Diurnal CO variations in the Venus mesophere from CO microwave spectra

Microwave spectra of carbon monoxide (¹²CO) in the mesosphere of Venus were measured in December 1978, May and December 1980, and January, September, and November 1982. These spectra are analyzed to provide mixing profiles of CO in the Venus mesosphere and best constrain the mixing profile of CO between ～ 100 and 80 km altitude. From the January 1982 measurement (which, of all our spectra, best constrains the abundance of CO below 80 km altitude) we find an upper limit for the CO mixing ratio below 80 km altitude that is two to three times smaller than the stratospheric (～65 km) value of 4.5 ± 1.0 × 10^?5 determined by P. Connes, J. Connes, L.D. Kaplan, and W. S. Benedict (1968, Astrophys. J.152, 731–743) in 1967, indicating a possible long-term change in the lower atmospheric concentration of CO. Intercomparison among the individual CO profiles derived from our spectra indicates considerable short-term temporal and/or spatial variation in the profile of CO mixing in the Venus mesosphere above 80 km. A more complete comparison with previously published CO microwave spectra from a number of authors specifies the basic diurnal nature of mesospheric CO variability. CO abundance above ～ 95 km in the Venus atmosphere shows approximately a factor of 2–4 enhancement on the nightside relative to the dayside of Venus. Peak nightside CO abundance above ～95 km occurs very near to the antisolar point on Venus (local time of peak CO abundance above ～95 km occurs at 0.6_?0.6^+0.7 hr after midnight on Venus), strongly suggesting that retrograde zonal flow is substantially reduced at an altitude of 100 km in the Venus mesosphere. In contrast, CO abundances between 80 and 90 km altitude show a maximum that is shifted from the antisolar point toward the morningside of Venus (local time of peak CO abundance between 80 and 90 km occurs at 8.5 ± 1.0 hr past midnight on Venus). The magnitude of the diurnal variation of CO abundance between 80 and 90 km is again, approximately a factor of 2–4. Disk-averaged spectra of Venus do not determine the exact form for the diurnal distribution of CO in the Venus mesosphere as indicated by comparison of synthetic spectra, based upon model distributions, and the measured spectra. However, the offset in phase for the diurnal variation for the >95 km and 80–90-km-altitude regions requires an asymmetric (in solar zenith angle) distribution.     

Molecular and low excitation emission in high mass post-main-sequence nebulae

We have undertaken mapping and spectroscopy of a broad range of type I post-Main-Sequence nebulae in COJ=1→0,J=2→1, andJ=3→2, using the 12 m antenna at Kitt Peak, and the 45 m facility of the Nobeyama Radio Observatory. As a consequence, we find COJ=2→1 emission associated with NGC 3132 and NGC 6445, determine the location of COJ=1→0 emission in the nucleus of NGC 6302, and obtain (for the first time) COJ=3→2 spectroscopy for a substantial cross-section of type I sources. LVG analysis of the results suggests densitiesn(H₂) ～ 10⁴ cm^?3, and velocity gradients dv/dr ～ 2×10² in both NGC 7027 and CRL 618, commensurate with uniform expansion of a constant velocity outflow, whilst for the case of NGC 2346 these values probably exceedn(H₂) ～ 4.0×10⁵ cm^?3. dv/dr ～ 2.6×10³ km s^?1 andT _k ～10² K, implying appreciable compression (and shock heating?) of the CO excitation zone. Hi masses extend over a typical range 0.01<M(Hi)/M _⊙<1, whilst corresponding estimates of the progenitor mass imply 0.7<M _prog/M _⊙<2.3; values significantly in excess of those pertinent for normal PN, although somewhat at the lower end of the type I mass range. COJ=3→2 profiles for CRL 2688 confirm the presence of an extended plateau with width Δv～85 km s^?1, whilst modestJ=3→2 enhancement is also observed for the high-velocity components in NGC 7027. TheJ=3→2 spectrum for NGC 2346 appears to mimic lower-frequency results reasonably closely, confirming the presence of a double-peaked structure towards the core, and predominantly unitary profiles to the north and south, whilst there is also evidence to suggest appreciableJ=3→2 asymmetry in CRL 618 compared to lower-frequency measures. The status of an extended cloud near HB 5 remains uncertain, although this clearly represents a remarkably complex region with velocity span ΔV～50 km s^?1. Our presentJ=3→2 results appear to track lower frequency measures extremely closely, implying local densitiesn(H₂)>3×10³ cm^?3—although temperatures close to theV _lsr of HB 5 are relatively weak, and of orderT _MB (J=3→2)≤0.9 K. Finally, as a result of both this, and previous investigations we find that of type I sources so far observed in CO, some ～42% appear to possess detectable levels of emissionT _r ^* >0.1 K. Similarly, in cross-correlating this data with other results, we note a closely linear relation betweenJ=2→1 antenna temperaturesT _MB, and the surface brightness of H₂ S(1) quadrupole emissionS(H₂)—a trend which appears also to be reflected betweenS(H₂) and corresponding parameters for [Oi], [Oii], [Ni], [Nii], and [Sii]. Such relations almost certainly arise from comparable secular variations in line intensities, although the CO, H₂, and optical emission components are likely to derive from disparate line excitation zones. As a consequence, it is clear that whilst H₂ S(1) emission is probably enhanced as a result of local shock activity, the evidence for post-shock excitation of the CO and optical forbidden lines is at best marginal. Similarly, although it seems likely that CO emission derives from circum-nebular Hi shells with kinetic temperatureT _k ～ 30 K or greater, the predominant fraction of low-excitation emission arises from a mix of charge exchange reactions, nebular stratification and, probably most importantly, the influence of UV shadow zones and associated neutral inclusions.     

