Gamma ray spectra of some lavas from Vesuvius

The authors have carried out the gamma-ray spectrometry of some Vesuvius lavas, by means of a S.E.L.O. equipment which consists of a 100 channels analyzer joined to a photomultiplier tube annexed to aNaI(T1) phosphor. TheU ²³⁸,Th ²³²,Ra ²²⁶ andK ₂ O contents have been determined and the following conclusions have been drawn: theU ²³⁸ seems to be present in the examined lavas and the contents are fairly equal within the errors; also theTh ²³² andK ₂ O contents show no sensible variations in the different lavas. TheRa ²²⁶ content is remarkably higher than that necessary for the equilibrium with the observedU ²³⁸ content and shows a decrease with the age of the lavas. TheRa ²²⁶ content which exceeds that necessary for the equilibrium with the observedU ²³⁸ content decreases with a law similar to the natural radioactive decay ofRa ²²⁶.     

On the content and vertical distribution of K,Th and U in the continental crust

The content of K, Th and U in the continental crust is estimated based on the assumption that the concentration of these elements decreases with depth asA_x = A₀e^?x/D [11], withA_x andA₀ the heat production rates at depthx and at the surface, respectively. Taking the weighted mean heat production rate of the intrusive rocks of the upper crust asA₀ = 2.33 μWm^?3, that of the granulites representing the lower crust asA_x = 0.72 μWm^?3, and the mean scale heightD= 9.5km [1] the average vertical distancex = b between these intrusives and granulites is 11.2 km. Withb known and the average concentrations of K, Th and U in granulites and intrusive rocks of the upper crust the scale heights of the vertical distribution of these elements areD_K = 71km,D_Th = 9.5km,D_U = 5.8km. The knowledge of these parameters permits to calculate the average concentrations of these elements in a 33.3 km thick crust:K= 2.19%,Th= 4.43ppm,U= 0.66ppm; Th/U = 6.7 and K/U = 3.3 × 10⁴. The resulting heat flow is 23.0 mW m^?2 which is practically identical with the value deduced from heat flow measurements. Assuming that the Th/U ratio of the entire crust—including the sediments—is 3.9, the high ratio of 6.7 in the crystalline crust indicates that about 7.2 × 10¹² t U were extracted from it. All rocks with Th/U ratios <3.9 are possible sinks of this U. About half that amount is deposited in sedimentary rocks, mainly in black shales. The second important sink are the volcanic rocks of the continental margins.     

A gamma spectrometric study of Mont-Blanc granite samples

Summary Gamma-ray spectra of the samples were measured by standard laboratory multichannel spectrometry. The weighted least squares method was applied to the digital output data in order to determine the concentrations of U²³⁸, Th²³² and K⁴⁰ present. U and Th increase towards the rim of the massif (from 4 ppm U and 20 ppm Th in the coarse-grained central facies to 23 ppm U and 42 ppm Th in the fine-grained rim variety), whereas K remains fairly constant at 3.85%.On leave Eidgenössische Technische Hochschule, Zurich (Switzerland)     

The effect of initial230Th disequilibrium on young UPb ages: the Makalu case,Himalaya

Comparative UPb dating of zircon, xenotime and monazite from two different samples of the Himalayan “Makalu” granite shows the two U decay series to be in disequilibrium, particularly in monazite. This disequilibrium is due to excess or deficit amounts of radiogenic²⁰⁶Pb which originate from an excess or deficit of²³⁰Th, respectively, occurring initially in the mineral. Such an initial disequilibrium is caused by UTh fractionation between the crystallising mineral and the magma. Therefore, the UPb ages of Th-rich minerals such as monazite (and allanite) have to be corrected for excess²⁰⁶Pb due to excess²³⁰Th, whereas Th-poor minerals such as zircon and xenotime require a correction for a deficit of²⁰⁶Pb due to deficiency of²³⁰Th. The extent of this correction depends on the degree of ThU fractionation and on the age of the rock. For the two monazite populations analysed here, these excess amounts of²⁰⁶Pb were, with reference to the amount of radiogenic²⁰⁶Pb, 8–10% and 15–20% respectively, and less than 1% for zircon and xenotime. The varying degrees of Th enrichment relative to U in monazite show that the ThU partition coefficients for this mineral are not constant within a single granite. Furthermore, for monazite there is evidence for excess amounts of radiogenic²⁰⁷Pb originating from the decay of initial excess²³¹Pa, also enriched during crystal growth.The very low Th/U ratios of 0.196 and 0.167, determined for thetwo whole rocks from which the minerals have been extracted, substantiate the view that granite formation is a fundamental mechanism for ThU fractionation in continental crust.The different ages of 21.9 ± 0.2m.y. and24.0 ± 0.4m.y., obtained by averaging the corrected²³⁸U²⁰⁶Pb ages of the monazites, suggest that the apparently homogeneous Makalu granite was generated over a period of at least 2 m.y.     

