Devolatilization or melting of carbonates at Meteor Crater,AZ?

We have investigated the carbonates in the impact melts and in a monolithic clast of highly shocked Coconino sandstone of Meteor Crater, AZ to evaluate whether melting or devolatilization is the dominant response of carbonates during high‐speed meteorite impact. Both melt‐ and clast‐carbonates are calcites that have identical crystal habits and that contain anomalously high SiO₂ and Al₂O₃. Also, both calcite occurrences lack any meteoritic contamination, such as Fe or Ni, which is otherwise abundantly observed in all other impact melts and their crystallization products at Meteor Crater. The carbon and oxygen isotope systematics for both calcite deposits suggest a low temperature environment (<100 °C) for their precipitation from an aqueous solution, consistent with caliche. We furthermore subjected bulk melt beads to thermogravimetric analysis and monitored the evolving volatiles with a quadrupole mass spectrometer. CO₂ yields were <5 wt%, with typical values in the 2 wt% range; also total CO₂ loss is positively correlated with H₂O loss, an indication that most of these volatiles derive from the secondary calcite. Also, transparent glasses, considered the most pristine impact melts, yield 100 wt% element totals by EMPA, suggesting complete loss of CO₂. The target dolomite decomposed into MgO, CaO, and CO₂; the CO₂ escaped and the CaO and MgO combined with SiO₂ from coexisting quartz and FeO from the impactor to produce the dominant impact melt at Meteor Crater. Although confined to Meteor Crater, these findings are in stark contrast to Osinski et al. (2008) who proposed that melting of carbonates, rather than devolatilization, is the dominant process during hypervelocity impact into carbonate‐bearing targets, including Meteor Crater.     

The reaction of carbonates in contact with laser-generated,superheated silicate melts: Constraining impact metamorphism of carbonate-bearing target rocks

We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1-bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate-derived CaO and MgO and release of CO₂ at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO₂ and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back-reactions between residual CaO and CO₂ produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high-temperature reactions between Ca-contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca- or Ca,Mg-contaminated and Ca- or Ca,Mg-normal silicate melts; (6) precipitation of Ca- or Ca,Mg-rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back-reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.     

CO2 release due to impact devolatilization of carbonate: Results of shock experiments

A study of pure, single crystal calcite shocked to pressures from 9.0 to 60.8 GPa was conducted to address contradictory data for carbonate shock behavior. The recovered materials were analyzed optically and by transmission electron microscopy (TEM), as well as by thermogravimetry (TGA), X‐ray diffraction (XRD), and Raman‐spectroscopy. In thin section, progressive comminution of calcite is observed although grains remain birefringent to at least 60.8 GPa. TGA analysis reveals a positive correlation between percent of mass loss due to shock and increasing shock pressure (R = 0.77) and suggests that shock loading leads to the modest removal of structural volatiles in this pressure range. XRD patterns of shocked Iceland spar samples produce peaks that are qualitatively and quantitatively less intense, more diffuse, and shift to lower ^o2θ. However, the regularity observed in these shocked powder patterns suggests that structures with very uniform unit cell separations persist to shock pressures as high as 60.8 GPa. Raman spectral analyses indicate no band asymmetry and no systematic peak shifting or broadening. TEM micrographs display progressively diminishing crystallite domain sizes. Selected area electron diffraction (SAED) patterns reveal no signatures of amorphous material. These data show that essentially intact calcite is recovered at shock pressures up to 60.8 GPa with only slight mass loss (~7%). This work suggests that the amount of CO₂ gas derived from shock devolatilization of carbonate by large meteorite impacts into carbonate targets has been (substantially) overestimated.     

