Longitudinal variability of methane and ammonia bands on jupiter: II. Temporal variations

A set of spectra was obtained of the Jovian Equatorial Zone central meridian 6190 Å CH₄ and 6450 Å NH₃ bands in February 1980, a year after the data reported by W.D. Cochran and A.L. Cochran ((1980) Icarus42, 102–110). These new data confirm the results of the previous study, and also permit a search for temporal, as well as longitudinal, variability of these molecular absorption bands. The new data set shows a correlation of NH₃ and CH₄ equivalent widths, as well as a lack of any strong correlation of red continuum reflectivity with equivalent width. These trends were also exhibited by the 1979 data. Longitude regions of larger or smaller than average equivalent width seem still to be evident a year later, with some slight drift in longitude. An increase in the average CH₄ and NH₃ equivalent width over the entire planet was detected during the one year interval. This is easily understood as the result of a global decrease in the mean altitude of the NH₃ cloud.     

Spatially resolved reflectivities of Jupiter during the 1976 opposition

Spatially resolved absolute reflectivities of several regions of the Jovian disk in the wavelength region 3000 to 10760 Å are presented. Spectra were obtained of the central meridian and limbs of the Equatorial Region, North Equatorial Belt, and North Tropical Zone. Equivalent widths of several CH₄ and NH₃ bands are measured. The spatial variations of continuum reflectivity and absorption band profiles are shown in various ratio spectra.     

Observations of the phase variation of Venus CO2 equivalent widths

We present equivalent widths of Venus CO₂ scans of the P branch (P8–P32) of the 5ν₃ band at 8689 Å, the P16 line of the 5ν₃ band, and the P14 line of the ν₁ + 5ν₃ band at 7820 Å covering phase angles between 5°.1 and 170°. The equivalent widths reach a minimum at 10°, in agreement with a phase function with a backward lobe at 160° which is caused by a single internal reflection within the cloud particles. This is evidence that Venus cloud particles are composed of liquid droplets. Maximum equivalent widths are observed at ～60°, a value which is closer to the maximum of single-layer Mie scattering models than to that of two-layer models. At high phase angles we observe equivalent widths greater than those computed from homogeneous scattering models, indicating that at high altitudes the mixing ratio of scattering particles to CO₂ increases with depth. At all phase angles, particularly at large phase angles, the temporal and spatial variations in the observed equivalent widths confuse the phase variation.     

Titan solar occultation observed by Cassini/VIMS: Gas absorption and constraints on aerosol composition

A solar occultation by Titan's atmosphere has been observed through the solar port of the Cassini/VIMS instrument on January 15th, 2006. Transmission spectra acquired during solar egress probe the atmosphere in the altitude range 70 to 900 km at the latitude of 71° S. Several molecular absorption bands of CH₄ and CO are visible in these data. A line-by-line radiative transfer calculation in spherical geometry is used to model three methane bands (1.7, 2.3, 3.3 μm) and the CO 4.7 μm band. Above 200 km, the methane 2.3 μm band is well fit with constant mixing ratio between 1.4 and 1.7%, in agreement with in situ and other Cassini measurements. Under 200 km, there are discrepancies between models and observations that are yet fully understood. Under 480 km, the 3.3 μm CH₄ band is mixed with a large and deep additional absorption. It corresponds to the C-H stretching mode of aliphatic hydrocarbon chains attached to large organic molecules. The CO 4.7 μm band is observed in the lower stratosphere (altitudes below 150 km) and is well fit with a model with constant mixing ratio of 33±10 ppm. The continuum level of the observed transmission spectra provides new constraints on the aerosol content of the atmosphere. A model using fractal aggregates and optical properties of tholins produced by Khare et al. [Khare, B.N., Sagan, C., Arakawa, E.T., Suits, F., Callcott, T.A., Williams, M.W., 1984. Icarus 60, 127-137] is developed. Fractal aggregates with more than 1000 spheres of radius 0.05 μm are needed to fit the data. Clear differences in the chemical composition are revealed between tholins and actual haze particles. Extinction and density profiles are also retrieved using an inversion of the continuum values. An exponential increase of the haze number density is observed under 420 km with a typical scale height of 60 km.     