An iron-rich deposit from the Northeast Pacific

An iron-rich deposit dredged from the upper flank of Dellwood Seamount in the Northeast Pacific has been analyzed for major and trace elements, rare-earth contents and uranium isotopic composition. In terms of mineralogy and overall chemical composition, the deposit resembles other iron-rich deposits variously attributed to volcanic hydrothermal activity. Both the relative concentrations of the rare-earth elements and the isotopic composition of uranium rule out seawater as the sole source of elements in this deposit. The rare-earth element pattern indicates that these elements were derived from the underlying basalt. The²³⁴U/²³⁸U ratio is significantly higher than in seawater and can best be explained by preferential leaching of²³⁴U generated by decay from its parent²³⁸U in the underlying rock and subsequent redeposition of the excess²³⁴U together with the Fe and minor metals. These data are consistent with a model for the origin of submarine metal-rich solutions involving mobilization of elements from the interior of slowly cooling basalts by circulating seawater.     

Contributions to the volcanological researches by determination of the radioactivity of eruptive products

Many new determinations of radioisotope contents of volcanic rocks have been carried out during the last years by techniques giving a satisfactory reliability. Particularly, detailed researches on Italian volcanoes, performed at the Istituto di Fisica Terrestre of the University of Napoli, have outlined the particular behaviour of the main natural radioisotopes in the relative evolutive processes. By comparing the results obtained for the Italian volcanoes with those obtained for other volcanoes from throughout the world, the former have been observed to be exceptionally high. A tentative interpretation is reported. Furthermore, the possibility of an absolute dating of eruptive events upon disequilibria which may be found in the Th²³² and U²³⁸ series is discussed. An example of contribution of a radiometric survey of volcanic areas to the knowledge of the structure of volcanoes is given.     

SEISMIC ATTENUATION IN THE VICINITY OF THE GEOTHERMAL ANOMALY AT URACH OBTAINED FROM NEAR-VERTICAL REFLECTION PROFILES1

The attenuation in the vicinity of the geothermal anomaly at Urach was determined by means of two near-vertical reflection profiles. The attenuation in the sediments and in the upper crust (3-4 km depth) was estimated by interpretation of the first (refracted) arrivals. For calculating the attenuation, the amplitude decay with respect to distance was used. Corrections for the spread factor, i.e. the geometric amplitude divergence was deduced from the traveltime curves. Below the anomaly, higher attenuation values (Q^?1～ 0.008) were observed compared with those in the undisturbed crust (Q^?1～ 0.002). This effect is probably due to the cracks and fissures in the upper part of the crystalline basement. The attenuation in the middle and lower crust was determined using near-vertical reflections from this depth interval. The use of the spectral ratio method leads to higher values of the effective attenuation Q^?1_eff below the heat flow anomaly compared to those of the‘ normal’crust. This zone of high Q^?1_eff coincides with the low velocity body below the heat flow anomaly. Both effects, the higher attenuation and the lower velocities, could be caused by high temperatures, cracks and fissures in the crust.     

Heat flow studies: Constraints on the distribution of uranium,thorium and potassium in the continental crust

To study the amount of heat generated by radioactive decay in the continental crust, the usual practice in the literature is to fit to the heat flow and radioactivity data a relationship of the form: Q = Q_r + D · A where Q and A are the observed heat flow and radiogenic heat production. Q_r is the “reduced” heat flow and D is a depth scale. This procedure implicitly assumes that uranium, thorium and potassium have identical distributions in the crust. We suggest that significant information may be lost as the three radioelements may in fact be affected by processes operating over different depths.Data published for four heat flow provinces throughout the world are used to estimate the distributions of uranium, thorium and potassium in the continental crust. These distributions are characterized by a depth scales defined as follows: D_i =∫0h C_i(z)C_i(0)dz where h is the thickness of the layer containing the bulk of radioactivity and C_i(z) the concentration of element i at depth z. Three depth scales are computed from a least-squares fit to the following relationship: Q = Q_r + D_U · A_U + D_T · A_T + D_K · A_T where Q is the observed heat flow and Q_r some constant (a reduced heat flow). A_i is the heat generation rate due to the radioactive decay of element i, and D_i is the corresponding depth scale.The analysis suggests that the three distributions are different and that they have the same basic features in the four provinces considered. The depth scale for potassium is large in granitic areas, that for thorium is small and that for uranium lies between the other two.We propose a simple model according to which each radioelement essentially provides a record for one process. Potassium gives a depth scale for the primary differentiation of the crust. Thorium gives the depth scale of magmatic or metamorphic fluid circulation. Finally, the uranium distribution reflects the late effects of alteration due to meteoric water. We show that the heat flow and radioactivity data are compatible with this model.Our analysis and numerical results are supported by data from deep boreholes and by geochemical evidence, such as detailed investigations of plutonic series and studies of U-Th-Pb systematics.     

