隐爆角砾岩——古地震的一种成因标志SCIEI北大核心CSCD

全球到处发育的隐爆角砾岩表明隐爆作用的普遍性,并标志着古地震的一种形成机制。隐爆角砾岩具有特殊的角砾形状和构造。地震地质资料表明大地震产生的地表破裂带没有肉眼可观测到的断层位移。材料聚集应变能估算值表明岩石聚集的应变能不足以产生大地震。携带高能量的地核-地幔流体不仅为自己逸散提供了能量,而且为产生地震提供了充足的能量。深部流体以运移-聚集-爆炸-运移-聚集-爆炸的循环方式向地表逃逸,在地球内部不同深度产生了不同震级的地震。因此,超高压流体隐爆应该是地震形成的主要机制。地震隐爆成因机制不仅能够更好地解释各种天然地震(中深源地震、震群、慢地震和非双力偶性地震等)以及全球地震、火山和地热带的空间吻合,而且能够解释隐爆角砾岩及其伴生矿的形成。     

Seismicity and faulting attributable to fluid extraction

The association between fluid injection and seismicity has been well documented and widely publicized. Less well known, but probably equally widespread are faulting and shallow seismicity attributable solely to fluid extraction, particularly in association with petroleum production.

Two unequivocable examples of seismicity and faulting associated with fluid extraction in the United States are: The Goose Creek, Texas oil field event of 1925 (involving surface rupture); and the Wilmington, California oil field events (involving subsurface rupture) of 1947, 1949, 1951 (2), 1955, and 1961. Six additional cases of intensity I–VII earthquakes (M < 4.6) without reported faulting may be attributable to shallow production from other large oil and gas fields. In addition to these examples are thirteen cases of apparently aseismic surface rupture associated with production from California and Texas oil fields. Small earthquakes in the Eloy—Picacho area of Arizona may be attributable to withdrawal of groundwater, but their relation to widespread fissuring is enigmatic. The clearest example of extraction-induced seismicity outside of North America is the 1951 series of earthquakes associated with gas production from the Po River delta near Caviga, Italy.

Faulting and seismicity associated with fluid extraction are attributed to differential compaction at depth caused by reduction of reservoir fluid pressure and attendant increase in effective stress. Surface and subsurface measurements and theoretical and model studies show that differential compaction leads not only to differential subsidence and centripetally-directed horizontal displacements, but to changes in both vertical- and horizontal-strain regimes. Study of well-documented examples indicates that the occurrence and nature of faulting and seismicity associated with compaction are functions chiefly of: (1) the pre-exploitation strain regime, and (2) the magnitude of contractional horizontal strain centered over the compacting materials relative to that of the surrounding annulus of extensional horizontal strain.

The examples cited include natural systems strained only by extraction of fluids, as well as some subsequently subjected to injection. Faulting and seismicity have accompanied both decrease and subsequent increase of fluid pressures; reversal of fluid-pressure decline by injection may enhance the likelihood of subsurface faulting and seismicity due chiefly to earlier fluid pressure reduction. A consistent common denominator appears to be continuing compaction at depth; the relative effects of fluid extraction followed by injection are not easily separated.     

Relationship of present saline fluid with paleomigration of basinal brines at the basement/sediment interface (Southeast basin – France)

