晶分异作用的产物。尽管各斑晶矿物中玻璃质岩浆包裹体的化学成分有所差异，但根据包裹体的岩石化学成分特征可以断定包裹体所代表的岩浆具有同源性，其差异只是反映了岩浆结晶演化的不同阶段或不同矿物结晶期，为进一步详细研究浮岩岩浆的结晶演化过程提供了最直接的资料。对比冲绳海槽酸性浮岩与玄武岩等不同岩石类型的岩石化学特征，可以证明这些岩石类型之间存在着密切的成因联系，包括同源性与继承性，它们分别是岩浆作用不同阶段的产物。另外，包裹体的成分主要取决于包裹体所在斑晶矿物的种类与成分，分析中未发现岩石化学性质明显不同的岩浆包裹体共存的现象，也没有在中酸性矿物中发现基性玻璃质岩浆包裹体，因此可以推断基本不存在不同性质的岩浆之间的直接混合作用。     

东海PN断面夏季温盐及化学要素的分布特征

由东海PN断面夏季温鼻度及化学要素CTD资料分析表明，东海夏季的温跃层和盐跃层在次表层生成，其强度随着跃层自陆架坡折区至近岸和外海的上移逐渐减弱。陆架区近表层的温度和盐度呈垂直均匀分布，冲绳海槽次表层呈高温、高盐，近表层呈高温，近表层呈高温、低盐，底层呈低温、次高盐特征。溶解氧浓度自近岸到外海由低变高，表层至底层溶解氧浓度在陆架区由高变低，冲绳海槽区则先由低变高然后又由变低。总二氧化碳浓度自表层至底层和自陆架坡折区到近岸和外海由低变高。磷酸盐和硅酸盐浓度自近岸至外海由高变低，而自表层至底层由低变高。陆架区的近表层和陆架坡折区分别有一个高碱度区。温盐及化学要素的分布特征与夏季海区垂直环流的反气旋运动、长江冲淡水及黑潮水入侵和海面强热辐射有关。此外，化学要素分布还与夏季海区的温盐结构、表混合层与大气间二氧化碳气体交换及表混合层中碳和营养盐光合作用的利用有关。     

Sediment Flux of Particulate Organic Phosphorus in the Open Black Sea

The interannual variation of the monthly average (weighted average) concentrations of particulate organic phosphorus (P_POM) in the photosynthetic layer, oxycline, redox zone, and H₂S zone in the open Black Sea is estimated based on long-term observation data. The suspension sedimentation rates from the studied layers are assessed using model calculations and published data. The annual variation of P_POM sediment fluxes from the photosynthetic layer, oxycline, redox zone, and upper H₂S zone to the anaerobic zone of the sea and the correspondingly annual average values are estimated for the first time. A regular decrease in the P_POM annual average flux with depth in the upper active layer is demonstrated. A correlation between the annual average values of P_POM sediment flux from the photosynthetic layer and ascending phosphate flux to this layer is shown, which suggests their balance in the open sea. The results are discussed in terms of the phosphorus biogeochemical cycle and the concept of new and regenerative primary production in the open Black Sea.     

Cenozoic sedimentary rocks on the northern slopes of the Kuril Deep-Water Basin (Sea of Okhotsk) and conditions of their formation

Sedimentary rocks from the northern slope of the Kuril Deep-Water Basin are examined. Four different-age lithological units are distinguished, and inferences about the probable conditions of their formation are made. The Paleogene-Lower Miocene deposits (lithological units I and II) are represented by the purest varieties of siliceous rocks, which implies their accumulation far away from the source areas under quiet hydrodynamical conditions of the waters. The composition of the microfossils suggests a relatively shallow-water marine basin. The Pliocene-Pleistocene deposits of lithological units III and IV were formed in an active hydrodynamical environment under conditions of synchronous explosive volcanism at bathyal depths. The presence of porcelanite outcrops on the continental slope of the basin, together with the micropaleontological data about the paleodepths of the sedimentation, allows us to assume that, in the region studied, the continental slope was formed as a result of vertical motions in the post-Middle Miocene time.     

