The effect of alternating different water qualities on accumulation and leaching of solutes in a Mediterranean cracking soil

The relevance of bypass flow on water flow, solute or pesticide transport is becoming increasingly recognized. Recent investigations proved that soil salinization may be influenced by bypass flow, i.e. the rapid transport of water and solutes via macropores and/or shrinkage cracks to subsoil and groundwater. This paper explores the role of bypass flow in the process of accumulation and leaching of solutes, as well as of sodium, in a Mediterranean cracking soil irrigated with saline/sodic waters. The results of bypass flow experiments performed on undisturbed soil cores showed that leaching of solutes occurred in concomitance with bypass fluxes when a low salinity solution was alternated with a high salinity solution. Exchange of solutes between the incoming solution and the soil matrix occurred during the bypass flow events at the contact surfaces (cracks walls) between the solution and the soil matrix and where cracks terminated in the soil samples. Concomitant exchanges of sodium were indicated by measurements performed in the effluent solution during the bypass flow measurements. The amount of Sodium released from the soil during the bypass flow events, as well as that of the soluble salts leached from the soil, were found to depend on the degree of soil cracking. These results indicated that:

• 1 in management of irrigation in cracking soils, under the occurrence of bypass fluxes, alternating a low salinity/sodicity water with a high salinity/sodicity solution can be effective for preventing salinization and sodification:
• 2 greater efficiency of removal of sodium/soluble salts can be obtained if application of the leaching solution is performed when the soil is at a considerable degree of cracking.

Copyright © 2002 John Wiley & Sons, Ltd.     

Solute transport and water content measurements in clay soils using time domain reflectometry

Abstract

Clayey and saline soils have been shown to be problematic for time domain reflectometry (TDR) measurements. This study presents some of these problems and discusses solutions to them. Thirteen solute transport experiments were carried out in three undisturbed soil columns of swelling clay soil from Tunisia, labelled S1, S2, and S3 respectively. The columns were collected at three different physiographical regions within a catchment. Water fluxes ranged from 1.2 to 7.2 cm day^?1. The large solute transport heterogeneity and large tailing indicated that preferential flow was most pronounced in S1. The preferential flow took place in voids between structural elements and in wormholes. In S3, preferential flow was also evident, but not to the same extent as in S1. In S2, the solute transport was more uniform with little preferential flow. The heterogeneity of the solute transport increased with the water flux in S1 and to a smaller extent in S3, whereas it remained constant in S2. In a previous dye experiment in the field, preferential flow in cracks was observed at those sites where S1 and S3 were collected. In the column experiments, preferential flow in these cracks was less due to the higher initial water content compared to the dye experiments, indicating that the desiccation cracks were closed by the swelling clay.     

Water and solute movement in a coarse-textured water-repellent field soil

Unstable water flow in water-repellent unsaturated soils can significantly affect the processes of infiltration and soil water redistribution. A field experiment was carried out to study the effect of water-repellency on water and bromide movement in a coarse-textured soil in the southwestern part of The Netherlands. The field data were analyzed using a relatively simple numerical model based on the standard Richards' equation for unsaturated water flow and the Fickian-based convection-dispersion equation for solute transport. Water-repellency was accounted for by multiplying the water content and the unsaturated hydraulic conductivity of the soil with F, a factor equal to the volumetric fraction of soil occupied by preferential flow paths resulting from the unstable flow process. The good comparison of simulated and measured bromide concentrations suggests that the model provides a viable method for simulating unstable water flow in water-repellent soils.     

