Eclogite and pyroxenite xenoliths from off-craton kimberlites near the Kaapvaal Craton, South Africa

Mantle xenoliths brought to the surface by kimberlite magmas along the south-western margin of the Kaapvaal craton in South Africa can be subdivided into eclogites sensu stricto, kyanite eclogites and orthopyroxene eclogites, all containing omphacite, and garnet clinopyroxenites and garnet websterites characterised by diopside. Texturally, chemically (major elements) and thermally, we observe an evolution from garnet websterites (T_EG = 742–781 °C) towards garnet clinopyroxenites (T_EG = 715–830 °C) and to eclogites (T_EG = 707–1056 °C, mean value of 913 °C). Pressures calculated for orthopyroxene-bearing samples suggest upper mantle conditions of equilibration (P = 16–33 kb for the garnet websterites, 18 kb for a garnet clinopyroxenite and 23 kb for an opx-bearing eclogite). The overall geochemical similarity between the two groups of xenoliths (omphacite-bearing and diopside-bearing) as well as the similar trace element patterns of clinopyroxenes and garnet suggest a common origin for these rocks. Recently acquired oxygen isotope data on garnet (δ¹⁸O_gnt = 5.25–6.78 ‰ for eclogites, δ¹⁸O_gnt = 5.24–7.03 ‰ for garnet clinopyroxenites) yield values ranging from typical mantle values to other interpreted as resulting from low-temperature alteration or precursors sea-floor basalts and associated rocks. These rocks could then represent former magmatic oceanic rocks that crystallised from a same parental magma as plagioclase free diopside-bearing and plagioclase-bearing crustal rocks. During subduction, these oceanic rock protoliths equilibrated at mantle depth, with the plagioclase-bearing rocks converting to omphacite and garnet-bearing lithologies (eclogites sensu largo), whereas the plagioclase-free diopside-bearing rocks converted to diopside and garnet-bearing lithologies (garnet websterites and garnet clinopyroxenites).     

HP–LT Variscan metamorphism in the Cubito-Moura schists (Ossa-Morena Zone, southern Iberia)

Multi-equilibrium thermobarometry shows that low-grade metapelites (Cubito-Moura schists) from the Ossa–Morena Zone underwent HP–LT metamorphism from 340–370 °C at 1.0–0.9 GPa to 400–450 °C at 0.8–0.7 GPa. These HP–LT equilibriums were reached by parageneses including white K mica, chlorite and chloritoid, which define the earliest schistosity (S₁) in these rocks. The main foliation in the schists is a crenulation cleavage (S₂), which developed during decompression from 0.8–0.7 to 0.4–0.3 GPa at increasing temperatures from 400–450 °C to 440–465 °C. Fe³⁺ in chlorite decreased greatly during prograde metamorphism from molar fractions of 0.4 determined in syn-S₁ chlorites down to 0.1 in syn-S₂ chlorites. These new data add to previous findings of eclogites in the Moura schists indicating that a pile of allochtonous rocks situated next to the Beja-Acebuches oceanic amphibolites underwent HP–LT metamorphism during the Variscan orogeny. To cite this article: G. Booth-Rea et al., C. R. Geoscience 338 (2006).     

Prograde and retrograde equilibria in garnet-cordierite gneisses in south-central Massachusetts

Partial electron microprobe analyses of garnet, biotite and cordierite in sillimanite-K feldspar gneisses of the Brimfield Formation in south-central Massachusetts indicate that the compositions of these minerals are not constant in a thin section. The FeO/MgO mol ratio of biotite is sensitive to the nature of other FeO-MgO minerals occurring in close proximity. The most iron-rich biotites are those that do not contact either cordierite or garnet. The most iron-poor biotites occur as inclusions in garnet. Biotites in direct contact with either cordierite or garnet have intermediate FeO/MgO ratios. The bulk of a given grain of garnet or cordierite is homogeneous in composition. Chemical zoning is absent. All grains of garnet and cordierite in a thin section are constant in composition. However, where garnet and cordierite abut biotite, the FeO/MgO ratio of the garnet rim is increased and that of cordierite is decreased. The FeO/MgO ratios of garnet, cordierite and biotite bare a regular relation to each other indicating a possible equilibrium state. However the distribution coefficient defined by the compositions of minerals in direct contact are greater than those defined by the compositions of the interiors of garnet and cordierite matched with the compositions of biotites removed from these phases. This pattern is believed to be the result of two thermal events. The first event produced the mineral assemblages and widespread equilibrium was obtained. A subsequent retrograde event left the mineralogy intact but caused cation exchange reactions at immediate contacts between garnet, cordierite and biotite. The physical conditions of the first event are estimated at P=5–6 kb, T=700–750° C. The retrograde event occurred at lower temperatures and very low activities of H₂O since no muscovite is developed at microcline-sillimanite contacts.     

