松辽盆地长岭断陷火山岩相地震特征及其响应关系

火山岩储层发育受岩性岩相的控制,为了提高岩性岩相地震识别的精度,选择松辽盆地南部长岭断陷营城组和火石岭组典型钻井火山岩进行井旁地震相分析,分别建立了酸性和中基性火山岩的岩相识别的模版.酸性与中基性火山岩最明显的差别为爆发相和喷溢相之间的差异,酸性岩爆发相具有席状,板状,平行—亚平行反射,连续性好、局部中等,强振幅,低频的特征;酸性岩喷溢相具有楔状、局部透镜,波形反射特征,连续性中—差,中弱振幅、见中强振幅,中高频特征.中基性岩爆发相具有板状,楔状,蠕虫形反射、偶见亚平行反射,中高振幅,中高频,连续性差、见连续性中—好的特征;中基性岩喷溢相具有板状,楔状,平行—亚平行反射、局部波形反射,连续性中等、局部较差,中强振幅,中频、局部高频的特征.根据酸性、中基性火山岩不同的电性特征,结合火山岩段表现的地震内部反射结构,几何形态等地震相特征.总结出不同火山岩之间地震相与测井相的对应关系,为新区识别火山岩相,预测火山岩储层,划分有利储集相带提供依据.     

The Whitsunday Volcanic Province, Central Queensland, Australia: lithological and stratigraphic investigations of a silicic-dominated large igneous province

Contrary to general belief, not all large igneous provinces (LIPs) are characterised by rocks of basaltic composition. Silicic-dominated LIPs, such as the Whitsunday Volcanic Province of NE Australia, are being increasingly recognised in the rock record. These silicic LIPs are consistent in being: (1) volumetrically dominated by ignimbrite; (2) active over prolonged periods (40–50 m.y.), based on available age data; and (3) spatially and temporally associated with plate break-up. This silicic-dominated LIP, related to the break-up of eastern continental Gondwana, is also significant for being the source of >1.4×10⁶ km³ of coeval volcanogenic sediment preserved in adjacent sedimentary basins of eastern Australia.The Whitsunday Volcanic Province is volumetrically dominated by medium- to high-grade, dacitic to rhyolitic lithic ignimbrites. Individual ignimbrite units are commonly between 10 and 100 m thick, and the ignimbrite-dominated sequences exceed 1 km in thickness. Coarse lithic lag breccias containing clasts up to 6 m diameter are associated with the ignimbrites in proximal sections. Pyroclastic surge and fallout deposits, subordinate basaltic to rhyolitic lavas, phreatomagmatic deposits, and locally significant thicknesses of coarse-grained volcanogenic conglomerate and sandstone are interbedded with the ignimbrites. The volcanic sequences are intruded by gabbro/dolerite to rhyolite dykes (up to 50 m in width), sills and comagmatic granite. Dyke orientations are primarily from NW to NNE.The volcanic sequences are characterised by the interstratification of proximal/near-vent lithofacies such as rhyolite domes and lavas, and basaltic agglomerate, with medial to distal facies of ignimbrite. The burial of these near-vent lithofacies by ignimbrites, coupled with the paucity of mass wastage products such as debris-flow deposits indicates a low-relief depositional environment. Furthermore, the volcanic succession records a temporal change in: (1) eruptive styles; (2) the nature of source vents; and (3) erupted compositions. An early explosive dacitic pyroclastic phase was succeeded by a later mixed pyroclastic-effusive phase producing an essentially bimodal suite of lavas and rhyolitic ignimbrite. From the nature and distribution of volcanic lithofacies, the volcanic sequences are interpreted to record the evolution of a multiple vent, low-relief volcanic region, dominated by several large caldera centres.     

