Regional variations in trace element concentrations in tissues of black tiger shrimp Penaeus monodon (Decapoda: Penaeidae) from South Vietnam

The goal of the present study was to examine the specific bioaccumulation of 22 trace elements in muscle, exoskeleton and hepatopancreas of black tiger shrimp Penaeus monodon from the Mekong River Delta (MRD), and the South Key Economic Zone (SKEZ), South Vietnam. The general tendency in most trace element concentrations among different tissues were hepatopancreas > exoskeleton > muscle. Comparisons of trace element levels in tissues between the two regions showed that concentrations of Se in muscle and As in all three tissues were higher in SKEZ; whereas in MRD, the higher concentrations of most elements such as Mn, Cu, Cd, Ba, Hg, were observed in tissues. These geographical variations in trace element levels may reflect the differences in human activities between the two regions of South Vietnam. The target hazard quotient (THQ) values for trace elements (<1) indicate that local residents are not exposed to potential health risks via the consumption of shrimp.     

Regional variations in trace element concentrations in tissues of black tiger shrimp Penaeus monodon (Decapoda: Penaeidae) from South Vietnam

The goal of the present study was to examine the specific bioaccumulation of 22 trace elements in muscle, exoskeleton and hepatopancreas of black tiger shrimp Penaeus monodon from the Mekong River Delta (MRD), and the South Key Economic Zone (SKEZ), South Vietnam. The general tendency in most trace element concentrations among different tissues were hepatopancreas>exoskeleton>muscle. Comparisons of trace element levels in tissues between the two regions showed that concentrations of Se in muscle and As in all three tissues were higher in SKEZ; whereas in MRD, the higher concentrations of most elements such as Mn, Cu, Cd, Ba, Hg, were observed in tissues. These geographical variations in trace element levels may reflect the differences in human activities between the two regions of South Vietnam. The target hazard quotient (THQ) values for trace elements (<1) indicate that local residents are not exposed to potential health risks via the consumption of shrimp.     

Mercury levels in selected bycatch fish species from industrial shrimp-trawl fishery in the SE Gulf of California

Baseline Hg concentration in bycatch fish from the SE Gulf of California were determined in muscle and liver of 19 species. Levels of Hg in muscle were compared with legal limits of this element in national and international legislation. Considering all fish species, mean concentrations in liver (2.458 ± 1.997 μg g⁻¹) were significantly higher (p < 0.05) than in muscle (0.993 ± 0.670 μg g⁻¹). The sequence of averaged Hg concentrations in most ichthyofauna was liver > muscle. Highest level of Hg in muscle (2.556 μg g⁻¹) and liver (7.515 μg g⁻¹) corresponded to Diapterus peruvianus and Ophioscion strabo, respectively. Considering muscle samples, none of the species had levels of Hg above the limit (1.0 μg g⁻¹ wet weight) in the Mexican legislation; with respect to the Japanese (0.4 μg g⁻¹ wet weight) and British (0.3 μg g⁻¹ wet weight) legislations, 26.3% and 31.6% of the species respectively, were above the corresponding limits.     

Silicate and carbonate melt inclusions associated with diamonds in deeply subducted carbonate rocks

Deeply subducted carbonate rocks from the Kokchetav massif (Northern Kazakhstan) recrystallised within the diamond stability field (P = 4.5–6.0 GPa; T ≈ 1000 °C) and preserve evidence for ultra high-pressure carbonate and silicate melts. The carbonate rocks consist of garnet and K-bearing clinopyroxene embedded in a dolomite or magnesian calcite matrix. Polycrystalline magnesian calcite and polyphase carbonate–silicate inclusions occurring in garnet and clinopyroxene show textural features of former melt inclusions. The trace element composition of such carbonate inclusions is enriched in Ba and light rare earth elements and depleted in heavy rare earth elements with respect to the matrix carbonates providing further evidence that the inclusions represent trapped carbonate melt. Polyphase inclusions in garnet and clinopyroxene within a magnesian calcite marble, consisting mainly of a tight intergrowth of biotite + K-feldspar and biotite + zoisite + titanite, are interpreted to represent two different types of K-rich silicate melts. Both melt types show high contents of large ion lithophile elements but contrasting contents of rare earth elements. The Ca-rich inclusions display high REE contents similar to the carbonate inclusions and show a general trace element characteristic compatible with a hydrous granitic origin. Low SiO₂ content in the silicate melts indicates that they represent residual melts after extensive interaction with carbonates. These observations suggest that hydrous granitic melts derived from the adjacent metapelites reacted with dolomite at ultra high-pressure conditions to form garnet, clinopyroxene – a hydrous carbonate melt – and residual silicate melts. Silicate and carbonate melt inclusions contain diamond, providing evidence that such an interaction promotes diamond growth. The finding of carbonate melts in deeply subducted crust might have important consequences for recycling of trace elements and especially C from the slab to the mantle wedge.     