HHSMT observations of the Venusian mesospheric temperature, winds, and CO abundance around the MESSENGER flyby

We present submillimeter observations of ¹²CO J=3-2 and 2-1, and ¹³CO J=2-1 lines of the Venusian mesosphere and lower thermosphere with the Heinrich Hertz Submillimeter Telescope (HHSMT) taken around the second MESSENGER flyby of Venus on 5 June 2007. The observations cover a range of Venus solar elongations with different fractional disk illuminations. Preliminary results like temperature and CO abundance profiles are presented.These data are part of a coordinated observational campaign in support of the ESA Venus Express mission. Furthermore, this study attempts to contribute to cross-calibrate space- and ground-based observations, to constrain radiative transfer and retrieval algorithms for planetary atmospheres, and to a more thorough understanding of the global patters of circulation of the Venusian atmosphere.     

Mesospheric vertical thermal structure and winds on Venus from HHSMT CO spectral-line observations

We report vertical thermal structure and wind velocities in the Venusian mesosphere retrieved from carbon monoxide (¹²CO J=2-1 and ¹³CO J=2-1) spectral line observations obtained with the Heinrich Hertz Submillimeter Telescope (HHSMT). We observed the mesosphere of Venus from two days after the second Messenger flyby of Venus (on 5 June 2007 at 23:10 UTC) during five days. Day-to-day and day-to-night temperature variations and short-term fluctuations of the mesospheric zonal flow were evident in our data. The extensive layer of warm air detected recently by SPICAV at 90-100 km altitude is also detected in the temperature profiles reported here.These data were part of a coordinated ground-based Venus observational campaign in support of the ESA Venus Express mission. Furthermore, this study attempts to cross-calibrate space- and ground-based observations, to constrain radiative transfer and retrieval algorithms for planetary atmospheres, and to contribute to a more thorough understanding of the global patterns of circulation of the Venusian atmosphere.     

Observational definition of the Venus mesopause: vertical structure, diurnal variation, and temporal instability

Submillimeter line observations of CO in the Venus middle atmosphere (mesosphere) were observed with the James Clerk Maxwell Telescope (JCMT, Mauna Kea) about the May 2000, February 2002 superior and July 1999, March 2001 inferior conjunctions of Venus. Combined ¹²CO and ¹³CO isotope spectral line measurements at 345 and 330 gHz frequencies, respectively, provided enhanced sensitivity and vertical coverage for simultaneous retrievals of atmospheric temperatures and CO mixing ratios over the altitude region 75-105 km with vertical resolution 4-5 km. Supporting millimeter ¹²CO spectral line observations with the Kitt Peak 12-m telescope (Steward Observatories) provide enhanced temporal coverage and CO mixing sensitivity. Implementation of CO/temperature profile retrievals for the 2000, 2002 dayside (superior conjunction) and 1999, 2001 nightside (inferior conjunction) periods yields a first-time definition of the vertical structure and diurnal variation of a low-to-mid-latitude mesopause within the Venus atmosphere. At the times of these 1999-2002 observations, the Venus mesopause was located at a slightly lower level in the nightside (0.5 mbar, ∼87 km) versus the dayside (0.2 mbar, ∼91 km) atmosphere. Average diurnal variation of Venus mesospheric temperatures appears to be ≤ 5 K at and below the mesopause. Diurnal variation of Venus thermospheric temperatures increases abruptly just above the mesopause, reaching 50 K by the 0.01-mbar pressure level (∼102 km). Atmospheric temperatures above and below the Venus mesopause exhibited global-scale (≥4000 km horizontal) variations of large amplitude (7-15 K) on surprisingly short timescales (daily to monthly) during the 2001 nightside and 2002 dayside observing periods. Venus dayside mesospheric temperatures observed during the 2002 superior conjunction were also 10-15 K warmer than observed during the 2000 superior conjunction. A characteristic timescale for these global temperature variations is not defined, but their magnitude is comparable to previous determinations of secular variability in nightside mesospheric temperatures (Clancy and Muhleman, 1991).     