Calpionellid zonation of the Jurassic–Cretaceous transition in North-Atlasic Tunisia. Updated Upper Jurassic stratigraphy of the ‘Tunisian trough’ and regional correlations

The analysis of calpionellid associations from jebels Amar and Jédidi sections in North-Atlasic Tunisia provides, for the first time, a precise biozonation of the Jurassic–Cretaceous transition succession. In the light of the new data obtained and considering recently published results, the age of Upper Jurassic formations is clarified, allowing correlations with the Tunisian ‘Dorsale’ and the North–South Axis successions. Within the Maghrebides' range, sections from the external zones correlated to the Tunisian successions are quite distinctive from their equivalent in the internal zones. Both have evolved in different palaeogeographic domains related to the early structuration of the northwestern and southwestern Tethys margins. To cite this article: M. Boughdiri et al., C. R. Geoscience 338 (2006).     

SEM–EDS analysis of western Mediterranean obsidians: a new tool for Neolithic provenance studies

The contents of Na, Al, Si, K, Ca and Fe of 99 obsidians from the western Mediterranean islands of Lipari, Palmarola, Pantelleria and Sardinia were determined with the energy-dispersive spectrometer of a scanning electron microscope (SEM–EDS). The Na and in a lesser way other elements contents characterize any obsidian source-island. In Sardinia (80 samples), the four Monte Arci obsidian geochemical types can be discriminated from binary diagrams of element contents or by a discriminant analysis based on the six elements measured. It is concluded that SEM–EDS offers a new option for Neolithic obsidian provenance studies in this region. To cite this article: F.-X. Le Bourdonnec et al., C. R. Geoscience 338 (2006).     

The degree of oxidation of iron in synthetic iron-magnesian biotites

Summary Chemical analytical and pyrolytical methods have been used to study the Fe⁺²/Fe⁺³ ratios and dehydroxylation reactions in synthetic biotites. It has been found for the biotites with Fe/(Fe + Mg) of 20 to 70 mole % that the oxidation degree decreases from 26 to 16% with increasing iron. Based on the measured amounts of water and hydrogen released during pyrolysis it is inferred that the deprotonization is a dominant reaction at low temperatures (T 600°C), accompanied by dehydration as the temperature increases. Depending on the composition, a complete dehydroxylation takes place at T 900 °C, and the measured amount of water corresponds to the iron oxidation degree in the starting samples. The results of this study have important implications with respect to determination of the formation conditions of biotite-bearing rocks, and also for improvement of the techniques for determination of different valence of iron and water.

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Le degré d'oxidation du fer en biotites synthétiques contenants le fer et le magnésium

Résumé Des méthodes chimiques et pyrolitiques ont été utilisées pour l'étude des rapports Fe⁺²/Fe⁺³ et de la réaction de la déhydroxilation en biotites synthétiques. On a trouvé pour les biotites avec Fe/(Fe + Mg) de 20-70 mole % que le degré d'oxidation décroît à partir de 26 jusqu'à 16% pendent que le contenu du fer s'accroît. Sur la base de la quantité d'eau et hydrogène liberée pendant la pyrolyse, on infère que la déprotonisation est une réaction dominante à températures basses (T = 600°C), mais quand la température s'accroît, la déprotonisation est accopagnée de la déhydratation. Dépendant de la composition il y a une déhydroxilation complète à T = 900°C, et la quantité de l'eau mesurée correspond au degré d'oxidation du fer dans les specimens initials. Les résultats de cette étude infuencent la détermination des conditions de formation des roches contenantes biotite et aussi l'amélioration des techniques de la détermination du fer de valences différentes et de l'eau.

     

Les argiles bleues du Cambrien inférieur de Saint-Pétersbourg et leur fissuration. Implications pour des stockages souterrains

The Lower Cambrian Saint Petersburg blue clays are composed of predominant illite and chlorite, sometimes accompanied by kaolinite. The <0.1 μm fraction has a high content of illite–smectite mixed layers. Particle-size distribution is more than 50% of clay particles and about 30% of silts. These blue clays correspond to plastic (and soft) clays; they may be compared to the Callovian clays of Bure (France), where storage of natural waste is envisaged. To cite this article: M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.