A new approach for constraining the magnitude of initial disequilibrium in Quaternary zircons by coupled uranium and thorium decay series dating

We have measured ²³⁸U–²⁰⁶Pb, ²³⁵U–²⁰⁷Pb, and ²³²Th–²⁰⁸Pb ages on Quaternary zircons by laser ablation, single-collector, magnetic sector inductively coupled plasma mass spectrometry (LA-ICP-MS). To obtain reliable ages for Quaternary zircons, corrections for initial disequilibrium associated with deficits and excesses of both ²³⁰Th and ²³¹Pa relative to secular equilibrium resulting from differential partitioning during zircon crystallization or source melting must be made. In contrast, the ²³²Th–²⁰⁸Pb decay system is clearly advantageous for samples affected by disequilibrium because the ²³²Th decay system lacks long-lived intermediate daughter isotopes. Conventionally, the initial disequilibrium for the ²³⁸U and ²³⁵U decay series has been determined by the distribution ratio between the melt and zircon (i.e., ƒ_Th/U = (Th/U)_Zircon/(Th/U)_Melt and ƒ_Pa/U = (Pa/U)_Zircon/(Pa/U)_Melt). In our study, these correction factors were determined from comparison of the measured ²³⁸U–²⁰⁶Pb and ²³⁵U–²⁰⁷Pb ages with ²³²Th–²⁰⁸Pb ages obtained for three zircons of known eruption and, in some cases, zircon crystallization ages (Kirigamine Rhyolite, Bishop Tuff, and Toga Pumice). The resulting correction factors are ƒ_Th/U = 0.19 ± 0.14 and ƒ_Pa/U = 3.66 ± 0.89 (Kirigamine Rhyolite), ƒ_Th/U = 0.24 ± 0.20 and ƒ_Pa/U = 3.1 ± 1.2 (Bishop Tuff), and ƒ_Th/U = 0.28 ± 0.17 and ƒ_Pa/U = 3.04 ± 0.99 (Toga Pumice). Although the uncertainties of these f values are relatively large, our results support the adequacy of the conventional approach for correction of initial disequilibrium. A recent study published results that apparently show zircon crystallization ages are younger than the eruption age of Bishop Tuff. It seems to be difficult to eliminate these discrepancies, even if the Th/U partitioning and disequilibrium generated during partial melting are taken into account for recalculation of its zircon age. However, magma chamber process and history of Bishop Tuff are too complex to obtain accurate zircon ages by U–Pb method. To overcome this, therefore, the Th–Pb zircon dating method is a key technique for understanding complex, pre-eruptive magma processes, and further efforts to improve its precision and accuracy are desirable.     

The concentrations of radioactive and trace elements in the granulites from the south-east margin of the Bohemian Massif (Czechoslovakia)

Summary The distribution of radioactive elements(Th, U, K) and trace elements(Rb, Sr, Ba, Pb, Zr, Ti, Cu, Cr, Ni, V) of acid granulites from the south-east margin of the Bohemian Massif (SW Moravia) was under study. The investigated rocks are characterized by a great variability ofTh/U ratios andTh andU contents; a linear relationship between theTh andU values was observed. A close relation between theU and biotite contents with a statistically significant linear correlation coefficient of +0.85 was found. In agreement with geological and petrological investigations, the concentrations of radioactive elements correspond to the contents observed in the rocks with metamorphic intensity between the amphibolite and granulite facies. The investigated rocks have extremely lowSr concentrations distinguishing them from other acid granulites of the world.Rb contents are rather variable reaching, however, the highest values among the acid granulites of various granulite areas.     