This paper investigates the isotopic composition (O, D, Sr, O_SO4, S_SO4, Cl, He) of a present saline fluid sample collected at the sediment/basement interface in the Permian continental formation at 634 m depth in the SE margin of the Massif Central shield (Ardèche margin of the Southeast basin of France). The fluid sample shows clear water–rock interaction processes, such as feldspar dissolution and kaolinite precipitation, which have led to high Na concentrations and water stable isotopes above the local meteoric water line. The geological formations of the SE margin of the Massif Central shield show that intensive fluid circulation phases occurred across the margin from the late Triassic to the middle Jurassic. The fluids most probably originated from fluid expulsion during burial of the thick Permo-Carboniferous sedimentary succession. These circulation phases were responsible for cementation of the margin and for the solutes in the matrix microporosity which were extracted by leaching core samples.The chemical and isotopic composition of the saline fluid sample at 634 m in the Permian rock is very similar to that of fluids in the microporosity of the rock matrix. Their S_SO4, O_SO4 and Sr isotopic compositions are close to those of cements investigated in fracture fillings in the same geological formations. Simple diffusion computations and comparison of the chemical composition of the present free fluid sample with matrix porosity fluids indicate that the solutes in the present free fluid sample are related to solutes originating from fluid circulation events which occurred 160–200 Ma ago through their diffusion from the matrix microporosity.A two-stage fluid flow regime is proposed to interpret the chemistry of present and paleo-fluids. (1) During the extensional context (Permian to Cretaceous), basinal brines migrated along the basement/sediment interface after expulsion from the subsiding basin. This fluid migration would be responsible for the solutes in the rock matrix microporosity and the solutes in the present free fluid sample. (2) Following the Alpine and Pyrenean compressive phases, gravity-driven meteoritic fluids slowly migrated from the surface down to the basement along major faults. This fluid regime would be responsible for the meteoric water collected in the present free fluid sample. Several investigations in Europe have shown that the existence of other saline fluids sampled elsewhere could be explained by these phases of fluid circulation related to specific geodynamic events.     

鄂尔多斯盆地多种能源矿产分布及其构造背景

借助“成矿系统”的思维, 探讨鄂尔多斯盆地成矿(藏)系统形成机制及其构造背景.盆地于中生代处于大地构造体制转折的重要阶段, 盆地边缘的造山活动显著, 盆内亦分别于晚三叠世、晚侏罗世与晚白垩世左右发生过3次构造热事件.区域构造体制转换事件导致了多种成藏(矿)作用的发生.盆地内部的构造热事件引发了有机流体的活动, 周缘造山作用产生了向盆内流动的无机含铀热液.有机和无机流体的活动过程中存在相互作用, 有机流体的存在形成氧化-还原障, 导致无机流体关键物理化学参数的转变, 在氧化-还原界面处成矿.突变成矿和界面成矿是多种能源矿产成矿过程的主要机制.      

Modeling of fluid pressure evolution related to sediment loading and thrust faulting in the Lanping basin: Implications for the formation of the Jinding Zn–Pb deposit, Yunnan, China

The Jinding Zn–Pb deposit occurs in Cretaceous and Paleocene siliciclastic rocks (mainly sandstones) in the Meso-Cenozoic Lanping basin, western Yunnan, China. With a reserve of approximately 200 Mt of ore containing 6.1% Zn and 1.3% Pb, Jinding is the largest sandstone-hosted Zn–Pb deposit in the world. Most previous studies assumed that the mineralizing fluids were derived from within the basin (including meteoric recharge), and the fluid flow was driven by topographic relief under a hydrostatic regime. In contrast, we propose that the mineralizing system was strongly overpressured based on observations of hydraulic fractures and fluid inclusion data. Numerical modeling results indicate that the overpressures could not have been produced by normal sediment compaction. Thrust faulting and input of mantle-derived fluids are likely responsible for the building-up of the high overpressures. The special hydrodynamic regime and potential contribution of mantle-derived fluids to the mineralizing system distinguish Jinding from other known sedimentary basin-related Pb–Zn deposits.     

A fluid inclusion study of the porphyry-greisen,tungsten-molybdenum deposit at Mount Pleasant,New Brunswick,Canada

Homogenization temperatures and salinity data are presented for fluid inclusions from hydrothermal gangue minerals (quartz and fluorite) associated with porphyry wolframite-molybdenite-arsenopyrite-sphaleritebismuth-chalcopyrite-cassiterite mineralization within the Fire Tower ore zone, Mt Pleasant, New Brunswick. The data indicate that ore mineral precipitation occurred within a temperature range of 260° to 490°C from moderate to high salinity (10–42 wt% NaCl equivalent) aqueous fluids. Two stages of hydrothermal activity characterized by high (>30 wt% NaCl equivalent) salinity fluids are recognized; one which occurred at relatively high temperature (350°–490°C); and one which took place at lower temperature (180°–250°C). The high salinity, high temperature stage is interpreted to be the result of resurgent boiling. Dilution of these early fluids by convecting meteoric water resulted in low to moderate salinity fluids, which dominate the inclusion population. The low temperature, high salinity fluid inclusions are interpreted to represent late residual fluids derived from boiling which occurred as a result of a change in the pressure regime from dominantly lithostatic to hydrostatic conditions.     

