热力学计算模拟对初始月幔结构的约束SCIEI北大核心CSCD

月球岩浆洋结晶形成的初始月球内部结构是其后续演化过程的开端,其结晶过程受月球岩浆洋的初始深度和物质组成这两个参数的制约。由于缺少直接来自月球深部的岩石样品,目前关于月球岩浆洋演化过程的探讨主要依赖实验和计算模拟手段。岩浆洋模型中形成的月壳厚度是否与探测结果一致是月球岩浆洋演化模型合理性的重要约束。最新的GRAIL(Gravity Recovery and Interior Laboratory)探测数据推算月壳厚度为34~43km,低于阿波罗时期认为的约70km,这对已有的月球岩浆洋演化模型提出了挑战。本文采用并修正FXMOTR程序包,针对月球岩浆洋在不同的初始深度和物质组成情况下的结晶过程,进行了一系列热力学计算模拟。通过量化月球岩浆洋的初始深度和物质组成对月壳厚度的影响,结合关于月球内部微量元素分配的研究结果,对比了月球岩浆洋结晶后期的残余熔体与原始克里普组分(urKREEP)的成分。本文的模拟结果显示,一个全月幔熔融且初始成分为月球初始上月幔组成(LPUM)的岩浆洋将在其深部结晶2.5%石榴子石,形成的月壳厚度符合GRAIL的约束,并且结晶出了合适的urKREEP成分。在此模型的基础上获取了月球初始的内部成分和密度结构,并对后期月幔翻转(Overturn)的程度进行了探讨。     

月球岩浆洋演化的实验岩石学研究进展SCIEI北大核心CSCD

由于缺少直接来自月球深部的岩石样品,实验和计算模拟是认识早期月球演化过程的有效方法和手段。20世纪70年代以来,陆续开展了大量的实验岩石学和实验地球化学工作对月球岩浆洋(lunar magma ocean,LMO)演化模型进行验证和修正。但是,学界对LMO模型中的两个关键性参数,即初始物质组成和熔融深度,仍然存在不同的认识。根据月震和重力探测数据推测的平均月壳厚度的差异、月球样品含水量的研究以及新的遥感数据解译发现月表广泛分布富镁铝尖晶石(Cr#<5)等等,直接影响我们对月球初始物质组成和LMO深度以及月球深部高压矿物相的评估。本文通过整理高温高压实验岩石学和实验地球化学在研究LMO演化方面的一系列研究成果,主要聚焦以下几个科学问题:(1)月球初始物质组成中的难熔元素和挥发分含量,以及LMO深度对月壳厚度、结晶矿物的种类及含量有着决定性的影响;(2)高压矿物相石榴子石在月球深部稳定存在的可能性及其对残余岩浆中微量元素的分配行为的制约;(3)特殊类型的月球样品(包括火山玻璃、镁质岩套等)的成因机制对月球深部物质组成具有指示意义;(4)月核的不同物质组成对LMO模型的初始成分含量,特别是微量元素的限定作用。我们以最新的观测数据和月球样品的分析结果为依据,对已有的LMO演化模型进行重新评估,提出月球深部含有石榴子石的LMO演化模型的可能性,并对该方向亟需开展的工作进行探讨。     

试论阜平杂岩的深熔作用

阜平杂岩中广泛产出浅色脉体,从而显示强烈的混合岩化作用.前人把引起混合岩化作用的机制归因于岩汁交代、重熔或无水深熔作用,似乎与实际的岩相结构不是很一致.矿物自形晶、钠长石净边结构和一些典型的矿物转化反应表明,阜平杂岩的混合岩化作用实际上经历了复杂的过程,主要表现为有水条件下的深熔作用.所形成的熔体有较大的流动性,可迁移一定的距离而进入邻近的岩石,对这些部位而言相当于发生了外来熔体的注入活动,造成熔体注入式混合岩化作用,形成一些交代反应和结构.因此,阜平杂岩混合岩化作用中的变质反应过程既包括长英质矿物的熔融(溶解),还涉及一种含水矿物(如黑云母)转化形成另外一种含水矿物(如角闪石)的化学反应.阜平杂岩的混合岩化作用最重要的机制是水致熔融或含水深熔作用,溶解性重熔或无水深熔作用则较为次要.     