Tectonic accretion of a subducted intraoceanic remnant arc in Cretaceous Hokkaido, Japan, and implications for evolution of the Pacific northwest

Abstract   An accretionary complex, which contains fragments of a remnant island arc, was newly recognized in the Cretaceous accretionary terranes in Hokkaido, Japan. It consists of volcanics, volcanic conglomerate, intermediate to ultramafic intrusive rocks with island-arc affinity including boninitic rocks, accompanied by chert and deformed terrigenous turbidites. Compared with the results of modern oceanic surveys, the preserved sequence from island-arc volcanics to chert, via reworked volcanics, is indicative of intraoceanic remnant arc, because the sequence suggests an inactive arc isolated within a pelagic environment before its accretion. The age of a subducting oceanic crust can be discontinuous before and after a remnant-arc subduction, resulting in abrupt changes in accretion style and metamorphism, as seen in Cretaceous Hokkaido. Subduction of such an intraoceanic remnant arc suggests that the subducted oceanic plate in the Cretaceous was not an extensive oceanic plate like the Izanagi and/or Kula Plates as previously believed by many authors, but a marginal basin plate having an arc–back-arc system like the present-day Philippine Sea Plate.     

Sedimentary evidence for an archaean shallow-water volcanic-sedimentary facies,Eastern Pilbara Block,Western Australia

Sedimentological studies of the dominantly volcanic, ca. 3.5 b.y. Warrawoona Group, eastern Pilbara Block, Western Australia, indicate widespread shallow-water deposition. Many cherty metasediments within the ultramafic-mafic sequence represent silicified carbonate mud, sand, breccia and conglomerate, and show cross-lamination, ripple marks, scour-and-fill structures, and evidence of reworking. At North Pole, some cherty metasediments appear to be silicified and baritized gypsiferous evaporites, and contain microfossils. Felsic volcaniclastic rocks include pyroclastic deposits, cross-laminated tuffaceous metasediments and conglomerate. Subaerial volcanism apparently increased as deposition proceeded.The depositional basin was large, volcanically active and apparently shallow with subdued marginal relief. Felsic volcanoes formed topographic highs within the basin from which sheets of volcanically derived sediments interfingered with ultramafic-mafic volcanics. The Onverwacht Group of the Barberton Mountain Land, South Africa, is of similar age to the Warrawoona Group and probably represents a similar environment, but other greenstone belts may have formed in contrasting basins, possibly under differing tectonic regimes.     

香港安山-英安质古火山颈群

香港中侏罗世屯门组火山岩主要由安山质熔岩、凝灰岩和凝灰角砾岩夹少量凝灰质砂岩组成。其中凝灰角砾岩初期曾误认为是沉积砾岩。1990年香港地质调查组重新研究后,确认是火山成因的凝灰角砾岩。按岩相分析,屯门组火山岩可分为火山通道相安山-英安质熔岩和爆发角砾岩,还有爆发空落相凝灰角砾岩。火山通道相又可分为火山颈相和岩墙相,分布在屯门组东西两侧。在青山东麓,出露一列NNW向呈断续、线状分布的火山颈群。近年来新出版的《香港地质考察指引》和《香港工程地质实践》等地质著作仍将该区爆发角砾岩误认为是沉积成因的砾岩,在地质勘探和工程设计上造成混乱,导致不应有的经济和时间上的损失。本文综合最新研究成果并与世界各地同类火山岩的特征进行对比,确证火山通道相爆发角砾岩的存在,并发现呈线状分布的古火山颈群。     

Petrogenesis and tectonic setting of bimodal volcanism in the Sakoli Mobile Belt, Central Indian shield