地震成因综述

本文从地质、地球物理、地球化学和能量等方面分析了地震的成因。源于地核地幔的流体携带大量热能,为岩浆起源、地震形成和地热田提供了充足的能量,然而岩石聚集的应变能不足以产生中等以上的地震。大地震(M≥6.0)绝大部分分布在海沟、火山岛弧和大陆裂谷带等拉张性构造带,如环太平洋海沟、东印度洋海沟、大洋中脊、非洲裂谷、地中海-黑海-里海-波斯湾、欧亚大陆中部的伊塞克湖-阿拉湖-乌布苏湖-库苏古尔湖-贝加尔湖裂谷。流体在地球深部物质运动、地壳运动、地震和火山活动中扮演着重要作用。全球到处发育的隐爆角砾岩表明隐爆作用的普遍性。深部流体向上运移、向地表逃逸的过程中发生爆炸,在地球内部产生了不同震级和震源深度的地震。因此,隐爆应该是产生地震的主要机制。地震成因的隐爆模型不仅能够更好地解释不连续、各向异性的非弹性介质中发生的各类地震,譬如中深源震、震群、慢地震和非双力偶性地震等,而且能够更好地诠释全球地震、火山和地热带在空间上的吻合以及隐爆角砾岩型矿藏的形成。     

The effect of metamorphic fluid flow on the nucleation and growth of garnets from Troms, North Norway

A spatial association is observed between the size distribution of garnet porphyroblasts and the size distribution of quartz veins in greenschist facies metapelites from Troms, North Norway. The size distribution of quartz veins reflects the flow regime of metamorphic fluids. The hypothesis that the flow regime of metamorphic fluids is also responsible for the size distribution of garnet crystals was tested by ascribing empirical acceleration parameters to the nucleation and growth rates of garnet crystals.
In regions where fluid flow was interpreted as pervasive', acceleration parameters for nucleation were high, whereas in regions where fluid flow was interpreted as channelled', acceleration parameters for growth were high. Accelerated crystal growth is further implied from the chemical zoning and crystal morphologies of garnets collected near discrete veins.
This spatial association may imply that fluid flow can be instrumental in controlling garnet crystallization. Fluid flow could affect garnet crystallization kinetics by facilitating thermal advection and/or mass transfer. In the study area, rhodochrosite (MnCO₃) veins provide evidence for mass transfer of Mn by fluid flow. An influx of Mn would expand the stability field of garnet to lower temperatures. The resulting thermal overstep could accelerate nucleation and/or growth of garnets.
The corollary of this study is that size distributions and chemical zoning of garnets, or other porphyroblast phases, can be used to study metamorphic fluid flow.     