Fabry-Perot determinations of midlatitude F-region neutral winds and temperatures from 1975 to 1979

Fabry-Perot interferometer measurements of the Doppler shifts and widths of the nightglow 630.0 nm line at Laurel Ridge Observatory, Pennsylvania are presented for the period 1975 to 1979, covering both solar minimum and solar maximum conditions. The F-region neutral wind vectors v_n and temperatures T_n deduced from these measurements show both day-to-day changes and overall seasonal patterns in the nocturnal variations during geomagnetically quiet conditions. Divergence in both the meridional and zonal horizontal flow is noted on occasion. The v_n results are compared with models including only solar EUV heating and those with EUV plus a high latitude heat source. The aggregate v_n data for solar cycle minimum conditions agree best with model predictions for winter zonal and equinoctal meridional winds and worst for winter meridional and summer zonal winds. At solar cycle maximum the predicted, rapid transition at equinox from summer to winter wind patterns and vice-versa is observed. The T_n data are in reasonable agreement with the MSIS model predictions.     

Ground-based observations of O2 (b1Σ+g−X3Σ−g) atmospheric bands in high latitude auroras

Analysis of observed spectrograms is based on comparison with synthetic spectra. The O₂(b¹Σ⁺_g?X³Σ^?_g Atm. (1,1) band in high latitude auroras observed from the ground is found to be the strongest in the Δv = 0 sequence. It is enhanced with altitude relative to the N₂ 1P(2, 0)and N⁺₂ M(2,0) bands, but the O₂ Atm. (2, 2) band has an unexpected low intensity. The range of rotational temperatures of the O₂ Atm. bands varies from approx. 200 to above 500 K which indicates that the altitude of the centroid of the emission region varies from about 100 km to the F-region. The highest temperature is found in the midday aurora associated with the magnetospheric cusp. Conspicuous relative variations between the intensities of N₂ and O₂ spectra are documented, but a satisfactory explanation of the variety is not given. Deviations of the observed O₂ Atm. band intensities from the vibrational intensity distribution predicted by Franck-Condor factors indicate that the excitation of the O₂ Atm. bands in aurora is not mainly due to particle impact on O₂, and the contribution due to energy transfer from hot O(¹D) atoms has to be found in future research.     

Inhomogeneous models of the atmosphere of Saturn

Analyses of ultraviolet, visible, and near-infrared spectra of Saturn lead to an inhomogeneous atmospheric model, having a clear gas layer which lies above an absorbing particle layer which lies above an ammonia haze layer. The boundary between the clear layer and the absorbing particle layer is at a pressure of 0.2 atm in the equatorial region and 0.3 atm in the temperate region. The boundary between the absorbing particle layer and the haze layer is at the radiative-convective boundary. Observations of ammonia absorption lines indicate that sunlight penetrates the haze to the ammonia sublimation level at a depth of 1.1 atm. Absorbing particles cause the observed decrease in reflectivity from visible to ultraviolet wavelengths. Consideration of the wavelength variation of Mie scattering parameters leads to an upper limit of about 0.2 μm for the particle radii and a particle number density of 10³ cm^?3. Some possible particle compositions are discussed. Comparison of computed 3-0 and 4-0 band hydrogen quadropole line equivalent widths with observed values leads to a haze layer optical thickness above the ammonia sublimation level of approximately 10. Equivalent widths computed for an equilibrium distribution of states agree better with observed values than those computed for a normal distribution. Methane 3ν₃ band manifold equivalent widths are in best agreement with measured equivalent widths for a CH₄/H₂ abundance ratio of 2 × 10^?3, which is 4.5 times the solar C/H ratio.     

Infrared spectral variations of three Mira variable carbon stars with the 11.3 μm SiC feature

The spectral variations of three Mira variable carbon stars, V CrB, T Dra and V Cyg in the infrared are investigated based on ISO SWS data. It is found that either continua or molecular/dust features were variable with time in the infrared for these carbon stars during one and a half year observations. When stars were brighter the infrared continuum spectra became blue while stars were fainter the infrared continuum spectra became red. In addition, during spectral variations there were the correlation between the 3.05 μm HCN+C₂H₂ and the 5.2 μm C₃ molecular band strengths and the anti-correlation between the 3.05 μm HCN+C₂H₂ molecular band strengths and 13.7 μm C₂H₂ band strengths while during variations the 11.3 μm SiC dust emission strengths were not clearly changed.     

