Zinc-lead skarn deposits at Leadville, New South Wales, Australia, and their distinction from volcanic-hosted massive sulphides

Exploration of Zn-rich sulphide deposits at Leadville, northern Lachlan Fold Belt, New South Wales, for over two decades has been largely on the premise that the mineralisation represents felsic volcanic-hosted massive sulphides (VHMS). Deposits are hosted by ?Silurian felsic metavolcanic, psammopelitic and calcareous metasedimentary rocks which have been intruded by the late Carboniferous I-type Gulgong Granite. Evidence for an epigenetic replacement (skarn) origin of the deposits, rather than representing metamorphosed volcanogenic massive sulphides, includes the proximity of evolved granitic intrusives and reactive carbonate rocks, a skarn mineral assemblage (with characteristic prograde and retrograde stages), lack of textural or lithological indications of an exhalative origin, and gossan and sulphide compositions consistent with Zn-Pb skarns and atypical of Lachlan Fold Belt VHMS deposits. Furthermore, sulphide lead isotope ratios are significantly more radiogenic than signatures for VHMS deposits in the Lachlan Fold Belt. Carbonate δ¹³C and δ¹⁸O and sulphide δ³⁴S values are consistent with the interaction of magmatic hydrothermal fluids with Palaeozoic carbonate rocks and a largely magmatic source of sulphur. It is concluded that the Leadville deposits are of skarn type, genetically related to the Gulgong Granite.     

The hydrothermal system of Central Jebilet (Variscan Belt,Morocco): A genetic association between bimodal plutonism and massive sulphide deposits?

Central Jebilet (Moroccan Variscan Belt) hosts several Cu and Pb–Zn massive sulphide deposits that are associated with a suite of gabbroic and microgranitic, tholeiitic to alkaline, intrusions emplaced 330 Ma ago. The intrusions and ore bodies form structural lineaments within marine Visean shales that are affected by very low to low-grade post-Visean metamorphism and contemporaneous shortening accompanied by the development of conjugate ductile to brittle shear zones. The ductile shear zones are localised in thermally softened aureoles around magmatic intrusions, while brittle deformation is common far from the intrusions. The intrusions have induced a contact metamorphism that reaches the hornblende hornfels facies, and their emplacement was accompanied by hydrothermal activity that leached base metals from the felsic intrusions.The massive sulphide deposits consist of steeply dipping elongate lenses that are located in shear zones 1–1.5 km away from the intrusions. They are dominated by pyrrhotite (up to 90%), sphalerite, galena, chalcopyrite, pyrite and arsenopyrite forming a mylonitic texture. Their wall rocks are altered to syntectonic mineral assemblages similar to those found in the alteration zones associated with the magmatic intrusions. The massive sulphide deposits located near the felsic intrusions are rich in lead and zinc compared to those located near the mafic intrusions, which are copper deposits. These relationships indicate that the whole Central Jebilet hydrothermal system could be described in terms of a lateral secretion of base metals from source zones (i.e. bimodal intrusions) to discharge zones (i.e. the Jebilet sulphide deposits). The metapelites in the contact metamorphic zone around felsic intrusions contain zincian ilmenite that was probably related to interaction of the host rocks with chlorine-rich fluid carrying zinc and other metals leached from the microgranites.     

Petrology and deformation of metamorphosed volcanic-exhalative sediments in the Gairloch Schist Belt,N.W. Scotland

The Gairloch Schist Belt in the Archaean to Early Proterozoic Lewisian Complex of north-west Scotland is largely composed of amphibolite facies metabasites and metagreywackes. These are associated with a distinctive suite of metamorphosed volcanic-exhalative sediments including quartz-magnetite rocks, garnet-grunerite rocks and compositionally variable, siliceous calcite- and dolomite-bearing lithologies. The carbonate horizons are locally rich in sulphide and carry Cu-Zn-Au mineralization. Meta-exhalites occur within parts of metavolcanic units characterized by metamorphosed tuffs and tuffs mixed with exhalative material. Quartz-magnetite and carbonate horizons were dismembered and underwent mylonitic recrystallization during regional compression. The associated metabasic rocks in the shear zones have suffered extensive phyllonitization. This style and degree of deformation are not developed elsewhere in the immediate area which suggests that ductile shear zones in the Gairloch Schist Belt were preferentially initiated near and localized around the meta-exhalative horizons.     

