大别山东南部高压—超高压变质岩的氢氧同位素地球化学

本文报道了大别山东南部安徽石马地区柯石英榴辉岩组合和黄镇地区石英榴辉岩组合的全岩及单矿物的氢氧同位素特征。石马榴辉岩的δ18O值在1.0‰～7.4‰之间,云母δD值为-76‰～-61‰;黄镇榴辉岩的全岩δ18O值为-1.1‰～-2.1‰,云母δD值为-89‰～-77‰。矿物之间的氢氧同位素分馏既有处于平衡状态者,也有处于不平衡状态者,反映这些岩石除继承变质前母体的18O亏损特征外,还经历了显著的同位素退化交换作用。石马和黄镇榴辉岩的矿物对氧同位素温度均给出两个峰值380～430℃与绿片岩相变质条件一致,600～640℃与高角闪岩相变质条件一致;给不出峰变质温度(750～800℃)是由于岩石经历了退变质流体的强烈改造作用。大别东南部高压-超高压榴辉岩的南部边界为石英榴辉岩与花岗片麻岩的界线,但氧同位素研究指示两者为原位接触关系。     

大别山高级变质岩云母Rb—Sr等时线年龄测定及其地质意义

应用云母Rb Sr等时线法对大别山高级变质岩的后期改造历史进行了初步的探讨。采用重液变温技术将云母按比重的区别 ,分成若干组分 ,然后用常规的Rb Sr方法测定。应用这种技术对大别山黄土岭太古代麻粒岩相岩石中的黑云母和产于超高压变质带内的石马含石榴石片麻岩的白云母进行了Rb Sr等时线年龄测定。黄土岭太古代麻粒岩相片麻岩中的黑云母 全岩Rb Sr等时线年龄为 12 7± 9Ma ,与该区片麻岩中的角闪石的K Ar和Ar Ar年龄 ,及燕山期花岗岩的Rb Sr年龄一致 ,说明这一太古代下地壳岩石受到了燕山期深熔 岩浆事件的影响 ;大别山东南部石马含石榴石片麻岩 (榴辉岩相 )中的白云母Rb Sr等时线年龄为 191± 10Ma ,反映了印支 早燕山期区域性低级变质事件的时代。研究表明 ,大别山区的不同构造单元中产出的不同类型的高级变质岩自中生代以来有不同的后期演化历史。     

NAMs柯石英中结构水的红外光谱和第一性原理计算

从微观尺度研究结构水的分布状态可以为超高压变质岩的形成环境、构造演化动力学过程提供重要的依据.为探讨大别山地区超高压变质岩中"名义上无水矿物"（nominal anhydrous minerals,NAMs）结构水的分布特征、赋存状态与超微结构缺陷的关系,对大别山石马地区榴辉岩中的柯石英进行了傅立叶变换红外光谱（FTIR）分析和第一性原理计算.FTIR研究表明柯石英主要吸收峰为（Ⅰ）3 561~3 580 cm-1、（Ⅱ）3 433~3 462 cm-1和（Ⅲ）3 412~3 425 cm-1;柯石英颗粒结构水含量为15×10-6~52×10-6,平均值是32×10-6.第一性原理理论计算得到了柯石英（4H）_Si和（AlH）_Si复合缺陷超晶胞模型（2×1×1）的形成能分别是-4.92 eV和-3.10 eV;含氢缺陷模型计算结果得到3 526 cm-1和3 198 cm-1的拉曼峰与柯石英的合成实验结果基本符合.FTIR分析表明石马地区柯石英结构水含量具有不均一性;模拟计算得到（4H）_Si复合缺陷模型比（AlH）_Si有更低的复合缺陷形成能,有更加稳定的结构,柯石英结构水中（OH）₄$ \Leftrightarrow $Si氢结合机制是优先模式,为实验研究提供理论依据.      