Résumé

Les « argiles bleues » du Cambrien Inférieur de Saint-Pétersbourg sont constituées d'illite dominante et de chlorite, avec parfois présence de kaolinite. Des interstratifiés illite/montmorillonite sont très abondants dans la phase <0,1 μm. Du point de vue granulométrique, outre plus de 50% de particules argileuses, il existe une phase silteuse de l'ordre de 30%. Du point de vue pétrophysique, ce sont des argiles plastiques, de consistance molle. Elles sont subhorizontales et ont jusqu'à 116 m d'épaisseur. Outre l'absence de métamorphisme, malgré leur âge, leur caractère le plus remarquable est leur réseau de fracturation, bien observable en carrière. Les joints sont nets, sans remplissage ni cimentation. Les plans verticaux sont particulièrement développés. Le volume unitaire des blocs de matrice ne dépasse guère 1 m³. Des traces d'oxydation témoignent de circulations d'eau. Ces argiles silteuses anciennes peuvent aider à mieux connaı̂tre et comprendre les argilites silteuses épigénétiques calloviennes du site de Bure (Haute-Marne, France), où un stockage souterrain de déchets nucléaires est envisagé. Pour citer cet article : M. Arnould et al., C. R. Geoscience 334 (2002) 1135–1140.     

Geology, geochemistry, and U–Pb geochronology of the Archean (2.74 Ga) Serra do Rabo granite stocks, Carajás Metallogenetic Province, northern Brazil

The Carajás region, located in the southeastern part of the Amazon Craton, has been considered one of the most important mineral provinces in the world. The Serra do Rabo Granite (SRG) crops out near the eastern termination of the Carajás fault as two granite stocks, elongated approximately in an E–W direction, concordant with the regional structures. Leucomicrocline granite, hornblende–microcline granite, biotite–hornblende–microcline granite, hornblende syenogranite, and subordinate aplite are identified. The granites are grayish pink and coarse to medium grained and have mainly hypidiomorphic granular texture. Granophyric textures are common. The accessory minerals are ilmenite, apatite, zircon, allanite, and rare pyroxene.The SRG rocks are either massive or foliated, with a slightly anastomosed continuous S₁ foliation (E–W/subvertical) outlined by the preferred orientation of quartz, feldspars, and mafic minerals. Locally, decimeter- to meter-wide mylonite/ultramylonite bands (S_1m) occur along the E–W foliation. The S₁ foliation was developed under higher temperatures than those of the S_1m mylonite foliation. The SRG structural evolution was controlled by progressive deformation under decreasing temperature, indicative of syntectonic emplacement. The SRG also has relatively high SiO₂, K₂O, and Na₂O contents; high FeO*/(FeO*+MgO) ratios; high Zr, Ba, Nb, and Ga; and very high rare-earth element contents. The chemical signature is moderately alkaline and metaluminous, comparable to that of the A-type, A2, and ALK-3 granites. The origin of the SRG magmas may be related to the partial melting of crustal sources, such as previously metamorphosed calc-alkaline granites.The SRG crosscuts supracrustal rocks, promoting low-pressure/high-temperature metamorphism. The interaction between regional compressive stresses and the ballooning effect of the granite stocks promoted slight aureole flattening and rheological changes in the supracrustal rocks. The U–Pb zircon age of 2743±1.6 Ma is interpreted as the age of zircon crystallization, granite stock emplacement, and regional horizontal shortening. Other 2.7 Ga syntectonic alkaline granites (e.g. Estrela, Plaquê, Planalto) have been reported in the region.     