The Sakoli Mobile Belt comprises bimodal volcanic rocks that include metabasalt, rhyolite, tuffs, and epiclastic rocks with metapelites, quartzite, arkose, conglomerate, and banded iron formation (BIF). Mafic volcanic rocks are tholeiitic to quartz‐tholeiitic with normative quartz and hypersthene. SiO₂ shows a large compositional gap between the basic and acidic volcanics, depicting their bimodal nature. Both the volcanics have distinct geochemical trends but display some similarity in terms of enriched light rare earth element–large ion lithophile element characteristics with positive anomalies for U, Pb, and Th and distinct negative anomalies for Nb, P, and Ti. These characteristics are typical of continental rift volcanism. Both the volcanic rocks show strong negative Sr and Eu anomalies indicating fractionation of plagioclases and K‐feldspars, respectively. The high Fe/Mg ratios for the basic rocks indicate their evolved nature. Whole rock Sm–Nd isochrons for the acidic volcanic rocks indicate an age of crystallization for these volcanic rocks at about 1675 ± 180 Ma (initial ¹⁴³Nd/¹⁴⁴Nd = 0.51017 ± 0.00017, mean square weighted deviate [MSWD] = 1.6). The εNd_t (t = 2000 Ma) varies between ?0.19 and +2.22 for the basic volcanic rock and between ?2.85 and ?4.29 for the acidic volcanic rocks. Depleted mantle model ages vary from 2000 to 2275 Ma for the basic and from 2426 to 2777 Ma for the acidic volcanic rocks, respectively. These model ages indicate that protoliths for the acidic volcanic rocks probably had a much longer crustal residence time. Predominantly basaltic magma erupted during the deposition of the Dhabetekri Formation and part of it pooled at crustal or shallower subcrustal levels that probably triggered partial melting to generate the acidic magma. The influence of basic magma on the genesis of acidic magma is indicated by the higher Ni and Cr abundance at the observed silica levels of the acidic magma. A subsequent pulse of basic magma, which became crustally contaminated, erupted as minor component along with the dominantly acidic volcanics during the deposition of the Bhiwapur Formation.     

A Pliocene shoaling basaltic seamount: Ba Volcanic Group at Rakiraki, Fiji

At Rakiraki in northeastern Viti Levu, the Pliocene Ba Volcanic Group comprises gently dipping, pyroxene-phyric basaltic lavas, including pillow lava, and texturally diverse volcanic breccia interbedded with conglomerate and sandstone. Three main facies associations have been identified: (1) The primary volcanic facies association includes massive basalt (flows and sills), pillow lava and related in-situ breccia (pillow-fragment breccia, autobreccia, in-situ hyaloclastite, peperite). (2) The resedimented volcaniclastic facies association consists of bedded, monomict volcanic breccia and scoria lapilli-rich breccia. (3) The volcanogenic sedimentary facies association is composed of bedded, polymict conglomerate and breccia, together with volcanic sandstone and siltstone-mudstone facies. Pillow lava and coarse hyaloclastite breccia indicate a submarine depositional setting for most of the sequence. Thick, massive to graded beds of polymict breccia and conglomerate are interpreted as volcaniclastic mass-flow deposits emplaced below wave base. Well-rounded clasts in conglomerate were reworked during subaerial transport and/or temporary storage in shoreline or shallow water environments prior to redeposition. Red, oxidised lava and scoria clasts in bedded breccia and conglomerate also imply that the source was partly subaerial. The facies assemblage is consistent with a setting on the submerged flanks of a shoaling basaltic seamount. The coarse grade and large volume of conglomerate and breccia reflect the high supply rate of clasts, and the propensity for collapse and redeposition on steep palaeoslopes. The clast supply may have been boosted by vigorous fragmentation processes accompanying transition of lava from subaerial to submarine settings. The greater proportion of primary volcanic facies compared with resedimented volcaniclastic and volcanogenic sedimentary facies in central and northwestern exposures (near Rakiraki) indicates they are more proximal than those in the southeast (towards Viti Levu Bay). The proximal area coincides with one of two zones where NW-SE-trending mafic dykes are especially abundant, and it is close to several, small, dome-like intrusions of intermediate and felsic igneous rocks. The original surface morphology of the volcano is no longer preserved, though the partial fan of bedding dip azimuths in the south and east and the wide diameter (exceeding 20 km) are consistent with a broad shield.     