The ultraviolet absorption band at 2175 Å: Correlations with other interstellar features

The hump in the ultraviolet part of the interstellar extinction curve is interpreted as a broad diffuse absorption band. Its equivalent width is estimated for 36 stars by means of OAO-2 data. The equivalent widths are correlated with the following parameters: colour excessE(B-V), colour excessE(B – V), depth of the band m _max, equivalent widths of the diffuse bands at 5780 and 6284 Å, and the column density of neutral hydrogenN _HI. The physical parameters half-width and oscillator strength of the band at 2175 Å are estimated.     

Interpretation of spatial and temporal variations of hydrogen quadropole absorptions in the Jovian atmosphere observed during the 1972 apparition

During the 1972 apparition of Jupiter, we carried out a patrol of the (3,0) S(1) and (4,0) S(1) quadrupole lines of molecular hydrogen in the equatorial region and in bands bounded by ±15 and ±49° zenographic latitude from the McDonald and Table Mountain Observatories. At the center of the Jovian disk, we found evidence of temporal variability of both lines over the duration of our observing period. We employ a technique which takes into account all radiative transfer processes in an inhomogeneous model of Jupiter's atmosphere, and use it to derive the effective level of formation of the spectral lines and the relative abundance of hydrogen. In this way, we are able to correlate measured changes in the equivalent widths of the hydrogen lines with variations in cloud structure. The effective pressure level at which the (4,0) S(1) line is formed varies in the range 2 ± 0.5 to 1.3 ± 0.2 atm, while for the (3,0) S(1) line, the pressure varies between 1.6 ± 0.5 and 1 ± 0.4 atm. If these variations are interpreted in terms of changes in elevation of the top of a dense lower cloud deck, the elevation apparently varied with an amplitude of 25 km during the observational period.Spatial variations in the strengths of both lines were also found. Both lines are weaker at the east limb than at the center of the disk (15–19%) while the variations toward the west limb are less pronounced (5%). Similar center-to-limb variations were found in the latitude bands bounded by ±15 and ±49°, although the lines were stronger in the northern component at the time of the observations.     

Observations of the 22 April 1982 stellar occultation by Uranus and the rings

The 22 April 1982 stellar occultation of KME 14 by Uranus was observed from Tenerife, Canary Islands, using the Teide Observatory 1.5-m telescope. From model fits to the immersion and emersion ring profiles, we obtained (1) midtimes of the ring events with a typical uncertainty of 0.01 sec; (2) ring widths for rings 4, α, β, γ, δ, and ϵ with a typical uncertainty of a few tenths of a kilometer; and (3) equivalent widths and normal optical depths of all nine rings. The immersion planetary occultation was clouded out, but emersion was successfully observed, and the stratospheric temperature profile was obtained by numerical inversion. The profile shows a temperature maximum near the 8-μbar pressure level, characterized by T(8 μbar) = 141°K and T(8 μbar)–T(13 μbar) = 5°K for the sampled suboccultation latitude of −11°.9. Both the mean temperature and the temperature variations are consistent with the latitude-dependent atmospheric structure found by B. Sicardy et al. (1985, Icarus 64, 88–106) from widely separated observations of the same event.     

High-dispersion spectroscopic observations of Venus near superior conjunction: III. The carbon dioxide band at 8689 Å

To investigate further the Venus inverse phase effect, 12 plates of the 8689 Å CO₂ band, taken in 1971, were analyzed for abundances and temperatures using the curve-of-growth method. We found an average rotational temperature of 230 ± 1°K for an average slope of the curve of growth of 0.56 ± 0.03. Day-to-day variations in the equivalent widths of the CO₂ lines can be as large as 25%, and long-term changes in the cloud-top temperature are confirmed. On the other hand, the widely accepted “inverse” phase effect of CO₂ line equivalent widths near superior conjunction receives no firm support from these results.     

Modeling infrared absorption bands with nonspherical particles

We investigated the two deepest absorption bands observed in the spectra of stars and protostars, the water-ice band with the center near 3.1 μm and the silicate band with the center near 9.7 μm, by using a core-mantle confocal spheroid model with various axial ratios and relative volumes of the core material. We considered the effect of grain size, shape, structure, chemical composition, and orientation on the central wavelengths of the two bands, their full widths at half maximum (FWHMs), the ratio of the optical depths at their centers, and the polarization. We found that the observed relationships between the FWHMs of the bands and the ratio of their optical depths at the band centers could be explained if we chose slightly oblate or prolate particles (a/b ? 2) of small sizes (r_v ? 0.35 μm) with a silicate core and a thin ice mantle (V_core/V_total ? 0.7).     