Temporal variability of solute transport under vadose zone conditions

The heterogeneity of the solute flux field in the horizontal plane at the field scale has been documented in several field studies. On the other hand, little information is available on the persistence of certain solute transport scenarios over consecutive infiltration cycles. This study was initiated to analyse the recurrence of solute leaching behaviour as estimated in two soil column tests emphasizing the preferential flow phenomenon. Twenty-four small-sized soil samples were subjected to two consecutive unsaturated steady-state flow leaching experiments with bromide as tracer. Observed breakthrough curves (BTCs) were analysed by the method of moments and by the advection–dispersion equation (ADE) to classify solute behaviour. Frequency distributions of the parameters indicating the solute velocity were heavily skewed or bimodal, reflecting the broad variability of the leaching scenarios, including some with pronounced preferential solute breakthrough. Exclusion of the preferential flow columns from our calculations revealed an average amount of 37% of immobile water. The large-scale BTCs derived from assembling the individual concentration courses of each run showed similar features, such as an early bromide breakthrough. However, two distinct apices, viz. one preferential and one matrix, were observed only in the first run, whereas the concentration decrease between the peaks was missing from the second run. A change in soil structure with continuous leaching was presumed to modify the interplay of the various flow domains, thereby altering the spreading of the BTCs. Correlation analysis between parameters of both tests suggests that preferential transport conditions are likely to occur at the same locations in the field over several infiltration cycles, whereas the ‘classical’ or expected matrix flow is time variant and therefore seems to be hardly predictable. © 1998 John Wiley & Sons, Ltd.     

Modelling water infiltration in cracked paddy field soil

Periodic paddy field flooding is a major source of groundwater recharge. Many paddy fields thus are used as groundwater recharge ponds after harvesting the first crop of the summer. Following rice harvesting, paddy field surfaces may crack into fissures as a result of drainage and exposure to sunlight. Field observation indicates that applying precipitation to the paddy field can increase the rate of infiltration. To quantitatively evaluate the amount of infiltration in a cracked paddy field, this study sets up a simple soil crack model to simulate the field infiltration process. A three‐dimensional groundwater model FEMWATER is adopted to simulate water movement in the paddy field subjected to various crack conditions. Using the field and laboratory data of irrigation water requirements, soil physical properties, hydraulic conductivities and soil profiles obtained from Ten‐Chung, FEMWATER simulates the water movement in the dry cracked paddy. Simulation results show that if the cracks develop extensively and penetrate the ploughed soil, the infiltration rate may increase significantly. The infiltration fluxes of crack with depths of 80, 60 and 27·5 cm are 18·77, 14·50 and 8·06 times higher than that of 20 cm, respectively. The simulation results of cracks with 80 cm depth correlated closely with field observations. The results of the study elucidate the processes of unsaturated water movement in a dry cracked paddy field. Copyright © 2004 John Wiley & Sons, Ltd.     

Modelling solute leaching during fingered flow by integrating and expanding various theoretical and empirical concepts

Abstract

Wetting front instability (fingered flow) accelerates solute transport through the unsaturated zone to the groundwater table. Whether fingers widen or dissipate close to the groundwater is unclear. Water flow in a two-dimensional artificial capillary fringe below a dry layer exhibiting fingered flow was investigated. The flow diverged strongly in the wet soil, suggesting that fingers dissipate. Expressions for the finger radius in dry and wet soil were combined and adapted to a soil hydraulic property parameterization popular in numerical modelling. The modified equation provided finger radii for soils in humid and arid climates. The fingers in the arid soil were excessively wide. The finger radii were used to model solute transport, assuming fingers dissipated in the subsoil. Modelling was cumbersome for the arid climate. One shower may often be insufficient to trigger fingering in arid regions with short, heavy showers. In soils with shallow groundwater, the diverging subsoil flow determines solute leaching.     