Evidence for shock‐induced anhydrite recrystallization and decomposition at the UNAM‐7 drill core from the Chicxulub impact structure

Drill core UNAM‐7, obtained 126 km from the center of the Chicxulub impact structure, outside the crater rim, contains a sequence of 126.2 m suevitic, silicate melt‐rich breccia on top of a silicate melt‐poor breccia with anhydrite megablocks. Total reflection X‐ray fluorescence analysis of altered silicate melt particles of the suevitic breccia shows high concentrations of Br, Sr, Cl, and Cu, which may indicate hydrothermal reaction with sea water. Scanning electron microscopy and energy‐dispersive spectrometry reveal recrystallization of silicate components during annealing by superheated impact melt. At anhydrite clasts, recrystallization is represented by a sequence of comparatively large columnar, euhedral to subhedral anhydrite grains and smaller, polygonal to interlobate grains that progressively annealed deformation features. The presence of voids in anhydrite grains indicates SO_x gas release during anhydrite decomposition. The silicate melt‐poor breccia contains carbonate and sulfate particles cemented in a microcrystalline matrix. The matrix is dominated by anhydrite, dolomite, and calcite, with minor celestine and feldspars. Calcite‐dominated inclusions in silicate melt with flow textures between recrystallized anhydrite and silicate melt suggest a former liquid state of these components. Vesicular and spherulitic calcite particles may indicate quenching of carbonate melts in the atmosphere at high cooling rates, and partial decomposition during decompression at postshock conditions. Dolomite particles with a recrystallization sequence of interlobate, polygonal, subhedral to euhedral microstructures may have been formed at a low cooling rate. We conclude that UNAM‐7 provides evidence for solid‐state recrystallization or melting and dissociation of sulfates during the Chicxulub impact event. The lack of anhydrite in the K‐Pg ejecta deposits and rare presence of anhydrite in crater suevites may indicate that sulfates were completely dissociated at high temperature (T > 1465 °C)—whereas ejecta deposited near the outer crater rim experienced postshock conditions that were less effective at dissociation.     

Experimental constraints on alkali condensation in chondrule formation

Abstract— To assess whether the alkali behavior observed in chondrules of primitive meteorites is attributable to volatilization from the raw materials of chondrules during chondrule formation events or attributable to condensation processes from the nebular gas, we set up a new experimental device able to expose silicate melt samples to a controlled alkali partial pressure at high temperature under fixed O fugacity. Using a mixture of potassium carbonate (K₂CO₃) and graphite (C) as the source of the K gas (K_g), we studied the condensation kinetics of K and its solubility in CaO‐MgO‐Al₂O₃‐SiO₂ silicate melts, according to the reaction 2 K _(g) + 1/2 _(g) = K₂O _(melt) From these results, we show that alkali entering in chondrules from the nebular gas is a viable mechanism to explain the chondrules alkali contents and their δ⁴¹K‐isotopic signatures, at timescales relevant to chondrule formation. Finally, we also suggest that chondrules may have formed in non‐canonical nebular environments and that the flash‐heating scenario is not a prerequisite to chondrule formation.     

Petrographic studies of the impact melts from Meteor Crater,Arizona, USA

Abstract— We investigated the ballistically dispersed melts from Meteor Crater, Arizona, USA to determine the stratigraphic extent of its melt zone from the compositional relationship of melts and target rocks. Most melt particles are crystallized, hydrated, and oxidized; pristine glasses are rare. Hydration and oxidation occurred at ambient temperatures long after the impact. The preserved glasses are generally clear and texturally homogeneous, but unlike typical impact melts, they have unusually heterogeneous compositions, both within individual particles and from sample to sample. For example, the average SiO₂ for individual particles ranges from 43 to 65%. The projectile content is unusually high and it is distributed bimodally, with specific samples containing either 5–10% or 20–30% FeO. These compositional heterogeneities most likely reflect the high carbonate content of the target rocks and the release of copious CO₂ that dispersed the melts, thereby terminating melt flow and mixing. The high projectile content and the CO₂ depleted residue of purely sedimentary rocks produced mafic melts that crystallized fine‐grained olivine and pyroxene. The melts fall into three compositional groups reflecting variable proportions of the major target formations, Moenkopi, Kaibab, and Coconino. Least‐square mixing calculations revealed one group to contain 55% Moenkopi, 40% quartz‐rich, upper Kaibab, and 5% meteorite, suggesting a source depth of <30 m from the pre‐impact surface. The other two melt groups have higher contents of meteorite (15–20%) and Kaibab (50–70%) and contain more SiO₂ than average Kaibab. The additional quartz may have been derived from Coconino or the upper Kaibab, implying melt depths >90 m or <30 m, respectively. Additional studies, especially hydrocode calculations, are needed to better understand the source depth of these melts and their exceptionally high projectile content.     