Pan-African deformations in the basement of the Negele area, southern Ethiopia

Polydeformed and metamorphosed Neoproterozoic rocks of the East African Orogen in the Negele area constituted three lithostructurally distinct and thrust-bounded terranes. These are, from west to east, the Kenticha, Alghe and Bulbul terranes. The Kenticha and Bulbul terranes are metavolcano-sedimentary and ultramafic sequences, representing parts of the Arabian-Nubian Shield (ANS), which are welded to the central Alghe gneissic terrane of the Mozambique Belt affinity along N-S-trending sheared thrust contacts. Structural data suggest that the Negele basement had evolved through three phases of deformation. During D1 (folding) deformation, north-south upright and inclined folds with north-trending axes were developed. East and west-verging thrusts, right-lateral shearing along the north-oriented Kenticha and Bulbul thrust contacts and related structural elements were developed during D2 (thrusting) deformation. The pervasive D1 event is interpreted to have occurred at 620-610 Ma and the D2 event ended prior to 554 Ma. Right-lateral strike-slips along thrust contacts are interpreted to have been initiated during late D2. During D3, left-lateral strike-slip along the Wadera Shear Zone and respective strike-slip movements along conjugate set of shear zones were developed in the Alghe terrane, and are interpreted to have occurred later than 557 Ma. The structural data suggest that eastward thrusting of the Kenticha and westward tectonic transport of the Bulbul sequences over the Alghe gneissic terrane of the Mozambique Belt, during D2, were accompanied by right-lateral strike-slip displacements along thrust contacts. Right-lateral strike-slip movements along the Kenticha thrust contact, further suggest northward movement of the Kenticha sequence during the Pan-African orogeny in the Neoproterozoic. Left-lateral strike-slip along the orogen-parallel NNE-SSW Wadera Shear Zone and strike-slip movements along a conjugate set of shear zones completed final terrane amalgamation between the Arabian-Nubian Shield and the Mozambique Belt in Neoproterozoic southern Ethiopia.     

Post-depositional tectonic modification of VMS deposits in Iberia and its economic significance

The original stratigraphic relationships and structure of VMS deposits are commonly obscured by deformation. This can also affect their economic significance, as shown by several Iberian Pyrite Belt (IPB, SW Iberia) examples. The contrasting rheologic properties of the different lithologies present in an orebody (massive sulphide, feeder stockwork, alteration envelope, volcanic and sedimentary rocks) play a major role in determining its overall behaviour. Variscan thin-skinned tectonics led to stacking of the massive pyrite and stockwork bodies in duplex structures, resulting in local thickening and increased tonnage of minable mineralization. Furthermore, differential mechanical behaviour of the different sulphide minerals localised the detachments along relatively ductile sulphide-rich bands. The result was a geochemical and mineralogical reorganisation of most deposits, which now consist of barren, massive pyrite horses, bounded by base metal-rich ductile shear zones. Metal redistribution was enhanced by mobilisation of the base metal sulphides from the initially impoverished massive pyrite, through pressure-solution processes, to tensional fissures within the already ductile shear zones. In NW Iberia, VMS deposits were also strongly overprinted by the Variscan deformation during emplacement of the Cabo Ortegal and órdenes allochthonous nappe complexes, but no stacking of the orebodies was produced. Original contacts were transposed, and the orebodies, their feeder zones and the country rock acquired pronounced laminar geometry. In lower-grade rocks (greenschist facies, Cabo Ortegal Complex), solution transfer mechanisms are common in pyrite, which remains in the brittle domain, while chalcopyrite shows ductile behaviour. In higher-grade rocks (amphibolite facies, órdenes Complex), metamorphic recrystallisation overprints earlier deformation textures. The contrasting behaviour of the IPB and NW Iberian deposits is explained by key factors that affect their final geometry, composition and economics, such as pre-deformation structure, size and mineralogical composition of the orebody and associated lithologies, temperature, crustal level, deviatoric stress and availability of a fluid phase during deformation and the style and rate of deformation.     

Oceanic lithosphere and ophiolites: Birth,life and final resting place of related ore deposits

In this contribution an overview of oceanic lithosphere, associated ore deposits (sulphides, Fe and Mn oxides, chromitites) and their final destination in ophiolitic rocks are presented. This is followed by a discussion on massive sulphide mineralisation formed at mid-ocean ridges (MOR) and/or supra-subduction zones (SSZ). The geological characteristics and the genesis of the Cu-rich massive sulphide deposits of Cyprus and of the Oman ophiolite are discussed based on an extensive review of the published literature. This is followed by a synopsis of the ophiolitic terranes and associated mineral system in the Urals. We also present an overview of the ophiolitic belts and sutures of the Tethyan orogens, focussing on the podiform chromite deposits that they typically host, with a special focus on the ophiolitic chromitites of Turkey. A final section deals with possible ophiolites of Proterozoic and Archaean ages and, where applicable, associated chromitites. In the concluding remarks a brief note is made of some specific ancient seafloor hydrothermal constructs that have been interpreted as black chimneys in volcanogenic massive sulphide (VMS) deposits now hosted in ophiolitic sequences.     

