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1.
Three Al-Cr exchange isotherms at 1,250°, 1,050°, and 796° between Mg(Al, Cr)2O4 spinel and (Al, Cr)2O3 corundum crystalline solutions have been studied experimentally at 25 kbar pressure. Starting from gels of suitable bulk compositions, close approach to equilibrium has been demonstrated in each case by time studies. Using the equation of state for (Al, Cr)2O3 crystalline solution (Chatterjee et al. 1982a) and assuming that the Mg(Al, Cr)2O4 can be treated in terms of the asymmetric Margules relation, the exchange isotherms were solved for Δ G *, and . The best constrained data set from the 1,250° C isotherm clearly shows that the latter two quantities do not overlap within three standard deviations, justifying the choice of asymmetric Margules relation for describing the excess mixing properties of Mg(Al, Cr)2O4 spinels. Based on these experiments, the following polybaric-polythermal equation of state can be formulated: , P expressed in bars, T in K, G m ex and W G,i Sp in joules/mol. Temperature-dependence of G m ex is best constrained in the range 796–1,250° C; extrapolation beyond that range would have to be done with caution. Such extrapolation to lower temperature shows tentatively that at 1 bar pressure the critical temperature, T c, of the spinel solvus is 427° C, with dTc/dP≈1.3 K/kbar. The critical composition, X c, is 0.42 , and changes barely with pressure. Substantial error in calculated phase diagrams will result if the significant positive deviation from ideality is ignored for Al-Cr mixing in such spinels.  相似文献   

2.
Metamorphosed pelitic rocks from Mica Creek, British Columbia contain sillimanite, kyanite with minor fibrolite and andalusite-bearing quartz pods. Mineral equilibria were used to infer peak P-T conditions and fluid compositions in equilibrium with the solid phases. Fluid inclusions in three schist samples appear to be good indicators of conditions affecting those rocks during and after peak metamorphic conditions. In samples from two localities, fluid inclusions from schist and quartz-rich segregations have densities appropriate to the peak metamorphic conditions. The observed compositions for these fluids (low salinity with 12 mole % dissolved CO2) agree with calculated values of 0.84 to 0.85, based upon paragonite-quartz-albite-Al2SiO5 equilibria. The fluids unmixed as the schists were uplifted and cooled; fluid inclusions trapped during this stage outline a solvus in the CO2-H2O-NaCl system. A later influx of fluids containing CH4 and N2 accompanied formation of andalusite-bearing plagioclaserich segregations. The restricted association of andalusite-bearing pods and low density fluids suggest a localized but pervasive fluid influx during uplift. Preservation of high density fluid inclusions during uplift and erosion, coupled with evidence for unmixing of H2O- and CO2-rich fluids on the solvus, provide constraints on the P-T uplift path.  相似文献   

3.
APL computer programs for the thermodynamic calculation of devolatilization and solid-solid equilibria operate using stored values for the molar volume and entropy of solids, the free energies of H2O and CO2, and the free energies of formation for 110 geologically-important phases. P-T-X CO 2 calculations of devolatilization equilibria can be made at pressures from 0.2 through 10 kb, and temperatures from 200 through 1,000° C. P-T-X calculations of solid-solid equilibria may be accomplished at pressures to 30 kb and temperatures to 1,000° C. Calculations can be extrapolations from experimental points, or direct calculations from thermochemical data alone. Options are available in these programs to consider effects of: real vs. ideal gas mixing, thermal expansion and compressibility, solid solution, fluid pressure differing from solid pressure, and uncertainties in high-temperature entropies.A collection of thermodynamic data programs accompanies the programs for calculating P-T-X CO 2 equilibria. Over a wide range of physical conditions, the data functions report free energies, entropies, fugacities of H2O and CO2, high temperature entropies of solids, and activities of components in H2O-CO2 mixtures.List of Symbols Activity of H2O and CO2 - Gf Free energy of formation of a phase from elements - Gr Free energy change of reaction - G r o Standard state free energy change of a reaction - Free energies of pure H2O and CO2 - H r o Standard state enthalpy change for a reaction - K Equilibrium constant - R Gas constant - S r o Standard state entropy change of reaction - S s o Standard state entropy change of solids in a reaction - Vs o Standard state volume change of a reaction - Vs o Standard state volume change of solids in a reaction - Mole fraction of H2O and CO2 - Activity coefficient of H2O and CO2  相似文献   