The water content and parental magma of the second chassignite NWA 2737: Clues from trapped melt inclusions in olivine

NWA 2737, the second known chassignite, mainly consists of cumulate olivine crystals of homogeneous composition (Fo = 78.7 ± 0.9). These brown colored olivine grains exhibit two sets of perpendicular planar defects due to shock. Two forms of trapped liquids, interstitial melts and magmatic inclusions, have been examined. Mineral assemblages within the olivine‐hosted magmatic inclusions include low‐Ca pyroxene, augite, kaersutite, fluorapatite, biotite, chromite, sulfide, and feldspathic glass. The reconstructed parental magma composition (A^#) of the NWA 2737 is basaltic and resembles both the experimentally constrained parental melt composition of chassiginites and the Gusev basalt Humphrey, albeit with lower Al contents. A^# also broadly resembles the average of shergottite parent magmas or LAR 06319. However, we suggest that the mantle source for the chassignite parental magmas was distinct from that of the shergottite meteorites, particularly in CaO/Al₂O₃ ratio. In addition, based on the analysis of the volatile contents of kaersutite, we derived a water content of 0.48–0.67 wt% for the parental melt. Finally, our MELTS calculations suggest that moderate pressure (approximately 6.8 kb) came closest to reproducing the crystallized melt‐inclusion assemblages.     

Cratering of icy targets by different impactors: Laboratory experiments and implications for cratering in the Solar System

Studies of impacts (impactor velocity about 5 km s⁻¹) on icy targets were performed. The prime goal was to study the response of solid CO₂ targets to impacts and to find the differences between the results of impacts on CO₂ targets with those on H₂O ice targets. The crater dimensions in CO₂ ice were found to scale with impact energy, with little dependence on projectile density (which ranged from nylon to copper, i.e., 1150-8930 kg m⁻³). At equal temperatures, craters in CO₂ ice were the same diameter as those in water ice, but were shallower and smaller in volume. In addition, the shape of the radial profiles of the craters was found to depend strongly on the type of ice and to change with impact energy. The impact speed of the data is comparable to that for impacts on many types of icy bodies in the outer Solar System (e.g., the satellites of the giant planets, the cometary nuclei and the Kuiper Belt objects), but the size and thus energy of the impactors is lower. Scaling with impact energy is demonstrated for the impacts on CO₂ ice. The issue of impact disruption (rather than cratering) is discussed by analogy with that on water ice. Expressions for the critical energy density for the onset of disruption rather than cratering are established for water ice as a function of porosity and silicate content. Although the critical energy density for disruption of CO₂ ice is not established, it is argued that the critical energy to disrupt a CO₂ ice body will be greater than that for a (non-porous) water ice body of the similar mass.     

Physical constraints on impact melt properties from Lunar Reconnaissance Orbiter Camera images

Impact melt flows exterior to Copernican-age craters are observed in high spatial resolution (0.5 m/pixel) images acquired by the Lunar Reconnaissance Orbiter Camera (LROC) Narrow Angle Camera (NAC). Impact melt is mapped in detail around 15 craters ranging in diameter from 2.4 to 32.5 km. This survey supports previous observations suggesting melt flows often occur at craters whose shape is influenced by topographic variation at the pre-impact site. Impact melt flows are observed around craters as small as 2.4 km in diameter, and preliminary estimates of melt volume suggest melt production at small craters can significantly exceed model predictions. Digital terrain models produced from targeted NAC stereo images are used to examine the three-dimensional properties of flow features and emplacement setting, enabling physical modeling of flow parameters. Qualitative and quantitative observations are consistent with low-viscosity melts heated above their liquidii (superheated) with limited amounts of entrained solids.     