冀北中低级变质表壳岩的年代学特征及其对华北克拉通构造演化的约束

华北克拉通在新太古代末期发生克拉通化,形成了现今规模的古陆,大量的太古宙岩石均经历了~2500Ma左右的区域高级变质作用(高角闪岩相-麻粒岩相)。而华北克拉通北部冀北地区出露一套中低级变质(绿片岩相-角闪岩相)的火山-沉积岩系,主要包括胡麻营地区红旗营子表壳岩和大阴山地区单塔子表壳岩中变质程度较低的部分。胡麻营地区红旗营子表壳岩系主要岩石组合为变基性火山岩、绿帘角闪岩、斜长角闪岩、含石榴石斜长角闪岩、角闪斜长片麻岩、黑云斜长片麻岩、黑云角闪斜长片麻岩、黑云二长片麻岩、石英片岩、磁铁石英岩等,SIMS锆石U-Pb定年结果表明斜长角闪岩形成于2486±18Ma(MSWD=1.4),而黑云斜长片麻岩形成于2507±37Ma(MSWD=2.0)。大阴山地区单塔子中低级变质表壳岩系主要由浅变质火山岩、云母石英片岩、斜长角闪岩、磁铁石英岩和大理岩等组成,SHRIMP锆石U-Pb定年结果显示,浅变质火山岩中的变玄武岩形成于2490±19Ma(MSWD=2.0),而变英安岩形成于2502±8Ma(MSWD=0.83)。因此,冀北中低级变质的表壳岩系主要形成于新太古代末期,形成年龄为2507~2486Ma;结合冀东青龙地区新太古代末期(2511~2503Ma)的浅变质火山-沉积岩系(青龙表壳岩),我们认为新太古代末期,中低级变质表壳岩系广泛分布于华北克拉通的核部和边缘地区,此套岩系覆盖在太古宙高级变质杂岩之上,代表华北克拉通化之后的稳定盖层,是克拉通化的主要标志之一。     

辽宁后仙峪硼矿区混合岩的LA-MC-ICP-MS锆石U-Pb年龄：对硼矿成矿演化的制约

辽东硼矿赋存于辽吉裂谷带的古元古代火山—沉积岩系之中,属沉积—变质型硼矿床,主矿区包括有后仙峪硼镁矿、翁泉沟硼铁矿和砖庙—杨木杆硼镁矿,一直以来是我国硼矿石的主产地。本次研究在后仙峪硼矿区采集了矿区外围的条痕状混合花岗岩(DSQ-08)和矿体上盘侵位于电英岩之中的含电气石混合花岗岩(HXY-19),挑选出其中的锆石单矿物进行LA-MC-ICP-MS测年。条痕状混合花岗岩中锆石的核部具有岩浆振荡环带,Th/U值为0.64~0.96,~(207)Pb/~(206)Pb年龄为2240±4Ma;含电气石混合花岗岩中锆石的内核和边部均具有极为清晰的岩浆振荡环带,Th/U值分别为0.12~1.05和0.41~1.08,~(207)Pb/~(206)Pb年龄分别记录了2157±6Ma和1932±26Ma两次锆石生长事件。含电气石的混合花岗岩的锆石边部形成于混合岩化过程之中,记录了辽河群下部岩石在1.9Ga左右发生的部分熔融作用事件,具有重要的地质意义。矿区外围的条痕状混合花岗岩和矿体周缘含电气石混合花岗岩的核部岩浆年龄较为接近,说明两种岩石可能均由古元古代的火山—沉积岩,在1.9Ga左右经部分熔融作用形成。因此,结合前人在后仙峪硼矿区内进行的硼同位素地球化学和岩相学方面的研究成果,我们认为后仙峪硼矿区混合花岗岩的锆石核部U-Pb年龄可基本确定辽吉裂谷早期的超基性火山岩和酸性火山岩的喷发、海相蒸发沉积事件均发生于2240~2157Ma左右,该时期的蒸发沉积作用初步形成硼酸盐矿;后期强烈的部分熔融和混合岩化作用发生在1932±26Ma,在超基性火山岩保护下,硼矿发生变质和小规模的迁移,形成了硼镁矿、硼镁铁矿及矿体周缘的电英岩和含电气石混合花岗岩。     

