藏南冈底斯带中段始新世岩浆作用的厘定及其大地构造意义

本文对藏南冈底斯带中段的花岗岩类和角闪辉长岩进行了锆石U-Pb年代学和全岩地球化学分析,据此阐明了岩体的形成机制与演化过程,并探讨了成岩时的大地构造背景。分析结果显示,研究区内花岗岩类和角闪辉长岩体的LA-ICPMS锆石U-Pb定年结果为41~55Ma,为始新世早-中期岩浆活动的产物,代表了区内岩体的成岩年龄。在地球化学组成上,花岗岩类属于钙碱性到高钾钙碱性系列,均富集轻稀土(LREE)和大离子亲石元素(LILE)(Rb、Ba和K),强烈亏损Nb、Ta、P等高场强元素(HFSE),具有弧型岩浆岩的地球化学组成。此外,花岗岩类的铝饱和指数(A/CNK)小于1.1,属于准铝质到弱过铝质的I型花岗岩。角闪辉长岩为石榴橄榄岩部分熔融的产物,并在后期侵位的过程中遭受到了壳源物质的混染。综合分析表明,研究区内的岩体形成于初始碰撞向主碰撞的转化阶段。始新世早期(～50Ma)新特提斯洋板片的断离引起软流圈物质上涌,导致岩石圈地幔发生部分熔融形成基性岩浆,随后基性岩浆底侵至下地壳并诱发下地壳发生部分熔融形成花岗岩质岩浆,最后经过岩浆混合作用形成始新世早-中期冈底斯地区的花岗岩类。     

西准噶尔北部塔斯特岩体辉长岩锆石U-Pb定年及其地质意义

西准噶尔北部萨吾尔地区晚古生代火山岩浆作用强烈,其形成构造环境一直是争议的焦点。塔斯特岩体作为区内最重要的复式岩体,主要由辉长岩、花岗闪长岩、二长花岗岩和钾长花岗岩组成,对其中的辉长岩进行LA-ICP-MS锆石U-Pb定年,206Pb/238U年龄加权平均值为345.3±2.3Ma(MSWD=1.8),说明塔斯特岩体形成于早石炭世中期。岩石地球化学特征显示,样品里特曼指数δ平均值为3.04,A/CNK(0.76~0.85)1.1,属于准铝质钙碱性岩石,岩石富集大离子亲石元素,而高场强元素和重稀土元素相对亏损,无明显的Eu异常,与西准噶尔地区后碰撞花岗岩类地球化学特征相似。综合研究认为,该辉长岩形成于后碰撞构造环境,可能是后碰撞阶段挤压-伸展转变期的产物。塔斯特辉长岩年龄是目前西准噶尔地区最老的后碰撞岩浆岩锆石年龄,表明西准噶尔地区在早石炭世中期已处于后碰撞构造环境,为西准噶尔地区后碰撞构造-岩浆演化下限的厘定提供了新的证据。     

西准噶尔晚古生代岩浆活动和构造背景

西准噶尔作为中亚造山带的一部分,吸引了大量学者的关注。蛇绿混杂岩带、花岗岩、中基性岩墙在本地区广泛出现,表明西准噶尔晚古生代构造演化极为复杂。但是在许多方面仍存在很多争议,例如西准噶尔蛇绿混杂岩带的形成时代、岩石组合和岩石成因;I型和A型花岗岩的岩石成因,构造背景和热机制;中基性-酸性岩墙群的年代学、岩石成因、构造背景和古应力场;西准噶尔晚古生代年代学格架和构造背景;西准噶尔显生宙地壳增生;西准噶尔基底特征和西准噶尔晚古生代构造演化等。笔者通过搜集前人的资料和数据,对西准噶尔区域发育的蛇绿混杂岩带、地层、古地理环境、花岗岩体和中基性岩墙群的总结,结合项目组野外与室内数据的研究,得到以下认识:(1)达尔布特和克拉玛依蛇绿混杂岩的形成环境为与俯冲相关的弧后盆地,源区来自含尖晶石二辉橄榄岩高程度部分熔融作用;(2)早石炭世花岗岩形成于俯冲环境,晚石炭世-早二叠世花岗岩形成于后碰撞环境,中二叠世花岗岩形成于板内环境;(3)I型花岗岩的成因与俯冲密切相关,而A型花岗岩和中基性岩墙产于后碰撞环境下;(4)A型花岗岩是下地壳受地幔底侵发生部分熔融并高度分离结晶的产物,中基性岩墙群普遍具有埃达克质岩的地球化学特点,可能产于受流体(或熔体)交代的残余洋壳板片的部分熔融;(5)中基性岩墙群稍晚于寄主岩体而形成,但两者均形成于后碰撞构造背景。在晚石炭世-早二叠世,西准噶尔处于近南北向的拉张应力体系;(6)西准噶尔在泥盆纪为洋盆体系;早石炭世,俯冲-碰撞过程结束;晚石炭世-早二叠世属于后碰撞环境;中晚二叠世处于板内环境。     