4.
The proportions of species in a C-O-H-S fluid in equilibrium with graphite, pyrite and pyrrhotite were calculated for a range of pressure, temperature and conditions, using the equilibrium constants and mass balance method, for ideal and non-ideal mixing in the fluid. Under typical metamorphic conditions, H2O, CO2, CH4 and H2S are the principal fluid species with H2S favored by higher temperatures, lower pressures and lower conditions. The dominance of H2S in the fluid at high temperatures leads to values of becoming significantly less than 1, and causes hydrous minerals to dehydrate at lower temperatures than the case when . The production of H2S-bearing fluids provides a mechanism for the selective transfer of sulfur from a graphite-pyrite-pyrrhotite bearing pelite into a pluton via a fluid phase, without requiring wholesale melting and assimilation of rocks. Such a process is feasible if a magma is intruded by stoping, which allows a significant volume of pelite country rock to be raised rapidly to temperatures approaching that of the magma. H2S-bearing fluids produced from graphite-pyrite-pyrrhotite pelites (due either to magmatic intrusion or regional metamorphism) may also mobilize ore-forming metals as sulfide complexes.  相似文献   

5.
Near-liquidus melting experiments were performed on a high-K latite at fO2's ranging from iron-wustite-graphite (IWG) to nickel-nickel oxide (NNO) in the presence of a C-O-H fluid phase. Clinopyroxene is a liquidus phase under all conditions. At IWG , the liquidus at 10 kb is about 1,150° C but is depressed to 1,025° C at NNO and . Phlogopite and apatite are near-liquidus phases, with apatite crystallizing first at pressures below 10 kb. Phlogopite is a liquidus phase only at NNO and high . Under all conditions the high-K latites show a large crystallization interval with phlogopite becoming the dominant crystalline phase with decreasing temperature. Increasing fO2 affects phlogopite crystallization but the liquidus temperature is essentially a function of . The chemical compositions of the near-liquidus phases support formation of the high-K latites under oxidizing conditions (NNO or higher) and high . It is concluded from the temperature of the H2O-saturated liquidus at 10 kb, the groundmass: crystal ratio and presence of chilled latite margins around some xenoliths that the Camp Creek high-K latite magma passed thru the lower crust at temperatures of 1,000° C or more.  相似文献   

6.
Trace element analyses of 1-atm and high-pressure experiments show that in komatiite and peridotite, the olivine (OL)/liquid (L) distribution coefficient for Al2O3 ( ) increases with pressure and temperature. Olivine in equilibrium with liquid accepts as much as 0.2 wt% Al2O3 in solution at 6 GPa. Convergence to equilibrium compositions at this high level is shown by cation diffusion of Al into synthetic forsterite crystals of low-Al contents in the presence of melt. Convergence to low-Al equilibrium compositions at lower P and T is shown by diffusion of Al out of synthetic forsterite with high initial Al content. Isobaric and isothermal experimental data subsets reveal that temperature and pressure variations both have real effects on . Variation in silicate melt composition has no detectable effect on within the limited range of experimentally investigated mixtures. Least-squares regression for 24 experiments, using komatiite and peridotite, performed at 1 atm to 6 GPa and 1300 to 1960°C, gives the best fit equation: Increase in with increasingly higher-pressure melting is consistent with incorporation of a spinel-like component of low molar volume into olivine, although other substitutions possibly involving more complex coupling cannot be ruled out. High P-T ultrabasic melting residues, if pristine, may be recognized by the high calculated from microprobe analyses of Al2O3 concentrations in residual olivines and estimated Al2O3 concentration in the last liquid removed. In general the low levels of Al in natural olivine from mantle xenoliths suggest that pristine residues are rarely recovered.  相似文献   