北淮阳盆岭带的构造演化与铀成矿

北淮阳盆岭构造带是大别造山带的重要组成部分。佛子岭岩群代表了早古生代扬子地块北缘大别古岛弧弧前海盆的火山沉积建造,在加里东运动陆块对接过程中变形变质。石炭系梅山群具磨拉石建造特征。在华力西印支期陆内俯冲褶皱带的基础上,燕山期沿桐柏桐城断裂伸展北移,近东西向断陷盆地发育,形成盆岭构造景观。南侧大别山强烈隆升,铸就了现今大别山变质核杂岩构造格局。中生代岩浆活动是区内重要铀源,具有成矿潜力的地质体是响洪甸正长岩体和北带粗面质火山碎屑岩     

大别—苏鲁超高压变质带内部的浅变质岩

大别苏鲁超高压变质带内部零星出露有若干呈构造残片状产出的浅变质岩，主要以变质碎屑岩－千枚岩－大理岩组合为代表，遭受过低绿片岩相变质和脆－韧性变形作用的改造，与围岩均为构造接触（断层或韧性剪切带）。微古生物化石研究表明，其原岩为震旦纪前后扬子板块北缘的浅海相沉积。同位素年代学研究指示，它们经历过加里东期和印支期构造热事件的影响，与区域超高压岩石经受的构造热事件时间一致；氧同位素研究得到，部分浅变质岩原岩曾遭受过高温大气降水热液蚀变，与区域超高压岩石经受的构造热事件时间一致；氧同位素研究得到，部分浅变质岩原岩曾遭受过高温大气降水热液蚀变，与区域超高压岩石的同位素特征一致。这些浅变质岩的原岩为扬子板块北缘震旦系沉积岩及其中的火山碎屑岩，构造上具有板块俯冲过程中的刮削岩片－构造加积楔的产状和形成机制，因此可以是大陆板块俯冲加积楔的一部分。     

大别造山带加里东期高压超高压变质作用的确定及其意义

文中综述了对大别造山带高压超高压变质作用形成时代的 3种观点。重点从高压超高压变质作用同位素定年技术、方法的完善与更新和大别造山带早古生代区域地质构造背景两个方面论证了大别造山带加里东期高压超高压变质作用的存在 ,得出了大别造山带高压超高压变质作用主要为加里东期的结论。这一认识对揭示世界一些大型造山带构造演化规律、研究中国加里东期区域构造格局和在大别造山带及邻区寻找金刚石、金红石、各种宝石、金、铜等矿产都有积极的意义。     

从源到汇:大别造山带物源区与合肥盆地南缘中生代沉积耦合关系——来自碎屑锆石U-Pb年龄证据

形成于印支期的大别造山带和周缘中生代盆地构成了一级源汇系统,其中位于造山带北缘的合肥盆地中生代地层发育,且以盆地南缘出露最好,这为盆山源汇系统研究提供了理想的沉积记录。笔者从合肥盆地南缘采集了10个砂岩样品和1个砾岩样品,进行锆石U/Pb (LA-ICP-MS)定年分析,获得了742个有效年龄(置信度不小于85%),范围为113±3. 6-2983 Ma。这些碎屑锆石年龄谱可以被分为5个年龄段:113-137 Ma,峰值131 Ma; 184-273 Ma,峰值226 Ma; 274-517. 3 Ma,具有2个峰值280 Ma和474 Ma; 532-856. 6 Ma,具有3个峰值572 Ma、649 Ma和772 Ma; 1786-2600 Ma,具有2个峰值2035 Ma和2506 Ma。同时,总结了物源区大别造山带不同单元锆石U-Pb年龄特征。根据锆石U/Pb年龄和Th/U值,发现这5个年龄段比较准确地记录了物源区地质体,分别是早白垩世的岩浆岩、大别山高压—超高压变质岩、北淮阳的浅变质岩、北大别的正片麻岩和卢镇关群变质岩。根据锆石最小年龄,修正了合肥盆地南缘中生代地层格架,为源汇系统研究确立了时间框架。合肥盆地南缘中生代沉积可以分为4个演化阶段:晚三叠世瑞替期—早侏罗世辛涅缪斯期、中—晚侏罗世、早白垩世早期和早白垩世晚期,并据此确定了每个阶段主要物源区特征及其时空变化。碎屑锆石U/Pb年龄和Th/U值限定了大别造山带仅存在三叠纪的超高压变质作用,且超高压变质岩折返到地表的最早时间是晚三叠世瑞替期,大别造山带大陆岛弧发育的时间是新元古代。上述研究结果不仅为恢复大别造山带构造古地理做出了新的贡献,而且更为盆山源汇系统研究提供了一个实例。     