Tenoumer impact crater,Mauritania: Impact melt genesis from a lithologically diverse target

Impact melt rocks from the 1.9 km diameter, simple bowl‐shaped Tenoumer impact crater in Mauritania have been analyzed chemically and petrologically. They are heterogeneous and can be subdivided into three types based on melt matrix color, occurrence of lithic clast components, amount of vesiculation (melt degassing), different proportions of carbonate melt mingled into silicate melt, and bulk rock chemical composition. These heterogeneities have two main causes (1) due to the small size of the impact crater, there was probably no coherent melt pool where a homogeneous mixture of melts, derived from different target lithologies, could be created; and (2) melt rock heterogeneity occurring at the thin section scale is due to fast cooling during and after the dynamic ejection and emplacement process. The overall period of crystal growth from these diverse melts was extremely short, which provides a further indication that complete chemical equilibration of the phases could not be achieved in such short time. Melt mixing processes involved in the generation of impact melts are, thus, recorded in nonequilibrium growth features. Variable mixing processes between chemically different melt phases and the formation of hybrid melts can be observed even at millimeter scales. Due to extreme cooling rates, different mixing and mingling stages are preserved in the varied parageneses of matrix minerals and in the mineral chemistry of microlites. ⁴⁰Ar³⁹Ar step‐heating chronology on specimens from three melt rock samples yielded five concordant inverse isochron ages. The inverse isochron plots show that minute amounts of inherited ⁴⁰Ar* are present in the system. We calculated a weighted mean age of 1.57 ± 0.14 Ma for these new results. This preferred age represents a refinement from the previous range of 21 ka to 2.5 Ma ages based on K/Ar and fission track dating.     

Localized shock-induced melting of sandstone at low shock pressures (<17.5 GPa): An experimental study

Shock-induced recovery experiments were performed to investigate melt formation in porous sandstones in the low shock pressure regime between 2.5 and 17.5 GPa. The sandstone shocked at 2.5 and 5 GPa is characterized by pore closure, fracturing of quartz (Qtz), and compression and deformation of phyllosilicates; no melting was observed. At higher pressures, five different types of melts were generated around pores and alongside fractures in the sandstone. Melting of kaolinite (Kln), illite (Ill), and muscovite (Ms) starts at 7.5, 12, and 15 GPa, respectively. The larger the amount of water in these minerals (Kln ~14 wt%, Ill ~6–10 wt%, and Ms ~4 wt% H₂O), the higher the shock compressibility and the lower the shock pressure required to induce melting. Vesicles in the almost dry silicate glasses attest to the loss of structural water during the short shock duration of the experiment. The compositions of the phyllosilicate-based glasses are identical to the composition of the parental minerals or their mixtures. Thus, this study has demonstrated that phyllosilicates in shocked sandstone undergo congruent melting during shock loading. In experiments at 10 GPa and higher, iron melt from the driver plate was injected into the phyllosilicate melts. During this process, Fe is partitioned from the metal droplets into the surrounding silicate melts, which induced unmixing of silicate melts with different chemical properties (liquid immiscibility). At pressures between 7.5 and 15 GPa, a pure SiO₂ glass was formed, which is located as short and thin bands within Qtz grains. These bands were shown to contain tiny crystals of experimentally generated stishovite.     