Venus upper atmospheric CO, temperature, and winds across the afternoon/evening terminator from June 2007 JCMT sub-millimeter line observations

The Venus mesosphere constitutes a highly variable transition region between the zonal rotation of the lower atmosphere and the diurnal circulation of the upper atmosphere. It further serves as the primary photochemical region of the Venus atmosphere. We obtained James Clerk Maxwell Telescope (JCMT, Mauna Kea Hawaii) sub-millimeter line observations of mesospheric ¹²CO and ¹³CO during coordinated space (MESSENGER and Venus Express) and ground-based observations of Venus in June of 2007. Such CO spectra line measurements support temperature, CO mixing ratio, and wind retrievals over the 80-110 km altitude range, encompassing the upper mesosphere and lower thermosphere of Venus. Five-point beam integrations were obtained across the observed Venus disk, allowing distinction of afternoon (noon to 6 p.m.) versus evening (6 p.m. to midnight) local times and northern (0-60N) versus southern (0-60S) latitudes. Distinctive diurnal variations (noon to midnight) are retrieved for both temperatures above 95 km and CO mixing ratios above 85 km altitudes. Separate CO line maps obtained on (UT) June 2, 3, 6, and 11 indicate moderate daily variability in afternoon and evening CO mixing ratios (20-50%) and temperatures (5-10 K). Average Venus mesospheric temperatures over this period were 10 K warmer than returned from 1978 to 1979 Pioneer Venus or 2000-01 sub-millimeter measurements, without evidence for the very large temperature inversions indicated by Venus Express SPICAV measurements at 90-100 km altitudes (Bertaux, J.L., Vandaele, A.-C., Korablev, O., Villard, E., Fedorova, A., Fussen, D., Quémerais, E., Belyaev, D., Mahieux, A., Montmessin, F., Muller, C., Neefs, E., Nevejans, D., Wilquet, V., Dubois, J.P. Hauchecorne, A., Stepanov, A., Vinogradov, I., Rodin, A., Bertaux, J.-L., Nevejans, D., Korablev, O., Montmessin, F., Vandaele, A.-C., Fedorova, A., Cabane, M., Chassefière, E., Chaufray, J.Y., Dimarellis, E., Dubois, J.P., Hauchecorne, A., Leblanc, F., Lefèvre, F., Rannou, P., Quémerais, E., Villard, E., Fussen, D., Muller, C., Neefs, E., Van Ransbeeck, E., Wilquet, V., Rodin, A., Stepanov, A., Vinogradov, I., Zasova, L., Forget, F., Lebonnois, S., Titov, D., Rafkin, S., Durry, G., Gérard, J.C., Sandel, B., 2007. A warm layer in Venus’ cryosphere and high-altitude measurements of HF, HCl, H₂O and HDO. Nature 450, 646-649). Measured Doppler shifts associated with June 2 and 11 ¹²CO line center absorptions indicate nearly supersonic (200 m/s, Mach 1) afternoon-to-evening (retrograde) circulation; composed of additive subsolar-to-antisolar (SSAS) and zonal retrograde wind components, which are not separable due to the particular observational geometry.     

A sensitive search for nitric oxide in the lower atmospheres of Venus and Mars: Detection on Venus and upper limit for Mars