辽宁树基沟铜锌矿床地球化学特征及成因

辽宁树基沟铜锌块状硫化物矿床产于太古宙绿岩带中,矿床形成后经历了强烈的变质和变形,变质程度达到高级角闪岩相。通过含矿岩系地球化学研究,讨论了岩浆来源、成岩构造背景及成因。研究表明,含矿岩系明显富集大离子亲石元素、轻稀土元素及活泼的不相容元素,相对亏损高场强元素和重稀土元素,具有较高的Th/Ta、Ce/Yb、La/Nb、La/Ta比值,其原始地幔标准化的微量元素蛛网图模式与典型钙碱性岛弧玄武岩模式极为相似,均呈"三隆起"的形式,原岩为一套中酸性火山-沉积岩组合,区内这套英安岩、流纹岩、安山岩-玄武岩的钙碱性火山岩组合是由同源岩浆分异所得,其形成于岛弧环境。综合矿床形成背景环境、成矿物质来源和矿床地质特征,笔者初步认为其成因类型为诺兰达型块状硫化物矿床。     

Gold potential of the Mpanda Mineral Field, SW Tanzania: evaluation based on geological, lead isotopic and aeromagnetic data

Gold and base metals of the Mpanda Mineral Field (MMF) is the focus of this paper. Gold veins and gold-bearing base metal occurrences are structurally controlled by conjugate sets of NW–SE and E–W trending faults and/or shear zones that crosscut high-grade metamorphic rocks and post-kinematic intrusions. It was anticipated that Palaeoproterozic country rocks could have been potential host rocks for the gold mineralisation in this area. This argumentation was based on Pb model ages of various deposits from the MMF. Recent fieldwork and Pb isotopic results presented herein indicate that epigenetic gold and base metal vein-type mineralisation in the MMF is post-Palaeoproterozoic.Our Pb isotope study concentrates on constraining the sources of metals in gold-bearing quartz reefs and base metal occurrences. Pb isotopes of whole rocks and minerals indicate that mineralisation was emplaced during the Neoproterozoic, contemporaneous with the intrusion of alkaline granites and carbonatite complexes (e.g., Sangu–Ikola carbonatite complex) at 720 Ma. The source of Pb in the mineral occurrences is compatible with that characteristic of the Palaeoproterozoic host rocks. Aeromagnetic data suggest that the gold-bearing, NNW–SSE trending area continues to the north beyond Mpanda town. Pb isotope results and aeromagnetic data have significant implications for future exploration programs within the region, in that the search should potentially focus on the defined geophysical borders and trendlines, and on Neoproterozoic, rather than Palaeoproterozoic vein systems.     

Metavolcanic host rocks,mineralization, and gossans of the Shaib al Tair and Rabathan volcanogenic massive sulphide deposits of the Wadi Bidah Mineral District,Saudi Arabia

The Wadi Bidah Mineral District of Saudi Arabia contains more than 16 small outcropping stratabound volcanogenic Cu–Zn–(Pb) ± Au-bearing massive sulphide deposits and associated zones of hydrothermal alteration. Here, we use major and trace element analyses of massive sulphides, gossans, and hydrothermally altered and least altered metamorphosed host rock (schist) from two of the deposits (Shaib al Tair and Rabathan) to interpret the geochemical and petrological evolution of the host rocks and gossanization of the mineralization. Tectonic interpretations utilize high-field-strength elements, including the rare earth elements (REE), because they are relatively immobile during hydrothermal alteration, low-grade metamorphism, and supergene weathering and therefore are useful in constraining the source, composition, and physicochemical parameters of the primary igneous rocks, the mineralizing hydrothermal fluid and subsequent supergene weathering processes. Positive Eu anomalies in some of the massive sulphide samples are consistent with a high temperature (>250°C) hydrothermal origin, consistent with the Cu contents (up to 2 wt.%) of the massive sulphides. The REE profiles of the gossans are topologically similar to nearby hydrothermally altered felsic schists (light REE (LREE)-enriched to concave-up REE profiles, with or without positive Eu anomalies) suggesting that the REE experienced little fractionation during metamorphism or supergene weathering. Hydrothermally altered rocks (now schists) close to the massive sulphide deposits have high base metals and Ba contents and have concave-up REE patterns, in contrast to the least altered host rocks, consistent with greater mobility of the middle REE compared to the light and heavy REE during hydrothermal alteration. The gossans are interpreted to represent relict massive sulphides that have undergone supergene weathering; ‘chert’ beds within these massive sulphide deposits may be leached wall-rock gossans that experienced silicification and Pb–Ba–Fe enrichment from acidic groundwaters generated during gossan formation.     