Calculation of the Model of Coesite Inclusions and Analysis of Their Retrometamorphic Paths

The process and path of retrometamorphism of coesite have great significance to our understanding of the P-T tracks of the exhumation of ultrahigh-pressure metamorphic rocks. Most of the coesites in the eclogite from Shima, Anhui Province, the Dabie Mountains, China, are found degraded to quartz partly or wholly, with ruptures occurring in the shells, outside which include the coesite and quartz. According to the microscopic observation, the sample of coesite inclusion is composed of garnet, quartz and coesite, based on which we have built a three-shelled composite sphere model to compute the transition of coesite. Based on the crystal growth formulas and pressure conditions of the ruptures in the garnet, we have calculated the radius of the quartz sphere, which depends on temperature, and eventually drawn the different retrometamorphic paths for different retrometamorphism rates.     

华中大别山高压变质地体的形成和差异岩石隆升－剥露：来自火成岩的证据

根据花岗岩类资料，分析了大别造山带自古生代以来的岩石隆升－剥露历史。认为北淮阳地块、大别地块西段及大悟地块的岩石隆升－剥露主要发生于侏罗纪之前，而大别地块东段在白垩纪之后还发生了强烈岩石隆升－剥露．本文指出，含超高压变质岩的大别地块东段自海西期以来的岩石隆升－剥露幅度达２０ｋｍ．这一深度的负荷压力与大陆碰撞过程中超过压和高应变条件的结合，有可能形成柯石英榴辉岩，但高压变质地体中的金刚石，更可能是早期慢源岩浆挟带到地壳中的捕虏晶。     

Sm-Nd Isotope Tracer Study of UHP Metamorphic Rocks: Implications for Continental Subduction and Collisional Tectonics

Sm-Nd isotope tracer techniques are powerful tools in identification of the protolith nature of UHP and HP rocks and can be used to constrain modeling of tectonic processes of continental collision. UHP rocks may have diverse origins, and not all of them carry the same significance for subduction of continental blocks. In this paper, Sm-Nd isotopic data are compiled for UHP and HP rocks, mostly represented by eclogites and garnet peridotites, from the Alpine, Hercynian (Variscan), and Caledonian belts of western Europe; the Pan-African belts of northern Africa; and the Ross belt of Antarctica. These data then are compared with the isotopic characteristics of the UHP rocks from the Dabie orogen of central China. Except for the coesite-bearing quartzitic metasediments of Dora-Maira (Western Alps), which are clearly of continental origin, all HP and UHP rocks (eclogites and ultramafic rocks) from the Alpine, Hercynian, and Pan-African belts have oceanic affinities with the characteristic positive ε_Nd(T) values (= metamorphic initial ¹⁴³Nd/¹⁴⁴Nd ratios). They represent segments of oceanic lithosphere that were subducted, underwent eclogite-facies metamorphism, and later were tectonically transported into orogenic zones during continental collisions. By contrast, the majority of UHP rocks from the European Caledonide and the Dabie orogen have negative ε_ND(T) values, indicating continental affinity. This suggests that these mafic and ultramafic rocks have had a long crustal residence time and that their UHP metamorphism is indicative of subduction of ancient and cold continental blocks, as represented by some Precambrian gneiss terranes containing mafic components including greenschists, amphibolites, or basic granulites.