High-resolution spectra of Venus and Mars at the NO fundamental band at 5.3 μm with resolving power ν/δν=76,000 were acquired using the TEXES spectrograph at NASA IRTF on Mauna Kea, Hawaii. The observed spectrum of Venus covered three NO lines of the P-branch. One of the lines is strongly contaminated, and the other two lines reveal NO in the lower atmosphere at a detection level of 9 sigma. A simple photochemical model for NO and N at 50-112 km was coupled with a radiative transfer code to simulate the observed equivalent widths of the NO and some CO₂ lines. The derived NO mixing ratio is 5.5±1.5 ppb below 60 km and its flux is . Predissociation of NO at the (0-0) 191 nm and (1-0) 183 nm bands of the δ-system and the reaction with N are the only important loss processes for NO in the lower atmosphere of Venus. The photochemical impact of the measured NO abundance is significant and should be taken into account in photochemical modeling of the Venus atmosphere. Lightning is the only known source of NO in the lower atmosphere of Venus, and the detection of NO is a convincing and independent proof of lightning on Venus. The required flux of NO is corrected for the production of NO and N by the cosmic ray ionization and corresponds to the lightning energy deposition of . For a flash energy on Venus similar to that on the Earth (∼¹⁰⁹ J), the global flashing rate is ∼90 s⁻¹ and ∼6 km⁻² y⁻¹ which is in reasonable agreement with the existing optical observations. The observed spectrum of Mars covered three NO lines of the R-branch. Two of these lines are contaminated by CO₂ lines, and the line at 1900.076 cm⁻¹ is clean and shows some excess over the continuum. Some photochemical reactions may result in a significant excitation of NO (v=1) in the lowest 20 km on Mars. However, quenching of NO (v=1) by CO₂ is very effective below 40 km. Excitation of NO (v=1) in the collisions with atomic oxygen is weak because of the low temperature in the martian atmosphere, and we do not see any explanation of a possible emission of NO at 5.3 μm. Therefore the data are treated as the lack of absorption with a 2 sigma upper limit of 1.7 ppb to the NO abundance in the lower atmosphere of Mars. This limit is above the predictions of photochemical models by a factor of 3.     

Martian CO abundance from the J = 1 → 0 rotational transition: Evidence for temporal variations

Mars was observed in the CO (J = 1 → 0) 2.6-mm wavelength line between 29 March and 1 April, 1980. The data were analyzed using a model atmosphere based on Viking measurements. A least-squares fit of the model to the observed line profile yielded an average CO mixing ratio of (3.2 ± 1.1) × 10^?3. This value is four times larger than that obtained by L. D. Kaplan, J. Connes, and P. Connes, 1969 (Astrophys. J.157, L187-L195) from analysis of an infrared spectrum obtained in 1967 by J. Connes, P. Connes, and J. P. Maillard, 1969 (Atlas of Near Infrared Spectra of Venus, Mars, Jupiter, and Saturn, Centre National de la Recherche Scientifique, Paris). Models of the Martian atmospheric chemistry indicate that this implied temporal variation could easily exist and that it would be due primarily to variations in the abundance of H₂O.     

High-resolution spectroscopy of Venus: Detection of OCS, upper limit to H2S, and latitudinal variations of CO and HF in the upper cloud layer

Venus was observed at 2.4 and 3.7 μm with a resolving power of 4×¹⁰⁴ using the long-slit high-resolution spectrograph CSHELL at NASA IRTF. The observations were made along a chord that covered a latitude range of ± 60° at a local time near 8:00. The continuous reflectivity and limb brightening at 2.4 μm are fitted by the clouds with a single scattering albedo 1−a=0.01 and a pure absorbing layer with τ=0.09 above the clouds. The value of 1−a agrees with the refractive index of H₂SO₄ (85%) and the particle radius of 1 μm. The absorbing layer is similar to that observed by the UV spectrometer at the Pioneer Venus orbiter. However, its nature is puzzling. CO₂ was measured using its R32 and R34 lines. The retrieved product of the CO₂ abundance and airmass is constant at 1.9 km-atm along the instrument slit in the latitude range of ± 60°. The CO mixing ratio (measured using the P21 line) is rather constant at 70 ppm, and its variations of ∼10% may be caused by atmospheric dynamics. The observed value is higher than the 50 ppm retrieved previously from a spectrum of the full disk, possibly, because of some downward extension of the mesospheric morningside bulge of CO. The observations of the HF R3 line reveal a constant HF mixing ratio of 3.5±0.5 ppb within ± 60° of latitude, which is within the scatter in the previous measurements of HF. OCS has been detected for the first time at the cloud tops by summing 17 lines of the P-branch. The previous detections of OCS refer to the lower atmosphere at 30-35 km. The retrieved OCS mixing ratio varies with a scale height of 1 to 3 km. The mean OCS mixing ratio is ∼2 ppb at 70 km and ∼14 ppb at 64 km. Vertical motions in the atmosphere may change the OCS abundance. The detected OCS should significantly affect Venus' photochemistry. A sensitive search for H₂S using its line at 2688.93 cm⁻¹ results in a 3 sigma upper limit of 23 ppb, which is more restrictive than the previous limit of 100 ppb.     