西南三江兰坪盆地大规模成矿的流体动力学过程——流体包裹体和盆地流体模拟证据

中国西南部云南兰坪盆地因金顶Zn-Pn矿床和新发现的白秧坪超大型Cu-Co-Ag矿床而驰名。金顶矿床以白垩系和第三系陆相碎屑岩为主岩,拥有2亿吨矿石,平均品位Zn6.08%、Pb1.29%(1500万吨金属),是目前中国最大的Zn-Pb矿床,也是世界上形成时代最新且唯一产于陆相沉积岩容矿的超大型Zn-Pb矿床。不同于世界上人们公认的沉积岩容矿基本类型,即SST、MVT和Sedex型,金顶矿床也许代表了Zn-Pb矿床的一个新类型。通常认为兰坪盆地大规模成矿流体起源于盆地卤水,流体流动以重力驱动为主,压力体系接近静水压力。但基于矿田内水压破裂观察、流体包裹体研究和盆地流体动力学模拟,我们认为深部超压流体的注入对整个成矿系统起着重要作用。闪锌矿及相关脉石矿物(石英、天青石、方解石、石膏)中流体包裹体观测的均一温度主体在110～150℃,盐度(质量分数)在1.6%～18.0%NaCl;在时间上,大规模成矿主要阶段伴随着流体温度的不断升高和盐度的逐渐降低;在空间上,金顶矿区空间上从东到西,成矿流体温度明显降低,盐度系统性升高。富CO2流体包裹体揭示成矿流体曾高达(513～1364)×105Pa,大大高于静水压力。数值模拟表明,盆地沉积和压实产生的流体超压可以忽略,区域构造推覆也不足以产生如此高的流体压力。我们认为成矿流体超压很可能是幔源流体注入引起的;幔源含矿的相对高温低盐度流体沿导矿构造注入金顶穹隆构造-岩性圈闭并与其中富H2S的相对低温高盐度卤水混合是兰坪盆地大规模成矿的关键动力学过程。这个特殊的流体动力学过程和成矿系统,使兰坪盆地的成矿有别于世界其他沉积盆地已知的成矿作用。     

Cathodoluminescence,fluid inclusion and stable C–O isotope study of tectonic breccias from thrusting plane of a thin-skinned calcareous nappe

Basal hydraulic breccias of alpine thin-skinned Muráň nappe were investigated by means of cathodoluminescence petrography, stable isotope geochemistry and fluid inclusions analysis. Our study reveals an unusual dynamic fluid regime along basal thrust plane during final episode of the nappe emplacement over its metamorphic substratum. Basal thrusting fluids enriched in ¹⁸O, silica, alumina, alkalies and phosphates were generated in the underlying metamorphosed basement at epizonal conditions corresponding to the temperatures of 400–450°C. The fluids fluxed the tectonized nappe base, leached evaporite-bearing formations in hangingwall, whereby becoming oversaturated with sulphates and chlorides. The fluids further modified their composition by dedolomitization and isotopic exchange with the host carbonatic cataclasites. Newly formed mineral assemblage of quartz, phlogopite, albite, potassium feldspar, apatite, dravite tourmaline and anhydrite precipitated from these fluids on cooling down to 180–200°C. Finally, the cataclastic mush was cemented by calcite at ambient anchizonal conditions. Recurrent fluid injections as described above probably enhanced the final motion of the Muráň nappe.     

Relation between electrical resistivity and earthquake generation in the crust of West Anatolia, Turkey

In this paper, we present a relation between the earthquake occurrence and electric resistivity structures in the crust, in West Anatolia and the Thrace region of Turkey. The relationship between magnetotelluric georesistivity models and crustal earthquakes in West Anatolia, during a period from 1900 to 2000, is investigated. It is found that most of the large crustal earthquakes occurred in and around the areas of the highest electrical resistivity in the upper crust, although rare small magnitude earthquakes are observed in some parts of the conductive lower crust in West Anatolian extensional terrain. The high-resistivity zones may represent rocks that are probably mechanically strong enough to permit sufficient stress to accumulate for earthquakes to occur in western Anatolia and the Thrace region. However, some recent studies state that the generation of a large earthquake is not only a pure mechanical process, but is closely related to fluid existence. We also reviewed recent world-wide researches including results from the Anatolian data for the first time and discussed all general findings in combination. Our findings show that the boundary between the resistive upper crust and the conductive lower crust correlates well with the cutout depth of the seismicity in West Anatolia and Thrace. This boundary is also attributed to the fluid bearing brittle–ductile transition zone in world literature. Fluid migration from the conductive lower crust to the resistive upper crust may contribute the seismicity in resistive zones. Alternatively, the upper–lower crust boundary may act as a stress concentrator and fluids may help to release strain energy in brittle parts of lower crust, by small magnitude earthquakes, whereas they may help in focusing strain in mechanically strong and electrically resistive zones for large earthquakes to occur.     