Bioavailability of heavy metals in water and sediments from a typical Mediterranean Bay (Málaga Bay,Region of Andalucía,Southern Spain)

Concentrations of heavy metals were measured in sediment and water from Málaga Bay (South Spain). In the later twentieth century, cities such as Málaga, have suffered the impact of mass summer tourism. The ancient industrial activities, and the actual urbanization and coastal development, recreation and tourism, wastewaters treatment facilities, have been sources of marine pollution. In sediments, Ni was the most disturbing metal because Ni concentrations exceeded the effects range low (ERL), concentration at which toxicity could start to be observed in 85% of the samples analyzed. The metal bioavailability decreased in the order: Cd > Ni > Pb > Cu > Cr. In the sea water samples, Cd and Pb were the most disturbing metals because they exceeded the continuous criteria concentration (CCC) of US EPA in a 22.5% and 10.0% of the samples, respectively. Statistical analyses (ANOVA, PCA, CA) were performed.     

Zircon U–Pb strain chronometry reveals deep impact-triggered flow

Large (> 100 km) meteorite impact cratering events play important roles in surface and biosphere evolution, however, their potential for widespread ductile modification of the lithosphere has been difficult to assess, due partly to our inability to isotopically age-correlate deep mineral fabrics with surface records. We have integrated benchmark U–Pb zircon dating methods (ID-TIMS, SHRIMP) with new microstructural techniques (EBSD, µXRD) to demonstrate that crystal–plastic deformation can cause rapid out-diffusion of radiogenic Pb and accompanying trace element alteration in crystalline zircon. We have used this phenomenon to directly date fabric in Archean zircons and xenoliths of the lower crust of South Africa at 2023 ± 15 million years, coeval with the 2020 ± 3 million year old Vredefort cratering event at surface, with extent ≥ 20,000 km². Our findings indicate that regional exogenic fabrics, similar to high-temperature tectonic fabrics, exist in ancient crust. Moreover, our results establish that crystal-plastic deformation in the lithosphere can now be directly dated and linked to planetary evolution by zircon U–Pb strain chronometry.     

Relation between mantle shear zone deformation and metasomatism in spinel peridotite xenoliths of Jeju Island (South Korea): Evidence from olivine CPO and trace elements

This study presents geochemical and fabric analysis of coarse-grained, porphyroclastic and mylonitic spinel peridotite xenoliths derived from the shallow subcontinental lithospheric mantle of Jeju Island (South Korea). Fabric analysis of olivines in the studied peridotites shows activation of the high temperature (0 1 0)[1 0 0] slip system; however, in the porphyroclastic and mylonitic peridotites, activation of (0 k l)[1 0 0] slip system results in a weaker fabric. Formation of porphyroclastic and mylonitic fabrics are thought to form in a shear-dominated environment. The results of the trace element analysis reveal that the smaller the grain size and weaker the fabric, the more enriched in LREE and HFSE are the peridotites, which indicates a strong relationship between metasomatic agents and mantle shear zones.     