Structure of the Venus mesosphere and lower thermosphere from measurements during entry of the pioneer Venus probes

Data on the thermal structure of the nightside middle atmosphere of Venus, from 84 to 137 km altitude, have been obtained from analysis of deceleration measurements from the third Pioneer Venus small probe, the night probe, which entered the atmosphere near the midnight meridian at 27°S latitude. Comparison of the midnight sounding with the morning sounding at 31°S latitude indicates that the temperature structure is essentially diurnally invariant up to 100 km, above which the nightside structure diverges sharply from the dayside toward lower temperatures. Very large diurnal pressure differences develop above 100 km with dayside pressure ten times that on the nightside at 126 km altitude. This has major implications for upper atmospheric dynamics. The data are compared with the measurements of G. M. Keating, J. Y. Nicholson, and L. R. Lake (1980, J. Geophys. Res., 85, 7941–7956) above 140 km with theoretical thermal structure models of Dickinson, and with data obtained by Russian Venera spacecraft below 100 km. Midnight temperatures are ～ 130°K, somewhat warmer than those reported by Keating et al.     

Solar radiation scattered in the Venus atmosphere: The Venera 11,12 data

Results of the scattered solar radiation spectrum measurements made deep in the Venus atmosphere by the Venera 11 and 12 descent probes are presented. The instrument had two channels: spectrometric (to measure downward radiation in the range 0.45 < γ < 1.17 μm) and photometric (four filters and circular angle scanning in an almost vertical plane). Spectra and angular scans were made in the height range from 63 km above the planet surface. The integral flux of solar radiation is 90 ± 12 W m^?2 measured on the surface at the subsolar point. The mean value of surface absorbed radiation flux per planetary unit area is 17.5 ± 2.3 W m^?2. For Venera 11 and 12 landing sites the atmospheric absorbed radiation flux is ～15 W m^?2 for H >; 43 km and ～45 W m^?2 for H < 48 km in the range 0.45 to 1.55 μm. At the landing sites of the two probes the investigated portion of the cloud layer has almost the same structure: it consists of three parts with boundaries between them at about 51 and 57 km. The base of clouds is near 48 km above the surface. The optical depth of the cloud layer (below 63 km) in the range 0.5 to 1 μm does not depend on the wavelength and is ～29 and ～38 for the Venera 11 and 12 landing sites, respectively. The single-scattering albedo, ω₀, in the clouds is very close to 1 outside the absorption bands. Below 58 km the parameter (1 ? ω₀) is <10^?3 for 0.49 and 0.7 μm. The parameter (1 ? ω₀) obviously increases above 60 km. Below 48 km some aerosol is present. The optical depth here is a strong function of wavelength. It varies from 1.5 to 3 at λ = 0.49 μm and from 0.13 to 0.4 at 1.0 μm. The mean size of particles below the cloud deck is about 0.1 μm. Below 35 km true absorption was found at λ < 0.55 μm with the (1 ? ω₀) maximum at H ≈ 15 km. The wavelength and height dependence of the absorption coefficient are compatible with the assumption that sulfur with a mixing ratio ～2 × 10^?8 normalized to S₂ molecules is the absorber. The upper limits of the mixing ratio for Cl₂, Br₂, and NO₂ are 4 × 10^?8, 2 × 10^?11, and 4 × 10^?10, respectively. The CO₂ and H₂O bands are confidently identified in the observed spectra. The mean value of the H₂O mixing ratio is 3 × 10^?5 < F_H2O < 10^?4 in the undercloud atmosphere. The H₂O mixing ratio evidently varies with height. The most probable profile is characterized by a gradual increase from F_H2O = 2 × 10^?5 near the surface to a 10 to 20 times higher value in the clouds.     

Possible H2staggered+ ultraviolet spectrum of Jupiter

An ultraviolet spectral probe for a hydrogen-rich planetary atmosphere, such as that of Jupiter, is suggested, utilizing discrete lines in the H₂^staggered+ 2pπ_u?1sσ_g electronic transition. For the Jovian atmosphere, the dominant mechanism for exciting H₂⁺ to its 2pπ_u state appears to be photoexcitation, principally through absorption of the solar Lyman-α line. We estimate that the Jovian column emission rate of the H₂⁺ 2pπ_u(ν′ = 2, J′ = 1) →1sσ_g(ν″ = 18,J″ = 0) fluorescent line at 1236.6 Å is if1 photon cmsu-2 secsu-1; i.e., that if1 photon secsu-1 of this radiation would strike a 15-cm diameter mirror in a Jupiter fly-by at an impact parameter of 3 × 10⁵km. The critical role of corrections to the Born-Oppenheimer approximation in the use of an H₂⁺ probe is discussed.     