Investigating landslide‐related cracks along the edge of two loess platforms in northwest China

Cracks are widely developed along the edge of loess platforms in northwest China. Field surveys reveal that these cracks can be grouped into shallow and deeply penetrating ones. The former occur at a small distance from the platform edge, normally penetrate into the top unsaturated loess with the penetration depth being controlled by the joints in loess. The latter penetrate deeper into the saturated loess farther away from the platform edge. These cracks control the inflow and drainage of irrigation water. The shallow penetrating crack can fail as a slide or fall with a volume of up to hundreds of cubic meters. The deeply penetrating crack can fail as a flow‐like landslide with a volume of thousands of cubic meters or more. A full‐scale field test simulating irrigation on the platform surface was conducted. The two types of crack can be interconnected so that the water applied in the test finally flowed into the deep crack and was discharged from the platform. Analysis of soil stress states and the results of field test show that the deeply‐penetrating cracks could have both positive as well as negative effects on slope stability. On the one hand, water can flow more freely in the cracks, and the loess could be saturated and trigger a landslide. On the other hand, the water can drain more easily along the crack and slope stability could be enhanced as the groundwater level is suppressed. Copyright © 2012 John Wiley & Sons, Ltd.     

Comparison of heat and bromide as ground water tracers near streams

Heat and bromide were compared as tracers for examining stream/ground water exchanges along the middle reaches of the Santa Clara River, California, during a 10-hour surface water sodium bromide injection test. Three cross sections that comprise six shallow (<1 m) piezometers were installed at the upper, middle, and lower sections of a 17 km long study reach, to monitor temperatures and bromide concentrations in the shallow ground water beneath the stream. A heat and ground water transport simulation model and a closely related solute and ground water transport simulation model were matched up for comparison of simulated and observed temperatures and bromide concentrations in the streambed. Vertical, one-dimensional simulations of sediment temperature were fitted to observed temperature results, to yield apparent streambed hydraulic conductivities in each cross section. The temperature-based hydraulic conductivities were assigned to a solute and ground water transport model to predict sediment bromide concentrations, during the sodium bromide injection test. Vertical, one-dimensional simulations of bromide concentrations in the sediments yielded a good match to the observed bromide concentrations, without adjustment of any model parameters except solute dispersivities. This indicates that, for the spatial and temporal scales examined on the Santa Clara River, the use of heat and bromide as tracers provide comparable information with respect to apparent hydraulic conductivities and fluxes for sediments near streams. In other settings, caution should be used due to differences in the nature of conservative (bromide) versus nonconservative (heat) tracers, particularly when preferential flowpaths are present.     

Vulnerability of three spatially variable soil groups for solute leaching

Solute leaching in unsaturated soil is influenced by the variability in hydraulic functions (water retention and conductivity) that govern the flow process. Variability in measured soil hydraulic functions of a coarse-, medium- and fine-textured soil group was quantified with the scaling theory of similar media. Solute leaching in these soils was calculated with Monte Carlo simulation assuming, successively, hydraulic conductivity, K, volumetric water content, 0, and pressure head, h, to be constant. In addition to variability in hydraulic functions, variability in the solute retardation factor was also taken into account. To examine this effect five solutes were considered: a conservative solute (chloride), a non-retarded solute subject to decay (nitrate), a retarded solute that does not decay (cadmium) and two organic solutes which are retarded but have different sorption and decay parameters (the pesticide atrazine and a chlorinated hydrocarbon). The numerical results obtained with Monte Carlo simulation were in a number of instances verified with analytical solutions. The three soil groups distinguished showed considerable differences in vulnerability for leaching of the five solutes, emphasizing the importance of the effect of variability in soil hydraulic functions when studying solute leaching. Numerical and analytical results showed good agreement. Therefore, in relatively simple situations analytical solutions are attractive. However, in complicated situations, analytical solutions are cumbersome and numerical solutions are the only realistic alternative.     

Percolation losses in paddy fields with a dynamic soil structure: model development and applications