7.
Near-liquidus phase relationships of a spinel lherzolite-bearing olivine melilitite from Tasmania were investigated over a P, T range with varying , , and . At 30 kb under MH-buffered conditions, systematic changes of liquidus phases occur with increasing ( = CO2/CO2 +H2O+olivine melilitite). Olivine is the liquidus phase in the presence of H2O alone and is joined by clinopyroxene at low . Increasing eliminates olivine and clinopyroxene becomes the only liquidus phase. Further addition of CO2 brings garnet+orthopyroxene onto the liquidus together with clinopyroxene, which disappears with even higher CO2. The same systematic changes appear to hold at higher and lower pressures also, only that the phase boundaries are shifted to different . The field with olivine- +clinopyroxene becomes stable to higher with lower pressure and approaches most closely the field with garnet+orthopyroxene+clinopyroxene at about 27 kb, 1160 °C, 0.08 and 0.2 (i.e., 6–7% CO2+ 7–8% H2O). Olivine does not coexist with garnet+orthopyroxene+clinopyroxene under these MH-buffered conditions. Lower oxygen fugacities do not increase the stability of olivine to higher and do not change the phase relationships and liquidus temperatures drastically. Thus, it is inferred that olivine melilitite 2927 originates as a 5% melt (inferred from K2 O and P2O5 content) from a pyrolite source at about 27kb, 1160 dg with about 6–7% CO2 and 7–8% H2O dissolved in the melt. The highly undersaturated character of the melt and the inability to find olivine together with garnet and orthopyroxene on the liquidus (in spite of the close approach of the respective liquidus fields) can be explained by reaction relationships of olivine and clinopyroxene with orthopyroxene, garnet and melt in the presence of CO2.  相似文献   

8.
Ignimbrites from the central North Island consist mainly of glass or its devitrified product (70–95%); their phenocryst mineralogy is varied and includes plag., hyp., ti-mag., ilm., aug., hblende, biot., san., qtz, ol., with accessory apatite, zircon and pyrrhotite. The Fe-Mg minerals can be used to divide the ignimbrites into four groups with hyp.+aug. reflecting high quench temperatures and biot.+hblende +hyp.+aug., low quench temperatures. Oxygen fugacities lie above the QMF buffer curve and even in ignimbrites with low crystal contents the solid phases apparently buffered fO2. Some ignimbrites contain the assemblage actinolite, gedrite, magnetite and hematite, reflecting post-eruption oxidation. The mineralogy also allows estimation of using pyrrhotite and thence , . The assemblage biotite-sanidine can be used to estimate and thence . Water fugacity is calculated in a variety of ways using both biotite and hornblende as well as the combining reaction . It is high and approaches P total in most ignimbrites (~4kb) but is lower in unwelded pumice breccias. Comparison of temperature estimates using mineral geothermometers for the various phenocryst phases suggests that the ignimbrite magmas showed temperature differences of 60–100 °C and pressure differences of several kilobars. Individual magma chambers therefore, would have extended over several kilometres vertically. The chemical potential of water may have been constant through the magma.  相似文献   

9.
The occurrence of critical assemblages among antigorite, diopside, tremolite, forsterite, talc, calcite, dolomite and magnesite in progressively metamorphosed ophicarbonate rocks, together with experimental data, permits the construction of phase diagrams in terms of the variables P, T, and composition of a binary CO2-H2O fluid. Equilibrium constants are given for the 30 equilibria that describe all relations among the above phases. Ophicalcite, ophidolomite, and ophimagnesite assemblages occupy partially overlapping fields in the diagram. The upper temperature limit of ophicalcite rocks lies below that of ophidolomite and ophimagnesite. The fluid phase in ophicarbonate rocks has 0.8$$ " align="middle" border="0"> , and there are indications that during their progressive metamorphism is approximately equal to P total.  相似文献   