Observations of CO in the stratosphere of Venus via its J = 0 → 1 rotational transition

We have observed carbon monoxide in the stratosphere of Venus at phase angles of 180 and 120° via the J = 0 → 1 rotational transition at 115.2712 GHz. The mixing ratio profile of CO has been obtained by fitting the theoretical spectrum produced by a small number of layers with constant CO mixing ratio to the line profile, and the results suggest that the CO mixing ratio below the 1-mb level increased by at least a factor of 10 between 180 and 120° phase angles. The depletion of CO on the nightside of the planet was not anticipated and may require either a new loss mechanism for CO which can operate without sunlight or an increase in the amount of vertical mixing on the nightside.     

Spatially-resolved high-resolution spectroscopy of Venus 1. Variations of CO2, CO, HF, and HCl at the cloud tops

Variations of the upper cloud boundary and the CO, HF, and HCl mixing ratios were observed using the CSHELL spectrograph at NASA IRTF. The observations were made in three sessions (October 2007, January 2009, and June 2009) at early morning and late afternoon on Venus in the latitude range of ±60°. CO₂ lines at 2.25 μm reveal variations of the cloud aerosol density (∼25%) and scale height near 65 km. The measured reflectivity of Venus at low latitudes is 0.7 at 2.25 μm and 0.028 at 3.66 μm, and the effective CO₂ column density is smaller at 3.66 μm than those at 2.25 μm by a factor of 4. This agrees with the almost conservative multiple scattering at 2.25 μm and single scattering in the almost black aerosol at 3.66 μm. The expected difference is just a factor of (1 − g)⁻¹ = 4, where g = 0.75 is the scattering asymmetry factor for Venus’ clouds. The observed CO mixing ratio is 52 ± 4 ppm near 08:00 and 40 ± 4 ppm near 16:30 at 68 km, and the higher ratio in the morning may be caused by extension of the CO morningside bulge to the cloud tops. The observed weak limb brightening in CO indicates an increase of the CO mixing ratio with altitude. HF is constant at 3.5 ± 0.2 ppb at 68 km in both morningside and afternoon observations and in the latitude range ±60°. Therefore the observations do not favor a bulge of HF, though HF is lighter than CO. Probably a source in the upper atmosphere facilitates the bulge formation. The recent measurements of HCl near 70 km are controversial (0.1 and 0.74 ppm) and require either a strong sink or a strong source of HCl in the clouds. The HCl lines of the (2-0) band are blended by the solar and telluric lines. Therefore we observed the P8 lines of the (1-0) band at 3.44 μm. These lines are spectrally clean and result in the HCl mixing ratio of 0.40 ± 0.03 ppm at 74 km. HCl does not vary with latitude within ±60°. Our observations support a uniformly mixed HCl throughout the Venus atmosphere.     

Chemical kinetic model for the lower atmosphere of Venus

A self-consistent chemical kinetic model of the Venus atmosphere at 0-47 km has been calculated for the first time. The model involves 82 reactions of 26 species. Chemical processes in the atmosphere below the clouds are initiated by photochemical products from the middle atmosphere (H₂SO₄, CO, S_x), thermochemistry in the lowest 10 km, and photolysis of S₃. The sulfur bonds in OCS and S_x are weaker than the bonds of other elements in the basic atmospheric species on Venus; therefore the chemistry is mostly sulfur-driven. Sulfur chemistry activates some H and Cl atoms and radicals, though their effect on the chemical composition is weak. The lack of kinetic data for many reactions presents a problem that has been solved using some similar reactions and thermodynamic calculations of inverse processes. Column rates of some reactions in the lower atmosphere exceed the highest rates in the middle atmosphere by two orders of magnitude. However, many reactions are balanced by the inverse processes, and their net rates are comparable to those in the middle atmosphere. The calculated profile of CO is in excellent agreement with the Pioneer Venus and Venera 12 gas chromatographic measurements and slightly above the values from the nightside spectroscopy at 2.3 μm. The OCS profile also agrees with the nightside spectroscopy which is the only source of data for this species. The abundance and vertical profile of gaseous H₂SO₄ are similar to those observed by the Mariner 10 and Magellan radio occultations and ground-based microwave telescopes. While the calculated mean S₃ abundance agrees with the Venera 11-14 observations, a steep decrease in S₃ from the surface to 20 km is not expected from the observations. The ClSO₂ and SO₂Cl₂ mixing ratios are ∼10⁻¹¹ in the lowest scale height. The existing concept of the atmospheric sulfur cycles is incompatible with the observations of the OCS profile. A scheme suggested in the current work involves the basic photochemical cycle, that transforms CO₂ and SO₂ into SO₃, CO, and S_x, and a minor photochemical cycle which forms CO and S_x from OCS. The net effect of thermochemistry in the lowest 10 km is formation of OCS from CO and S_x. Chemistry at 30-40 km removes the downward flux of SO₃ and the upward flux of OCS and increases the downward fluxes of CO and S_x. The geological cycle of sulfur remains unchanged.     