Mineralogy and geochemistry of biotites from Proterozoic granitoids of western Arunachal Himalaya: Evidence of bimodal granitogeny and tectonic affinity

Felsic magmatic rocks in Kameng corridor of western Arunachal Himalaya are represented by extensively exposed Palaeoproterozoic porphyritic muscovite-biotite granite (GGn) of the Bomdila Group and small stock-like Mesoproterozoic hornblende-biotite granite (HBG) of the Salari Group. Mineralogy and chemical composition of biotites from GGn and HBG have been utilized to understand the nature and tectonic environment of their parental felsic melts. Biotites in GGn (FeO^t/MgO=3.1–4.6) are Fe-biotites and have shown affinity with primary biotites co-precipitating with muscovite in a peraluminous (S-type) felsic melt of syn-collisional tectonic environment. Biotites in HBG (FeO^t/MgO=1.3–2.2) are transitional between Fe and Mg biotites evolved from Fayalite-Magnetite-Quartz (FMQ) to Nickel-Nickel Oxide (NNO) buffers and are related to primary biotites co-existing with amphibole and other ferromagnesian minerals in a calc-alkaline metaluminous (I-type) felsic melt mostly formed in a subduction setting. Both GGn and HBG biotites exhibit Mg⇌Fe substitution, which is more pronounced in HBG biotites. GGn biotites exhibit 2Al⇌3Fe²⁺ substitution as expected in peraluminous melt, whereas 3Mg⇌2Al substitution normally expected to operate in metaluminous melt is less pronounced in HBG biotites. GGn biotites are markedly enriched in siderophyllite, and depleted in phlogopite components as compared to HBG biotites, which point to diverse genetic conditions. HBG biotites indicate oxidizing environment of the felsic melt unlike the reducing nature of the porphyritic granite (GGn).     

Chemical mineralogy of the Monchique alkaline complex,southern Portugal

Some 500 microprobe analyses from 43 rock samples, covering the entire range of major and minor intrusive rock-types, define the following ranges of mineral composition: plagioclases (An_70-30), alkali feldspars (Or_98-20 and Ab_90–99), olivines (Fo_85-82), clinopyroxenes (aluminous titanaugite through salite and aegirine-augite to acmite), amphiboles (subsilicic kaersutite through pargasite to hastingsite, edenite or katophorite), biotites (titanbiotite to titaniferous manganiferous lepidomelane). Varied discontinuous reaction relationships are evident petrographically between these minerals (e.g. amphibole overgrowths on pyroxenes or biotites), but most appear to reflect reequilibration during slow magmatic cooling, or perhaps local disequilibrium effects, and there is little evidence for significant subsolidus, hydrothermal or deuteric modification of the primary mineralogy.Although these mineral ranges are reasonably typical of differentiated alkaline gabbroic-syenitic intrusions, Monchique also shows many unusual features: e.g. a restricted stability range for olivine, the absence of amphiboles from all rocks with 54<%SiO₂<58, a lack of alkali amphiboles corresponding to the acmite-rich pyroxenes, the presence of acmite-poor pyroxenes and aluminous biotites in peralkaline rocks, and irregular Ti variation in biotites. Mineral/ host-rock relationships also show peculiarities: e.g. Mg/ (Mg+Fe) ratios of mafic minerals and An contents of plagioclases increase as host-rock fractionation index (FI) increases from gabbroic (FI 30–40%) to alkali feldspar-bearing essexitic (FI c. 50) rocks. Thereafter, Mg ratios decrease only slightly, such that many malignites and miaskitic syenites (FI 70–90) carry pyroxenes and biotites which are no more, and sometimes less evolved than those in the gabbroic rocks (FI 30–40).Such features confirm earlier suggestions from whole-rock geochemistry, that a major evolutionary process in the complex was a relatively discontinuous segregation of already somewhat evolved essexitic magma into more basic and more felsic magmas, rather than an incremental gabbrosyenite crystal fractionation. They also confirm that the complex represents neither a single in situ differentiating magma pulse, nor a series of simply related pulses, but an irregular and largely irresolvable juxtaposition of magma-batches of widely varying compositions and evolutionary histories.     

The crystalline complexes of Hamadan (Sanandaj–Sirjan zone, western Iran): metasedimentary Mesozoic sequences affected by Late Cretaceous tectono-metamorphic and plutonic events

The Hamadan area is characterised by various metamorphic rocks where the slates yielded Jurassic fossils. The entire column, representing the Mesozoic from at least the Jurassic to the Mid-Cretaceous, has been affected by tectono-metamorphic events and the emplacement of Late Cretaceous granitic rocks. A timing of these events is based on the ⁴⁰K–⁴⁰Ar ages carried mainly on separated amphiboles, biotites and muscovites, and interpreted as the ages of their isotopic closure. Results are ranging between 91 and 70 Ma. To cite this article: A. Baharifar et al., C. R. Geoscience 336 (2004).