Indicator minerals as guides to base metal sulphide mineralisation in Betul Belt, central India

Zn-bearing minerals that act as indicator minerals for base metal sulphide mineralization from the Proterozoic Betul Belt, central India with special emphasis on their genetic significance have been discussed. Sulphide mineralisation is hosted by the felsic volcanic rocks and has similarities with volcanic-hosted massive sulphide deposits in other parts of the world. Synvolcanic hydrothermal alteration is crudely zoned with an inner high Mg-Ca core and an outer wider envelop of Al-Fe rich mineral assemblage. Most of the prospects have strata bound, moderately to steeply dipping, multiple, sub-parallel sheet like ore bodies composed of disseminated and semi-massive to massive ores. Zn-bearing spinel, staurolite, biotite and ilmenite typically occur within the foot-wall alteration zones in close proximity to the sulphide mineralization. Zincian spinel is ubiquitous irrespective of the nature of alteration zone. Zincian staurolite is nearly absent in Mg-Ca alteration zones but commonly present in Al-Fe alteration zone along with zincian ilmenite. Zn-bearing biotite in intimate association with zincian spinel is generally found in Mg-Ca alteration zone and in the transition to Al-Fe alteration zone. Most of these indicator minerals can be considered as products of desulphidation of sphalerite during metamorphism. Mechanisms other than desulphidation like formation of gahnite by overstepping of the zinc saturation limit of biotite during retrogression to chlorite and formation of zincian staurolite at the expense of gahnite is also recorded. Field presence of these minerals has immense significance in exploration in Betul Belt as they occur in close spatial relationship with the sulphide rich zones and therefore act as direct vectors to ore.     

Kinematic analysis of sinistral cataclastic shear zones along the northern margin of the Mino Belt, central Japan

In this paper, cataclastic shear zones along the northern margin of the Mino Belt, central Japan are described, and the significance of the shearing in the tectonic evolution of SW Japan is examined. The Mino Belt in SW Japan is composed of accretionary complexes of Jurassic to Early Cretaceous age. Field investigation revealed that remarkable cataclastic shear zones trending east to northeast run along the northern margin of the Mino Belt. Closely spaced cleavage is developed in these shear zones. Lineation on the cleavage plunges at shallow to moderate angles. Deformation structures (e.g. composite planar fabric and asymmetric structure of clasts) in the sheared rocks clearly indicate a sinistral sense of shear. The shearing ceased by latest Cretaceous time, because the sheared rocks are overlain by unsheared Upper Cretaceous volcanic rocks. The sinistral shearing may be closely related to Cretaceous sinistral movement along the eastern margin of Asia. Sinistral shearing along the northern margin of the Mino Belt can be considered as a key for re-examining the tectonic development of SW Japan.     

Gold mineralization in the Jiangnan Orogenic Belt of South China: Geological,geochemical and geochronological characteristics,ore deposit-type and geodynamic setting

Located in the southeastern margin of the Yangtze Block and generally interpreted as the Neoproterozoic collisional product of the Yangtze with the Cathaysia Blocks of South China, the Jiangnan Orogenic Belt (JOB) contains a number of gold (Au) (-polymetallic) ore deposits and mineral showings, mostly hosted by Neoproterozoic low-grade metamorphic volcaniclastic and sedimentary rocks. The mineralization styles mainly include auriferous quartz veins and disseminated mineralization in altered mylonite and cataclasite that are developed along shear zones, fracture zones and inter- or intra-formational fault zones closely related to regional folding and shearing deformation. Three gold mineralizing epochs are recognized in the JOB. The ca. 423–397 Ma mineralization was associated with the early Paleozoic tectonothermal event(s), which induced widespread emplacement of Silurian S-type granites, low-grade metamorphism and enrichment of gold in the Neoproterozoic rocks (i.e., forming Au source beds). The second Au mineralization epoch, occurring at ca. 176–170 Ma (Jurassic), was related to the subduction of the Paleo-Pacific plate beneath the South China continental margin. The third and most important Au mineralization epoch took place at ca. 144–130 Ma (early Cretaceous), when a Basin-and-Range tectonic pattern was developed, characterized by NE–NNE-trending strike-slip faults, granitic domes and metamorphic core complexes (MCC), and basins filled with red bed lithologies. C, H, O, He-Ar, S and Pb isotopic and fluid-inclusion data suggest that the ore fluids were predominantly metamorphic and/or magmatic, with variable input of mantle-derived fluids and the progressive involvement of meteoric waters in the later stages of mineralization. Ore materials were mostly contributed by the Neoproterozoic source beds, plus a possible contribution from mantle- or magma-derived components. The Au (-polymetallic) deposits in the JOB, particularly those formed in the early Cretaceous, share many geological and geochemical features with the orogenic-type and Carlin-type deposits. In the context of tectonic evolution of South China, the gold mineralization in the JOB may be considered an “intracontinental reactivation type”, characterized by synchronous development of Au–polymetallic mineralization, reactivation of stuctures developed in Neoproterozoic metamorphic rocks, and widespread granite emplacement in the late Mesozoic.     