表生还原条件下翡翠水岩反应的热力学计算

一些翡翠在表生还原条件下可观察到明显的水岩反应过程以及颜色与组织的改变。根据地质现象,从热力学计算的角度探讨了翡翠中的主矿物硬玉发生水岩反应后形成部分新的自生矿物的可能性。热力学计算的结果显示,在表生作用过程中,在环境存在额外的Mg2＋与Fe2＋的条件下,翡翠最易与Mg2＋和Fe2＋发生反应生成绿泥石。该结果为大多数无色翡翠经过表生还原作用后出现暗绿色-水绿色的颜色提供了一定的理论解释。     

大桥坞产铀火山-侵入杂岩的岩浆混合作用及其对赣杭构造带铀成矿潜力的指示意义

浙江省大桥坞铀矿床赋矿围岩为一套火山-侵入杂岩,锆石U-Pb定年显示该套杂岩的成岩时代为138~125 Ma。Hf同位素分析结果显示随着成岩时代变新,这些岩石中锆石εHf(t)值从约-13.0升高到约-3.0。锆石饱和温度同样表现出升高的趋势,从~749℃升高到~846℃。以上特征表明大桥坞地区火山-侵入杂岩为壳幔岩浆混合成因,且幔源物质加入的比例随成岩时代变新而增多。综合前人对赣杭构造带相山、芙蓉山和沐尘地区花岗质岩石的研究结果,发现这些岩石的全岩εNd(t)值和锆石εHf(t)值在135~112 Ma期间分别从-9.0升高到-2.0和-10.0升高到2.0,表明其成因上可能同壳幔岩浆混合有关,且随着成岩时代变新幔源岩浆的加入逐渐增多。Sr-Nd同位素模拟显示幔源岩浆加入的比例在135~112 Ma期间从0升高到~60%。由于幔源岩浆较壳源岩浆贫U和Th,前者的加入会稀释壳源岩浆中U和Th的含量,降低其铀成矿潜力。幔源物质加入越多,铀成矿潜力越低。赣杭构造带壳幔岩浆混合作用呈西弱东强的地质事实,可能是该带上铀矿床的分布呈西大东小格局的重要原因之一。因此,赣杭构造带东段找矿需关注富铀基底(花岗岩或长英质变质岩基底)与早白垩世火山岩盖层相结合的地区。     

峨眉山大火成岩省中苦橄岩与其共生岩石的地球化学特征及其对源区的约束

本文对在峨眉山玄武岩省中新发现的苦橄质岩石及其共生玄武岩的地球化学特征进行了研究,结果表明,除苦橄质岩石外,与其共生的玄武质岩石均属高Ti玄武岩。其主要元素特征与大多数大陆溢流玄武岩省相似,表现为高Fe_8、(CaO/Al_2O_3)_8和低Na_8,指示其形成压力高;其稀土和微量元素配分曲线相似,表现为轻稀土富集、高场强元素(HFSE)相对亏损,并且不存在Nb、Ta的负异常,而存在P和K的相对亏损。一些反映源区特征的比值,如La/Ta、La/Sm、(La/Nb)_(PM)、(Th/Ta)_(PM),Ta/Hf,Nb/Zr等,变化范围小,均指示了其地幔柱成因,且上升过程中很少或没有受到岩石圈地幔或地壳物质的混染,是石榴子石二辉橄榄岩在>75km时经大约7％的部分熔融的产物。而地幔柱的轴部位置可能位于现今云南丽江县城一带。     