The hydraulic characteristics of the plough pan of paddy fields provide continuous ponding conditions during the growing season and control the water use efficiency in wet rice production. Its saturated hydraulic conductivity K_s, however, exhibits a large spatiotemporal variability as a consequence of a highly dynamic soil structure involving temporary shrinkage cracks. Water flow through the earthen bunds surrounding the fields further contributes to the uncertainty in water flux calculations. The objective of this study was to develop a simple deterministic model with stochastic elements (‘PADDY‐FLUX’) for depiction of deep percolation, and to assess the effect of different water management scenarios on percolation in two channel command areas. Darcy's law is used as the fundamental equation for water flow calculations with the ponding water depth h as a time‐dependent variable. Flux uncertainty is estimated by a Monte‐Carlo‐type implementation. K_s is treated as a random variable of a bimodal probability density function (PDF), which is the weighted sum of two Gaussian PDFs (accounting for a matrix and a preferential flow domain). The weighing factor α is a function of h, reflecting an increasing risk for preferential flow situations after desiccation and the development of shrinkage cracks. Under‐bund percolation is calculated using transfer functions. The results demonstrate that percolation losses increase in the following order: continuous soil saturation < continuous flooding (CF) < mid‐season drainage and intermittent irrigation (MD + II) < mid‐season drainage and continuous flooding. The bunds contribute up to 54 and 17% to total fluxes under CF and MD + II, respectively. Preferential water fluxes are responsible for the major part of water losses as soon as desiccation causes the formation of shrinkage cracks. As a conclusion, continuous soil saturation should be promoted as the least water‐intensive irrigation regime, while intermittent irrigation is recommended only in case that irreversible shrinkage cracks have already developed. Copyright © 2010 John Wiley & Sons, Ltd.     

Simulations of water movement and solute transport through different soil texture configurations under negative‐pressure irrigation

This study examined the effects of different soil texture configurations on water movement and solute transport to provide a reliable scientific basis for the application of negative‐pressure irrigation (NPI) technology. HYDRUS‐2D was used to analyse water movement and solute transport under NPI. The main results are as follows: (a) HYDRUS‐2D can be used to simulate water movement and solute transport under NPI, as there was good agreement between the simulated and measured values for water contents, NaCl concentrations, cumulative water infiltration, and wetting distances in the horizontal and vertical directions; the Nash–Sutcliffe efficiency coefficients were in the range of 0.94–0.97. (b) Layered soils have obvious effects on water movement under NPI. With the emitter position in the loam layer, when a coarse texture of loamy sand was present below the loam layer (namely, L‐LS), irrigation water accumulated in the topsoil, and this led to an increase in evaporation compared with the homogeneous loam profile. However, fine texture silty loam or silty clay loam layers beneath the loam layer (namely, L‐SiL or L‐SiCL, respectively) was more conducive to water infiltration into the lower layer, and this increased the amount of water infiltration and simultaneously reduced the surface evaporation effectively. (c) Layered soils have obvious effects on solute transport under NPI, and salt accumulation will readily occur in the clay‐rich soil layer at the interface. The maximum soil salt accumulation of L‐LS occurred above the soil interface between the two soil layers with a value of 21.80 g/kg; however, for L‐SiCL and L‐SiL, the maximum salt accumulation occurred below the soil interface between the two soil layers, with values of 23.80 g/kg and 20.08 g/kg, respectively. (d) Interlayered soils showed remarkable changes in the water infiltration characteristics and salt‐leaching intensities under NPI, and the properties for the soil profile with a silty loam interlayer were better than those for the soil profile with a silty clay loam interlayer. The soil profile with a loamy sand interlayer had the lowest amount of water infiltration, which resulted in reductions of the salt‐leaching intensities. Thus, NPI is clearly not suitable for loamy sand soil. Overall, the results demonstrated that soil texture configurations affected water movement and solute transport under NPI. Therefore, careful consideration should be given to the use of NPI to achieve target soil water and solution conditions and reduce water loss.     