Plate-plume-accretion tectonics in Proterozoic terrain of northeastern Rajasthan, India: Evidence from mafic volcanic rocks of north Delhi fold belt

Abstract   The northern part of the Aravalli mountain belt of northwestern Indian shield is broadly composed of three Proterozoic volcano-sedimentary domains, i.e. the Bayana, the Alwar and the Khetri basins, comprising collectively the north Delhi fold belt. Major, trace and rare earth element concentrations of mafic volcanic rocks of the three basins exhibit considerable diversity. Bayana and Alwar volcanics are typical tholeiites showing close similarity with low Ti–continental flood basalts (CFB) with the difference that the former shows enriched and the latter flat incompatible trace element and rare earth element (REE) patterns. However, the Khetri volcanics exhibit a transitional composition between tholeiite and calc-alkaline basalts. It appears that the melts of Bayana and Alwar tholeiites were generated by partial melting of a common source within the spinel stability field possibly in the presence of mantle plume. During ascent to the surface the Bayana tholeiites suffered crustal contamination but the Alwar tholeiites erupted unaffected. Geochemically, the Khetri volcanics are arc-like basalts which were generated in a segment of mantle overlying a Proterozoic subduction zone. It is suggested that at about 1800 Ma the continental lithosphere in northeastern Rajasthan stretched, attenuated and fractured in response to a rising plume. The produced rifts have undergone variable degrees of crustal extension. The extension and attenuation of the crust facilitated shallowing of the asthenosphere which suffered variable degree of melting to produce tholeiitic melts – different batches of which underwent different degrees of lithospheric contamination depending upon the thickness of the crust in different rifted basins. The occurrence of subduction-related basaltic rocks of Khetri Belt suggests that a basin on the western margin of the craton developed into a mature oceanic basin.     

Evolution of an englacial volcanic ridge: Pillow Ridge tindar, Mount Edziza volcanic complex, NCVP, British Columbia, Canada

Glaciovolcanic deposits are critical for documenting the presence and thickness of terrestrial ice-sheets, and for testing hypotheses about inferred terrestrial ice volumes based on the marine record. Deposits formed by the coincidence of volcanism and ice at the Mount Edziza volcanic complex (MEVC) in northern British Columbia, Canada, preserve an important record for documenting local and possibly regional ice dynamics. Pillow Ridge, located at the northwestern end of the MEVC, formed by ice-confined, fissure-fed eruptions. It comprises predominantly pillow lavas and volcanic breccias of alkaline basalt composition, with subordinate finer-grained volcaniclastic deposits and dykes. The ridge is presently  4 km long,  1000 m in maximum width, and  600 m high. Fifteen syn- and post-eruptive lithofacies are recognized in excellent exposures along the glacially dissected western side of the ridge. We recognize five lithofacies associations: (1) poorly sorted tuff breccia and dykes, (2) proximal pillow lava, dykes and tuff breccia, (3) distal pillow lava, poorly sorted conglomerate and well-sorted volcanic sandstone, (4) interbedded tuff, lapilli tuff, and tuff breccia units, and (5) heterolithic volcanogenic conglomerate and sandstone. Given the abundance of pillow lavas and the lack of surrounding topographic barriers capable of impounding water, we agree with Souther [Souther, J.G., 1992. The late Cenozoic Mount Edziza volcanic complex. Geol. Soc. Can. Mem., vol. 420. 320 pp] that the bulk of the edifice formed while confined by ice, but have found evidence for a more complex and variable eruption history than that which he proposed. Preliminary estimates of water-ice depths derived from FTIR analyses of H₂O give ranges of 300 to 680 m assuming 0 ppm CO₂, and 857 to 1297 m assuming 25 ppm CO₂. Variations in depth estimates among samples may indicate that water/ice depths changed during the evolution of the ridge, which is consistent with our interpretations for the origins of different lithofacies associations. Given that the age of the units are likely to be ca. 0.9 Ma [Souther, J.G., 1992. The late Cenozoic Mount Edziza volcanic complex. Geol. Soc. Can. Mem., vol. 420. 320 pp], Pillow Ridge may be the best documentation of a regional high stand of the Cordilleran Ice Sheet (CIS) in the middle Pleistocene, and an excellent example of the lithofacies and stratigraphic complexities produced by variations in water levels during a prolonged glaciovolcanic eruption.     