西藏班公湖-怒江缝合带北缘多龙矿集区晚三叠世—侏罗纪增生杂岩结构及其对成矿地质背景的约束

西藏班公湖-怒江缝合带北缘多龙斑岩铜金矿集区出露的晚三叠世—体罗纪增生杂岩属总体无序、局部有序的非史密斯地层,由基质和块体2个部分组成.基质为晚三叠世—侏罗纪砂泥质复理石建造,块体由大小不等的玄武岩、安山玄武岩、灰岩、砂岩、硅质岩、辉长岩、超基性岩等组成.增生杂岩系变形强烈,发育强烈的构造置换作用,块体与基质之间由透入性挤压面理、剪切面理或韧性剪切断层分隔,为典型造山带大陆增生边缘的增生杂岩.多龙斑岩铜矿的含矿斑岩体侵位于侏罗纪增生杂岩系或以侏罗纪增生杂岩系为基底的岛弧型火山岩系中,属增生楔基础上发育的具有超大型潜力的岛弧型斑岩铜金矿床,其外围的拿若、色拉、拿顿、地保那木岗、鹫山、铁格龙和尕尔勤等系列铜金铅锌矿床点,在空间上均赋存于早白垩世花岗闪长斑岩体内部及其与侏罗纪增生杂岩系的内外接触带中,受矿集区北东向走滑断裂的控制,呈北东向成群展布,二者具有相似的成矿环境与成矿条件,其深部可能存在统一的斑岩型铜金铅锌矿床,属于统一的斑岩浅成低温热液成矿系统.班公湖-怒江缝合带北缘多龙矿集区晚三叠世—侏罗纪增生杂岩的识别,为正确认识多龙超大型斑岩铜金矿床的成矿地质背景和缝合带的演化提供了新的线索.     

西藏班公湖-怒江缝合带北缘多龙矿集区晚三叠世—侏罗纪增生杂岩结构及其对成矿地质背景的约束

西藏班公湖-怒江缝合带北缘多龙斑岩铜金矿集区出露的晚三叠世—侏罗纪增生杂岩属总体无序、局部有序的非史密斯地层,由基质和块体2个部分组成。基质为晚三叠世—侏罗纪砂泥质复理石建造,块体由大小不等的玄武岩、安山玄武岩、灰岩、砂岩、硅质岩、辉长岩、超基性岩等组成。增生杂岩系变形强烈,发育强烈的构造置换作用,块体与基质之间由透入性挤压面理、剪切面理或韧性剪切断层分隔,为典型造山带大陆增生边缘的增生杂岩。多龙斑岩铜矿的含矿斑岩体侵位于侏罗纪增生杂岩系或以侏罗纪增生杂岩系为基底的岛弧型火山岩系中,属增生楔基础上发育的具有超大型潜力的岛弧型斑岩铜金矿床,其外围的拿若、色拉、拿顿、地保那木岗、鹫山、铁格龙和尕尔勤等系列铜金铅锌矿床点,在空间上均赋存于早白垩世花岗闪长斑岩体内部及其与侏罗纪增生杂岩系的内外接触带中,受矿集区北东向走滑断裂的控制,呈北东向成群展布,二者具有相似的成矿环境与成矿条件,其深部可能存在统一的斑岩型铜金铅锌矿床,属于统一的斑岩浅成低温热液成矿系统。班公湖-怒江缝合带北缘多龙矿集区晚三叠世—侏罗纪增生杂岩的识别,为正确认识多龙超大型斑岩铜金矿床的成矿地质背景和缝合带的演化提供了新的线索。     

Experimental and Thermodynamic Constraints on the Sulphur Yield of Peralkaline and Metaluminous Silicic Flood Eruptions