Multiple scattering and the phase variation of equivalent widths for phase functions of typeP(cosθ)=ϖ+ϖ1 P 1(cosθ)+ϖ2 P 2(cosθ)

After computing theH-functions for 21 different phase functions corresponding to various combinations of \(\bar \varpi \) ₁=?₁/?and \(\bar \varpi \) ₂=?₂/?along with 15 values of ?, variations of equivalent widths with phase angle have been obtained for these cases for lines with Lorentz profile with the continuum albedo ? _c =0.99. It is found that: (i) The absolute values of equivalent width at any phase angle are Inversely related to the value of phase function for that angle; (ii) The usual inverse phase effect occurs whenever the phase function has a maximum at α=0 and a dip somewhere between α=0 and α=180; (iii) Whenever the phase function has minima at α=0 and α=180 one obtains an incipient inverse phase effect at large phase angles; and (iv) The total variations are larger for weaker lines.     

Investigation of the linear polarization in infrared absorption bands

We consider the effects of the grain size, shape, structure, and chemical composition as well as the angle between the grain rotation axis and the incident ray on the full widths at half maximum (FWHM) of the polarization bands in the two deepest infrared absorption bands observed in the spectra of protostars, the water-ice band centered at 3.1 μm and the silicate band centered at 9.7 μm, using a core—mantle confocal spheroid model with various axial ratios a/b and relative volumes of the core material. We have found that the observed polarization bands with FWHM_p < 0.3 μm in the water-ice absorption band can be explained only by oblate and prolate particles with r _v ≤ 0.35 μm and the polarization bands with FWHM_p ≈ 0.3 μm can be explained only by particles with r _v ≈ 0.35 μm. Broad silicate absorption bands (FWHM ≈ 3 μm) with broad polarization bands (FWHM_p ≈ 2.7 μm) can be explained by particles with r _v ≈ 0.35 μm. Narrow silicate absorption bands (FWHM ≤ 3 μm) with any FWHM of the polarization bands can be explained by a mixture of particles of two types of olivine. Narrow polarization bands (FWHM_p ≈ 2 μm) with broad absorption bands can be explained only by very small particles, r _v ≤ 0.1 μm. We have found the relationships between the effective polarization and extinction cross sections and estimated the ranges of observed polarizabilities that can be explained by particles of given shape and orientation in each of the bands independently. Independent studies of the observational data for each of the bands are shown to give a wider choice of particle model parameters.     

High dispersion spectroscopic observations of Venus near superior conjunction IV. Results for the carbon dioxide bands in the IV-N photographic region

Phase curves for the CO₂ bands at 7883, 7820, and 8689 Å are presented. While the weaker bands at 7820 and 7883 Å show a definite “inverse phase effect,” the band at 8689 Å shows a more normal phase curve; it also exhibited much larger day-to-day variations in the CO₂ abundance near superior conjunction in 1971. Because the variation of the phase curves with band strength is comparable to temporal variations on Venus, simultaneous observations of strong and weak bands are still needed to determine the dependence on band strength accurately.     

An analysis of Saturn's methane 3ν3 band profiles in terms of an inhomogeneous atmosphere

Observed profiles of the R branch of Saturn's CH₄3v₃ band are compared with synthetic profiles computed from inhomogeneous models which are consistent with Saturn's H₂ quadrupole line equivalent widths. A C/H ratio approximately three times the solar value and a CH₄ abundance of about 100 mam are found. Scattering plays a significant role in the formation of manifold profiles below a depth where the H₂ abundance is 20–30 km am.     