Preconcentration of trace multi-elements in water samples using Dowex 50W-x8 and Chelex-100 resins prior to their determination using inductively coupled plasma atomic emission spectrometry (ICP-OES)

This work presents a solid phase extraction (SPE) method for simultaneous preconcentration of trace elements in water samples prior to their ICP-OES determination. Dowex 50W-x8 and Chelex-100 resins were used as SPE sorbent materials for preconcentration of trace Cd, Co, Cr, Cu, Fe, Ni, Pb and Zn. The optimum sample pH, eluent concentration and sample flow rates were found to 6, 3.0 mol L⁻¹ and 3.0 mL min⁻¹, respectively. In terms of multi-element preconcentration capabilities, Dowex 50W-x8 appeared to be a better sorbent. The recoveries for all the tested analytes were >95%. However, Chelex-100 showed a better performance in terms of recovery (>95%) towards Cu, Fe and Zn. Under optimized conditions using Dowex 50W-x8, the relative standard deviations for different metals were <3%. The limits of detection and limits of quantification ranged from 0.01–0.39 μg L⁻¹ and 0.05–0.1.3 μg L⁻¹, respectively. The accuracy of the preconcentration method was confirmed by spike recovery test and the analysis of certified reference materials. The SPE method was applied for preconcentration of the analyte ions in tap water, bottled water and wastewater samples.     

Deep pooling of low degree melts and volatile fluxes at the 85°E segment of the Gakkel Ridge: Evidence from olivine-hosted melt inclusions and glasses

We present new analyses of volatile, major, and trace elements for a suite of glasses and melt inclusions from the 85°E segment of the ultra-slow spreading Gakkel Ridge. Samples from this segment include limu o pele and glass shards, proposed to result from CO₂-driven explosive activity. The major element and volatile compositions of the melt inclusions are more variable and consistently more primitive than the glass data. CO₂ contents in the melt inclusions extend to higher values (167–1596 ppm) than in the co-existing glasses (187–227 ppm), indicating that the melt inclusions were trapped at greater depths. These melt inclusions record the highest CO₂ melt concentrations observed for a ridge environment. Based on a vapor saturation model, we estimate that the melt inclusions were trapped between seafloor depths (～ 4 km) and ～ 9 km below the seafloor. However, the glasses are all in equilibrium with their eruption depths, which is inconsistent with the rapid magma ascent rates expected for explosive activity. Melting conditions inferred from thermobarometry suggest relatively deep (25–40 km) and cold (1240°–1325 °C) melting conditions, consistent with a thermal structure calculated for the Gakkel Ridge. The water contents and trace element compositions of the melt inclusions and glasses are remarkably homogeneous; this is an unexpected result for ultra-slow spreading ridges, where magma mixing is generally thought to be less efficient based on the assumption that steady-state crustal magma chambers are absent in these environments. All melts can be described by a single liquid line of descent originating from a pooled melt composition that is consistent with the aggregate melt calculated from a geodynamic model for the Gakkel Ridge. These data suggest a model in which deep, low degree melts are efficiently pooled in the upper mantle (9–20 km depth), after which crystallization commences and continues during ascent and eruption. Based on our melting model and the assumption that CO₂ is perfectly incompatible, we show that the highest CO₂ concentrations of the melt inclusions (～ 1600 ppm) are consistent with the calculated CO₂ concentrations of primary undegassed melts. The highest measured CO₂/Nb ratio (443) of Gakkel Ridge melt inclusions predicts a mantle CO₂ content of 134 ppm and would result in a global ridge flux of 2.0 × 10¹² mol CO₂/yr.     

Volatile and trace elements in basaltic glasses from Samoa: Implications for water distribution in the mantle

We report volatile (H₂O, CO₂, F, S, Cl) and trace element data for submarine alkalic basalt glasses from the three youngest Samoan volcanoes, Ta'u, Malumalu and Vailulu'u. Most samples are visibly sulfide saturated, so have likely lost some S during fractionation. Cl / K ratios (0.04–0.15) extend to higher values than pristine MORBs, but are suspected to be partly due to source differences since Cl / K roughly varies as a function of ⁸⁷Sr / ⁸⁶Sr. There are no resolvable differences in the relative enrichment of F among sources, and compatibility of F during mantle melting is established to be nearly identical to Nd. Shallow degassing has affected CO₂ in all samples, and H₂O only in the most shallowly erupted samples from Vailulu'u. Absolute water contents are high for Samoa (0.63–1.50 wt.%), but relative enrichment of water compared to equally incompatible trace elements (Ce, La) is low and falls entirely below normal MORB values. H₂O / Ce (58–157) and H₂O / La (120–350) correlate inversely with ⁸⁷Sr / ⁸⁶Sr compositions (0.7045–0.7089). This leads us to believe that, because of very fast diffusion of hydrogen in mantle minerals, recycled lithospheric material with high initial water and trace element content will lose water to the drier ambient mantle during storage within the inner Earth. The net result is the counter-intuitive appearance of greater dehydration with greater mantle enrichment. We expect that subducted slabs will experience a two-stage dehydration history, first within subduction zones and then in the ambient mantle during long-term convective mixing.     