Transpressive Structures in the Ghadir Shear Belt,Eastern Desert,Egypt: Evidence for Partitioning of Oblique Convergence in the Arabian‐Nubian Shield during Gondwana Agglutination

Transpressional deformation has played an important role in the late Neoproterozoic evolution of the ArabianNubian Shield including the Central Eastern Desert of Egypt. The Ghadir Shear Belt is a 35 km-long, NW-oriented brittleductile shear zone that underwent overall sinistral transpression during the Late Neoproterozoic. Within this shear belt, strain is highly partitioned into shortening, oblique, extensional and strike-slip structures at multiple scales. Moreover, strain partitioning is heterogeneous along-strike giving rise to three distinct structural domains. In the East Ghadir and Ambaut shear belts, the strain is pure-shear dominated whereas the narrow sectors parallel to the shear walls in the West Ghadir Shear Zone are simple-shear dominated. These domains are comparable to splay-dominated and thrust-dominated strike-slip shear zones. The kinematic transition along the Ghadir shear belt is consistent with separate strike-slip and thrustsense shear zones. The earlier fabric(S1), is locally recognized in low strain areas and SW-ward thrusts. S2 is associated with a shallowly plunging stretching lineation(L2), and defines ～NW-SE major upright macroscopic folds in the East Ghadir shear belt. F2 folds are superimposed by ～NNW–SSE tight-minor and major F3 folds that are kinematically compatible with sinistral transpressional deformation along the West Ghadir Shear Zone and may represent strain partitioning during deformation. F2 and F3 folds are superimposed by ENE–WSW gentle F4 folds in the Ambaut shear belt. The sub-parallelism of F3 and F4 fold axes with the shear zones may have resulted from strain partitioning associated with simple shear deformation along narrow mylonite zones and pure shear-dominant deformation in fold zones. Dextral ENEstriking shear zones were subsequently active at ca. 595 Ma, coeval with sinistral shearing along NW-to NNW-striking shear zones. The occurrence of upright folds and folds with vertical axes suggests that transpression plays a significant role in the tectonic evolution of the Ghadir shear belt. Oblique convergence may have been provoked by the buckling of the Hafafit gneiss-cored domes and relative rotations between its segments. Upright folds, fold with vertical axes and sinistral strike-slip shear zones developed in response to strain partitioning. The West Ghadir Shear Zone contains thrusts and strikeslip shear zones that resulted from lateral escape tectonics associated with lateral imbrication and transpression in response to oblique squeezing of the Arabian-Nubian Shield during agglutination of East and West Gondwana.     

陕西周至马鞍桥金矿床地质特征及成因分析

阐述了马鞍桥金矿区的地层、构造、岩浆岩特征，总结了金矿床矿体、矿石及化学成分的基本特点，分析了围岩、剪切构造带、中酸性岩体与金矿化的关系，认为马鞍桥金矿的成矿物质来源于围岩泥盆系罗汉寺岩群，成矿作用严格受脆性剪切变形变质带控制，剪切同期中酸性岩浆活动为含矿热液上升迁移和富集成主矿体提供了必要的热能。含矿热液与韧性剪切变质岩之间交代作用的强度是导致金的沉淀和富集形成金矿体的关键。矿床为韧性剪切带蚀变岩型金矿。     

Applying the box plot to the recognition of footwall alteration zones related to VMS deposits in a high-grade metamorphic terrain, South Africa, a lithogeochemical exploration application