地震动促进石油运移的一种模式及其发生边界

天然和人工地震动使地下孔隙流体瞬时产生相对于地层介质的加速运动趋势,即产生了作用于流体的瞬时冲力。在不考虑质量扩散力条件下,本文以岩石孔喉结构理想模型和充填其中的石油受力分析为基础,对水平、垂向两地震动作用方向上,促进石油运移时的油柱长度、孔隙、喉道等边界条件进行了分析,并考虑了静水常压和异常压力两种地层状态下的情况。研究表明,在无裂缝作为运移通道的条件下,地震动作用可以使油柱在岩石破裂前,突破一定岩石孔隙结构的喉道发生运移。对该地震动促进石油运移模式的边界条件分析认为,小孔喉比值、大半径孔隙和连续一定长度的油柱利于油柱突破喉道运移的发生,油柱在水平向地震动作用于静水常压地层、垂向地震动作用于静水常压地层、水平向地震动作用于低过剩压力梯度地层、垂向地震动作用于高过剩压力梯度地层等4种情况下,地震动促使运移发生的难度依次降低。     

Carbonic fluid inclusions in South Indian granulites: evidence for entrapment during charnockite formation

Field evidence and fluid inclusion studies on South Indian incipient charnockites suggest that charnockite formation occurred during a decompressional brittle regime following the ‘peak’ of metamorphism and regional deformation. The most abundant type of inclusions in quartz and garnet grains in these charnockites contain high-density carbonic fluids, although lower-density fluids occur in younger arrays of inclusions. Discrete fluid inclusion generations optically are observed to decrepitate over well-defined temperature intervals, and quantitative measurements of CO₂ abundance released from these inclusions by stepped thermal decrepitation show up to a four-fold increase (by volume) in the incipient charnockites relative to the adjacent gneisses from which they are derived. Studies based on optical thermometry, visual decrepitation and stepped-heating inclusion release together indicate that entrapment of carbonic fluids coincided with charnockite formation. We confirm that an influx of carbon dioxide-rich fluids is associated with the amphibolite-granulite transition, as recorded by the incipient charnockites, the remnants of which are commonly preserved as the earliest generation of high-density fluid inclusions.     

中国大陆科学钻探主孔0-2000米流体地球化学异常与地震的关系

CCSD流体中He、N2、Ar是记录地震的敏感载体，可能记录了本地一些中小地震及远强震的异常信息。与远强震对应的流体异常幅度大，一般始于远强震前数天，且He、He／Ar、N2／Ar多为负异常，Ar多为正异常；而本地中小地震大多造成主孔流体组分的小幅度波动变化。远强震可能改变了CCSD钻探区的地下流体循环，地震期间监测到泥浆中相对富Ar贫N2和He的地下流体贡献增加，震后，地震引起的附加流体贡献逐渐消失。CCSD的流体组分和比值可能记录了区内地壳应力变化，反映了远强震期间区域构造活动乃至地球深部构造活动产生的场兆、源兆信息，地壳屈曲的假设可以加深CCSD流体作为远强震敏感载体的理解。远强震期间CCSD流体异常也可能是记录了震前长周期波传播至CCSD主孔时激发的流体变化，反映了震源区的应力变化。     

Fluid Flow History in Lower Triassic Bulgo Sandstone,Central Sydney Basin,Australia

INTRODUCTIONThe Sydney basin(Fig.1) forms the southernm ost partofthe Sydney- Gunnedah- Bowen basin system (Bembrick et al.,1973) .It started as a rift and evolved into a foreland basin inMiddle Triassic with sediments lapping unconformably on thedeformed and metamorphosed rocks of the L achlan fold belt inthe west and abutting the New England fold belt in thenortheast along the east- dipping Hunter thrust.The Sydneybasin is separated from the Gunnedah basin by the MountCoricudgy an…     

Tertiary metallogenesis in the Eastern Alps: the Waldenstein hematite deposit (Austria)