高钾,钙碱性Ⅰ型花岗岩类的成因

许多Ⅰ型花岗岩类岩浆是由较老的变火成岩经部分熔融而形成的，这类溶体的组成大致是钙碱性和准铝质的。这些熔体是花岗质至英云闪长质熔体，是在其下地壳源区内的极端热条件下形成的。     

新疆准噶尔地区花岗岩中微粒闪长质包体特征及后碰撞花岗质岩浆起源和演化

新疆准噶尔地区也布山、庙儿沟两个晚古生代后碰撞准铝一过铝质花岗岩体中，广泛发育大量的暗色微粒闪长质包体。岩石学、矿物学、主量元素和微量元素地球化学研究表明，包体与其寄主岩存在明显的亲缘关系。东准噶尔也布山黑云母花岗岩体中的暗色微粒包体与寄主岩有相似的地球化学成分，表明它是与寄主花岗岩相同成因的同源包体，是来自上地幔的基性岩浆经过高度演化、结晶分异的产物；西准噶尔庙儿沟二长花岗岩体中含钾长石斑晶的微粒包体则主要是由幔源的下地壳基性岩部分熔融形成的残余体，被酸性岩浆携带并发生成分上的同化和混染，最后在上地壳侵位的产物。同准噶尔碱性花岗岩一样，载荷包体的准铝一过铝质花岗岩是晚古生代后碰撞阶段构造一岩浆活动的岩石类型之一，其形成和演化标志了准噶尔地区后碰撞幔源岩浆底侵作用导致大陆地壳垂向生长的过程。     

高温高压下花岗闪长质熔体的斜长石结晶作用实验研究

对花岗闪长质熔体在500MPa～2000MPa,650℃～750℃和一定水含量条件下结晶作用实验的结果表明,斜长石在500MPa和水饱和条件下的结晶温度为675℃,斜长石的结晶及其成分明显受温度、压力和熔体水含量影响。花岗闪长质熔体有斜长石结晶时残余熔体的SiO2含量高于无斜长石结晶的情况。花岗闪长质熔体发生角闪石、黑云母和斜长石结晶后的残余熔体在主量元素组成上与典型的A型花岗岩基本一致,也与初始物产地的A型花岗岩接近。因此,实验研究初步从主量元素上证明,东准噶尔A型花岗岩浆可以来源于花岗闪长质岩浆的分异结晶作用。     

东准噶尔卡拉麦里蛇绿岩带南侧侵入体的岩石学、地球化学及年代学特征

东准噶尔卡拉麦里蛇绿岩带南侧分布有大量的石炭纪侵入体,主要出露于五彩城、滴水泉一带及野马站地区。通过对卡拉麦里断裂以南侵入体岩石类型、锆石年代学、地球化学的综合分析,划分出早石炭世后碰撞I型花岗岩类及晚石炭世陆内双峰式侵入岩(碱长花岗岩+角闪辉长岩)。结合断裂以北黄羊山、老鸦泉岩体新近发表的数据及区域内火山岩的研究成果,对卡拉麦里地区石炭纪—二叠纪构造-岩浆演化过程给出了新认识,即卡拉麦里地区从后碰撞到陆内伸展的构造转换时间为早石炭世末期—晚石炭世早期,后碰撞阶段岩浆岩以钙碱性I型花岗岩、玄武安山岩、安山岩为特点,陆内伸展阶段以典型的双峰式岩浆岩(辉长岩+花岗岩、玄武岩+流纹岩)及A型花岗岩为特点,卡拉麦里地区具有正εNd值的花岗岩类来源于亏损地幔形成的年轻地壳的部分熔融。     

大别山沙村中生代A型花岗岩和基性岩的源区演化关系

A型花岗岩的成因虽存在不同的认识模式,但对大别山沙村A型花岗岩的岩石化学和地球化学研究结果表明,其物质源自大陆岩石圈地幔的部分熔融,含有古老地壳信息。结合被侵入基性岩的地球化学和年代学资料,推测大别造山带中生代岩石圈地幔的地球化学性质与下扬子地幔相似。花岗岩中锆石SHRIMP法U-Pb年龄为119.0±3.2Ma,说明其岩浆侵位于早白垩世,与邻近的基性岩侵位时间相近但稍晚。在三叠纪因大陆俯冲碰撞增厚的岩石圈在早白垩世被拉张减薄,含有古老地壳成分的扬子陆下岩石圈地幔及其上覆下地壳发生部分熔融,形成了不同成分的碰撞后岩浆岩。其中部分基性岩浆分异结晶成为辉长岩,而A型花岗岩可能是同一地幔源区物质小比例部分熔融后分异结晶的产物。     