Alteration zones (more commonly foot wall alteration zones) are related to volcanic-hosted massive sulfide (VMS) deposits and represent unique features that may be targeted during exploration. Of these, the chloritic foot wall alteration pipe is the most extensive and characteristic of VMS deposits. This feature is geochemically identified by a strong relative enrichment in aluminium and magnesium and a coupled depletion in calcium and sodium, giving rise to chloritic rocks in the primary environment of formation. During high grade regional metamorphism such chloritic precursor rock types are replaced by an unusual mineral paragenesis, typically containing magnesium rich cordierite, phlogopite, orthoamphiboles or orthopyroxenes and aluminium rich minerals such as sillimanite and corundum. This suggests that the unusual geochemical features of the alteration zone, retained during the deformation and metamorphism, should be recognisable in lithogeochemical exploration.The massive sulfide deposit in the eastern part of the metamorphic Namaqua Province, South Africa, at Areachap, Kantienpan and the defunct Prieska Cu–Zn Mine are hosted by a Mid-Proterozoic volcano sedimentary succession known as the Areachap Group. These deposits were affected by a complex deformation and metamorphic history and represent examples of upper amphibolite to granulite grade metamorphosed VMS deposits.The application of the known lithogeochemical methods is especially complicated where the geology is not well understood, due to the poor rock exposure of complexly deformed and metamorphosed areas, such as in the eastern part of the Namaqua Province.The box plot presents a more readily applicable lithogeochemical method to characterize and identify the alteration process, but it was designed for relatively un-metamorphosed environments. It is demonstrated here that the box plot may also be applied to high-grade metamorphic terrains and that the mineral phases used in defining the boxplot in low grade metamorphic environments may be replaced by their equivalents in high grade metamorphic terrains. The compositional trends of the metamorphic minerals themselves may be used in defining the boxplot for high grade metamorphic terrains. These include the transition of: annite to phlogopite; grossular to almandine or pyrope, augite to enstatite or clinoenstatite, and hornblende to gedrite or cummingtonite. Close to the ore zone, the relative Mg content of pyroxene, cordierite and biotite are higher than further away from this zone. It could be demonstrated that the changes in the mineral compositions are gradational when comparing unaffected rocks with progressively more altered wall rocks.Conclusions based on an application of the isocon method demonstrate that primary footwall alteration zones in the Areachap Group's VMS deposits are characterized by elemental depletion of Na₂O, CaO, Sr, Ni, V and La and enrichment of MgO, Fe₂O_3(total), S, Zn, SiO₂, Co and F. It is shown that the whole rock compositions of rocks that were independently identified as the metamorphic equivalents of altered rocks, using the isocon method, plot in the correct place in the box plot for high grade regionally metamorphosed terrains. This establishes the box plot as an effective and practical tool for lithogeochemical exploration for VMS deposits in complexly deformed high grade metamorphosed terrains.     

Metallogeny and tectonic development of the Tasman Fold Belt System in Queensland

The northern part of the Tasman Fold Belt System in Queensland comprises three segments, the Thomson, Hodgkinson- Broken River, and New England Fold Belts. The evolution of each fold belt can be traced through pre-cratonic (orogenic), transitional, and cratonic stages. The different timing of these stages within each fold belt indicates differing tectonic histories, although connecting links can be recognised between them from Late Devonian time onward. In general, orogenesis became younger from west to east towards the present continental margin. The most recent folding, confined to the New England Fold Belt, was of Early to mid-Cretaceous age. It is considered that this eastward migration of orogenic activity may reflect progressive continental accretion, although the total amount of accretion since the inception of the Tasman Fold Belt System in Cambrian time is uncertain.The Thomson Fold Belt is largely concealed beneath late Palaeozoic and Mesozoic intracratonic basin sediments. In addition, the age of the more highly deformed and metamorphosed rocks exposed in the northeast is unknown, being either Precambrian or early Palaeozoic. Therefore, the tectonic evolution of this fold belt must remain very speculative. In its early stages (Precambrian or early Palaeozoic), the Thomson Fold Belt was probably a rifted continental margin adjacent to the Early to Middle Proterozoic craton to the west and north. The presence of calc-alkaline volcanics of Late Cambrian Early Ordovician and Early-Middle Devonian age suggests that the fold belt evolved to a convergent Pacific-type continental margin. The tectonic setting of the pre-cratonic (orogenic) stage of the Hodgkinson—Broken River Fold Belt is also uncertain. Most of this fold belt consists of strongly deformed, flysch-type sediments of Silurian-Devonian age. Forearc, back-arc and rifted margin settings have all been proposed for these deposits. The transitional stage of the Hodgkinson—Broken River Fold Belt was characterised by eruption of extensive silicic continental volcanics, mainly ignimbrites, and intrusion of comagmatic granitoids in Late Carboniferous Early Permian time. An Andean-type continental margin model, with calc-alkaline volcanics erupted above a west-dipping subduction zone, has been suggested for this period. The tectonic history of the New England Fold Belt is believed to be relatively well understood. It was the site of extensive and repeated eruption of calc-alkaline volcanics from Late Silurian to Early Cretaceous time. The oldest rocks may have formed in a volcanic island arc. From the Late Devonian, the fold belt was a convergent continental margin above a west-dipping subduction zone. For Late Devonian- Early Carboniferous time, parallel belts representing continental margin volcanic arc, forearc basin, and subduction complex can be recognised.A great variety of mineral deposits, ranging in age from Late Cambrian-Early Ordovician and possibly even Precambrian to Early Cretaceous, is present in the exposed rocks of the Tasman Fold Belt System in Queensland. Volcanogenic massive sulphides and slate belt-type gold-bearing quartz veins are the most important deposits formed in the pre-cratonic (orogenic) stage of all three fold belts. The voicanogenic massive sulphides include classic Kuroko-type orebodies associated with silicic volcanics, such as those at Thalanga (Late Cambrian-Early Ordovician. Thomson Fold Belt) and at Mount Chalmers (Early Permian New England Fold Belt), and Kieslager or Besshi-type deposits related to submarine mafic volcanics, such as Peak Downs (Precambrian or early Palaeozoic, Thomson Fold Belt) and Dianne. OK and Mount Molloy (Silurian—Devonian, Hodgkinson Broken River Fold Belt). The major gold—copper orebody at Mount Morgan (Middle Devonian, New England Fold Belt), is considered to be of volcanic or subvolcanic origin, but is not a typical volcanogenic massive sulphide.The most numerous ore deposits are associated with calc-alkaline volcanics and granitoid intrusives of the transitional tectonic stage of the three fold belts, particularly the Late Carboniferous Early Perman of the Hodgkinson—Broken River Fold Belt and the Late Permian—Middle Triassic of the southeast Queensland part of the New England Fold Belt. In general, these deposits are small but rich. They include tin, tungsten, molybdenum and bismuth in granites and adjacent metasediments, base metals in contact meta somatic skarns, gold in volcanic breccia pipes, gold-bearing quartz veins within granitoid intrusives and in volcanic contact rocks, and low-grade disseminated porphyry-type copper and molybdenum deposits. The porphyry-type deposits occur in distinct belts related to intrusives of different ages: Devonian (Thomson Fold Belt), Late Carboniferous—Early Permian (Hodgkinson—Broken River Fold Belt). Late Permian Middle Triassic (southeast Queensland part of the New England Fold Belt), and Early Cretaceous (northern New England Fold Belt). All are too low grade to be of economic importance at present.Tertiary deep weathering events were responsible for the formation of lateritic nickel deposits on ultramafics and surficial manganese concentrations from disseminated mineralisation in cherts and jaspers.     