Transmission electron microscopy of minerals in the martian meteorite Allan Hills 84001

Abstract— We have studied carbonate and associated oxides and glasses in a demountable section of Allan Hills 84001 (ALH 84001) using optical, scanning, and transmission electron microscopy (TEM) to elucidate their origins and the shock history of the rock. Massive, fracture‐zone, and fracture‐filling carbonates in typical locations were characterized by TEM, X‐ray microanalysis, and electron diffraction in a comprehensive study that preserved textural and spatial relationships. Orthopyroxene is highly deformed, fractured, partially comminuted, and essentially unrecovered. Lamellae of diaplectic glass and other features indicate shock pressures >30 GPa. Bridging acicular crystals and foamy glass at contacts of orthopyroxene fragments indicate localized melting and vaporization of orthopyroxene. Carbonate crystals are >5 mm in size, untwinned, and very largely exhibit the R3c calcite structure. Evidence of plastic deformation is generally found mildly only in fracture‐zone and fracture‐filling carbonates, even adjacent to highly deformed orthopyroxene, and appears to have been caused by low‐stress effects including differential shrinkage. High dislocation densities like those observed in moderately shocked calcite are absent. Carbonate contains impactderived glasses of plagioclase, silica, and orthopyroxene composition indicating brief localized impact heating. Stringers and lenses of orthopyroxene glass in fracture‐filling carbonate imply flow of carbonates and crystallization during an impact. Periclase (MgO) occurs in magnesite as 30–50 nm crystals adjacent to voids and negative crystals and as ?1 μm patches of 3 nm crystals showing weak preferred orientation consistent with (111)_MgO//(0001)_carb, as observed in the thermal decomposition of CaCO₃ to CaO. Magnetite crystals that are epitaxially oriented at voids, negative crystals, and microfractures clearly formed in situ. Fully embedded, faceted magnetites are topotactically oriented, in general with (111)_mag//(0001)_carb, so that their oxygen layers are aligned. In optically opaque rims, magnetites are more irregularly shaped and, except for the smallest crystals, poorly aligned. All magnetite and periclase crystals probably formed by exsolution from slightly non‐stoichiometric, CO₂‐poor carbonate following impact‐induced thermal decomposition. Any magnetites that existed in the rock before shock heating could not have preserved evidence for biogenic activity.     

Composition of impact melt particles and the effects of post‐impact alteration in suevitic rocks at the Yaxcopoil‐1 drill core,Chicxulub crater,Mexico

Abstract Petrographical and chemical analysis of melt particles and alteration minerals of the about 100 m‐thick suevitic sequence at the Chicxulub Yax‐1 drill core was performed. The aim of this study is to determine the composition of the impact melt, the variation between different types of melt particles, and the effects of post‐impact hydrothermal alteration. We demonstrate that the compositional variation between melt particles of the suevitic rocks is the result of both incomplete homogenization of the target lithologies during impact and subsequent post‐impact hydrothermal alteration. Most melt particles are andesitic in composition. Clinopyroxene‐rich melt particles possess lower SiO₂ and higher CaO contents. These are interpreted by mixing of melts from the silicate basement with overlying carbonate rocks. Multi‐stage post‐impact hydrothermal alteration involved significant mass transfer of most major elements and caused further compositional heterogeneity between melt particles. Following backwash of seawater into the crater, palagonitization of glassy melt particles likely caused depletion of SiO₂, Al₂O₃, CaO, Na₂O, and enrichment of K₂O and FeO_tot during an early alteration stage. Since glass is very susceptible to fluid‐rock interaction, the state of primary crystallization of the melt particles had a significant influence on the intensity of the post‐impact hydrothermal mass transfer and was more pronounced in glassy melt particles than in well‐crystallized particles. In contrast to other occurrences of Chicxulub impactites, the Yax‐1 suevitic rocks show strong potassium metasomatism with hydrothermal K‐feldspar formation and whole rock K₂0 enrichment, especially in the lower unit of the suevitic sequence. A late stage of hydrothermal alteration is characterized by precipitation of silica, analcime, and Na‐bearing Mg‐rich smectite, among other minerals. This indicates a general evolution from a silica‐undersaturated fluid at relatively high potassium activities at an early stage toward a silica‐oversaturated fluid at relatively high sodium activities at later stages in the course of fluid rock interaction.     