Subduction erosion of forearc mantle wedge implicated in the genesis of the South Sandwich Island (SSI) arc: Evidence from boron isotope systematics

The South Sandwich volcanic arc is sited on a young oceanic crust, erupts low-K tholeiitic rocks, is characterized by unexotic pelagic and volcanogenic sediments on the down-going slab, and simple tectonic setting, and is ideal for assessing element transport through subduction zones. As a means of quantifying processes attending transfer of subduction-related fluids from the slab to the mantle wedge, boron concentrations and isotopic compositions were determined for representative lavas from along the arc. The samples show variable fluid-mobile/fluid-immobile element ratios and high enrichments of B/Nb (2.7 to 55) and B/Zr (0.12 to 0.57), similar to those observed in western Pacific arcs. δ¹¹B values are among the highest so far reported for mantle-derived lavas; these are highest in the central part of the arc (+ 15 to + 18‰) and decrease toward the southern and northern ends (+ 12 to + 14‰). δ¹¹B is roughly positively correlated with B concentrations and with ⁸⁷Sr/⁸⁶Sr ratios, but poorly coupled with other fluid-mobile elements such as Rb, Ba, Sr and U. Peridotites dredged from the forearc trench also have high δ¹¹B (ca. + 10‰) and elevated B contents (38–140 ppm). Incoming pelagic sediments sampled at ODP Site 701 display a wide range in δ¹¹B (+ 5 to ? 13‰; average = ? 4.1‰), with negative values most common. The unusually high δ¹¹B values inferred for the South Sandwich mantle wedge cannot easily be attributed to direct incorporation of subducting slab materials or fluids derived directly therefrom. Rather, the heavy B isotopic signature of the magma sources is more plausibly explained by ingress of fluids derived from subduction erosion of altered frontal arc mantle wedge materials similar to those in the Marianas forearc. We propose that multi-stage recycling of high-δ¹¹B and high-B serpentinite (possibly embellished by arc crust and volcaniclastic sediments) can produce extremely ¹¹B-rich fluids at slab depths beneath the volcanic arc. Infiltration of such fluids into the mantle wedge likely accounts for the unusual magma sources inferred for this arc.     

Constraints on the nature of the subvolcanic reservoir at South Sister volcano,Oregon from U-series dating combined with sub-crystal trace-element analysis of plagioclase and zircon

We present sub-crystal-scale ²³⁸U–²³⁰Th zircon ages and ²³⁸U–²³⁰Th–²²⁶Ra plagioclase ages of bulk mineral separates from the Holocene (2.0–2.3 ka) eruptions of the Rock Mesa (RM) and Devil's Hills (DH) rhyolites at South Sister volcano, Oregon. We link these age data with sub-crystal trace-element analyses of zircon and plagioclase to provide insight into the subvolcanic system at South Sister, as an example of a small-volume continental arc volcano. Our results document the presence of coeval yet physically-distinct regions within the magma reservoir and constrain the timescales over which these heterogeneities existed. Zircons from the RM and DH dominantly record ages from 20 to 80 ka, with some grains recording ages > 350 ka, whereas plagioclase records ²³⁰Th–²²⁶Ra ages of 2.3–6.8 ka (RM) and 4.0–9.6 ka (DH-3) and a ²³⁸U–²³⁰Th age of 10 ± 34 ka (DH-3). We interpret zircons with ages < 350 ka as antecrysts inherited from a longer lived upper-crustal magma reservoir from which the rhyolites were generated, based on crystallization ages coeval with earlier periods of silicic volcanism at South Sister, the undersaturated nature of the RM and DH magmas with respect to zircon, and Ti-in-zircon temperatures consistent with low-temperature (< 815 °C) crystallization. In contrast, plagioclase ages are near the eruption age and dominantly preserve information about the recent (< 10 ka), higher-temperature evolution of the host magmas. Although zircon and plagioclase record different crystallization ages, each phase crystallized over the same time period in the RM compared to DH rhyolites. Linking these crystal age data with sub-crystal trace-element analyses demonstrates that zircon and plagioclase have distinct trace-element characteristics between eruptions, which require that the RM and DH crystals (and therefore magmas) were derived from distinct regions that had evolved independently for > 50 ka within a heterogeneous magmatic system and coexisted as physically-distinct, dominantly-liquid bodies prior to eruption. Thus, we favor a model where rhyolites are generated in independent batches by accumulation of evolved liquids in a heterogeneous, largely crystalline reservoir. Similarities in crystal age and chemical data to that at other young silicic systems (e.g., Mount St. Helens, Okataina Caldera Complex) suggest that this model may be more generally applicable to silicic magmas.     