Résumé

La région de Hamadan expose des roches métamorphiques dont les termes les moins transformés contiennent des fossiles jurassiques. Au cours du Crétacé supérieur, elle a été affectée par un événement tectono-métamorphique régional et elle a été le siège d'une activité plutonique. Les résultats des datations ⁴⁰K–⁴⁰Ar des amphiboles et des micas séparés des roches métamorphiques et plutoniques qui s'étagent entre 91 et 70 Ma montrent l'importance de ces événements et leur étalement au cours du Crétacé supérieur. Pour citer cet article : A. Baharifar et al., C. R. Geoscience 336 (2004).     

Apport de la gravimétrie à l'étude des structures profondes du Sahel de Tunisie (cas de la région de Kairouan–Sousse–Monastir)

The monotony of the surface and of the deep structure of the Sahel domain in eastern Tunisia (low topographic area covered by a Quaternary series) induces the possible existence of an important subsiding collapsed block and associated faulted zones. Gravity data analyses have permitted the reconnaissance of the crustal and gravimetric setting of the northern part of the Sahel domain and the discussion of main outlines of subsurface structures. The deep structure of a particular zone (Kairouan–Sousse–Monastir area) demonstrates the existence of an east-west en-doigt-de-gant crustal thinning confirmed by the gravity data. This deep structuring is perfectly showed by the high-resolution second-order enhanced analytic signal technique developed to image geologic boundaries such as contacts and faults. This technique, correlated with the distribution of all seismic events in the last century, has permitted to define an important east–west Kairouan–Sousse–Monastir tectonic corridor (CKSM). This corridor corresponds to major faults oriented east-west, were some folded structures can be developed. To cite this article: H. Gabtni, C. R. Geoscience 337 (2005).     

Compositions of biotite,amphibole, apatite and silicate melt inclusions from the Tongchang mine,Dexing porphyry deposit,SE China: Implications for the behavior of halogens in mineralized porphyry systems

The Dexing deposit, located in the Circum-Pacific ore belt, is the largest porphyry copper deposit in eastern China. It is composed of 3 separate plutons, which host three mines: Tongchang, Fujiawu and Zhushahong mines. The porphyritic granodiorite samples studied in this investigation were collected from the Tongchang ore-forming pluton of this giant deposit. This paper presents electron microprobe analyses of biotite, apatite, amphibole, plagioclase, potassium feldspar and rehomogenized glassy melt inclusions from the Tongchang porphyritic granodiorites. Petrographic observations of the samples are consistent with portions of the granodioritic magma represented by our samples being overprinted by potassic hydrothermal fluid which variably altered these minerals.All of the studied micas are Mg-rich biotites. The biotites are separated into altered magmatic and secondary types based on their petrographic and geochemical characteristics. The phlogopite components of the secondary biotites are typically higher than those of the altered magmatic biotites, and the X_Mg values of all biotites correlate negatively with Cl contents, consistent with the Mg–Cl avoidance principle. The X_Mg values also correlate negatively with (K₂O + Na₂O + BaO), FeO and TiO₂ for both generations of biotites. The calculated log (fH₂O/fHCl) values (for 690 K) of the coexisting potassic fluids, which are determined from the altered magmatic biotite compositions, range from 4.43 to 4.67, and are very similar to those of other major porphyry deposits. However, the log(fH₂O/fHF) and log(fHF/fHCl) values for the same batch of hydrothermal fluids are significant higher and lower than those of these other porphyry deposits, respectively.The Cl concentrations of amphiboles and melt inclusions range from 0.18 to 0.32 wt.% and 0.15 to 0.44 wt.%, respectively. Most apatites trapped in biotite and plagioclase phenocrysts display a bimodal Cl distribution: 0.19 to 1.35 wt.% and 1.48 to 3.73 wt.%. Similarly, the S contents of the apatite also show a distinct bimodal distribution reflecting the effects of variable anhydrite saturation during evolution of the Tongchang melt and variable dissolution of anhydrite by saline aqueous fluids. The Cl contents of the apatites from the Tongchang system are typically higher than those of other studied porphyry deposits. Furthermore, the Cl contents of the melt inclusions are at or very near the Cl saturation levels (0.36 to 0.46 wt.% at 850 °C and 50 MPa and 0.42 to 0.54 wt.% at 850 °C and 200 MPa) for these melt compositions at shallow crustal pressures. These findings suggest that the area of the granodioritic magma represented by our samples, and perhaps the bulk of the Tongchang granodioritic magma was rich in Cl. The melt inclusion compositions are consistent with a high-salinity, hydrosaline liquid being exsolved directly from the granodioritic melt directly. This high-salinity hydrosaline liquid was likely very efficient at dissolving, transporting and precipitating ore metals in the mineralizing magmatic–hydrothermal system.     