油气勘探新领域:火山岩油气藏——松辽盆地大型火山岩气田发现的启示

通过观念转变和理论与技术创新,大庆油田在松辽盆地徐家围子断陷深层火山岩天然气勘探获得重大突破,使火山岩由原来的油气勘探"禁区"变为"靶区".从而带动了全国的火山岩油气勘探,促使国内油气储量的不断增长.研究表明,各类火山岩均有可能成为良好的储层.与沉积岩相比,火山岩在盆地深层具有体积大、储层物性受埋深影响小、孔渗条件好等...     

Late Miocene valley-confined subglacial volcanism in northern Alexander Island,Antarctic Peninsula

Isolated, Late Miocene volcanogenic sequences in northern Alexander Island, Antarctic Peninsula, form an unusual, cogenetic association of volcaniclastic, sandy-gravelly lithofacies (including tillites) and volcanic (lava/hyalocalstite) lithofacies. Using simple lithofacies analysis and theoretical considerations of hydrodynamic effects of subglacial eruptions, valley-confined volcanic activity beneth thin, wet-based ice is suggested. The Alexander Island successions are complete enough to be regarded as model sequences for this uncommonly recorded type of eruptive/depositional activity. The sedimentary lithofacies represent resedimented tuffs and meltout or flow tills, which were probably deposited in subglacial ice tunnels eroded or enlarged by volcanically heated meltwater. The volcanic lithofacies formed by the interaction of hot magma with the ice tunnel walls (generating abundant meltwater) and water-saturatedsediments, resulting in the formation of heterogeneous masses of lava and hyaloclastite. There is no obvious sequence organisation in the sedimentary sections. This is probably due to a complex interplay of eruption-related and environmental hydrodynamic factors affecting the relative proportions of water and entrained sediment.     

安徽省霍山县东溪-南关岭金矿地质特征与成矿条件

东溪-南关岭金矿为北淮阳东段发现的第一个原生金矿,产于磨子潭-晓天中生代火山盆地边缘,容矿围岩为安山质-英安质火山岩,矿化和蚀变受桐柏-桐城深大断裂带的次级构造带控制。该金矿发育陡倾斜的脉状矿体和缓倾斜的似层状矿体,成因类型为冰长石-绢云母型浅成低温热液金矿。火山岩盆地之下的变质基底可能起到了初始矿源层作用,桐柏-桐城断裂带及其次级构造破碎带为重要的导岩导矿构造,早白垩世强烈的岩浆活动提供了热源、动力源和部分矿源。参照国内外类似金矿的特征,认为本区成矿地质条件良好,有可能隐伏着与石英正长岩体有关的细脉浸染型矿化,晓天火山盆地具有良好的找矿前景。     

Depositional model of Permian Luodianian volcanic island and its impact on the distribution of fusulinid assemblage in southern Qinghai, Northwest China