10.
A great wealth of analytical data for fluid inclusions in minerals indicate that the major species of gases in fluid inclusions are H2O, CO2, CO, CH4, H2 and O2. Three basic chemical reactions are supposed to prevail in rock-forming and ore-forming fluids: $$\begin{gathered} H_2 + 1/2{\text{ O}}_{\text{2}} = H_2 O, \hfill \\ CO + 1/2{\text{ O}}_{\text{2}} = CO_2 , \hfill \\ CH_4 + 2{\text{O}}_{\text{2}} = CO_2 + 2H_2 O, \hfill \\ \end{gathered} $$ and equilibria are reached among them. \(\lg f_{O_2 } - T,{\text{ }}\lg f_{CO_2 } - T\) and Eh-T charts for petrogenesis and minerogenesis in the supercritical state have been plotted under different pressures. On the basis of these charts \(f_{O^2 } ,{\text{ }}f_{CO_2 } \) , Eh, equilibrium temperature and equilibrium pressure can be readily calculated. In this paper some examples are presented to show their successful application in the study of the ore-forming environments of ore deposits.  相似文献   

11.
The diffusion of water in a peralkaline and a peraluminous rhyolitic melt was investigated at temperatures of 714–1,493 K and pressures of 100 and 500 MPa. At temperatures below 923 K dehydration experiments were performed on glasses containing about 2 wt% H2O t in cold seal pressure vessels. At high temperatures diffusion couples of water-poor (<0.5 wt% H2O t ) and water-rich (~2 wt% H2O t ) melts were run in an internally heated gas pressure vessel. Argon was the pressure medium in both cases. Concentration profiles of hydrous species (OH groups and H2O molecules) were measured along the diffusion direction using near-infrared (NIR) microspectroscopy. The bulk water diffusivity () was derived from profiles of total water () using a modified Boltzmann-Matano method as well as using fittings assuming a functional relationship between and Both methods consistently indicate that is proportional to in this range of water contents for both bulk compositions, in agreement with previous work on metaluminous rhyolite. The water diffusivity in the peraluminous melts agrees very well with data for metaluminous rhyolites implying that an excess of Al2O3 with respect to alkalis does not affect water diffusion. On the other hand, water diffusion is faster by roughly a factor of two in the peralkaline melt compared to the metaluminous melt. The following expression for the water diffusivity in the peralkaline rhyolite as a function of temperature and pressure was obtained by least-squares fitting:
where is the water diffusivity at 1 wt% H2O t in m2/s, T is the temperature in K and P is the pressure in MPa. The above equation reproduces the experimental data (14 runs in total) with a standard fit error of 0.15 log units. It can be employed to model degassing of peralkaline melts at water contents up to 2 wt%.  相似文献   

12.
Calcite in schists of the metamorphic complex at Naxos is depleted both in 13C and in 18O with respect to massive marbles. This effect is attributed to isotope exchange with circulating CO2-rich fluids, which had an >0.5 according to fluid inclusions. The carbon isotopic composition of the calcites is close to equilibrium with fluid inclusion CO2 at metamorphic temperatures. Mass balance calculations assuming initial 13C values of 0 for calcite and –5 for the fluid, give integrated fluid/rock volume ratios between 0.1 and 2.0. Such high fluid/rock ratios are supported by observations on the distribution of CO2/H2O ratios of fluid inclusions, carbon isotopic compositions of fluid inclusion CO2 and oxygen isotope systematics of silicates.  相似文献   