内蒙元宝山侵人岩地球化学特征及其与成矿的关系

元宝山矿区内侵入岩分布广泛.中侏罗世碱长花岗岩与二长花岗岩同源且属同一岩体,以高硅、高钾、富碱、低钙、准铝一弱过铝质为特征,具中等含量的稀土元素丰度值,轻稀土明显富集、重稀土相对平坦,负铕异常强烈,属A型花岗岩,是下地壳物质经部分熔融作用在造山后的伸展机制背景下形成的.晚侏罗世花岗斑岩与流纹斑岩SiO2含量稍低,Al2O3含量偏高且变化范围大,A/CNK显示其为过铝质花岗岩,具S型花岗岩的典型特征,是下地壳发生深融作用并混入少量地幔物质,形成于碰撞后的构造环境中.区内具铅锌矿化、银矿化、钼矿化,流纹斑岩体为其成矿母岩.     

准噶尔东部早志留世两类花岗岩的岩石成因及构造意义

哈尔里克山西段早志留世二长花岗岩和正长花岗岩呈北西西向带状展布,侵入奥陶系塔水组（O_1-2t）,LA-ICP-MS锆石U-Pb年龄为438.8±2.3~435.8±3.1 Ma。岩石高硅（SiO₂含量73.0%~77.8%）、富钾（K₂O含量3.31%~4.26%）、低镁（MgO含量0.03%~0.59%）,铝饱和指数A/CNK值1.02~1.08,属高钾钙碱性弱过铝质岩石。二长花岗岩轻重稀土分馏显著,Eu异常中等,亏损Nb、Ta、Ti、P,富集Rb、Ba、K,表现为分异的Ⅰ型花岗岩特征,源区为基性下地壳;正长花岗岩强烈亏损Eu、P、Ti、Sr,不同程度富集Rb、K、Zr、Hf,表现为A型花岗岩特征,其源区为缺水的浅部长英质地壳。结合区域地层不整合资料,认为东准噶尔地区早志留世为后碰撞环境而非岛弧带,后碰撞软流圈上涌带来的热熔融准噶尔年轻地壳形成了岩性丰富的东准噶尔志留纪后碰撞岩浆岩组合。      

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

Composition,formation conditions,and genesis of the Talatui gold deposit,the Eastern Transbaikal Region,Russia

The mineral composition of the Talatui gold deposit has been studied with modern methods. Previously unknown minerals (ilmenite, siegenite, glaucodot, wittichenite, matildite, hessite, pilsenite, zircon, tremolite, cummingtonite, hercynite, and goethite) have been identified in the ore. A high Re content has been detected in molybdenite. The spatiotemporal separation of Au and Ag is caused by different mineral species of these elements and their diachronous precipitation during the ore-forming process. Gold crystallized along with early mineral assemblages, beginning from virtually pure gold (the fineness is 996). Silver precipitated largely at the end of the process as hessite (Ag₂Te) and matildite (AgBiS₂). The temperature of ore deposition varied from 610 to 145°C, the pressure was 3370–110 bar, and the salt concentration ranged from 56.3 to 0.4 wt % NaCl equiv. The heterogeneous state (boiling) of fluid at the early stages has been documented. The chemical and isotopic compositions of the fluid testify to its magmatic nature and the participation of meteoric water at late stages in the ore-forming process. Thermodynamic modeling reproduces the main specific features of ore formation, including separation of Au and Ag. A physicochemical model of the gold mineralization in the Darasun ore district has been proposed. On the basis of several attributes, the Talatui deposit has been referred to the prophyry gold-copper economic type.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

藏北羌塘丁固—加措地区康托组的时代

自西藏区域地质调查大队创建康托组以来,康托组岩石地层单位广泛应用于羌塘地区,普遍认为其时代为新近纪.笔者于丁固-加措地区的康托组地层中采获古近纪轮藻化石Obtusocharat sp.,O.lanpingenis,Gyrogona qinajiangica和部分孢粉化石,并在康托组底部安山岩中获K-Ar年龄65.1～66.5Ma.上述轮藻组合与同位素年龄指示的地层时代为古新世-始新世,据此将测区康托组的时代确定为古近纪.由于测区康托组之上被唢纳湖组或鱼鳞山组角度不整合覆盖,因此康托组时代的确定不仅进一步完善了测区新生代地层系统,还指示测区在康托组与唢纳湖组或鱼鳞山组之间发生了一次强烈的构造运动.