Many basaltic flood provinces are characterized by the existenceof voluminous amounts of silicic magmas, yet the role of thesilicic component in sulphur emissions associated with trapactivity remains poorly known. We have performed experimentsand theoretical calculations to address this issue. The meltsulphur content and fluid/melt partitioning at saturation witheither sulphide or sulphate or both have been experimentallydetermined in three peralkaline rhyolites, which are a majorcomponent of some flood provinces. Experiments were performedat 150 MPa, 800–900°C, fO₂ in the range NNO –2 to NNO + 3 and under water-rich conditions. The sulphur contentis strongly dependent on the peralkalinity of the melt, in additionto fO₂, and reaches 1000 ppm at NNO + 1 in the most stronglyperalkaline composition at 800°C. At all values of fO₂,peralkaline melts can carry 5–20 times more sulphur thantheir metaluminous equivalents. Mildly peralkaline compositionsshow little variation in fluid/melt sulphur partitioning withchanging fO₂ (D_S 270). In the most peralkaline melt, D_S risessharply at fO₂ > NNO + 1 to values of >500. The partitioncoefficient increases steadily for S_bulk between 1 and 6 wt% but remains about constant for S_bulk between 0·5 and1 wt %. At bulk sulphur contents lower than 4 wt %, a temperatureincrease from 800 to 900°C decreases D_S by 10%. These results,along with (1) thermodynamic calculations on the behaviour ofsulphur during the crystallization of basalt and partial meltingof the crust and (2) recent experimental constraints on sulphursolubility in metaluminous rhyolites, show that basalt fractionationcan produce rhyolitic magmas having much more sulphur than rhyolitesderived from crustal anatexis. In particular, hot and dry metaluminoussilicic magmas produced by melting of dehydrated lower crustare virtually devoid of sulphur. In contrast, peralkaline rhyolitesformed by crystal fractionation of alkali basalt can concentrateup to 90% of the original sulphur content of the parental magmas,especially when the basalt is CO₂-rich. On this basis, we estimatethe amounts of sulphur potentially released to the atmosphereby the silicic component of flood eruptive sequences. The peralkalineEthiopian and Deccan rhyolites could have produced 10¹⁷ and10¹⁸ g of S, respectively, which are comparable amounts to publishedestimates for the basaltic activity of each province. In contrast,despite similar erupted volumes, the metaluminous Paraná–Etendekasilicic eruptives could have injected only 4·6 x 10¹⁵g of S in the atmosphere. Peralkaline flood sequences may thushave greater environmental effects than those of metaluminousaffinity, in agreement with evidence available from mass extinctionsand oceanic anoxic events. KEY WORDS: silicic flood eruptions; sulphur; experiment; Ethiopia; Deccan     

非均匀月壤介质的被动微波辐射传输模拟

基于非均匀月壤物理模型和辐射传输方程,模拟月壤介质中的微波辐射传输特性,探讨频率、月壤厚度等与月表亮温的关系。结果表明:在低频段,月壤微波辐射亮温的动态变化范围较大,可探测的月壤厚度大,3 GHz时的最大可探测月壤厚度达12.4 m;在高频段对应的可探测月壤厚度较小,特别是从50GHz往后的频率段内,最大可探测月壤厚度均小于2 m。不同频率的亮温-厚度变化曲线没有交叉点,且频率越高,所能探测的月壤厚度越小。根据模拟结果,建立了月壤厚度与亮温的查找表。基于查找表,利用单个波段的亮温数据即可得到月壤厚度信息。     

鲁西北平原地热热源机制的气体同位素约束

利用地热系统中气体的组分、丰度及同位素组成,可以识别地热流体的来源,追溯其热源形成机制。鲁西北平原地热资源自1998年以来大规模开发利用,但对其热源形成机制的认识尚不明确。本文利用溶解性气体组分和同位素特征对鲁西北平原热源成生条件进行了研究。溶解气成分结果表明,地热气体组分均以N₂为主,主要为大气降水入渗成因,在相对封闭的地质环境中深循环,混合一定量的地壳深部或地幔来源的气体。利用³He/⁴He比值,定量计算出研究区壳幔热源配分比为0.90～1.57,热源主要为地壳岩石放射性生热与来自上地幔沿深大断裂的对流热。其中,砂岩热储受构造活动影响较小,地幔热流占45%左右。而岩溶热储受构造控热明显:处于深大断裂或济南岩体与灰岩接触带附近的岩溶热储地幔热流占比相对较大,达48.77%～52.75%,显示除了正常的大地热流传导产热,沿深大断裂、岩体与灰岩接触带存在来自上地幔的对流聚热;处于齐广断裂与济南岩体中间的稳定地块地幔热流相对较小,仅占38.87%～40.97%,指示构造相对稳定区获得深部热流较少。     