Pan-riftizational tectonic activity reached climax at Luodianian (Permian) in the East Tethyan Domain, Qinghai-Tibet Plateau. Because of eruptive volcanics and influence of terrigenous materials, a complex volcanic-sedimentary landform formed on the sea floor in southern Qinghai. Four sedimentary facies types were recognized based on detailed field mapping. Spatially, platform facies volcanic-limestone type was located at the center belt approximately trending NWW, surrounded by shallow water slope facies tuff/tuffite type at the two flanks and deep water slope facies breccia/calcirudite at the most outside. The depression facies sandstone-mudstone type, which comprised mainly mudstone, de-posited between volcanic islands (platform facies volcanic-limestone type). Based on the field map-ping and stratigraphic section data, seven rift-related sedimentary facies were recognized and a depo-sitional model for volcanic island was proposed. It is revealed that some volcanic island chain formed quickly and intermittently in the Qamdo Block during violent eruption, and small carbonate reef, shoal, platform occurred above or on edge of volcanic island, and some slope sedimentary facies surrounded volcano island chain during dormant period of volcanic activities. Three types of fusulinid assemblages were distinguished in the carbonate rocks, which deposited in varied positions of a palaeo-volcanic island: (1) Misellina-Schwagerina assemblage occurred above or on edge of volcanic island, (2) Para-fusulina assemblage was located at restricted depression facies among volcanic islands or carbonate platform, and (3) the reworked Pseudofusulina-Schwagerina assemblage occurred at slope facies near margin of volcanic island, which originally deposited in the shallow-water carbonate platform, then collapsed along the volcanic island margin with fusulinid-bearing grain-supported carbonate con-glomerate or calcirudite, and finally re-deposited on the deeper slope. The sedimentary sequence re-sulting from calm shallow water was deposited at the interior of the Qamdo Block from the Devonian to early Early Permian. At the beginning of the peak period of activity of pan-riftzation (Luodianian), al-ternate volcanic island and shallow marine environment within continent crust came into being. Uni-form and stable shallow-water carbonate platform was formed during the Xiangboan. This suggested that the activity of rift basin was evidently weakened. Subsequently the instability of the basin appre-ciably increased with the occurrence of basalt in late Kuhfengian. At last the whole Qamdo Block turned into the closure period of rift during the Late Permian.     

Geochemical variation with time in the Cenezoic volcanic rocks of southwest Hokkaido, Japan

Abundances of major and trace elements were determined for the Tertiary volcanic rocks from SW Hokkaido. The Late Miocene to Pliocene volcanic rocks of this region show geochemical features similar to those of the Quaternary rocks, that is, K/Si, Th/Si and LREE/HREE ratios increasing across the arc, east to west, from the Pacific to the Japan Sea side. In contrast, the Early Miocene volcanic rocks, which are geographically restricted to the Japan Sea coast, are distinct from all later volcanics and show “within-plate” characteristics — in particular, high concentrations of HFS elements. The Quaternary basalts have low Hf/Yb ratios and Hf contents, whereas the Early Miocene basalts are high in Hf/Yb and Hf, similar to Hawaiian alkali basalts. The compositional variation with time may result from the progressive depletion of incompatible HFS elements in the mantle source. Th/Yb ratios increase from Early Miocene to Quaternary, possibly reflecting increase in the LIL element contribution to the mantle source during that time.     

Geochemistry of calc-alkaline volcanics in northwestern Nigeria,and a possible Pan-African suture zone

Major and trace element characteristics of dacites and rhyolites overlying and intruding basement rocks in northwestern Nigeria most closely resemble those of intracontinental orogenic volcanic associations. REE patterns point to a deep-seated source for the magmas, perhaps involving garnet fractionation at mantle depths and low-pressure plagioclase fractionation. The occurrence of calc-alkaline volcanics, small basic-ultrabasic complexes and major transcurrent faulting, is consistent with the presence of a Pan-African suture zone in northwestern Nigeria.     

Field and geochemical data bearing on the development of a mesozoic volcano-tectonic rift zone and back-arc basin in southernmost South America

A broad zone of dominantly subaerial silicic volcanism associated with regional extensional faulting developed in southern South America during the Middle Jurassic, contemporaneously with the initiation of plutonism along the present Pacific continental margin. Stratigraphic variations observed in cross sections through the silicic Jurassic volcanics along the Pacific margin of southernmost South America indicate that this region of the rift zone developed as volcanism continued during faulting, subsidence and marine innundation. A deep, fault-bounded submarine trough formed near the Pacific margin of the southern part of the volcano-tectonic rift zone during the Late Jurassic. Tholeiitic magma intruded within the trough formed the mafic portion of the floor of this down-faulted basin. During the Early Cretaceous this basin separated an active calc-alkaline volcanic arc, founded on a sliver of continental crust, from the then volcanically quiescent South American continent. Geochemical data suggest that the Jurassic silicic volcanics along the Pacific margin of the volcano-tectonic rift zone were derived by crustal anatexis. Mafic lavas and sills which occur within the silicic volcanics have geochemical affinities with both the tholeiitic basalts forming the ophiolitic lenses which are the remnants of the mafic part of the back-arc basin floor, and also the calc-alkaline rocks of the adjacent Patagonian batholith and their flanking lavas which represent the eroded late Mesozoic calc-alkaline volcanic arc. The source of these tholeiitic and calc-alkaline igneous rocks was partially melted upper mantle material. The igneous and tectonic processes responsible for the development of the volcano-tectonic rift zone and the subsequent back-arc basin are attributed to diapirism in the upper mantle beneath southern South America. The tectonic setting and sequence of igneous and tectonic events suggest that diapirism may have been initiated in response to subduction.     