The early thermal and magnetic state of the cratered highlands of Mars

Surface heat flows are calculated from elastic lithosphere thicknesses for the heavy cratered highlands of Mars, in terms of the fraction of the surface heat flow derived from crustal heat sources. Previous heat flow estimations for Mars used linear thermal gradients, which is equivalent to ignoring the existence of heat sources within the crust. We compute surface heat flows following a methodology that relates effective thickness and curvature of an elastic plate with the strength envelope of the lithosphere, and assuming crustal heat sources homogeneously distributed in a radioactive element-rich layer 20 or 60 km thick. The obtained results show that the surface heat flow increases with the proportion of heat sources within the crust, and with the decrease of both radioactive element-rich layer thickness and surface temperature. Also, the results permit us to calculate representative temperatures for the crust base, rock strength for the upper mantle, and lower and upper limits to the crustal magnetization depth and intensity, respectively. For Terra Cimmeria, an effective elastic thickness of 12 km implies between 30% and 80% of heat sources located within the crust. In this case the uppermost mantle would be weak at the time of loading, and temperatures in the lower crust cold enough to favor unrelaxed crustal thickness variations and to permit deep Curie depths in the highlands, as suggested by the observational evidence.     

A preliminary model for 3-D rheological structure of the lithosphere in North China

3-D rheological structure is mainly the spatial distribution of lithospheric strength or viscos-ity, its strength and viscosity are indispensable parameters in quantitative study of the lithosphere deformation. Plate tectonics theory initially divided the…     

Variability of natural and bomb-produced radionuclide distributions in abyssal red clay sediments

The nature of sedimentation and mixing are examined in abyssal red clay sediments from the North Central Pacific using three types of indicators: ²³⁰Th/²³²Th, organic¹⁴C, and¹³⁷Cs and ^239.240Pu.²³⁰Th/²³²Th analysed revealed that the clay sedimentation rate in three box cores collected within a 50 km radius was less than 1.0 mm/10³ yr. However, analyses of the organic carbon in thin layers of sediment revealed that radiocarbon was present much deeper in the cores (down to 20 cm) than was expected from the ²³⁰Th/²³²Th distribution. In addition, both the stratigraphy and inventory of radiocarbon was significantly different between box cores. The distributions and inventories of¹³⁷Cs and^239.240Pu were similar to that found for radiocarbon, further illustrating the spatial variability of radionuclides in oligotrophic North Pacific red clays. These data suggest that bioturbational processes are important for transporting organic carbon down into the sediment column.     

Evolution of uranogenic and thorogenic lead, 2. Some differences in the variations of the206Pb/204Pb and208Pb/204Pb ratios

On the basis of a dynamic model of a continuous Pb isotope evolution, the variations in the isotopic ratios of uranogenic and thorogenic Pb in a number of young ore deposits, ocean sediments and volcanic rocks from mid-ocean ridges, oceanic islands, island arcs and continents are evaluated. The deviations in the Th/U ratio from its model values are calculated. A model parameterT which indicates a more ancient enrichment in U/Pb (crustal-type Pb sources) or younger enrichment in U/Pb (mantle-type Pb sources) is also calculated. The relative change in the Th/U ratio is close to 1 for mantle-type Pb sources (lowerT values) and decreases for crustal-type Pb sources (higherT values). An interpretation of these changes could be connected with the differences in the U and Th geochemical behaviours in metamorphic processes under the conditions of a deeper (mantle) or crustal source owing to the differences in their valence states. In some cases they have similar (U⁴⁺ and Th⁴⁺) migration abilities; in others (U⁶⁺ and Th⁴⁺), considerably different.     

On the geothermal regime of some tectonic units in Romania

Heat flow values of 33–58 mW m^–2 were found for the Transylvanian Depression, 45–57 mW m^–2 for the crystalline nucleus of the Eastern Carpathians, and 70–120 mW m^–2 for the Neogene volcanic area. Temperature-depth profile and some geophysical implications of the low values for the Transylvanian Depression are discussed, rendering evident clear-cut differences between this tectonic unit and other Noegene depressions. The heat flow values for the other two investigated tectonic units are usual ones for areas of their age.A preliminary map of the heat flow distribution over the Romanian territory is presented and its relation to other geophysical fields is discussed. A positive correlation was found between gravity and heat flow, and a negative one between crustal thickness and heat flow. A general conclusion could be drawn that the heat flow distribution over the Romanian territory seems to be governed by processes taking place in the upper mantle, rather than by the radioactive decay within the crust.     