13.
In the 6 component system CaO-MgO-Al2O3-SiO2-CO2-H2 with 9 solid phases (quartz, plagioclase, epidote, tremolite, talc, chlorite, magnesite, calcite, dolomite) and a fluid phase, all 17 possible fluid-absent reactions have been set up and balanced. Using molar entropy and volume data for the solid phases, these reactions are arranged in P-T space about the 8 possible fluid-absent invariant points after the method of Schreinemakers. Field observations in Ordovician greenschist facies basic volcanics at Sofala N.S.W., indicate that neither talc+epidote nor magnesite+calcite are stable under the conditions of metamorphism. Assuming these conditions to apply to the theoretical study here, the fluid-absent invariant points are arranged in a relative fashion with fluid-absent reactions subdividing P-T space into smaller areas.A scheme which permits a fluid of composition (i.e. a fluid containing CO2 and H2O together with other components), is modeled by treating H2O as a mobile component independent of CO2, and by allowing values that lie off the locus of binary H2O-CO2. Taking into account that neither talc+epidote nor magnesite +calcite is to be permitted, the fluid scheme is used to set up and balance all 39 possible fluid-bearing reactions. These are then arranged about 20 valid fluid-bearing invariant points in space after the method of Korzhinskii and Sehreinemakers.A characteristic solid phase assemblage is defined for each P-T area using chemographic relations inherent from the fluid-absent boundary reactions. The fluid-bearing invariant points that have a solid assemblage compatible with the characteristic assemblage in a particular P-T area are stable within the P-T regime of that area. When these stable fluidbearing invariant points are arranged in a relative fashion in space, they outline a fluid grid which can be used to study the possible effects of local variation in X fluid over the particular P-T regime.Symbols Used U chemical potential - S entropy - V molar volume - n coefficient of a phase in a reaction - X mole fraction - T temperature - P pressure - F number of degrees of freedom - C number of components - p number of phases - s solid - slope of reaction - 1 quartz - 2 plagioclase - 3 epidote - 4 tremolite - 5 talc - 6 chlorite - 7 dolomite - 8 magnesite - 9 calcite  相似文献   

14.
P, T, \(X_{{\text{CO}}_{\text{2}} }\) relations of gehlenite, anorthite, grossularite, wollastonite, corundum and calcite have been determined experimentally at P f =1 and 4 kb. Using synthetic starting minerals the following reactions have been demonstrated reversibly
  1. 2 anorthite+3 calcite=gehlenite+grossularite+3 CO2.
  2. anorthite+corundum+3 calcite=2 gehlenite+3 CO2.
  3. 3anorthite+3 calcite=2 grossularite+corundum+3CO2.
  4. grossularite+2 corundum+3 calcite=3 gehlenite+3 CO2.
  5. anorthite+2 calcite=gehlenite+wollastonite+2CO2.
  6. anorthite+wollastonite+calcite=grossularite+CO2.
  7. grossularite+calcite=gehlenite+2 wollastonite+CO2.
In the T, \(X_{{\text{CO}}_{\text{2}} }\) diagram at P f =1 kb two isobaric invariant points have been located at 770±10°C, \(X_{{\text{CO}}_{\text{2}} }\) =0.27 and at 840±10°C, \(X_{{\text{CO}}_{\text{2}} }\) =0.55. Formation of gehlenite from low temperature assemblages according to (4) and (2) takes place at 1 kb and 715–855° C, \(X_{{\text{CO}}_{\text{2}} }\) =0.1–1.0. In agreement with experimental results the formation of gehlenite in natural metamorphic rocks is restricted to shallow, high temperature contact aureoles.  相似文献   