HCN radio emission from Comet Kohoutek (1973f)

Radio emission spectra of the J = 1?0 ground state transition of H¹²C¹⁴N has been detected in comet Kohoutek (1973f) before and after perihelion passage. The HCN gas production rate is about 10²⁸ molecules sec^?1 at a heliocentric distance of ～0.4 AU. Multiple Doppler shifts in the observed spectrum suggest jets with velocities ranging up to several km sec^?1.     

Circulation of the Venus upper mesosphere/lower thermosphere: Doppler wind measurements from 2001–2009 inferior conjunction,sub-millimeter CO absorption line observations

Sub-millimeter ¹²CO (346 GHz) and ¹³CO (330 GHz) line absorptions, formed within the mesospheric to lower thermospheric altitude (70–120 km) region of the Venus atmosphere, have been mapped across the nightside disk of Venus during 2001–2009 inferior conjunctions, employing the James Clerk Maxwell Telescope (JCMT). Radiative transfer analysis of these thermal line absorptions supports temperature and CO mixing profile retrievals, as described in a companion paper (Clancy et al., 2012). Here, we consider the analysis of the sharp line absorption cores of these CO spectra in terms of accurate Doppler wind profile measurements at 95–115 km altitudes versus local time (～8 pm–4 am) and latitude (～60N–60S). These Doppler wind measurements support determinations of the nightside zonal and subsolar-to-antisolar (SSAS) circulation components over a variety of timescales. The average behavior fitted from 21 retrieved maps of ¹²CO Doppler winds (obtained over hourly, daily, weekly, and interannual intervals) indicates stronger average zonal (85 m/s retrograde) versus SSAS (65 m/s) circulation at the 1 μbar pressure (108–110 km altitude) level. However, the absolute and relative magnitudes of these circulation components exhibit extreme variability over daily to weekly timescales. Furthermore, the individual Doppler wind measurements within each nightside mapping observation generally show significant deviations (20–50 m/s, averaged over 5000 km horizontal scales) from the simple zonal/SSAS solution, with distinct local time and latitudinal characters that are also time variable. These large scale residual circulations contribute 30–70% of the observed nightside Doppler winds at any given time, and may be most responsible for global variations in nightside lower thermospheric trace composition and temperatures, as coincidentally retrieved CO abundance and temperature distributions do not correlate with solution retrograde zonal and SSAS winds (see companion paper, Clancy et al., 2012). Limited comparisons of these nightside submillimeter results with dayside infrared Doppler wind measurements suggest distinct dayside versus nightside circulations, in terms of zonal winds in particular. Combined ¹²CO and ¹³CO Doppler wind mapping observations obtained since 2004 indicate that the average zonal and SSAS wind components increase by 50–100% between altitudes of 100 and 115 km. If gravity waves originating from the cloud levels are responsible for the extension of zonal winds into the thermosphere (Alexander, M.J. [1992]. Geophys. Res. Lett. 19, 2207–2210), such waves deposit substantial momentum (i.e., break) in the lower nightside thermosphere.     

Radiative forcing of the Venus mesosphere: I. Solar fluxes and heating rates

Most of the solar energy absorbed by Venus is deposited in the atmosphere, at levels more than 60 km above the surface. This unusual flux distribution should have important consequences for the thermal structure and dynamical state of that atmosphere. Because there are few measurements of the solar flux at levels above 60 km, a radiative transfer model was used to derive the structure and amplitude of the solar fluxes and heating rates in the Venus mesosphere (60–100 km). This model accounts for all sources of extinction known to be important there, including absorption and scattering by CO₂, H₂O, SO₂, H₂SO₄ aerosols and an unidentified UV absorber. The distributions of these substances in our model atmosphere were constrained by a broad range of spacecraft and ground-based observations. Above the cloud tops, (71 km), near-infrared CO₂ bands absorb enough sunlight to produce globally averaged heating rates ranging from 4° K/day (24-hr period) at 71 km to more than 50° K/day at 100 km. The sulfuric acid aerosols that compose the Venus clouds are primarily scattering agents at solar wavelengths. These aerosols reflect about 75% of the incident solar flux before it can be absorbed by the atmosphere or surface. The unknown substance that causes the observed cloud-top ultraviolet contrasts is responsible for most of the absorption of sunlight within the upper cloud deck (57.5−71 km). This substance absorbs almost half of the sunlight deposited on Venus and contributes to solar heating rates as large as 6° K/day at levels near 65 km. With the exception of CO₂, all of the important sources of solar extinction have concentrations that vary with position, and, in general, these concentrations are not well known. To determine the sensitivity of the model results to these uncertainties, the concentrations of these opacity sources were varied in the model atmosphere and solar fluxes were computed for each case. These tests indicate that CO₂ dominates the solar absorption at levels above the cloud tops and that heating rates are relatively insensitive to the distribution of other sources of extinction there. Within the upper cloud deck, uncertainties in the distribution of the UV absorber and the H₂SO₄ aerosols can produce heating rate errors as large as 50% at some levels. Diurnally averaged solar heating rates for the nominal opacity distribution were computed as a function of latitude at altitudes between 55 and 100 km, where most of the solar flux is deposited. The zonal wavenumber 1 (diurnal) and zonal wavenumber 2 (semidiurnal) components of the diurnally varying solar heating rates were also computed in this domain. These results should be sufficiently reliable for use in numerical dynamical models of the Venus atmosphere.     