Relationship between tissue phosphorus and seawater phosphate in the brown alga Hormosira banksii

We measured tissue phosphorus content of high and low intertidal Hormosira banksii to test the hypothesis that tissue phosphorus content would be greater in individuals from the low intertidal because of greater total uptake associated with longer immersion in seawater. Moreover, we predicted that tissue phosphorus would be greater at sites where the seawater contained higher phosphate concentrations. There was a positive, linear relationship between local seawater phosphate concentrations and tissue phosphorus content of H. banksii from high and low intertidal zones at six different sites in winter. However, there were no comparable relationships in summer, even though the range of seawater phosphate concentration was similar in both seasons. The phosphorus contents of low intertidal H. banksii were significantly greater than high intertidal H. banksii in winter, but not in summer. Reasons for these differences may be related to greater access to seawater phosphate in low intertidal algae (than those in the high intertidal) in winter, followed by greater utilisation of the internal phosphorus between winter and summer, due to faster growth rates in the low intertidal.     

Particle-bound phosphorus along an urbanized coastal plain estuary

The distribution of particle-bound phosphorus in the suspended sediment of the Delaware Estuary was examined with a sequential chemical leaching technique. The phosphorus content of particles was highest in the tidal river (140–250 μmol g⁻¹) near major anthropogenic inputs. Despite this enrichment of river particles with phosphorus, suspended particles within the salinity gradient had a phosphorus content more similar to the world's average. Sequential chemical leaches revealed that particulate phosphorus was associated with organic matter, aluminum oxides, iron oxides, and apatite in all areas of the estuary. However, ‘excess’ particle-bound phosphorus in the tidal river was associated mainly with iron oxides (27%), aluminum oxides (23%), and organic matter (50%). Within the salinity gradient, particulate phosphorus associated with iron oxides, aluminum oxides, and apatite all decreased with increasing salinity. Estuarine mixing was simulated to determine whether the observed decreases in particle-bound phosphorus pools in field samples were due to release into solution. During simulated mixing, particulate phosphorus associated with iron and aluminum oxides decreased, but no change was observed in apatite-bound phosphorus. The results of the mixing study combined with the observed particle-bound phosphorus distributions suggest that phosphate concentrations along the Delaware Estuary may be partially ‘buffered’ by aluminum and iron oxide phases.     

缅甸安达曼海域中部天然气成因与气源

位于主动大陆边缘的缅甸安达曼海域中部天然气资源丰富,成因多样。天然气成因类型直接影响勘探领域与方向的确定。通过气体组分、CH4和CO2碳同位素资料,对缅甸安达曼海域中部天然气成因类型及气源岩进行了判识。结果表明:上新统部分天然气具有较轻CH4碳同位素,为生物成因气,部分碳同位素较重的天然气属于热成因气;中新统及渐新统天然气CH4碳同位素均较重,属于热成因气;CO2碳同位素显示其存在无机、有机2种成因;此外,还存在少量生物气与热成因气或无机气的混源气。认为该区无机成因CO2与CH4共存体系通过基底断裂来源于地壳深部或上地幔;上新统生物气来自上新统未熟源岩;产于上新统、中新统热成因气,来源于上新统下部、中新统或渐新统上部等深层高-过成熟烃源岩。     

南沙群岛南科1井白云岩发育特征及铁白云石成因机制的初步研究

南海自新生代以来发育了大量的碳酸盐岩台地和生物礁,并普遍发生白云岩化作用,具有广阔的油气勘探前景。文章通过开展岩相学观察、矿物学分析、常微量元素和碳氧同位素分析,同时结合Fe组分及Fe同位素地球化学分析,对南沙群岛南科1井白云岩的发育特征和成岩环境进行了系统研究。结果表明:南科1井上中新统—下更新统白云岩主要形成于近地表环境中,溶蚀孔隙发育,残余结构明显。白云岩层中发育有多个与暴露成因有关的界面,未发现石膏层的存在。同时,白云岩普遍具有低Fe、Mn和Sr的特征以及与现代海水相似的REE分布模式, δ¹³C和δ¹⁸O多为正值,但不存在相关性。整体来看,白云岩可能形成于轻微蒸发海水的渗透回流作用,还受到了与古气候变冷有关的海平面下降的控制。此外,南科1井岩芯中多个层位发育铁白云石,并且集中分布在暴露面附近。Fe组分和Fe同位素组成结果显示,白云岩中Fe主要来源于海水中碳酸盐的沉淀,成岩过程中基本不存在额外的陆源或热液来源的Fe混入。铁白云石主要形成于低温和浅埋藏环境中,大气淡水对生物骨架、生物碎屑以及自生碳酸盐矿物的淋滤-溶解作用为其提供了重要的...     