Lithospheric contributions to high-MgO basanites from the Cumbre Vieja Volcano,La Palma,Canary Islands and evidence for temporal variation in plume influence

New geochemical and isotopic data are presented from the oldest part of the Cumbre Vieja volcano, La Palma (Canary Islands), located near the assumed emergence of the Canary mantle plume. The volcanics comprise a suite dominated by basanite flows with subordinate amounts of phono-tephrite, tephri-phonolite and phonolite flows and intrusives. Two compositionally different basanite groups have been identified, both with HIMU (high-μ)-type incompatible trace element characteristics: Primitive high-MgO basanites (10.7–12.1% MgO), found only at the base of a stratigraphic profile near Fuencaliente on the south coast, and intermediate-MgO basanites (6.0–7.3% MgO), exposed in the upper part of the profile and widespread on the east coast of La Palma. The high-MgO basanites are interpreted as near-primary mantle melts (primary composition 14–15% MgO) derived by progressive melting (2.9% to 4.5%) of a common lithospheric mantle source. Model calculations indicate that it is not possible to generate the intermediate-MgO basanites from the high-MgO group by crystal fractionation of observed phenocrysts. Relative to intermediate-MgO basanites, the high-MgO flows have lower concentrations of LIL and HFS elements, except for Ti, which is markedly enriched in the primitive rocks (3.7–4.7% TiO₂ vs 3.4–3.9% TiO₂). Fuencaliente volcanics display limited temporal isotopic variations suggested to be a result of mixing of melts originating from the rising plume and the metazomatized lithospheric mantle. ⁸⁷Sr / ⁸⁶Sr and ¹⁴³Nd / ¹⁴⁴Nd ratios range 0.70305–0.70311 and 0.51285–0.51291, respectively, while the corresponding ranges in Pb-isotope ratios are ²⁰⁶Pb / ²⁰⁴Pb = 19.46–19.64, ²⁰⁷Pb / ²⁰⁴Pb = 15.55–15.61, and ²⁰⁸Pb / ²⁰⁴Pb = 39.16–39.53. The overall variation of the Cumbre Vieja isotopic data can be accounted for by mixtures of three mantle components in the proportions 72–79% plume source (LVC = low velocity component), 9–16% depleted mantle (DM) and up to 12% enriched mantle (EMI). Negative Δ7 / 4 Pb (− 0.6 to − 5.4) in the Cumbre Vieja volcanics suggest derivation from a young HIMU mantle source. The relative abundance of plume source material increase in younger rocks in the Fuencaliente section, suggesting waning plume–lithosphere interaction during the emplacement of this part of the Cumbre Vieja volcano. The high-MgO volcanics define regular and systematic geochemical trends, interpreted as partial melting trends, when plotted against abundances of highly incompatible elements (P, Ce). Evaluation of minor and trace element variation in consecutive melts suggests control by residual amphibole, phlogopite, garnet and a Ti-bearing phase, possibly ilmenite. The melting mode changed gradually, allowing increasing input from residual phlogopite during partial melting. The residual mineralogy constrains the source region of the high-MgO basanites to the lowermost oceanic lithospheric mantle, presumably around 100 km depths.     