Maohokite,a post‐spinel polymorph of MgFe2O4 in shocked gneiss from the Xiuyan crater in China

Maohokite, a post‐spinel polymorph of MgFe₂O₄, was found in shocked gneiss from the Xiuyan crater in China. Maohokite in shocked gneiss coexists with diamond, reidite, TiO₂‐II, as well as diaplectic glasses of quartz and feldspar. Maohokite occurs as nano‐sized crystallites. The empirical formula is (Mg_0.62Fe_0.35Mn_0.03)²⁺Fe³⁺₂O₄. In situ synchrotron X‐ray microdiffraction established maohokite to be orthorhombic with the CaFe₂O₄‐type structure. The cell parameters are a = 8.907 (1) Å, b = 9.937(8) Å, c = 2.981(1) Å; V = 263.8 (3) ų; space group Pnma. The calculated density of maohokite is 5.33 g cm^?3. Maohokite was formed from subsolidus decomposition of ankerite Ca(Fe²⁺,Mg)(CO₃)₂ via a self‐oxidation‐reduction reaction at impact pressure and temperature of 25–45 GPa and 800–900 °C. The formation of maohokite provides a unique example for decomposition of Fe‐Mg carbonate under shock‐induced high pressure and high temperature. The mineral and its name have been approved by the Commission on New Minerals, Nomenclature and Classification of the International Mineralogical Association (IMA 2017‐047). The mineral was named maohokite after Hokwang Mao, a staff scientist at the Geophysical Laboratory, Carnegie Institution of Washington, for his great contribution to high pressure research.     

High‐pressure phases in shock‐induced melt veins of the Umbarger L6 chondrite: Constraints of shock pressure

Abstract— We report a previously undocumented set of high‐pressure minerals in shock‐induced melt veins of the Umbarger L6 chondrite. High‐pressure minerals were identified with transmission electron microscopy (TEM) using selected area electron diffraction and energy‐dispersive X‐ray spectroscopy. Ringwoodite (Fa₃₀), akimotoite (En₁₁Fs₈₉), and augite (En₄₂Wo₃₃Fs₂₅) were found in the silicate matrix of the melt vein, representing the crystallization from a silicate melt during the shock pulse. Ringwoodite (Fa₂₇) and hollandite‐structured plagioclase were also found as polycrystalline aggregates in the melt vein, representing solid state transformation or melting with subsequent crystallization of entrained host rock fragments in the vein. In addition, Fe₂SiO₄‐spinel (Fa₆₆‐Fa₉₉) and stishovite crystallized from a FeO‐SiO₂‐rich zone in the melt vein, which formed by shock melting of FeO‐SiO₂‐rich material that had been altered and metasomatized before shock. Based on the pressure stabilities of the high‐pressure minerals, ringwoodite, akimotoite, and Ca‐clinopyroxene, the melt vein crystallized at approximately 18 GPa. The Fe₂SiO₄‐spinel + stishovite assemblage in the FeO‐SiO₂‐rich melts is consistent with crystallization of the melt vein matrix at the pressure up to 18 GPa. The crystallization pressure of ?18 GPa is much lower than the 45–90 GPa pressure one would conclude from the S6 shock effects in melt veins (Stöffler et al. 1991) and somewhat less than the 25–30 GPa inferred from S5 shock effects (Schmitt 2000) found in the bulk rock.     

The Lawn Hill annulus: An Ordovician meteorite impact into water‐saturated dolomite

The Lawn Hill Impact Structure (LHIS) is located 250 km N of Mt Isa in NW Queensland, Australia, and is marked by a highly deformed dolomite annulus with an outer diameter of ~18 km, overlying low metamorphic grade siltstone, sandstone, and shale, along the NE margin of the Georgina Basin. This study provides detailed field observations from sections of the Lawn Hill annulus and adjacent areas that demonstrate a clear link between the deformation of the dolomite and the Lawn Hill impact. ⁴⁰Ar‐³⁹Ar dating of impact‐related melt particles provides a time of impact in the Ordovician (472 ± 8 Ma) when the Georgina Basin was an active depocenter. The timing and stratigraphic thickness of the dolomite sequence in the annulus suggest that there was possibly up to 300 m of additional sedimentary rocks on top of the currently exposed Thorntonia Limestone at the time of impact. The exposed annulus is remarkably well preserved, with preservation attributed to postimpact sedimentation. The LHIS has an atypical crater morphology with no central uplift. The heterogeneous target materials at Lawn Hill were probably low‐strength, porous, and water‐saturated, with all three properties affecting the crater morphology. The water‐saturated nature of the carbonate unit at the time of impact is thought to have influenced the highly brecciated nature of the annulus, and restricted melt production. The impact timing raises the possibility that the Lawn Hill structure may be a member of a group of impacts resulting from an asteroid breakup that occurred in the mid‐Ordovician (470 ± 6 Ma).     