Mid-infrared detection of large longitudinal asymmetries in Io's SO2 atmosphere

We have observed about 16 absorption lines of the ν₂ SO₂ vibrational band on Io, in disk-integrated 19-μm spectra taken with the TEXES high spectral resolution mid-infrared spectrograph at the NASA Infrared Telescope Facility in November 2001, December 2002, and January 2004. These are the first ground-based infrared observations of Io's sunlit atmosphere, and provide a new window on the atmosphere that allows better longitudinal and temporal monitoring than previous techniques. Dramatic variations in band strength with longitude are seen that are stable over at least a 2 year period. The depth of the strongest feature, a blend of lines centered at 530.42 cm⁻¹, varies from about 7% near longitude 180° to about 1% near longitude 315° W, as measured at a spectral resolution of 57,000. Interpretation of the spectra requires modeling of surface temperatures and atmospheric density across Io's disk, and the variation in non-LTE ν₂ vibrational temperature with altitude, and depends on the assumed atmospheric and surface temperature structure. About half of Io's 19-μm radiation comes from the Sun-heated surface, and half from volcanic hot spots with temperatures primarily between 150 and 200 K, which occupy about 8% of the surface. The observations are thus weighted towards the atmosphere over these low-temperature hot spots. If we assume that the atmosphere over the hot spots is representative of the atmosphere elsewhere, and that the atmospheric density is a function of latitude, the most plausible interpretation of the data is that the equatorial atmospheric column density varies from about 1.5×¹⁰¹⁷ cm⁻² near longitude 180° W to about 1.5×¹⁰¹⁶ cm⁻² near longitude 300° W, roughly consistent with HST UV spectroscopy and Lyman-α imaging. The inferred atmospheric kinetic temperature is less than about 150 K, at least on the anti-Jupiter hemisphere where the bands are strongest, somewhat colder than inferred from HST UV spectroscopy and millimeter-wavelength spectroscopy. This longitudinal variability in atmospheric density correlates with the longitudinal variability in the abundance of optically thick, near-UV bright SO₂ frost. However it is not clear whether the correlation results from volcanic control (regions of large frost abundance result from greater condensation of atmospheric gases supported by more vigorous volcanic activity in these regions) or sublimation control (regions of large frost abundance produce a more extensive atmosphere due to more extensive sublimation). Comparison of data taken in 2001, 2002, and 2004 shows that with the possible exception of longitudes near 180° W between 2001 and 2002, Io's atmospheric density does not appear to decrease as Io recedes from the Sun, as would be expected if the atmosphere were supported by the sublimation of surface frost, suggesting that the atmosphere is dominantly supported by direct volcanic supply rather than by frost sublimation. However, other evidence such as the smooth variation in atmospheric abundance with latitude, and atmospheric changes during eclipse, suggest that sublimation support is more important than volcanic support, leaving the question of the dominant atmospheric support mechanism still unresolved.     

Spatially resolved methane band photometry of Saturn: I. Absolute reflectivity and center-to-limb variations in the 6190-, 7250-, and 8900-Å bands

We present spatially resolved measurements of Saturn's absolute reflectivity in methane bands at 6190, 7250, and 8900 Å and in nearby continuum regions. Images were obtained through narrow-band interference filters with a 500 × 500-pixel charge-coupled device. Band/continuum ratios were measured to high accuracy by referencing to the ring brightness in each image. Several data processing techniques enhanced the quality of the observations. These are the use of the ring symmetry to find center position and orientation, accurate subtraction of ring light, and constrained image deconvolution. Uncertainty in the continuum absolute reflectivity is ±10%. Uncertainties in band/continuum ratios are from one to several percent. The Equatorial Zone was much brighter than any other latitude in the strong 8900 band image. Northern mid-latitudes were brighter than southern mid-latitudes. The latter observation indicates fewer high-altitude aerosols in the south, a possible result of atmospheric dynamics or seasonal sublimation of NH₃ crystals. The data are tabulated and presented in a form suitable for quantitative scattering model analyses.     

Spatially resolved absolute spectral reflectivity of Jupiter: 3390–8400 Å

Observational determinations of the absolute spectral reflectivities of visually distinct regions of Jupiter are presented. The observations cover the 3390–8400 Å region at 10 Å resolution, and they are compared with observations using 150–200 Å filters in the 3400–6400 Å range. The effective reflectivities for several regions (on the meridian) in the 3400–8400 Å range are: South Tropical Zone, 0.76±0.05; North Tropical Zone, 0.68±0.08; South Equatorial Belt, 0.63±0.08; North Equatorial Belt, 0.62±0.04; and the Great Red Spot, 0.64±0.09. Reflectivities near the limb are also observed. The appropriate blue and red reflectivities are tabulated in support of the Pioneer 10 and 11 imaging photopolarimeter experiments. For the regions listed above, equivalent widths of molecular bands vary as: CH₄ (6190 Å), 14–16 Å; CH₄ (7250 Å), 77–86 Å; and NH₃ (7900 Å), 87–95 Å. Significant differences from the results of C. B. Pilcher, R. G. Prinn, and T. B. McCord (“Spectroscopy of Jupiter: 3200 to 11200 Å,” J. Atmos. Sci.30, 302–307.)