Evidence for contamination of recent Hawaiian lavas from230Th-238U data

²³⁰Th-²³⁸U radioactive disequilibrium was studied in the historical lava flows of the Mauna Loa and Kilauea, Hawaii. Large variations of the (²³⁰Th/²³²Th) ratio among lavas of the same volcano that were erupted at a few years' interval are interpreted as due to contamination. The contamination probably occurs by assimilation of zeolitic minerals formed by seawater interaction while the magma resides in a superficial chamber.     

The control of alkalies and uranium in seawater by ocean crust alteration

Alteration of the oceanic crust during hydrothermal circulation of seawater produces fluxes of K, Rb and Cs between these reservoirs which are significant compared to the river input of these elements. The ocean crust U flux, on the other hand, is probably not significant. The upper crust, altered at low temperature, is a sink for all of these elements (as shown by direct analysis of upper crustal materials). The lower crust is a source for K, Rb, and Cs, based on the observation that high-temperature fluids exiting the crust as “host springs” are enhanced over seawater in K, Rb and Cs concentration. While the sign of the hot spring fluxes may be correct, the absolute magnitudes cannot be, as the calculated yearly hot spring flux of Rb and Cs significantly exceeds the total Rb and Cs inventory of newly formed unaltered crust. By modelling the crust as a melt/cumulate combination, we show that the crust as a whole is a sink for K, Rb, Cs, and probably U, with yearly fluxes of1.1 × 10¹³, 2.6 ×10¹⁰, 6.0 × 10⁸ and 1.0 × 10⁹g, respectively (com to yearly river dissolved fluxes of7.4 × 10¹³, 3.5 × 10¹⁰, 6.4 × 10⁸and1.0 × 10¹⁰g, respectively). The alteratio oceanic crust appears capable of quantitatively balancing the river inputs of Rb and Cs. For K, an additional sink comprising～ 85% of the river input is necessary. Because this missing K sink cannot be arbitrarily manipulated without destroying the Rb and Cs balances, a sink with K/Rb higher than the continental crust is required, and may possible be found in the sediments of the continental shelves.     

Spatial variation of U-Th series radionuclides and trace metals in deep-sea manganese encrustations

A series of measurements to assess the spatial variability on a scale of a few centimeters of UTh series nuclides and trace metals in surface layers of deep-sea ferromanganese encrustations are reported here. Two samples, one from an Atlantic seamount and another from MANOP site S in the Pacific are reported.The inventories of²³⁰Th_exc cm^?2 and²³¹Pa_exc cm^?2 as well as the ratios of the inventories are seen to vary by large amounts in samples only a few centimeters apart. These observations infer that the fluxes of these radionuclides to small areas on the ferromanganese crust may also vary with time. No strong correlation between the radioisotope inventories and concentrations of various elements has been observed.     

Fine chronology of volcanic processes using 238U-230Th systematics

The²³⁰Th-²³⁸U radioactive disequilibrium method was applied to the study of recent volcanic rocks from Costa Rica. Most samples are from the Irazu volcano. Some samples were dated by internal isochrons using the (²³⁰Th/²³²Th)-(²³⁸U/²³²Th) diagram, others were studied only by whole rock analyses. The evolution of the parent magma may be followed by the initial (²³⁰Th/²³²Th)₀ ratios of the rocks. A model involving a differentiating magma chamber that existed for 140,000 years under the Irazu volcano correlates well with the observations. Other volcanoes seem to be in earlier stages of their evolution. Continuing study may help to solve the tholeiitic to andesitic volcanism relationship.     

Growth rates of Pacific manganese nodules as deduced by uranium-series and hydration-rind dating techniques

Growth rates of four Pacific ferromanganese deposits have been determined by uranium-series and hydration-rind dating techniques. This represents the first time these two methods have been applied to the same samples. Of the four samples analyzed, two agree in both techniques and two show a wide disparity. The samples that do not agree have uranium-series rates which are low compared to those deduced by the hydration-rind techniques. The same samples also display steep²³²Th activity gradients in the outer layers of the ferromanganese material. Since the half-life of²³²Th is extremely long (10¹⁰ yr), these gradients could not be due to radioactive decay. This suggests that the distribution of²³⁰Th, at least in these cases, may also be a result of some process other than radioactive decay.One of our samples which has a steep²³²Th gradient produces a²³⁰Th “exposure age” which is indistinguishable to the calculated hydration age within the analytical uncertainty. The rate of growth calculated on the basis of the slope of the decline of²³⁰Th within the deposit, however, is low by over one order of magnitude when compared to the rate determined by the hydration-rind method. Although previous results indicate that the distribution of²³²Th is usually quite random within ferromanganese deposits, our results indicate that caution should be exercised when assessing their growth rates on the basis of uranium-series results.