The dynamics of the carbon cycle in the surface water of the Norwegian Sea

Historical data of total dissolved inorganic carbon (C_T), together with nitrate and phosphate, have been used to model the evolution of these constituents over the year in the Atlantic water of the Norwegian Sea. Changes in nutrient concentration in the upper layer of the ocean are largely related to biological activity, but vertical mixing with the underlying water will also have an impact. A mixing factor is estimated and used to compute the entrainment of these constituents into the surface water from below. After taking the mixing contribution into account, the resulting nutrient concentration changes are attributed to biological production or decay. The results of the model show that the change in C_T by vertical mixing and by biological activity based on nutrient equivalents needs another sink to balance the carbon budget. It cannot be the atmosphere as the surface water is undersaturated with respect to carbon dioxide and is, thus, a source of C_T in this region. Inasmuch as the peak deficit of carbon is more than a month later than for the nutrients, the most plausible explanation is that other nitrogen and phosphate sources than the inorganic salts are used together with dissolved inorganic carbon during this period. As nitrate and phosphate show a similar trend, it is unlikely that the explanation is the use of ammonia or nitrogen fixation but rather dissolved organic nitrogen and phosphate, while dissolved organic carbon is accumulating in the water.     

Sensitive determination of enzymatically labile dissolved organic phosphorus and its vertical profiles in the oligotrophic western North Pacific and East China Sea

Trace concentrations of labile dissolved organic phosphorus (LDOP) in oligotrophic seawater were measured by use of an enzymatic procedure and a nanomolar phosphate analytical system consisting of a gas-segmented continuous flow analyzer with a liquid waveguide capillary cell. LDOP, defined as DOP hydrolyzed by alkaline phosphatase (AP) from Escherichia coli, was quantified as the difference between the phosphate concentrations of the seawater sample with and without AP treatment. For sensitive measurement of LDOP, we found that phosphate contamination derived from commercially available AP must be corrected, and azide treatment before AP treatment proved effective in removing biological effect that occurs during DOP hydrolysis. Field observations at six stations of the western North Pacific and the East China Sea during the boreal summer revealed that, in the upper 200 m of the water column, LDOP concentrations ranged from the detection limit (3 nM) to 243 nM, and phosphate concentrations ranged from 5 to 374 nM. The spatial distribution patterns of LDOP were similar to those of phosphate. Most of the depth profiles for LDOP and phosphate showed concentrations were extremely low, <25 nM, between the surface and the deep chlorophyll maximum layer (DCML) and increased below the DCML. Strongly depleted LDOP and phosphate above the DCML suggest that LDOP is actively hydrolyzed under phosphate-depleted conditions and utilized by microbes.     

悬浮沉积物对磷酸盐的吸附与释放及藻类对吸附磷的利用

本文用1987年12月采自平度县大泽山水库的水样和沉积物样品,实验研究了悬浮沉积物对磷酸盐的吸附与释放以及藻类对悬浮沉积物吸附磷的利用。实验证明,悬浮沉积物对PO_4—P的吸附相当迅速,24小时即趋于饱和;绝对吸附量随水中原有PO_4—P浓度和沉积物含量增加而增加,相对吸附量也随水中原有PO_4—P浓度的增加而增加,但随沉积物含量的增加而减少;悬浮沉积物的吸磷或释磷,取决于沉积物吸附的磷量与水中溶存PO_4—P浓度两者的相对关系,在吸附释放平衡条件下,二者的数量变化呈对数相关。藻类培养结果表明,悬浮沉积物吸附磷能被藻类直接利用。据此,作者提出应当用总活性磷,而不是溶解无机磷作为浅水型内陆水域有效磷的指标。     

A simple fractionation method for determination of phosphorus components in phytoplankton: Application to natural populations of phytoplankton in summer surface waters of Tokyo Bay

A simple procedure for fractionation of phosphorus components in natural populations of phytoplankton has been developed. By a combination of a trichloroacetic acid (TCA) extraction, a hot dilute acid treatment, a charcoal treatment and an organic solvent extraction, cellular phosphorus was divided into orthophosphate, nucleotide phosphorus, sugar phosphates, acid-soluble polyphosphates, lipid phosphorus, nucleic acid phosphorus, acid-insoluble polyphosphates, and residual phosphorus. The recovery of phosphorus was 94±5%. This technique was applied to natural populations of phytoplankton in summer surface waters of Tokyo Bay. Nucleic acid phosphorus and orthophosphate were most abundant, and accounted for 30 to 50% of total phytoplankton phosphorus. The nucleic acid phosphorus was proportional to the biomass of phytoplankton, irrespective of ambient nutrient concentrations. The orthophosphate showed the largest change in association with the change in cellular phosphorus content as well as in ambient phosphate. The orthophosphate serves as a phosphorus reserve in the natural populations of phytoplankton in summer surface waters of Tokyo Bay whereSkeletonema costatum was dominant. Acid-insoluble polyphosphates tended to increase when ambient concentration of phosphate was high, but their amounts were almost one order of magnitude lower than that of orthophosphate.     