In the Dabie orogen, none of the UHP eclogites analyzed thus far have shown oceanic affinity; thus they do not represent subducted Tethys Ocean crust. The preservation of ultrahigh ε_ND(0) values (+170 to +260) in eclogites of very low Nd concentrations (average 0.5 ppm) from the Weihai region and of the extraordinarily low δ¹⁸O in many eclogites and gneisses, the general absence of syntectonic granites in the Dabie Shan, and the available age data obtained by different techniques all point to a rapid rate of exhumation and the absence of a pervasive aqueous fluid phase during the entire process of subduction and exhumation of the Dabie UHP terrane.     

大别山石马地区石榴黑云片麻岩的Sm-Nd、K-Ar年龄及冷却速率

南大别地体中榴辉岩的围岩──石榴黑云片麻岩具有角闪岩相变质矿物组合,其变质温度为525℃,Sm-Nd矿物等时线年龄为(229±3)Ma.黑云母的K-Ar封闭温度为300℃,相应K-Ar年龄为(231±5)Ma.因此该片麻岩在230Ma左右从525℃迅速冷却到300℃以下。然而该区榴辉岩在印支期(221Ma)变质温度为700℃左右,直到134Ma才降至400-450℃。说明该区榴辉岩与该片麻岩具有不同的冷却史。它不支持榴辉岩是原地(in situ)成因的。     

桐柏—大别山高压超高压变质带

桐柏—大别山高压超高压变质带自南向北可划分为３个带：绿帘－蓝片岩相变质带，高压榴辉岩相变质和超高压榴辉岩相变质带，超高压变质带形成于加里东期洋壳俯冲作用过程中，而前两个高压变质带则是印支期陆－陆俯冲－碰撞作用的产物。     

大别山东南缘侏罗系磨山组沉积环境及地质意义

侏罗纪是大别造山带与周缘盆地盆山关系研究的一个重要时期,分布在大别造山带周缘的侏罗纪地层为大别山的造山过程以及深俯冲岩石的折返、剥蚀提供了很好的约束。本文选取大别造山带东南缘安庆月山地区侏罗系磨山组为研究对象,对磨山组碎屑岩进行了详细的粒度分析、碎屑组分分析、重矿物分析和碎屑锆石年代学分析。碎屑岩岩石、沉积特征和粒度分析都指示早侏罗世磨山组为三角洲前缘水下分流河道沉积。碎屑组分分析、重矿物分析结合碎屑锆石年代学分析指示磨山组碎屑岩物源主要来自南侧的华南板块,大别造山带宿松杂岩可能为其提供了少量物源,但碎屑物源中未见石榴子石和典型的三叠纪变质锆石,说明此时大别高压-超高压榴辉岩可能仍未折返至地表。     

MORPHOLOGY AND INTERNAL STRUCTURE OF THE KAMENSK AND GUSEV ASTROBLEMES

The Kokchetav and Dabie Shan complexes are typical examples of ultrahigh-pressure metamorphic complexes (UHPM) and are important units of the largest suture zones within the Eurasian continent. The Dabie Shan complex is located in the center of a long Permian-Triassic high-pressure (HP) belt between the Sino-Korean and Yangtze cratons. Other members of this belt are the Sulu region of of NE China, the Imjingang belt in Korea, the Sangun and Marginal Hida belts in Kyushu, the Spassk zone in the Sikhote-Alin of the Russian Far East, and the Bikou, Animaqing, Ailaoshan, and Lancang belts in China bounding the western margin of the Yangtze craton. The Kokchetav complex is located in the center of the largest Early Paleozoic HP belt in Asia, which includes the North Qilian complex, the Kekesu and Atbashi zones of the Tien Shan, and the Aktyuz and Makbal areas in the North Kyrgyz Range.

The structure of the Kokchetav complex is interpreted as a mega-melange zone that consists of seven tectonic units separated by tectonic thrusts or faults. There are many similarities between the Kokchetav and Dabie Shan tectonic units. Principal differences relate to the rocks of coeval island-arc series abundantly exposed in the Kokchetav area, but absent in the Dabie Shan, and to the ongoing subduction and island-arc magmatism in Kokchetav after the collision and UHP metamorphism compared to the final collision after UHP metamorphism in the Dabie Shan.