Constraints on the Source Components of Lavas Forming the Hawaiian North Arch and Honolulu Volcanics

Hawaiian volcanoes, dominantly shields of tholeiitic basalt,form as the Pacific Plate migrates over a hotspot in the mantle.As these shields migrate away from the hotspot, highly alkaliclavas, forming the rejuvenated stage of volcanism, may eruptafter an interval of erosion lasting for 0·25–2·5Myr. Alkalic lavas with geochemical characteristics similarto rejuvenated- stage lavas erupted on the sea floor north ofOahu along the Hawaiian Arch. The variable Tb/Yb, Sr/Ce, K/Ce,Rb/La, Ba/La, Ti/Eu and Zr/Sm ratios in lavas forming the NorthArch and the rejuvenated-stage Honolulu Volcanics were controlledduring partial melting by residual garnet, clinopyroxene, Fe–Tioxides and phlogopite. However, the distinctively high Ba/Thand Sr/Nd ratios of lava forming the North Arch and HonoluluVolcanics reflect source characteristics. These characteristicsare also associated with shield tholeiitic basalt; hence theyarise from the Hawaiian hotspot, which is interpreted to bea mantle plume. Inversion of the batch melting equation usingabundances of highly incompatible elements, such as Th and La,requires enriched sources with 10–55% clinopyroxene and5–25% garnet for North Arch lavas. The ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Ndratios in lavas forming the North Arch and Honolulu Volcanicsare consistent with mixing between the Hawaiian plume and adepleted component related to mid-ocean ridge basalts. Specifically,the enrichment of incompatible elements coupled with low ⁸⁷Sr/⁸⁶Srand high ¹⁴³Nd/¹⁴⁴Nd relative to bulk Earth ratios is best explainedby derivation from depleted lithosphere recently metasomatizedby incipient melt (<2% melting) from the Hawaiian plume.In this metasomatized source, the incompatible element abundances,as well as Sr and Nd isotopic ratios, are controlled by incipientmelts. In contrast, the large range of published ¹⁸⁷Os/¹⁸⁸Osdata (0·134–0·176) reflects heterogeneitycaused by various proportions of pyroxenite veins residing ina depleted peridotite matrix. KEY WORDS: Hawaiian plume; Honolulu Volcanics; North Arch; plume–lithosphere interaction; rejuvenated stage; trace element geochemistry; alkalic lavas     

基于试验的模拟月壤表层取样理论修正及其应用

月球探测对于我国各方面综合实力的提升均具有巨大的推动作用。当前我国各研发机构对月球采样的研发重点集中于采样机具的设计制造上,对采样机具和月壤之间相互作用却研究较少。与地球土壤相比,月壤的形成环境与条件完全不同,从而造就了其较为特殊的物理力学性质。在利用与真实月壤类似的模拟月壤进行的薄壁圆筒贯入试验中,发现存在月壤滞留和月壤附壁现象,从而分析得出在采样机具表面与月壤相互作用的理论分析中,除了传统的摩擦力理论外,还可通过最大抗剪强度进行分析。通过对试验现象和数据对比摩擦力理论和最大抗剪强度理论发现,最大抗剪强度理论更加符合实际情况。故将最大抗剪强度理论引入已有的月球螺旋钻进采样的理论模型中,通过计算得出基于最大抗剪强度理论计算的螺旋临界转速低于基于摩擦力理论计算的临界转速,在一定程度上能够降低采样机具的能耗。     

月壤中纳米金属铁的太空风化成因及模拟方法分析

月壤中普遍存在着大量由太空风化作用产生的纳米金属铁,这些纳米金属铁在一定程度上改变了月球表面的物理、化学和光学特征.纳米金属铁在月壤中主要赋存于胶结质玻璃相中和月壤颗粒的表面,胶结质玻璃相的纳米金属铁起源于微陨石轰击富含太阳风氢粒子的月壤产生的高温熔融还原作用,颗粒表面的纳米金属铁来自微陨石轰击引起的蒸发沉积作用和太阳...     