Using data assimilation method to calibrate a heterogeneous conductivity field and improve solute transport prediction with an unknown contamination source

Hydraulic conductivity distribution and plume initial source condition are two important factors affecting solute transport in heterogeneous media. Since hydraulic conductivity can only be measured at limited locations in a field, its spatial distribution in a complex heterogeneous medium is generally uncertain. In many groundwater contamination sites, transport initial conditions are generally unknown, as plume distributions are available only after the contaminations occurred. In this study, a data assimilation method is developed for calibrating a hydraulic conductivity field and improving solute transport prediction with unknown initial solute source condition. Ensemble Kalman filter (EnKF) is used to update the model parameter (i.e., hydraulic conductivity) and state variables (hydraulic head and solute concentration), when data are available. Two-dimensional numerical experiments are designed to assess the performance of the EnKF method on data assimilation for solute transport prediction. The study results indicate that the EnKF method can significantly improve the estimation of the hydraulic conductivity distribution and solute transport prediction by assimilating hydraulic head measurements with a known solute initial condition. When solute source is unknown, solute prediction by assimilating continuous measurements of solute concentration at a few points in the plume well captures the plume evolution downstream of the measurement points.     

Multi-functional heat pulse probe measurements of coupled vadose zone flow and transport

Simultaneous measurement of coupled water, heat, and solute transport in unsaturated porous media is made possible with the multi-functional heat pulse probe (MFHPP). The probe combines a heat pulse technique for estimating soil heat properties, water flux, and water content with a Wenner array measurement of bulk soil electrical conductivity (EC_bulk). To evaluate the MFHPP, we conducted controlled steady-state flow experiments in a sand column for a wide range of water saturations, flow velocities, and solute concentrations. Flow and transport processes were monitored continuously using the MFHPP. Experimental data were analyzed by inverse modeling of simultaneous water, heat, and solute transport using an adapted HYDRUS-2D model. Various optimization scenarios yielded simultaneous estimation of thermal, solute, and hydraulic parameters and variables, including thermal conductivity, volumetric water content, water flux, and thermal and solute dispersivities. We conclude that the MFHPP holds great promise as an excellent instrument for the continuous monitoring and characterization of the vadose zone.     

Modelling soil solute release and transport in run‐off on a loessial slope with and without surface stones

Stone covers on loessial slopes can increase the time of infiltration by slowing the velocity of the overland flow, which reduces the transport of solutes, but few mechanistic models have been tested under water‐scouring conditions. We carried out field experiments to test a previously proposed, physically based model of water and solute transport. The area of soil infiltration was calculated from the uncovered surface area, and Richards' equation and the kinematic wave equation were used to describe water infiltration and flow along slopes with stone covers. The transport of chemicals into the run‐off from the surface soil, presumably by diffusion, and their movement in the soil profile could be described by the convection–diffusion equations of the model. The simulated and measured data correlated well. The stones on the soil surface reduced the area available for infiltration but increased the Manning coefficient, eventually leading to increased water infiltration and decreased solute loss with run‐off. Our results indicated that the traditional model of water movement and solute migration could be used to simulate water transport and solute migration for stone‐covered soil on loessial slopes.     

Implementation of Solute Transport in the Vadose Zone into the “HYDRUS Package for MODFLOW”

The “HYDRUS package for MODFLOW” is an existing MODFLOW package that allows MODFLOW to simultaneously evaluate transient water flow in both unsaturated and saturated zones. The package is based on incorporating parts of the HYDRUS-1D model (to simulate unsaturated water flow in the vadose zone) into MODFLOW (to simulate saturated groundwater flow). The coupled model is effective in addressing spatially variable saturated-unsaturated hydrological processes at the regional scale. However, one of the major limitations of this coupled model is that it does not have the capability to simulate solute transport along with water flow and therefore, the model cannot be employed for evaluating groundwater contamination. In this work, a modified unsaturated flow and transport package (modified HYDRUS package for MODFLOW and MT3DMS) has been developed and linked to the three-dimensional (3D) groundwater flow model MODFLOW and the 3D groundwater solute transport model MT3DMS. The new package can simulate, in addition to water flow in the vadose zone, also solute transport involving many biogeochemical processes and reactions, including first-order degradation, volatilization, linear or nonlinear sorption, one-site kinetic sorption, two-site sorption, and two-kinetic sites sorption. Due to complex interactions at the groundwater table, certain modifications of the pressure head (compared to the original coupling) and solute concentration profiles were incorporated into the modified HYDRUS package. The performance of the newly developed model is evaluated using HYDRUS (2D/3D), and the results indicate that the new model is effective in simulating the movement of water and contaminants in the saturated-unsaturated flow domains.     