Dynamical properties of the Venus mesosphere from the radio-occultation experiment VeRa onboard Venus Express

The dynamics of Venus’ mesosphere (60–100 km altitude) was investigated using data acquired by the radio-occultation experiment VeRa on board Venus Express. VeRa provides vertical profiles of density, temperature and pressure between 40 and 90 km of altitude with a vertical resolution of few hundred meters of both the Northern and Southern hemisphere. Pressure and temperature vertical profiles were used to derive zonal winds by applying an approximation of the Navier–Stokes equation, the cyclostrophic balance, which applies well on slowly rotating planets with fast zonal winds, like Venus and Titan. The main features of the retrieved winds are a midlatitude jet with a maximum speed up to 140 ± 15 m s^?1 which extends between 20°S and 50°S latitude at 70 km altitude and a decrease of wind speed with increasing height above the jet. Cyclostrophic winds show satisfactory agreement with the cloud-tracked winds derived from the Venus Monitoring Camera (VMC/VEx) UV images, although a disagreement is observed at the equator and near the pole due to the breakdown of the cyclostrophic approximation. Knowledge of both temperature and wind fields allowed us to study the stability of the atmosphere with respect to convection and turbulence. The Richardson number Ri was evaluated from zonal field of measured temperatures and thermal winds. The atmosphere is characterised by a low value of Richardson number from ～45 km up to ～60 km altitude at all latitudes that corresponds to the lower and middle cloud layer indicating an almost adiabatic atmosphere. A high value of Richardson number was found in the region of the midlatitude jet indicating a highly stable atmosphere. The necessary condition for barotropic instability was verified: it is satisfied on the poleward side of the midlatitude jet, indicating the possible presence of wave instability.     

Ion flow and momentum transfer in the Venus plasma environment

An analysis of ion data from 390 Venus Express, VEX, orbits demonstrates that the flow of solar wind- and ionospheric ions near Venus is characterized by a marked asymmetry. The flow asymmetry of solar wind H⁺ and ionospheric O⁺ points steadily in the opposite direction to the planet’s orbital motion, and is most pronounced near the Pole and in the tail/nightside region. The flow asymmetry is consistent with aberration forcing, here defined as lateral forcing induced by the planet’s orbital motion. In addition to solar wind forcing by the radial solar wind expansion, Venus is also subject a lateral/aberration forcing induced by the planet’s orbital motion transverse to the solar wind flow.The ionospheric response to lateral solar wind forcing is analyzed from altitude profiles of the ion density, ion velocity and ion mass-flux. The close connection between decreasing solar wind H⁺ mass-flux and increasing ionospheric O⁺ mass-flux, is suggestive of a direct/local solar wind energy and momentum transfer to ionospheric plasma. The bulk O⁺ ion flow is accelerated to velocities less than 10 km/s inside the dayside/flank Ionopause, and up to 6000 km in the tail. Consequently, the bulk O⁺ outflow does not escape, but remains near Venus as a fast (km/s) O⁺ zonal wind in the Venus polar and nightside upper ionosphere. Furthermore, the total O⁺ mass-flux in the Venus induced magnetosphere, increases steadily downward to a maximum of 2 × 10⁻¹⁴ kg/(m² s) at ≈400 km altitude, suggesting a downward transport of energy and momentum. The O⁺, and total mass-flux, decay rapidly below 400 km. With no other plasma mass-flux as replacement, we argue that the reduction of ion mass-flux is caused by ion-neutral drag, a transfer of ion energy and momentum to neutrals, implying that the O⁺ plasma wind is converted to a neutral (thermosphere) wind at Venus. Incidentally, such a neutral wind would go in the same direction as the Venus atmosphere superrotation.