Impact metamorphism of CaCO3‐bearing sandstones at the Haughton structure,Canada

Abstract— Impact‐metamorphosed CaCO₃‐bearing sandstones at the Haughton structure have been divided into 6 classes, based to a large extent on a previous classification developed for sandstones at Meteor Crater. Class 1a sandstones (<3 GPa) display crude shatter cones, but no other petrographic indications of shock. At pressures of 3 to 5.5 GPa (class 1b), porosity is destroyed and well‐developed shatter cones occur. Class 2 rocks display planar deformation features (PDFs) and are characterized by a “jigsaw” texture produced by rotation and shear at quartz grain boundaries. Calcite shows an increase in the density of mechanical twins and undergoes micro‐brecciation in class 1 and 2 sandstones. Class 3 samples display multiple sets of PDFs and widespread development of diaplectic glass, toasted quartz, and symplectic intergrowths of quartz, diaplectic glass, and coesite. Textural evidence, such as the intermingling of silicate glasses and calcite and the presence of flow textures, indicates that calcite in class 3 sandstones has undergone melting. This constrains the onset of melting of calcite in the Haughton sandstones to > 10 < 20 GPa. At higher pressures, the original texture of the sandstone is lost, which is associated with major development of vesicular SiO₂ glass or lechatelierite. Class 5 rocks (>30 GPa) consist almost entirely of lechatelierite. A new class of shocked sandstones (class 6) consists of SiO₂‐rich melt that recrystallized to microcrystalline quartz. Calcite within class 4 to 6 sandstones also underwent melting and is preserved as globules and euhedral crystals within SiO₂ phases, demonstrating the importance of impact melting, and not decomposition, in these CaCO₃‐bearing sandstones.     

Impacts onto H2O ice: Scaling laws for melting, vaporization, excavation, and final crater size

Shock-induced melting and vaporization of H₂O ice during planetary impact events are widespread phenomena. Here, we investigate the mass of shock-produced liquid water remaining within impact craters for the wide range of impact conditions and target properties encountered in the Solar System. Using the CTH shock physics code and the new 5-phase model equation of state for H₂O, we calculate the shock pressure field generated by an impact and fit scaling laws for melting and vaporization as a function of projectile mass, impact velocity, impact angle, initial temperature, and porosity. Melt production nearly scales with impact energy, and natural variations in impact parameters result in only a factor of two change in the predicted mass of melt. A fit to the π-scaling law for the transient cavity and transient-to-final crater diameter scaling are determined from recent simulations of the entire cratering process in ice. Combining melt production with π-scaling and the modified Maxwell Z-model for excavation, less than half of the melt is ejected during formation of the transient crater. For impact energies less than about 2 × 10²⁰ J and impact velocities less than about 5 km s⁻¹, the remaining melt lines the final crater floor. However, for larger impact energies and higher impact velocities, the phenomenon of discontinuous excavation in H₂O ice concentrates the impact melt into a small plug in the center of the crater floor.     