The specularite deposit at Waldenstein is an epigenetic replacement/vein-type hematite mineralization with distinct alteration zones. It is situated in highly metamorphosed schists and, gneisses of the Koralm Crystalline Complex. Sericitization and chloritization are strictly bound to this alteration and occur within a few meters of the hematite veins. Radiometric dating of the sericitization and the implicity of the mineralization yield a Middle Eocene age. Petrographic evidence proves an early, relatively reduced paragenesis (magnetite, ilmenite) being partly replaced by hematite and chlorite during the main phase of ore formation. Fluid inclusion and stable isotope investigations indicate that formation temperatures were approximately 300°C during the main stage and decreased to 200°C in the latest stage of the hydrothermal event. The H-isotope compositions of chlorites and of fluid inclusions in quartz indicate the influence of seawater. This also explains the high salinities determined by fluid inclusion studies (20–30% NaCl equiv.). According to the genetic model presented in this paper the hydrothermal activity started when the deformation accompanying the uplift of the Koralm Crystalline Complex passed from a ductile to brittle regime (Middle Eocene). The brittle faults acted as channelways for rising, deep fluids, probably of metamorphic origin. Temperature differences between the different uplifting crustal segments supported fluid circulation. Precipitation of the ore occurred at shallow crustal levels where the hydraulic regime was dominated by seawater, and oxidation of the original reducing fluids took place.     

Evolution of gas and aqueous fluid in low-permeability argillaceous rocks during uplift and exhumation of the central Swiss Alps

Fluid chemistry and the hydraulic regime in a marl formation of the Swiss Alps were studied by a number of techniques. Fluid inclusions record the conditions of maximum burial and regional low-temperature metamorphism, whereas fluid samples and hydraulic tests derived from deep boreholes reflect present-day, near-surface conditions. The characterization of the different types of fluids places constraints on the geochemical and hydraulic evolution of low-permeability argillaceous rocks during uplift and exhumation.Fluid inclusions were studied by microthermometry and sampled directly by decrepitation techniques. They contain a two-phase system consisting of an aqueous fluid and a coexisting CH₄-rich gas (T=190–250°C, P_lith≈2500 bar). Bulk and isotopic compositions of aqueous fluid inclusions are consistent with a mixture of connate seawater and water derived from the dehydration of clay minerals. Methane was generated in situ by thermal cracking of kerogen. Textural evidence and stable isotopic signatures of carbonates in veins and in the rock matrix indicate local buffering of fluid compositions and very low water/rock ratios. Free fluids residing in the present-day fracture and matrix porosity consist of CH₄-saturated Na–Cl groundwater with minute amounts of free CH₄ gas which occurs in druses. Their chemical and isotopic compositions are very similar to those of the fluid inclusions, suggesting a common origin. Post-metamorphic admixtures of externally derived waters cannot be identified, and it is suggested that present-day Na–Cl groundwaters that occur in the central parts of the marl have resided in the formation since the time of metamorphism some 20 Ma b.p. The only major change in the fluid composition has been the outgassing of CH₄ from the formation, most probably by diffusion.The hydraulic regime during metamorphism was characterized by localized fluid underpressures in open veins because widely scattered, sub-hydrostatic pressures were often identified in fluid inclusions. The central part of the argillaceous rock body, approximately coinciding with the region where Na–Cl groundwaters occur, has sub-hydrostatic pressures today, as indicated by hydraulic tests in deep boreholes.Both the closed-system behavior derived from the chemical and isotopic characteristics of the fluids and the (recurrent or continuous) existence of hydraulic underpressures suggest very low permeabilities of argillaceous rocks during metamorphism and throughout subsequent uplift and exhumation. All fluids present in the central parts of the formation are either connate or produced in situ. Even though major events of brittle faulting and unloading due to uplift occurred since the peak of metamorphism, fluid flow through the formation has been negligible.     