15.
The biotite zone assemblage: calcite-quartz-plagioclase (An25)-phengite-paragonite-chlorite-graphite, is developed at the contact between a carbonate and a pelite from British Columbia. Thermochemical data for the equilibrium paragonite+calcite+2 quartz=albite+ anorthite+CO2+H2O yields: $$\log f{\text{H}}_{\text{2}} {\text{O}} + \log f{\text{CO}}_{\text{2}} = 5.76 + 0.117 \times 10^{ - 3} (P - 1)$$ for a temperature of 700°K and a plagioclase composition of An25. By combining this equation with equations describing equilibria between graphite and gas species in the system C-H-O, the following partial pressures: \(P{\text{H}}_2 {\text{O}} = 2572{\text{b, }}P{\text{CO}}_2 = 3162{\text{b, }}P{\text{H}}_2 = 2.5{\text{b, }}P{\text{CH}}_4 = 52.5{\text{b, }}P{\text{CO}} = 11.0{\text{b}}\) are obtained for \(f{\text{O}}_2 = 10^{ - 26}\) . If total pressure equals fluid pressure, then the total pressure during metamorphism was approximately 6 kb. The total fluid pressure calculated is extremely sensitive to the value of \(f{\text{O}}_2\) chosen.  相似文献   

16.
The positions of the liquidi and the near-liquidus phases of olivine-melilitite+CO2 have been determined under MH-buffered and furnace-buffered conditions up to 40 kb. It is found that CO2 alone lowers the liquidus compared to dry conditions, yet its influence is minor compared to H2O. The major role of CO2 is to favour the growth of orthopyroxene and garnet over that of olivine at least at high pressures. CO2-contents of glasses from experiments just above the liquidus (MH-buffered) were determined as 5.1 % at 10kb; 7.5 % at 20kb, 9.3 % at 30kb and 10–11 % (estimated) at 40 kb. Experiments on (pyrolite –40 % olivine)+H2O+CO2 show that CO2 occurs under mantle conditions as carbonate under subsolidus conditions and dissolved in a melt above the solidus. At 30kb, the solidus lies between 1,000 ° C and 1,050 ° C for vapour-saturated conditions, at and at .  相似文献   

17.
The Al-in-hornblende barometer, which correlates Altot content of magmatic hornblende linearly with crystallization pressure of intrusion (Hammarstrom and Zen 1986), has been calibrated experimentally under water-saturated conditions at pressures of 2.5–13 kbar and temperatures of 700–655°C. Equilibration of the assemblage hornlende-biotite-plagioclase-orthoclasequartz-sphene-Fe-Ti-oxide-melt-vapor from a natural tonalite 15–20° above its wet solidus results in hornblende compositions which can be fit by the equation: P(±0.6 kbar) = –3.01 + 4.76 Al hbl tot r 2=0.99, where Altot is the total Al content of hornblende in atoms per formula unit (apfu). Altot increase with pressure can be ascribed mainly to a tschermak-exchange ( ) accompanied by minor plagioclase-substitution ( ). This experimental calibration agrees well with empirical field calibrations, wherein pressures are estimated by contact-aureole barometry, confirming that contact-aureole pressures and pressures calculated by the Al-in-hornblende barometer are essentially identical. This calibration is also consistent with the previous experimental calibration by Johnson and Rutherford (1989b) which was accomplished at higher temperatures, stabilizing the required buffer assemblage by use of mixed H2O-CO2 fluids. The latter calibration yields higher Altot content in hornblendes at corresponding pressures, this can be ascribed to increased edenite-exchange ( ) at elevated temperatures. The comparison of both experimental calibrations shows the important influence of the fluid composition, which affects the solidus temperature, on equilibration of hornblende in the buffering phase assemblage.  相似文献   