Effect of target properties and impact velocity on ejection dynamics and ejecta deposition

Impact craters are formed by the displacement and ejection of target material. Ejection angles and speeds during the excavation process depend on specific target properties. In order to quantify the influence of the constitutive properties of the target and impact velocity on ejection trajectories, we present the results of a systematic numerical parameter study. We have carried out a suite of numerical simulations of impact scenarios with different coefficients of friction (0.0–1.0), porosities (0–42%), and cohesions (0–150 MPa). Furthermore, simulations with varying pairs of impact velocity (1–20 km s⁻¹) and projectile mass yielding craters of approximately equal volume are examined. We record ejection speed, ejection angle, and the mass of ejected material to determine parameters in scaling relationships, and to calculate the thickness of deposited ejecta by assuming analytical parabolic trajectories under Earth gravity. For the resulting deposits, we parameterize the thickness as a function of radial distance by a power law. We find that strength—that is, the coefficient of friction and target cohesion—has the strongest effect on the distribution of ejecta. In contrast, ejecta thickness as a function of distance is very similar for different target porosities and for varying impact velocities larger than ~6 km s⁻¹. We compare the derived ejecta deposits with observations from natural craters and experiments.     

Carbonate abundances and isotopic compositions in chondrites

We report the bulk C abundances, and C and O isotopic compositions of carbonates in 64 CM chondrites, 14 CR chondrites, 2 CI chondrites, LEW 85332 (C2), Kaba (CV3), and Semarkona (LL3.0). For the unheated CMs, the total ranges of carbonate isotopic compositions are δ¹³C ≈ 25–75‰ and δ¹⁸O ≈ 15–35‰, and bulk carbonate C contents range from 0.03 to 0.60 wt%. There is no simple correlation between carbonate abundance and isotopic composition, or between either of these parameters and the extent of alteration. Unless accretion was very heterogeneous, the uncorrelated variations in extent of alteration and carbonate abundance suggests that there was a period of open system behavior in the CM parent body, probably prior to or at the start of aqueous alteration. Most of the ranges in CM carbonate isotopic compositions can be explained by their formation at different temperatures (0–130 °C) from a single fluid in which the carbonate O isotopes were controlled by equilibrium with water (δ¹⁸O ≈ 5‰) and the C isotopes were controlled by equilibrium with CO and/or CH₄ (δ¹³C ≈ ?33‰ or ?20‰ for CO‐ or CH₄‐dominated systems, respectively). However, carbonate formation would have to have been inefficient, otherwise carbonate compositions would have resembled those of the starting fluid. A quite similar fluid composition (δ¹⁸O ≈ ?5.5‰, and δ¹³C ≈ ?31‰ or ?17‰ for CO‐ or CH₄‐dominated systems, respectively) can explain the carbonate compositions of the CIs, although the formation temperatures would have been lower (~10–40 °C) and the relative abundances of calcite and dolomite may play a more important role in determining bulk carbonate compositions than in the CMs. The CR carbonates exhibit a similar range of O isotopes, but an almost bimodal distribution of C isotopes between more (δ¹³C ≈ 65–80‰) and less altered samples (δ¹³C ≈ 30–40‰). This bimodality can still be explained by precipitation from fluids with the same isotopic composition (δ¹⁸O ≈ ?9.25‰, and δ¹³C ≈ ?21‰ or ?8‰ for CO‐ or CH₄‐dominated systems, respectively) if the less altered CRs had higher mole fractions of CO₂ in their fluids. Semarkona and Kaba carbonates have some of the lightest C isotopic compositions of the meteorites studied here, probably because they formed at higher temperatures and/or from more CO₂‐rich fluids. The fluids responsible for the alteration of chondrites and from which the carbonates formed were almost certainly accreted as ices. By analogy with cometary ices, CO₂ and/or CO would have dominated the trapped volatile species in the ices. The chondrites studied are too oxidized for CO‐dominated fluids to have formed in their parent bodies. If CH₄ was the dominant C species in the fluids during carbonate formation, it would have to have been generated in the parent bodies from CO and/or CO₂ when oxidation of metal by water created high partial pressures of H₂. The fact that the chondrite carbonate C/H₂O mole ratios are of the order predicted for CO/CO₂‐H₂O ices that experienced temperatures of >50–100 K suggests that the chondrites formed at radial distances of <4–15 AU.