Investigations on the Possible Re-equilibration of Aqueous Fluid Inclusions in Barite: A Study of Barite and Calcite from the Hutti Gold Deposit, Karnataka, India

Re-equilibration of fluid inclusions in crystals takes place by loss or gain of solvents and solutes from fluid inclusions and by changes in their volumes. Volume change of fluid inclusions are primarily dictated by elastic properties and available slip planes of host crystals. In the present study, the phase-behavior of fluids entrapped in co-precipitated calcite and barite is studied. While calcite contains only biphase fluid inclusions, barite has predominantly monophase fluid inclusions. Fluid inclusion petrography, microthermometry and leachate analysis are used to establish the nature of entrapped fluids and entrapment temperature is substantiated through independent sulfur isotope geothermometry using coexisting barite and pyrite. Phase transitions in the monophase fluid inclusions in barite are explained in terms of over-pressuring of fluids in these fluid inclusions relative to fluids entrapped in calcite owing to the low bulk modulus of barite.     

Fluid inclusion evidence for hydrothermal fluid evolution in the Darreh-Zar porphyry copper deposit,Iran

The Darreh-Zar porphyry copper deposit is associated with a quartz monzonitic–granodioritic–porphyritic stock hosted by an Eocene volcanic sedimentary complex in which magmatic hydrothermal fluids were introduced and formed veins and alteration. Within the deepest quartz-rich and chalcopyrite-poor group A veins, LVHS2 inclusions trapped high salinity, high temperature aqueous fluids exsolved directly from a relatively shallow magma (0.5 kbar). These late fluids were enriched in NaCl and reached halite saturation as a result of the low pressure of magma crystallization and fluid exsolution. These fluids extracted Cu from the crystallizing melt and transported it to the hydrothermal system. As a result of ascent, the temperature and pressure of these fluids decreased from 600 to 415 °C, and approximately 500–315 bars. At these conditions, K-feldspar and biotite were stabilized. Type A veins were formed at a depth of ∼1.2 km under conditions of lithostatic pressure and abrupt cooling. Upon cooling and decompressing, the fluid intersected with the liquid–vapor field resulting in separation of immiscible liquid and vapor. This stage was recorded by formation of LVHS1, LVHS3 and VL inclusions. These immiscible fluids formed chalcopyrite–pyrite–quartz veins with sericitic alteration envelopes (B veins) under the lithostatic–hydrostatic pressure regime at temperatures between 415 and 355 °C at 1.3 km below the paleowater table. As the fluids ascended, copper contents decreased and these fluids were diluted by mixing with the low salinity-external fluid. Therefore, pyrite-dominated quartz veins were formed in purely hydrostatic conditions in which pressure decreased from 125 bars to 54 bars and temperature decreased from 355 to 298 °C. During the magmatic-hydrothermal evolution, the composition and P–T regime changed drastically and caused various types of veins and alterations. The abundance of chalcopyrite precipitation in group B veins suggests that boiling and cooling were important factors in copper mineralization in Darreh-Zar.     

Hydrothermal activity in the Obiro deposit embedded in the Tagawa acidic rocks,Uetsu region,NE Japan

The Obiro deposit is located in the Tagawa Acidic Rocks (AR), Uetsu region, NE Japan. The Tagawa AR is composed of a volcanic phase of dacitic welded tuff and a plutonic phase of porphyritic granodiorite. Drill core and ore samples were collected from the deposit and examined by XRD, EPMA, and microthermometry. The drill core samples have suffered pervasively from sericite (illite) alteration, whereas pinkish K‐feldspar alteration halo occur close to veins. The results of EPMA and microthermometry is interpreted as that the magnatic‐hydrothermal fluids has changed as follows; the granodioritic magma intruded at about 1.0 kb and 700°C near the water‐saturated granite solidus; after cooling to about 500°C the fluids boiled according to a change in the pressure regime from lithostatic to hydrostatic; mixing with meteoric water led to sulfide mineralization at around 400°C or less. The main reasons for the mineralization in the Obiro deposit are as follows; the oxidized magma intruded at a shallower level, and thereafter hydrothermal fluids were boiled, resulting in a saline fluid. The saline fluid then dissolved metals such as Pb, Zn, Cu, and Bi, and these metals precipitated during cooling accompanied by dilution of the meteoric water and increasing pH, resulting in decreasing solubility.