Geochemistry and Ar/Ar geochronology of Miocene volcanic rocks from the Karaburun Peninsula: Implications for amphibole-bearing lithospheric mantle source,Western Anatolia

New geochemical and ⁴⁰Ar/³⁹Ar age data are presented from the Neogene volcanic units of the Karaburun Peninsula, the westernmost part of Western Anatolia. The volcanic rocks in the region are associated with Neogene lacustrine deposition and are characterized by (1) olivine-bearing basaltic-andesites to shoshonites (Karaburun volcanics), high-K calc-alkaline andesites, dacites and latites (Yaylaköy, Arma?anda? and Kocada? volcanics) of ~ 16–18 Ma, and (2) mildly-alkaline basalts (Ovac?k basalt) and rhyolites (Urla volcanics) of ~ 11–12 Ma. The first group of rocks is enriched in LILE and LREE with respect to the HREE and HFSE on N-MORB-normalised REE and multi-element spider diagrams. They are comparable geochemically with volcanic rocks in the surrounding regions such as Chios Island and other localities in Western Anatolia. The Ovac?k basalt is geochemically similar to the first stage early–middle Miocene volcanic rocks but differs from NW Anatolian late Miocene alkali basalts.     

Geochemistry and spatial distribution of late-Paleozoic mafic volcanic rocks in the surrounding areas of the Gonghe Basin: Implications for Majixueshan triple-junction and east Paleotethyan archipelagic ocean

The late-Paleozoic mafic volcanic rocks occurring in the surrounding areas of the Gonghe basin are distributed in the A’nyêmaqên ophiolite zone, Zongwulong tectonic zone and Kuhai-Saishitang volcanic zone. The mafic volcanics in the A’nyêmaqên zone formed an ancient ridge-centered hotspot around the Majixueshan OIB, the Kuhai-Saishitang mafic rocks consist of E-MORB and continental rift basalts and the Zongwulong volcanic rocks are enriched N-MORB. The regionally low Nb/U and Ce/Pb ratios reflect the influence of the OIB material on the mafic magma source. From geochemistry, spatial distribution and tectonic relationship of the mafic rocks, an ancient triple-junction centered at the Majixueshan can be inferred. The existence of the Kuhai-Saishitang aulacogen may have provided a tectonic channel for the Majixueshan OIB materials metasomatizing the magma source for the Zongwulong rocks. The formation of the triple-junction and the rifting of the Zongwulong zone have separated the orogens and massifs in the region.

     

Volcanological and magmatological evolution of Stromboli volcano (Aeolian Islands): The roles of fractional crystallization,magma mixing,crustal contamination and source heterogeneity