Fractures,hydrothermal alterations and permeability in the Soultz Enhanced Geothermal System

Borehole studies of the Soultz-sous-Forêts granite are dedicated to deep geothermics. The hydraulic properties of the reservoir are mainly controlled by the occurrence of some altered cataclastic shear zones showing a low natural permeability characterized by the occurrence of brines. Those zones show a fracture cluster organisation with sealed fractures of various types (post-filled joints, sheared fractures, veins). The main hydrothermal deposits observed within the permeable zones are geodic quartz, carbonates, illite and more locally sulphides. The fracture wall–rocks are intensely transformed: dissolution of igneous minerals, crystallization of new minerals, porosity and permeability increase. It is important to characterize the newly-formed minerals in order to choose the reagents used to improve the permeability of the exchanger by chemical stimulations. This article represents a synthesis of the studies completed by the authors between 1990 and 2008 on the fracture networks, hydrothermal alterations and mineral crystallizations they induced and data about the flow pathways in the exchanger.     

甘肃敦煌-北山早前寒武纪岩石组合-构造初步框架

甘肃敦煌－北山地区广泛出露早前寒武纪岩石。这些岩石在早期的《甘肃省区域地质志》中被确定为前长城系、长城系、奥陶－志留系及部分石炭系。本文认为这些岩石应属太古宙和古元古代。据此，重新厘定了该区早前寒式纪岩石－构造框架。自南向北划分为敦煌太古宙杂岩区、北山南带古元古代剪切构造区和北山北带古元古代－太古宙杂岩区，并根据变形特点和岩石组合，进一步划分出次级带。     

The Xitieshan volcanic sediment-hosted massive sulfide deposit,North Qaidam,China: Geology,structural deformation and geochronology