The Caledonian Kokchetav complex formed in the Early Paleozoic, whereas the Indosinian Dabie Shan complex formed in the Early Mesozoic; however, both complexes are characterized by a close succession of events and the occurrence of a Late Proterozoic protolith. In both cases magmatic events occurred in 150-m.y. intervals. Retrograde stages, cooling histories, and exhumation processes are similar for both complexes.

Comparison of mineral assemblages in those complexes indicates higher temperature and pressure in the Kokchetav peak assemblages. The best containers for preserved UHP mineral assemblages are metacarbonate rocks and zircon and garnet from metapelites and felsic rocks in both regions. The Dabie Shan UHP assemblages are better preserved than the Kokchetav ones, which has to do either with their higher temperature or with specific kinetics. Oxidation conditions deduced from mineral distributions, mineral chemistry, and composition of fluid inclusions indicate the higher oxygen potential in the Dabie Shan than in the Kokchetav rocks.

The comparison allows us to conclude the following:

1. The small size of sheets and blocks of UHPM rocks supports a model for reverse flows within a subduction-accretionary wedge or tectonic exhumation of thin sheets, but not uplifting of large blocks.

2. The preservation of coesite and diamond, and the presence of thin reactionary rims (primarily in the Dabie Shan), provides evidence for a very short time of retrograde reactions and high velocity of block uplifting. Thus, three exhumation stages are accepted: (1) superfast uplifting; (2) rapid uplifting up to the sole of the continental crust; and (3) slow uplifting within the continental crust. In the Kokchetav complex, the first stage is absent.

3. For the Dabie Shan we suggest a complex scenario implying two-stage subduction and subsequent collision. Comparison with the Kokchetav complex shows that UHP metamorphism is not likely to have resulted from a collision, but the latter was responsible for the superfast exhumation of thin sheets of UHPM rocks from depths of over 100 km.     

TEM and HRTEM Study of Microstructures in Omphacite from UHP Eclogites at Shima, Dabie Mountains, China

Transmission electron microscope (TEM) and high resolution transmission electron microscope (HRTEM) analyses have been performed on omphacite from ultra-high pressure (UHP) eclogites at the locality of Shima, Dabie Mountains, China. TEM reveals that the microstructures consist dominantly of dislocation substructures, including free dislocations, loops, tiltwalls, dislocation tangles and subboundaries. They were produced by high-temperature ductile deformation, of which the main mechanism was dislocation creep. Antiphase domain (APD) boundaries are common planar defects; an age of 470±6 Ma for UHP eclogite formation has been obtained from the equiaxial size of APDs in ordered omphacites from Shima, coincident with ages given by single-zircon U-Pb dating (471±2 Ma). HRTEM reveals C2/c and P2ln space groups in different parts of one single omphacite crystal, and no exsolution is observed in the studied samples, which is attributed to rapid cooling. It is suggested that the UHP eclogites underwent a long     

华南东段加里东期花岗岩类形成构造背景探讨

根据近年对区域地质调查取得的认识和前人的研究成果,研究了华南东段加里东期花岗岩类的地质产状、分布规律、形成时代以及Nd、Sr同位素特征;结合研究区超镁铁质-镁铁质岩及火山岩的形成时代、震旦纪—奥陶纪的沉积环境、加里东期构造事件的构造变形特征,对加里东期花岗岩类的形成背景进行了探讨。结果表明,加里东期花岗岩类形成于410～460Ma,大部分岩体属于S型花岗岩,岩浆来源于地壳物质的部分熔融;极少数为I型花岗岩,有幔源物质参与。研究区在早古生代不存在与俯冲有关的弧火山岩,也不存在大面积的早古生代I型花岗岩,震旦纪—奥陶纪地层主要形成于浅海环境。研究提出,加里东期花岗岩类主体形成于板内构造环境。     