18.
Iron chlorites with compositions intermediate between the two end-members daphnite (Fe5Al2Si3O10(OH)8) and pseudothuringite (Fe4Al4Si2O10(OH)8) were synthesized from mixtures of reagent chemicals. The polymorph with a 7 Å basal spacing initially crystallized from these mixtures at 300 °C and 2 kb after two weeks. Conversion to a 14 Å chlorite required a further 6 weeks at 550 °C. Shorter conversion times were required at higher water pressures. The products contained up to 20% impurities.The maximum equilibrium decomposition temperature for iron chlorite, approximately 550 °C at 2kb, is at an between assemblages (1) and (2) listed below. Synthetic iron chlorite will break down by various reactions with variable P, T, and fugacity of oxygen. For the composition FeAlSi = 523, the sequence of high temperature breakdown products with increasing traversing the magnetite field for P total = =2kb is: (1) corierite+ fayalite+hercynite; (2) cordierite+fay alite+magnetite; (3) cordierite+magnetite+quartz; (4) magnetite+mullite+quartz. Almandine should replace cordierite in assemblages (1) and (2) but it did not nucleate. The significance of the relationship between iron cordierite and almandine in this system is discussed.At water pressures from 4 to 8.5 kb and at the nickel-bunsite buffer, iron chlorite+quartz break down to iron gedrite+magnetite with temperature 550 to 640 °C along the curve. At temperatures 50 °C greater and along a parallel curve, almandine replaces iron gedrite. For on this buffer curve, almandine is unstable below approximately 4 kb for temperatures to approximately 750 °C.  相似文献   

19.
The equilibrium curve for the reaction 3 dolomite + 1 K-feldspar + 1 H2O=1 phlogopite + 3 calcite + 3 CO2 was determined experimentally at a total gas pressure of 2000 bars using two different methods.
  1. In the first case water alone was added to the reactants. The CO2 component of the gas phase was producted solely by the reaction under favourable P-T conditions. This manner of carrying out the reaction is called the “water method”. With this method sufficient time must be allowed for the gas phase to attain a constant composition (see Fig. 1). Reverse reactions were carried out using reaction products of the forward reaction.
  2. In the second case silver oxalate + water were added to the reactants. Breakdown of the silver oxalate leads to formation of a CO2-H2O gasphase of definite composition. At constant temperature and gas pressure the \(X_{{\text{CO}}_{\text{2}} } \) determines whether the reaction products will be phlogopite + calcite or dolomite + K-feldspar. In this case it is not necessary to wait for equilibrium to be attained. This method is abbreviated the “oxalate method”. Reactants for reverse reactions are not identical with the products of the forward reaction.
At high temperatures the results of the two different methods agree well (see Tables 1 and 2). Equilibrium was attained in one case at 490° C and \(X_{{\text{CO}}_{\text{2}} } \) of approximately 0.77, and in the other case at 520° C and \(X_{{\text{CO}}_{\text{2}} } \) of 0.90. At lower temperatures there are considerable differences in the results. With the water method an \(X_{{\text{CO}}_{\text{2}} } \) of about 0.25 was reached at 450° C. With the oxalate method dolomite K-feldspar and water still react with each other at even higher \(X_{{\text{CO}}_{\text{2}} } \) values. Phlogopite, calcite and CO2 are formed together with metastable talc. There are no criteria to indicate which of the methods is the correct one at lower temperatures and in Fig. 2, therefore, both equilibrium curves are plotted.  相似文献   

20.
The addition of Fe and Cr to the simple system MgO-SiO2-Al2O3 markedly affects the activities of phases involved in the equilibrium
\textMg\text2 \textSiO\text4 \text + MgAl\text2 \textSiO\text6 \text = MgAl\text2 \textO\text4 \text + Mg\text2 \textSi\text2 \textO\text6 \textOlivine + Opx\textsolid solution \text = Spinel + Opx\textsolid solution \begin{gathered} {\text{Mg}}_{\text{2}} {\text{SiO}}_{\text{4}} {\text{ + MgAl}}_{\text{2}} {\text{SiO}}_{\text{6}} {\text{ = MgAl}}_{\text{2}} {\text{O}}_{\text{4}} {\text{ + Mg}}_{\text{2}} {\text{Si}}_{\text{2}} {\text{O}}_{\text{6}} \hfill \\ {\text{Olivine + Opx}}_{{\text{solid solution}}} {\text{ = Spinel + Opx}}_{{\text{solid solution}}} \hfill \\ \end{gathered}  相似文献   

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