Phosphorus and nitrogen cyclings in the pelagic system of hiroshima bay: Results of numerical model simulation

A numerical ecosystem model expressing both phosphorus and nitrogen cyclings in the pelagic system of Hiroshima Bay, Japan, was developed in order to investigate the seasonal variations of these elements and their annual budgets. Based on the geophysical and chemical structures of the bay, Hiroshima Bay was divided into northern and southern boxes, themselves divided into two layers of an upper 5 m and a lower layer according to the stratification of the water column. The model consists of equations representing all relevant physical and biological processes. The results revealed that the internal regeneration of materials was an important source of bioavailable nutrients for phytoplankton growth in the water column. The incorporation of phytoplankton aggregation improved the accuracy of the outputs in comparison to the observed data, especially during the stratified summer season. The results also indicated that phosphorus limitation of phytoplankton growth occurs in the upper layer during summer while light limitation occurs in the lower layer. In addition, physical processes such as diffusion and advection were also important as they ensured that most of regenerated nutrients in the lower layer were transported to the upper layer. Thus, these processes might support the high primary production and the production of oysters that are extensively cultured in this bay. Considering the informative results obtained, the model used in this study provides a sound basis and tool to describe the dynamics of phosphorus and nitrogen cyclings in Hiroshima Bay.     

Composition of ferromanganese nodules from Riga Bay (Baltic Sea)

An average sample of ferromanganese nodules from Riga Bay was investigated by analytical electron microscopy coupled with atomic absorption, neutron activation, and ICP-MS methods. It is established that the nodules consist of colloform and poorly crystallized Fe and Mn hydroxides with an admixture of dispersed inclusions of better crystallized particles allowing revealing their mineralogical nature by the microdiffraction method. The major mineral phases are ferroxigite and Fe-vernadite with subordinate magnetite, asbolane, and todorokite. The chemical composition of the nodules is dominated by iron followed by cobalt and lead, while nickel, molybdenum, and tungsten associate with the manganese phase. The concentration of several minor elements in the Riga Bay nodules is slightly lower as compared with their average values for the entire Baltic Sea; some elements such as silver, bismuth, cadmium, niobium, tin, and thallium were never analyzed before.     

大亚湾营养物质变异特征

利用大亚湾现场调查和室内模拟数据,以及大亚湾生态网络17～18年8个航次的现场调查资料,采用营养状态质量指数(NQI)的方法评价大亚湾海域富营养化水平,结果表明,大亚湾海域除部分养殖海区为中营养状态外,大部分为贫营养状态;溶解态的无机磷和硅在过去10a多有较大幅度的下降,而溶解态的无机氮、溶解氧和叶绿素a则上升;浮游植物生长由过去认为由氮控制转变为现在由磷控制.分析了养殖海区底层海水、上覆水、沉积物间隙水中营养盐的含量及其化学形态.估算了沉积物-海水界面营养盐扩散通量,NH₄+,NO₂-,NO₃-,HPO₄2-,H₄SiO₄平均通量分别为302.0,-0.06,-1.82,2.53,47.6μmol/(m2·d).室内模拟了天然海水体系表层沉积物营养盐的吸附-解吸及其磷酸盐在沉积物上的吸附等温线.论述了大亚湾海域营养盐与赤潮的关系.     

长江口理化因子影响初级生产力的探索Ⅱ.磷不是长江口浮游植物生长的限制因子

1985年8月至1986年8月在长江口及其附近海域的50个大面观测站进行了磷酸盐和初级生产力逐月调查。通过分析磷酸盐的水平分布特征,发现长江口海域的磷酸盐浓度没有明显的季节变化,几乎不受长江流量变化的影响,因此认为,长江输送磷酸盐浓度不能由丰水期与枯水期决定;磷酸盐浓度与初级生产力的断面分布和时间变化的分析表明,磷酸盐浓度并不一定离岸越远越低,也没有周期性的季节变化;初级生产力的值几乎不受磷酸盐浓度变化的影响。根据营养盐限制的判断方法和法则,在长江口及其附近海域,磷并不是浮游植物生长的限制因子,仅靠氮磷比值来得到磷限制或氮限制的结论是不完善的。