Isotope provinces, mechanisms of generation and sources of the continental crust in the Central Asian mobile belt: geological and isotopic evidence

The available geological, geochronological and isotopic data on the felsic magmatic and related rocks from South Siberia, Transbaikalia and Mongolia are summarized to improve our understanding of the mechanisms and processes of the Phanerozoic crustal growth in the Central Asian mobile belt (CAMB). The following isotope provinces have been recognised: ‘Precambrian’ (T_DM=3.3–2.9 and 2.5–0.9 Ga) at the microcontinental blocks, ‘Caledonian’ (T_DM=1.1–0.55 Ga), ‘Hercynian’ (T_DM=0.8–0.5 Ma) and ‘Indosinian’ (T_DM=0.3 Ga) that coincide with coeval tectonic zones and formed at 570–475, 420–320 and 310–220 Ma. Continental crust of the microcontinents is underlain by, or intermixed with, ‘juvenile’ crust as evidenced by its isotopic heterogeneity. The continental crust of the Caledonian, Hercynian and Indosinian provinces is isotopically homogeneous and was produced from respective juvenile sources with addition of old crustal material in the island arcs or active continental margin environments. The crustal growth in the CAMB had episodic character and important crust-forming events took place in the Phanerozoic. Formation of the CAMB was connected with break up of the Rodinia supercontinent in consequence of creation of the South-Pacific hot superplume. Intraplate magmatism preceding and accompanying permanently other magmatic activity in the CAMB was caused by influence of the long-term South-Pacific plume or the Asian plume damping since the Devonian.     

Geochronological, isotopic, and geochemical data from Permo-Triassic granitic gneisses and granitoids of the Colombian Central Andes

New U–Pb SHRIMP ages in zircon, Ar–Ar ages in micas and amphiboles, Nd–Sr isotopes, and major and REE geochemical analyses in granitic gneisses and granitic stocks of the Central Cordillera of Colombia indicate the presence of a collisional orogeny in Permo-Triassic times in the Northern Andes related to the construction of the Pangea supercontinent. The collision is recorded by metamorphic U–Pb SHRIMP ages in inherited zircons around 280 Ma and magmatic U–Pb SHRIMP ages in neoformed zircons around 250 Ma within syntectonic crustal granitic gneisses. Magmatic U–Pb SHRIMP and Ar–Ar Triassic ages around 228 Ma in granitic stocks indicate the presence of late tectonic magmatism related to orogenic collapse and the beginning of the breakup of the supercontinent. During this period, the Central Cordillera of Colombia would have been located between the southern United States and northern Venezuela, in the leading edge of the Gondwana supercontinent.     

Mangerite magmatism associated with a probable Late-Permian to Triassic Hongseong–Odesan collision belt in South Korea

The Odesan area in the eastern Gyeonggi Massif, South Korea, consists principally of migmatitic and porphyroblastic gneisses intruded by mangerite. Mafic mangerites with SiO₂ contents from 52.40 to 54.20 wt.% have higher FeO* + MgO (14.98–18.28 wt.%) and CaO contents (5.80–7.84 wt.%) but lower total alkali contents (4.74 < Na₂O + K₂O < 5.80 wt.%) than felsic mangerites (55.9 < SiO₂ < 60.61 wt.%, 9.51< FeO* + MgO < 11.62 wt.%, 3.28 < CaO < 5.68 wt.%, 6.72 < Na₂O + K₂O < 8.05 wt.%). Fe-numbers (FeO* / [MgO + FeO*]) are 0.44–0.47 for mafic mangerites and 0.38–0.42 for felsic mangerites. The mangerites show calc-alkaline affinities in an AFM plot and resemble high-Ba–Sr granitoids with low Rb / Sr ratios of 0.25–0.10. Their MORB-normalized compositions show enrichment in LILE (decoupled LIL/HFS pattern) and negative anomalies in Ti–Nb–Ta. Their geochemical characters are consistent with their formation by partial melting of a basaltic source at temperatures higher than 1025 °C. The mangerites of the present study differ from mangerite formed in a typical within-plate tectonic setting in their high mg# and Sr concentrations and negative Nb and Ta anomalies. Their LILE enrichment and negative Ti–Nb–Ta anomalies could well have been inherited from a pre-collision subduction event. A mean U–Pb zircon age of 257 Ma for the mangerite demonstrates that the tectonic belt connecting the Hongseong and Odesan areas represents a probable extension of the late Permian–Triassic collision belt between the North China and South China blocks into South Korea, with collision occurred earlier in South Korea.     