Siderophile element patterns,PGE nuggets and vapour condensation effects in Ni-rich quench chromite-bearing microkrystite spherules, ∼ 3.24 Ga S3 impact unit,Barberton greenstone belt,Kaapvaal Craton,South Africa

Energy dispersive spectrometry (EDS), laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS) track analyses of chlorite-dominated quench-textured microkrystite spherules and LA-ICPMS spot analyses of intra-spherule Ni-rich skeletal quench chromites from the 3243 ± 4 Ma Barberton S3 impact fallout unit (lower part of the Mapepe Formation, Fig Tree Group, Barberton greenstone belt, Kaapvaal Craton, South Africa) reveal fractionated siderophile and PGE trace element patterns corresponding to chondrite-contaminated komatiite/basalt compositions. The chlorites, interpreted as altered glass, contain sharp siderophile elements and PGE spikes inherited from decomposed metal and Ni-rich chromite particles. LA-ICPMS spot analysis identifies PGE-rich micronuggets in Ni–chromites (Ir ∼ 12–100 ppm, Os ∼ 9–86 ppm, Ru ∼ 5–43 ppm) and lower levels of the volatile PGEs (Rh ∼ 1–11 ppm, Pd ∼ 0.68–0.96 ppm). Previously reported PGE anomalies in the order of hundreds of ppb in some Barberton microkrystite spherules are accounted for in terms of disintegration of PGE-rich micronuggets. Replacement of the Ni-chromites by sulphide masks primary chondritic patterns and condensation element distribution effects. High refractory/volatile PGE ratios pertain to both the chlorites and the Ni-rich chromites, consistent with similar compositional relations in microkrystite spherules from other impact fallout units in the Barberton greenstone belt and the Pilbara Craton, Western Australia. The near-consistent low Pt/Re and high V/Cr and V/Sc ratios in chlorite of the spherules, relative to komatiites, are suggestive of selective atmospheric condensation of the spherules which favored the relatively more refractory Re and V. Selective condensation may also be supported by depletion in the volatile Yb relative to Sm. Ni–Cr relationships allow estimates of the proportion of precursor crustal and meteoritic components of the spherules. Mass balance calculations based on the iridium flux allow estimates of the order of magnitude of the diameter of the chondritic projectile.     

Remediation studies of trace metals in natural and treated water using surface modified biopolymer nanofibers

In this study, remediation results of trace metals in natural water and treated water using three functionalized nanofiber mats of cellulose and chitosan are reported. The nanofiber materials, packed in mini-columns, were employed for the remediation of five toxic trace metals (Cd, Pb, Cu, Cr and Ni) from natural water samples. Trace metals in real water samples were undetectable as the concentrations were lower than the instrument’s detection limits of 0.27 × 10⁻³ (Cd) and 4.2 × 10⁻² (Pb) μg mL⁻¹, respectively. However, after percolation through the functionalised biosorbents in cartridges, detectability of the metal ions was enhanced. The starting volume of the natural water sample was 100 mL, which was passed through a column containing the nanofibers sorbent and the retained metals eluted with 5 mL of 2.0 M nitric acid. The eluate was analyzed for metals concentrations. An enrichment factor of 20 for the metals was realized as a result of the pre-concentration procedure applied to handle the determination of the metals at trace levels. The order of remediation of the studied metals using the nanofibers was as follows: chitosan/PAM-g-furan-2,5-dione < cellulose-g-furan-2,5-dione < cellulose-g-oxolane-2,5-dione. The modified biopolymer nanofibers were able to adsorb trace metals from the river water and treated water, thereby confirming their capability of water purification. These materials are proposed as useful tools and innovative approach for improving the quality of drinking for those consumers in small scale households.     

Content and distribution of trace metals in surface sediments from the northern Bering Sea,Chukchi Sea and adjacent Arctic areas

Concentrations of trace metals (Zn, Cr, Cu, V, Cd and Pb), total organic carbon (TOC), black carbon (BC) and their granulometry were examined in 25 surface sediment samples from the northern Bering Sea, Chukchi Sea and adjacent areas. Trace metal concentrations in the sediments varied from 21.06–168.21 mg kg⁻¹ for Zn, 8.91–46.94 mg kg⁻¹ for Cr, 2.69–49.39 mg kg⁻¹ for Cu, 32.46–185.54 mg kg⁻¹ for V, 0.09–0.92 mg kg⁻¹ for Cd, and 0.95–15.25 mg kg⁻¹ for Pb. The geoaccumulation index (I_geo) indicated that trace metal contamination (Zn and Cd) existed in some stations of the study area. The distribution of grain size plays an important role in influencing the distribution of trace metals (Zn, Cr, Cu, V, and Pb) in sediments from the Chukchi Sea and adjacent areas.     