大别山石马地区榴辉岩P-T-t轨迹及其构造意义

在大别山石马地区榴辉岩石榴石中包裹有与柯石英同期的绿辉石,据此,将这里的榴辉岩相变质作用划分为早期的柯石英榴辉岩阶段和晚期重结晶榴辉岩阶段。它们的P-T-t轨迹表明:产于片麻岩中的榴辉岩至少经历了两阶段的抬升过程:(1)在221Ma(印支期)时,由于陆壳俯冲所产生的大规模逆冲构造使其快速抬升;(2)在134Ma(燕山期)陆壳俯冲后的拉张抬升环境下,榴辉岩随山体一起缓慢上升。     

大别山北缘西段双桥中生代火山岩地球化学及锆石U-Pb同位素年代学

首次对大别山北缘西段(河南省境内)中生代火山岩进行了锆石原位U-Pb同位素测年。结果表明,罗山县双桥火山岩集中区石英安山岩锆石LA-ICP-MS U/Pb年龄为133.1±1.5 Ma,与大别东段中生代火山岩主体毛坦厂组的时代一致,属早白垩世,稍早于或与大别山区大规模花岗岩岩基侵位时代相同;与长江中下游地区的宁芜和庐枞盆地火山岩喷发时间同步,可能同属中国东部中生代巨量岩浆活动的重要组成部分,与太平洋板块斜向俯冲引起的大陆岩石圈重力不稳而产生的拆沉导致岩石圈强烈减薄深部动力学过程相联系。大别山西段早白垩世火山岩属高钾钙碱性系列粗安岩-英安岩-流纹岩组合。中酸性火山岩显示轻稀土元素富集、重稀土元素强烈亏损、弱或基本无负Eu异常的稀土元素配分模式以及高Sr低Yb特征,反映岩浆部分熔融源区残余有石榴石,说明当时存在加厚的成熟陆壳。高(87Sr/86Sr)i(0.707 56)、极低的εNd(t)(-20.1)和大离子亲石元素富集、高场强元素Nb、Ta明显亏损,显示岩浆源区的壳源性质。以上特征反映大别山地区该时期岩石圈伸展程度和软流圈上涌规模远不如长江中下游同时期以幔源为主的中基性火山岩发育的宁芜和庐枞地区。     

大别山东南麓中新生代碎屑岩地球化学特征及其对物源的制约

位于大别山东南麓的安庆-潜山地区中新生代碎屑岩比较发育,主元素分析表明,砂岩主要为杂砂岩,其次是岩屑砂岩和长石砂岩。根据主元素、微量元素和稀土元素特征值分析结果,中、上三叠统和下、中侏罗统的源岩来源广泛,属于大陆岛弧、活动大陆边缘和被动大陆边缘构造背景,可能反映了前陆盆地物源的二元特征。古近系源岩主要为活动大陆边缘和大陆岛弧构造环境,说明物源仅来自大别山造山带。稀土元素比值及相关系数分析揭示,中晚三叠世黄马青群的源岩主要为宿松群的长英质片岩、浅粒岩以及大别杂岩,侏罗纪磨山组大致类似于大别群的花岗片麻岩,罗岭组与大别群比较类似。显示大别山造山带在中晚三叠世已经隆升并遭受剥露。     

大别造山带变质岩和花岗岩的钕同位素组成及其地质意义

大别造山带８个变质岩和４个花岗岩样品的Ｓｍ－Ｎｄ分析结果表明，大别地块不同构造单元的岩石有不同的钕同位素模式年龄。总体上，北大别地块变质岩的钕模式年龄较老；南大别超高压地块的较年轻，但变化范围大。侵人于大别地块不同构造单元的花岗岩与北大别地块变质岩有相同的Ｎｄ（１２２Ｍａ）值范围，表明它们有相似的物质来源。南大别地块是覆盖在具有古老物源的变质岩之上的一个构造岩片。