The Xitieshan deposit (~ 64 Mt at 4.86% Zn, 4.16% Pb, 58 g/t Ag, and 0.68 g/t Au) is hosted by the Middle to Late Ordovician Tanjianshan Group of the North Qaidam tectonic metallogenic belt, NW China. This belt is characterized by island arc volcanic, ultra-high pressure (UHP) metamorphic and ophiolitic rocks. The Tanjianshan Group constitutes a succession of metamorphosed bimodal volcanic and sedimentary rocks, which are interpreted to have formed on the margin of a back-arc ocean basin between the Qaidam block and the Qilian block.Four stratigraphic units are identified within the Ordovician Tanjianshan Group. From northeast to southwest they are: 1) unit a, or the lower volcanic-sedimentary rocks, comprising bimodal volcanic rocks (unit a-1) and sedimentary rocks (unit a-2) ranging from carbonates to black carbonaceous schist; 2) unit b, or intermediate-mafic volcaniclastic rocks, characterized by intermediate to mafic volcaniclastic rocks intercalated with lamellar carbonaceous schist and minor marble lenses; 3) unit c, a purplish red sandy conglomerate that unconformably overlies unit b, representing the product of the foreland basin sedimentation during the Early Silurian; 4) unit d, or mafic volcanic rocks, from base to up, comprising the lower mafic volcaniclastic rocks (unit d-1), middle clastic sedimentary rocks (unit d-2), upper mafic volcaniclastic rocks (unit d-3), and uppermost mafic volcanic rocks (unit d-4). Unit a-2 hosts most of the massive sulfides whereas unit b contains subordinate amounts.The massive stratiform lenses constitute most of the Xitieshan deposit with significant amount of semi-massive and irregularly-shaped sulfides and minor amounts in stringer veins. Pyrite, galena and sphalerite are the dominant sulfide minerals, with subordinate pyrrhotite and chalcopyrite. Quartz is a dominant gangue mineral. Sericite, quartz, chlorite, and carbonate alteration of host rocks accompanies the mineralization.U-Pb zircon geochronology yields three ages of 454 Ma, 452 Ma and 451 Ma for the footwall felsic volcanic rocks in unit a-1, sedimentary host rocks in unit a-2 and hanging-wall unit b, respectively. The Xitieshan deposit is considered to be coeval with the sedimentation of unit a-2 and unit b of the Tanjianshan Group. The Xitieshan deposit has been intensely deformed during two phases (main ductile shear and minor ductile-brittle deformation). The main ductile shear deformation controls the general strike of the ore zones, whereas minor deformation controls the internal geometry of the ore bodies. ⁴⁰Ar-³⁹Ar age of muscovite from mylonitized granitic gneisses in the ductile shear zone is ~ 399 Ma, which is interpreted to date the Xitieshan ductile shear zone, suggesting that Early Devonian metamorphism and deformation post-dated the Tanjianshan Group.The Xitieshan deposit has many features similar to that of the Bathurst district of Canada, the Iberian Pyrite Belt of Spain, the Wolverine volcanogenic massive sulfide deposit in Canada. Based on its tectonic setting, host-rock types, local geologic setting, metal grades, geochronology, temperatures and salinities of mineralizing fluid and source of sulfur, the Xitieshan deposit has features similar to sedimentary exhalative (SEDEX) and VMS deposits and is similar to volcanic and sediment-hosted massive sulfide (VSHMS) deposits.     

Structural architecture of the northern composite terrane, the Eastern Ghats Mobile Belt, India: Implications for Gondwana tectonics

New data from structural mapping and tectonic evaluation in the northern parts of the Eastern Ghats Mobile Belt (EGMB-north) involving the interpretation of satellite images, field traverses, critical outcrop mapping and kinematic studies of macro- as well as microstructures of the shear zone rocks together with the geometry and disposition of Gondwana basins led to, for the first time, the elucidation of post-Grenvillian structural architecture of the terrane. This helps in assessing the sequence of successive tectonothermal events that were responsible for the origin and progressive evolution of the Permo-Carboniferous coal bearing sediments along the Mahanadi rift that forms significant in the reconstruction models of east Gondwana.The composite terrane of high-grade metamorphic rocks (EGMB-north), strikes E–W in contrast to the regional NE–SW trend of the EGMB. The structural architecture obtained from this study is controlled by the boundary shear zones and associated link shear zones. The dextral kinematic displacements along the Northern Boundary Shear Zone (NBSZ) as well as the Mahanadi Shear Zone (MSZ) and Koraput–Sonapur–Rairakhol Shear Zone (KSRSZ) were derived from multi-scale field based structural observations. A N–S structural cross-section presents a crustal-scale ‘flower structure’ across the composite terrane exposing different domains displaying distinctive internal structures with widely varying different geological evolution history and strain partitioning, separated by crustal-scale shear zones. Deep seismic imaging and gravity signatures support ‘flower structure’ model. The pervasive first formed gneissic fabrics were continuously reworked and partitioned into a series of E–W, crustal-scale shear zones.The Neoproterozoic regional dextral transpressional tectonics along the shear zones and their repeated reactivation could be responsible for initiation and successive evolution of Gondwana basins and different episodes of sedimentation. Available geochronological data shows that the structural architecture presented here is post-Grenvillian, which has been repeatedly reactivated through long-lived transpressional tectonics. The composite terrane is characterized by all the typical features of an oblique convergent orogen with transpressional kinematics in the middle to lower crust. The kinematic changes from transpression to transtensional stresses were found to be associated with global geodynamics related to the transformation from Rodinia to Gondwana configuration.