Geochemical Constraints on the Mantle Source of the Upper Permian Emeishan Continental Flood Basalts,Southwestern China

The widespread Emeishan igneous province in southwestern China comprises the Emeishan continental flood basalts (ECFB) and associated mafie-ultramafic intrusions. The ECFB have variable SiO₂, ranging from 43.6 to 52.1 wt%, Al₂O₃ from 5.0 to 12.6 wt%, and total alkali (K₂O + Na₂O) from 0.7 to 6.5 wt%. These oxides exhibit negative correlations with MgO (5.4 - 23.1 wt%), implying fractional crystallization of olivine and clinopyroxene, which occur as phenocrysts in the rocks. Linear correlations between Zr, Nb, and La suggest that crustal contamination is not important. The primitive-mantle-normalized trace-element patterns show that the ECFB are enriched in high-field-strength trace elements, large-ion-lithophile elements, and light-rare-earth elements, similar to ocean-island basalt. Incompatible element ratios of the ECFB, such as Zr/Nb (7-10), Th/La (0.1-0.15), and Rb/Nb (0.9-1.7), differ from those of primitive mantle, N-MORB, and continental crust, but are similar to ocean-island basalts from an enriched mantle source (EM-1). However, the ECFB have isotopic ratios (¹⁴³Nd/¹⁴⁴Nd = 0.51229 -0.51276 and ⁸⁷Sr/⁸⁶Sr = 0.70480-0.70647) that imply that the ECFB were derived from a homogeneous, primitive lower mantle carried upward by a mantle plume.

We propose that the original melts derived from the mantle plume were contaminated through interaction at shallower depth with an enriched lithospheric mantle. This model suggests that the lithospheric mantle beneath the ECFB was modified by subduction of an oceanic slab.     

Tertiary Ultrapotassic Volcanism in Serbia: Constraints on Petrogenesis and Mantle Source Characteristics

The Serbian province of Tertiary ultrapotassic volcanism isrelated to a post-collisional tectonic regime that followedthe closure of the Tethyan Vardar Ocean by Late Cretaceous subductionbeneath the southern European continental margin. Rocks of thisprovince form two ultrapotassic groups; one with affinitiesto lamproites, which is concentrated mostly in the central partsof the Vardar ophiolitic suture zone, and the other with affinitiesto kamafugites, which crops out in volcanoes restricted to thewestern part of Serbia. The lamproitic group is characterizedby a wide range of ⁸⁷Sr/⁸⁶Sr_i (0·70735–0·71299)and ¹⁴³Nd/¹⁴⁴Nd_i (0·51251–0·51216), whereasthe kamafugitic group is isotopically more homogeneous witha limited range of ⁸⁷Sr/⁸⁶Sr_i (0·70599–0·70674)and ¹⁴³Nd/¹⁴⁴Nd_i (0·51263–0·51256). ThePb isotope compositions of both groups are very similar (²⁰⁶Pb/²⁰⁴Pb18·58–18·83, ²⁰⁷Pb/²⁰⁴Pb 15·62–15·70and ²⁰⁸Pb/²⁰⁴Pb 38·74–38·99), falling withinthe pelagic sediment field and resembling Mesozoic flysch sedimentsfrom the Vardar suture zone. The Sr and Nd isotopic signaturesof the primitive lamproitic rocks correlate with rare earthelement fractionation and enrichment of most high field strengthelements (HFSE), and can be explained by melting of a heterogeneousmantle source consisting of metasomatic veins with phlogopite,clinopyroxene and F-apatite that are out of isotopic equilibriumwith the peridotite wall-rock. Decompression melting, with varyingcontributions from depleted peridotite and ultramafic veinsto the final melt, accounts for consistent HFSE enrichment andisotopic variations in the lamproitic group. Conversely, themost primitive kamafugitic rocks show relatively uniform Srand Nd isotopic compositions and trace element patterns, andsmall but regular variations of HFSE, indicating variable degreesof partial melting of a relatively homogeneously metasomatizedmantle source. Geochemical modelling supports a role for phlogopite,apatite and Ti-oxide in the source of the kamafugitic rocks.The presence of two contrasting ultrapotassic suites in a restrictedgeographical area is attributable to the complex geodynamicsituation involving recent collision of a number of microcontinentswith contrasting histories and metasomatic imprints in theirmantle lithosphere. The geochemistry of the Serbian ultrapotassicrocks suggests that the enrichment events that modified thesource of both lamproitic and kamafugitic groups were relatedto Mesozoic subduction events. The postcollisional environmentof the northern Balkan region with many extensional episodesis consistent at regional and local levels with the occurrenceof ultrapotassic rocks, providing a straightforward relationshipbetween geodynamics and volcanism. KEY WORDS: kamafugite; lamproite; Mediterranean; Serbia; mantle metasomatism; veined mantle; petrogenesis     