Vertical and horizontal distribution of magnetic susceptibility and metal contents in an industrial district of central Iran

This study was conducted to determine the vertical and horizontal distribution of selected metals and magnetic susceptibility (χlf) in an industrial site located in Isfahan province, central Iran. For this purpose, we used a grid sampling methodology and excavated 202 profiles. Soil samples were then collected from 0–30, 60–90, and 120–150 cm depths. The mass magnetic susceptibility (χ) of the soil samples was measured at both low and high frequencies (χlf and χhf) using the Bartington MS2 dual frequency sensor; and χfd was also calculated. Soil samples were also analyzed for iron (Fe), manganese (Mn), lead (Pb), zinc (Zn), copper (Cu), nickel (Ni), chromium (Cr) and cobalt (Co) concentrations. The results showed that there were positive significant correlations among selected metals including Zn, Pb, Fe and Mn, which were mainly added through coal fly ash from an iron smelting factory at the studied site, while the concentration of Ni, Cr and Co was mainly controlled by the parent material of the soils. The trends in results at the site of study were similar in vertical and horizontal distribution for the industrial originated metals as judged by pollution load index (PLI) using χlf. The results of SEM/EDX also confirmed the presence of spheroid of magnetic particles in the surface soil samples taken in close proximity of the factory. Based on the results using the contamination factors (CF) determined for selected metals, the following order was observed: Pb > Zn > Mn > Fe > Cu > Ni ≥ Co > Cr. The results also suggested that magnetic methods could be used to estimate the metal contamination from anthropogenic sources in industrial soils.     

Magnetic properties and heavy metal pollution of soils in the vicinity of a cement plant,Xuzhou (China)

This study characterized the magnetic property and levels of heavy metals of the topsoils near a cement plant. The concentrations of five selected heavy metals (Pb, Cu, Zn and Cd) were measured on 32 topsoil samples (0–20 cm) collected near a cement plant via inductively coupled plasma/mass spectroscopy (ICP-MS). The orders of enrichment factors (EF), on average, were Cd (7.3) > Cu (3) > Zn (2.9) > Pb (2.1), respectively. A self-organizing map (SOM) was applied to the concentrations of heavy metals for “correlation hunting”. Mineral magnetic concentration parameters, such as the specific magnetic susceptibility (χ), susceptibility of anhysteretic remanent magnetization (χ_ARM), saturation isothermal remanent magnetization (SIRM), together with interparametric ratios (such as IRM_− 100mT/SIRM, SIRM/χ, χ_ARM/SIRM) show that ferrimagnetic, superparamagnetic (SP) and multi-domain (MD) minerals dominated the soils. The results of correlation analysis indicate that copper showed a significant correlation with χ, χ_ARM and SIRM but such a relationship with χ, χ_ARM and SIRM was only weakly identified for Zn, Cd and Pb.     

Interaction of adakitic melt-peridotite: Implications for the high-Mg# signature of Mesozoic adakitic rocks in the eastern North China Craton