Numerical method of moments for solute transport in a nonstationary flow field conditioned on hydraulic conductivity and head measurements

The unconditional stochastic studies on groundwater flow and solute transport in a nonstationary conductivity field show that the standard deviations of the hydraulic head and solute flux are very large in comparison with their mean values (Zhang et al. in Water Resour Res 36:2107–2120, 2000; Wu et al. in J Hydrol 275:208–228, 2003; Hu et al. in Adv Water Resour 26:513–531, 2003). In this study, we develop a numerical method of moments conditioning on measurements of hydraulic conductivity and head to reduce the variances of the head and the solute flux. A Lagrangian perturbation method is applied to develop the framework for solute transport in a nonstationary flow field. Since analytically derived moments equations are too complicated to solve analytically, a numerical finite difference method is implemented to obtain the solutions. Instead of using an unconditional conductivity field as an input to calculate groundwater velocity, we combine a geostatistical method and a method of moment for flow to conditionally simulate the distributions of head and velocity based on the measurements of hydraulic conductivity and head at some points. The developed theory is applied in several case studies to investigate the influences of the measurements of hydraulic conductivity and/or the hydraulic head on the variances of the predictive head and the solute flux in nonstationary flow fields. The study results show that the conditional calculation will significantly reduce the head variance. Since the hydraulic head measurement points are treated as the interior boundary (Dirichlet boundary) conditions, conditioning on both the hydraulic conductivity and the head measurements is much better than conditioning only on conductivity measurements for reduction of head variance. However, for solute flux, variance reduction by the conditional study is not so significant.     

Infiltration and solute transport under a seasonal wetland: bromide tracer experiments in Saskatoon,Canada

In the northern glaciated plain of North America, the duration of surface water in seasonal wetlands is strongly influenced by the rate of infiltration and evaporation. Infiltration also plays important roles in nutrient exchange at the sediment–water interface and groundwater recharge under wetlands. A whole‐wetland bromide tracer experiment was conducted in Saskatchewan, Canada to evaluate infiltration and solute transport processes. Bromide concentrations of surface water, groundwater, sediment pore water and plant tissues were monitored as the pond water‐level gradually dropped until there was no surface water. Hydraulic head gradients showed strong lateral flow from under the wetland to the treed riparian zone during the growing season. The bromide mass balance analysis showed that in early spring, almost 50% of water loss from the wetland was by infiltration, and it increased to about 70% in summer as plants in and around the wetland started to transpire more actively. The infiltration contributed to recharging the shallow, local groundwater under the wetland, but much of it was taken up by trees without recharging the deeper groundwater system. Emergent plants growing in the wetlands incorporated some bromide, but overall uptake of bromide by vegetation was less than 10% of the amount initially released. After one summer, most of the subsurface bromide was found within 40–80 cm of the soil surface. However, some bromide penetrated as deep as 2–3 m, presumably owing to preferential flow pathways provided by root holes or fractures. Copyright © 2004 Crown in the Right of Canada. Published by John Wiley & Sons, Ltd.     

A coupled model for simulating surface water and groundwater interactions in coastal wetlands