Le gisement AgHg de Zgounder (Jebel Siroua, Anti-Atlas, Maroc) : un épithermal néoprotérozoïque de type Imiter

The Zgounder ore deposit (Anti-Atlas, Morocco), is hosted in a PII–PIII Proterozoic volcanosedimentary series. Disseminated mineralization is dominated by mercuriferous native silver (2 to 30 wt.% Hg), with few silver sulfosalts (acanthite, pearceite), arsenopyrite and base-metal sulfides. Arsenic grade of arsenopyrite and homogenisation temperatures of fluid inclusions indicate initial conditions of high temperature (above 400 °C). Lead isotope compositions comfort a Late-Proterozoic age and a crustal origin for metals. Similarities are obvious with the neighbouring silver ore deposit of Imiter and lead to consider Zgounder as another example of Neoproterozoic epithermal deposit in the Anti-Atlas of Morocco, a region that appears more and more as a silver metallogenic province. To cite this article: É. Marcoux, A. Wadjinny, C. R. Geoscience 337 (2005).     

Interpretation of gamma-ray logs: The distribution of uranium in carbonate platform

High gamma-radioactivity in carbonates is usually ascribed to uranium of detrital minerals and organic matter, and to thorium and potassium of clays. The present study based on Urgonian marls and marly limestones (France) shows that some of the most radioactive values correspond instead to some ‘pure’ limestones. These peaks are generally associated with a sequence boundary or a maximum flooding surface. Low-level γ-spectrometry and ICP–MS analyses show that although high radioactivities are mostly associated with uranium, there is no obvious correlation between uranium enrichment and lithology. Also, correlation between high radioactivity and argillaceous beds might not be systematic. To cite this article: M.C. Raddadi et al., C. R. Geoscience 337 (2005).     

A Late Hauterivian short-lived anoxic event in the Mediterranean Tethys: the ‘Faraoni Event’

A Late Hauterivian interval (127.5 Ma), called the ‘Faraoni Event’, which is characterised by the deposition of deep-marine black shales in the Mediterranean Tethys, is demonstrably of sufficient geological brevity to be qualified as an anoxic event. This event lies within the Pseudothurmannia catulloi ammonite subzone, coincides with the extinction of the calcareous nannofossil species Lithraphidites bollii, and records an increase in a globular planktonic foraminifer. High quantities of marine organic matter were preserved in pelagic successions from northern and central Italy, Switzerland, southeastern France, southern Spain and probably elsewhere in the Mediterranean Tethys and Atlantic Ocean. Carbon-isotope stratigraphy from Tethyan and Atlantic sections shows a minor positive excursion in the uppermost part of the Hauterivian and Lowermost Barremian, suggesting accelerated extraction of organic carbon from the ocean reservoir just after the ‘Faraoni Event’. The duration of this short event is less than 100 ka according to cyclostratigraphy and coincides with a third-order sea-level rise. It is likely that similar forcing mechanisms responsible for global OAEs operated during this short time interval. To cite this article: F. Baudin, C. R. Geoscience 337 (2005).     

Enregistrement de phénomènes de resédimentation au cours du Maastrichtien supérieur et du Paléocène supérieur (J. Serj, Tunisie atlasique) : apport micropaléontologique et signature tectono-eustatique

Sedimentological and biostratigraphic analysis of Campanian–Maastrichtian reduced series of the J. Serj permitted to characterize two episodes of submarine erosion. The first is pre-Upper Maastrichtian (Rosita contusa zone), the second is pre-Upper Palaeocene (Morozovella velascoensis zone). Thus, two type-1 boundary surfaces are distinguished. These surfaces limit three stratigraphic intervals in apparent continuity. Syn-sedimentary tectonic activity is attested by gravity deposits or processes (conglomerates, slumps). To cite this article: A. Amri et al., C. R. Geoscience 337 (2005).