浙东南晚中生代玄武岩的地球化学特征及其对源区物质的指示意义

浙江东南部晚中生代上、下火山岩系（以下简称上、下岩系）中均有玄武岩产出,本文对这些玄武岩分别进行了元 素地球化学和Sr-Nd-Pb同位素研究。不同岩系玄武岩的主量元素均表现出富碱、富Al等特征。但微量元素存在差异,下岩 系天台和青田样品具有轻稀土富集以及Ba, Pb和Sr富集,Eu负异常,Nb, Ta, Zr和Hf亏损的特征。上岩系玄武岩的元素特征 也有差别,永嘉花坦、宁波玄坛地、新昌镜岭和永嘉镜架山等地样品的元素特征表现出的性质与下岩系样品相似,武义玄 武岩样品没有Ta, Nb亏损特征,金衢盆地玄武岩的元素特征则介于两者之间。对应的,这些玄武岩样品的同位素组成也有 明显差异,下岩系玄武岩的初始同位素组成范围为 I Sr=0.70850~0.70897,εN（d t） = -5.6~-4.1,（206Pb/204Pb） i =18.21~18.38,（207Pb/204Pb） i =15.55~15.58,（208Pb/204Pb） i =38.26~38.49,接近下岩系中酸性岩浆岩的范围,反映了下地壳物质对其岩浆源区的显著影响。上岩系玄武岩有明显差异,表现出与元素特征对应的分组现象。其中永嘉花坦、宁波玄坛地、新昌镜岭和永嘉镜架山样品 I Sr = 0.70734~0.70936, εN（d t）= -7.1~-2.1,（ 206Pb/204Pb） i =18.01~18.40,（ 207Pb/204Pb） i = 15.54~15.62,（ 208Pb/204Pb） i=37.99~38.62, 具有富集特征, 可能来自活动大陆边缘; 而武义和金衢盆地样品的 I Sr=0.70533~0.70589, εNd（ t） =0.4~3.3,（206Pb/204Pb） i =17.23~18.11,（ 207Pb/204Pb） i =15.46~15.53,（ 208Pb/204Pb） i =36.91~38.43,具有类似OIB特征,趋向亏损地幔端元。上下岩系玄武岩的元素和同位素组成的研究表明,玄武岩的物质来源有较明显的差别,且表现出随时间变化的特征。其中下岩系玄武岩源区中可能有古老岩石圈地幔、下地壳物质和俯冲蚀变洋壳物质的贡献,而上岩系中玄武岩源区有可能是类似下岩系玄武岩性质的岩石圈、软流圈地幔和下地壳物质等的贡献。浙东南晚中生代岩石圈演化的动力学过程可能与太平洋板块俯冲有关,但不能排除岩石圈地幔拆沉的影响,具体的讨论还需要更多的岩石学和/或地幔包体资料的补充。     

Hf Isotope Systematics of Kimberlites and their Megacrysts: New Constraints on their Source Regions

Kimberlites from Southern Africa, along with their low-Cr megacrysts,have unusual Hf–Nd isotopic characteristics. Group I andTransitional kimberlites define arrays trending oblique to,and well below, the Nd–Hf isotope ‘mantle array’,defined by oceanic basalts, i.e. they have negative