Coastal wetlands are characterized by strong, dynamic interactions between surface water and groundwater. This paper presents a coupled model that simulates interacting surface water and groundwater flow and solute transport processes in these wetlands. The coupled model is based on two existing (sub) models for surface water and groundwater, respectively: ELCIRC (a three‐dimensional (3‐D) finite‐volume/finite‐difference model for simulating shallow water flow and solute transport in rivers, estuaries and coastal seas) and SUTRA (a 3‐D finite‐element/finite‐difference model for simulating variably saturated, variable‐density fluid flow and solute transport in porous media). Both submodels, using compatible unstructured meshes, are coupled spatially at the common interface between the surface water and groundwater bodies. The surface water level and solute concentrations computed by the ELCIRC model are used to determine the boundary conditions of the SUTRA‐based groundwater model at the interface. In turn, the groundwater model provides water and solute fluxes as inputs for the continuity equations of surface water flow and solute transport to account for the mass exchange across the interface. Additionally, flux from the seepage face was routed instantaneously to the nearest surface water cell according to the local sediment surface slope. With an external coupling approach, these two submodels run in parallel using time steps of different sizes. The time step (Δt_g) for the groundwater model is set to be larger than that (Δt_s) used by the surface water model for computational efficiency: Δt_g = M × Δt_s where M is an integer greater than 1. Data exchange takes place between the two submodels through a common database at synchronized times (e.g. end of each Δt_g). The coupled model was validated against two previously reported experiments on surface water and groundwater interactions in coastal lagoons. The results suggest that the model represents well the interacting surface water and groundwater flow and solute transport processes in the lagoons. Copyright © 2011 John Wiley & Sons, Ltd.     

Effect of anisotropy on solute transport in degraded fen peat soils

Peat soils are heterogeneous, anisotropic porous media. Compared to mineral soils, there is still limited understanding of physical and solute transport properties of fen peat soils. In this study, we aimed to explore the effect of soil anisotropy on solute transport in degraded fen peat. Undisturbed soil cores, taken in vertical and horizontal direction, were collected from one drained and one restored fen peatland both in a comparable state of soil degradation. Saturated hydraulic conductivity (K _s) and chemical properties of peat were determined for all soil cores. Miscible displacement experiments were conducted under saturated steady state conditions using potassium bromide as a conservative tracer. The results showed that (1) the K _s in vertical direction (K _sv) was significantly higher than that in horizontal direction (K_sh), indicating that K _s of degraded fen peat behaves anisotropically; (2) pronounced preferential flow occurred in vertical direction with a higher immobile water fraction and a higher pore water velocity; (3) the 5% arrival time (a proxy for the strength of preferential flow) was affected by soil anisotropy as well as study site. A strong correlation was found between 5% arrival time and dispersivity, K _s and mobile water fraction; (4) phosphate release was observed from drained peat only. The impact of soil heterogeneity on phosphate leaching was more pronounced than soil anisotropy. The soil core with the strongest preferential flow released the highest amount of phosphate. We conclude that soil anisotropy is crucial in peatland hydrology but additional research is required to fully understand anisotropy effects on solute transport.     

FracKfinder: A MATLAB Toolbox for Computing Three-Dimensional Hydraulic Conductivity Tensors for Fractured Porous Media

Fractures in porous media have been documented extensively. However, they are often omitted from groundwater flow and mass transport models due to a lack of data on fracture hydraulic properties and the computational burden of simulating fractures explicitly in large model domains. We present a MATLAB toolbox, FracKfinder, that automates HydroGeoSphere (HGS), a variably saturated, control volume finite-element model, to simulate an ensemble of discrete fracture network (DFN) flow experiments on a single cubic model mesh containing a stochastically generated fracture network. Because DFN simulations in HGS can simulate flow in both a porous media and a fracture domain, this toolbox computes tensors for both the matrix and fractures of a porous medium. Each model in the ensemble represents a different orientation of the hydraulic gradient, thus minimizing the likelihood that a single hydraulic gradient orientation will dominate the tensor computation. Linear regression on matrices containing the computed three-dimensional hydraulic conductivity (K) values from each rotation of the hydraulic gradient is used to compute the K tensors. This approach shows that the hydraulic behavior of fracture networks can be simulated where fracture hydraulic data are limited. Simulation of a bromide tracer experiment using K tensors computed with FracKfinder in HGS demonstrates good agreement with a previous large-column, laboratory study. The toolbox provides a potential pathway to upscale groundwater flow and mass transport processes in fractured media to larger scales.