The present paper reports the results of a detailed stratigraphical, petrological and geochemical investigation on the island of Stromboli, Aeolian arc, Southern Tyrrhenian sea. Major and trace element data determined on a large quantity of samples from well-established stratigraphic positions indicate that the magmatological evolution of the island through time was more complex than previously known. The activity of the exposed part of Stromboli, which occurred over a time span of about 100 000 years, started with the emission of high-K calc-alkaline (HKCA) volcanics, which were covered by calc-alkaline (CA), shoshonitic (SHO), high-K calc-alkaline (HKCA) and potassic (KS) products. The most recent activity consists of HKCA lavas and the present-day SHO-basaltic volcanics emitted by mildly explosive “strombolian” activity. Most of the products are lavas, with minor amounts of pyroclastic rocks emplaced mainly during the early stages of activity. The transition from the SHO to the KS cycle was associated with the collapse of the upper part of the volcanic apparatus; the transition from KS to the present-day SHO activity has been found to have occurred at the time of the sliding of the western portion of the volcano that generated the “Sciara del Fuoco” depression. The rock series cropping out at Stromboli show variable enrichment in potassium, incompatible trace elements and radiogenic Sr which increase from CA through HKCA, and SHO up to KS rocks. Major, trace element and Sr-isotopic data agree in indicating that the HKCA and SHO series evolved by crystal/liquid fractionation starting from different parental liquids, whereas crustal assimilation appears to have been the leading process during the evolution of KS volcanics. Mixing processes also played a role although they can be well documented only when they occurred between magmas with different isotopic and geochemical characteristics. Geochemical modelling based on trace element and isotopic data indicates that the mafic magmas of the different volcanic series may be generated by melting of an upper mantle heterogeneously enriched in incompatible elements and radiogenic Sr by addition, via subduction, of different amounts of crustal material. Geochemical data, however, are also in agreement with the alternative hypothesis that the most mafic magmas of the different series have been generated by combined processes of fractional crystallization, assimilation and mixing of a CA magma in a deep-sited magma chamber; the mafic magmas formed by these complex processes were successively emplaced in a shallow reservoir where they evolved by simple fractional crystallization (HKCA and SHO series) and by assimilation of crustal material (KS). The occurrence of changes in the geochemical signatures of the magmas at the time of the structural modification of the volcano is believed to favour the hypothesis that the variable composition observed in the volcanic rocks of Stromboli is the result of processes occurring within the volcanic system.     

The Geochemistry of Volcanogenic Mineralization in the Northwestern Segment of the Pacific Ore Belt: Northeast Russia

This paper considers the geochemistry of volcanogenic mineralization in the northeastern segment of the Pacific Ore Belt (Northeast Russia). We give new evidence for the compositions and concentrations of trace and rare-earth elements (REE) in the ores of volcanogenic fields: Au-Ag epithermal (of various types and ages), Cu-Mo-Au porphyritic, Au-Bi related to granitoidal intrusions, Sn-Ag subvolcanic and kies polymetallic enriched in Au and Ag, as well as REEs in alkaline volcanic rocks. Geochemical signatures have been compiled for 17 formation types of volcanogenic fields. It was found that the ore-forming fluids in most fields belonged to an NaCl-H₂O hydrothermal system that was enriched in Cl relative to F; the values of Y/Ho in the ores of nearly all types correspond with the interval of ratios characteristic for present-day hydrothermal fluids in backarc basins; most of the ores that we studied had near-chondrite spectra with configurations similar to those of the REE spectra in volcanic rock sequences of the andesite-diorite series. Comparative analysis of REE spectra in the distribution of trace elements over classes of gold concentration shows synchronous enrichment of ores in similar sets of trace elements. The high Co/Ni ratio in volcanogenic ores probably reflects the superposition of a later magmatic fluid upon an earlier mineralization. Samples from ores of volcanogenic fields, except for Kuroko, show δCe and δEu varying from negative to mildly positive values, thus indicating low-oxidizing conditions during deposition. It was found for Au-Ag epithermal ores that they are enriched in a wide range of trace elements; they have low concentrations of REEs, the light REEs are more abundant than the heavy ones, and the Eu anomalies vary considerably from small negative to low and high positive values. The results provide evidence of an exhalation hydrothermal origin of the Khotoidokh field. It has been shown that the REEs in the ores of the Bol’shoe field are of the type that is most valuable to industry. The results can be used to deal with practical problems: determining the formation type and evaluating the industrial value of a field; detecting accessory components in ores; and discriminating between the types of geochemical anomalies (in rocks or in soil) and stray fluxes as to the potential of a field.