Abundant dunite and harzbugite xenoliths are preserved in Early Cretaceous high-Mg# [63–67, where Mg# = molar 100 × Mg/(Mg + Fe_tot)] diorite intrusions from western Shandong in the North China Craton (NCC). Dunite and some harzburgite xenoliths typically preserve areas of orthopyroxenite (sometimes accompanied by phlogopite) either as veins or as zones surrounding chromite grains. Harzburgite is chiefly composed of olivine, orthopyroxene, minor clinopyroxene and chromian-spinel. High Mg#'s (averaging 91.4) and depletions in Al₂O₃ and CaO (averaging 0.52 wt.% and 0.29 wt.%, respectively) in harzburgite and dunite xenoliths suggest that they are residues formed by large degrees of polybaric melting. However, olivines and orthopyroxenes from dunite xenoliths spatially associated with orthopyroxenite display lower Mg#'s (i.e., 82–87 and 83–89, respectively), suggesting that an adakitic melt–peridotite reaction has taken place. This is consistent with the production of veined orthopyroxene or orthopyroxene + phlogopite in dunite and some harzburgite xenoliths in response to the introduction of adakitic melt into the previously depleted lithospheric mantle (i.e., harzburgite and dunite xenoliths). The presence of orthopyroxene in veins or as a zones surrounding chromite in peridotite xenoliths is thought to be representative of adakitic melt metasomatism. The dunite and harzbugite xenoliths are relatively rich in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), poor in heavy rare earth elements (HREEs) and high field strength elements (HFSEs), and lack Eu anomalies on chondrite normalized trace element diagrams. The initial ⁸⁷Sr/⁸⁶Sr ratios and εNd(t) values for the xenoliths range from 0.7058 to 0.7212 and + 0.18 to ? 19.59, respectively. Taken together, these features, combined with the strong depletion in HFSE and the existence of Archean inherited zircons in the host rocks, suggest that the adakitic melt was derived from the partial melting of early Mesozoic delaminated lower continental crust. The interaction of the adakitic melt with peridotite is responsible for the high-Mg# character of the early Cretaceous diorites in western Shandong.     

Miocene to Late Quaternary Patagonian basalts (46–47°S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction

Miocene to Quaternary large basaltic plateaus occur in the back-arc domain of the Andean chain in Patagonia. They are thought to result from the ascent of subslab asthenospheric magmas through slab windows generated from subducted segments of the South Chile Ridge (SCR). We have investigated three volcanic centres from the Lago General Carrera–Buenos Aires area (46–47°S) located above the inferred position of the slab window corresponding to a segment subducted 6 Ma ago. (1) The Quaternary Río Murta transitional basalts display major, trace elements, and Sr and Nd isotopic features similar to those of oceanic basalts from the SCR and from the Chile Triple Junction near Taitao Peninsula (e.g., (⁸⁷Sr/⁸⁶Sr)_o = 0.70396–0.70346 and εNd = + 5.5 − + 3.0). We consider them as derived from the melting of a Chile Ridge asthenospheric mantle source containing a weak subduction component. (2) The Plio-Quaternary (< 3.3 Ma) post-plateau basanites from Meseta del Lago Buenos Aires (MLBA), Argentina, likely derive from small degrees of melting of OIB-type mantle sources involving the subslab asthenosphere and the enriched subcontinental lithospheric mantle. (3) The main plateau basaltic volcanism in this region is represented by the 12.4–3.3-Ma-old MLBA basalts and the 8.2–4.4-Ma-old basalts from Meseta Chile Chico (MCC), Chile. Two groups can be distinguished among these main plateau basalts. The first group includes alkali basalts and trachybasalts displaying typical OIB signatures and thought to derive from predominantly asthenospheric mantle sources similar to those of the post-plateau MLBA basalts, but through slightly larger degrees of melting. The second one, although still dominantly alkalic, displays incompatible element signatures intermediate between those of OIB and arc magmas (e.g., La/Nb > 1 and TiO₂ < 2 wt.%). These intermediate basalts differ from their strictly alkalic equivalents by having lower High Field Strength Element (HFSE) and higher εNd (up to + 5.4). These features are consistent with their derivation from an enriched mantle source contaminated by ca. 10% rutile-bearing restite of altered oceanic crust. The petrogenesis of the studied Mio-Pliocene basalts from MLBA and MCC is consistent with contributions of the subslab asthenosphere, the South American subcontinental lithospheric mantle and the subducted Pacific oceanic crust to their sources. However, their chronology of emplacement is not consistent with an ascent through an asthenospheric window opened as a consequence of the subduction of segment SCR-1, which entered the trench at 6 Ma. Indeed, magmatic activity was already important between 12 and 8 Ma in MLBA and MCC as well as in southernmost plateaus, i.e., 6 Ma before the subduction of the SCR-1 segment. We propose a geodynamic model in which OIB and intermediate magmas derived from deep subslab asthenospheric mantle did uprise through a tear-in-the-slab, which formed when the southernmost segments of the SCR collided with the Chile Trench around 15 Ma. During their ascent, they interacted with the Patagonian supraslab mantle and, locally, with slivers of subducted Pacific oceanic crust that contributed to the geochemical signature of the intermediate basalts.