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1.
Xuchao Zhao Yangting Lin Qing‐Zhu Yin Jianchao Zhang Jialong Hao Michael Zolensky Peter Jenniskens 《Meteoritics & planetary science》2014,49(11):2038-2046
The Sutter's Mill (SM) carbonaceous chondrite is a regolith breccia, composed predominantly of CM2 clasts with varying degrees of aqueous alteration and thermal metamorphism. An investigation of presolar grains in four Sutter's Mill sections, SM43, SM51, SM2‐4, and SM18, was carried out using NanoSIMS ion mapping technique. A total of 37 C‐anomalous grains and one O‐anomalous grain have been identified, indicating an abundance of 63 ppm for presolar C‐anomalous grains and 2 ppm for presolar oxides. Thirty‐one silicon carbide (SiC), five carbonaceous grains, and one Al‐oxide (Al2O3) were confirmed based on their elemental compositions determined by C‐N‐Si and O‐Si‐Mg‐Al isotopic measurements. The overall abundance of SiC grains in Sutter's Mill (55 ppm) is consistent with those in other CM chondrites. The absence of presolar silicates in Sutter's Mill suggests that they were destroyed by aqueous alteration on the parent asteroid. Furthermore, SM2‐4 shows heterogeneous distributions of presolar SiC grains (12–54 ppm) in different matrix areas, indicating that the fine‐grained matrix clasts come from different sources, with various thermal histories, in the solar nebula. 相似文献
2.
Larry R. Nittler Rhonda M. Stroud Conel M. O'D. Alexander Kaitlin Howell 《Meteoritics & planetary science》2020,55(6):1160-1175
We report a correlated NanoSIMS‐transmission electron microscopy study of the ungrouped carbonaceous chondrite Northwest Africa (NWA) 5958. We identified 10 presolar SiC grains, 2 likely presolar graphite grains, and 20 presolar silicate and/or oxide grains in NWA 5958. We suggest a slight modification of the commonly used classification system for presolar oxides and silicates that better reflects the grains’ likely stellar origins. The matrix‐normalized presolar SiC abundance in NWA 5958 is ppm (2σ) similar to that seen in many classes of unmetamorphosed chondrites. In contrast, the matrix‐normalized abundance of presolar O‐rich phases (silicates and oxides) is ppm (2σ), much lower than seen in interplanetary dust particles and the least‐altered CR, CO, and ungrouped C chondrites, but close to that reported for CM chondrites. NanoSIMS mapping also revealed an unusual 13C‐enriched (δ13C≈100–200‰) carbonaceous rim surrounding a 1.4 μm diameter phyllosilicate grain. Transmission electron microscopy (TEM) analysis of two presolar grains with a likely origin in asymptotic giant branch stars identified one as enstatite and one as Al‐Mg spinel with minor Cr. The enstatite grain amorphized rapidly under the electron beam, suggesting partial hydration. TEM data of NWA 5958 matrix confirm that it has experienced aqueous alteration and support the suggestion of Jacquet et al. (34) that this meteorite has affinities to CM2 chondrites. 相似文献
3.
Abstract– Although it has been suggested that the ungrouped carbonaceous chondrite Adelaide and the K chondrite Kakangari could be considered highly primitive, our study of their presolar grain abundances shows that both have experienced more secondary processing than other primitive chondrites with high presolar grain abundances. Presolar grains are rare in Kakangari and are present in reduced abundances in Adelaide (approximately 70 ppm for O‐anomalous grains). Thermal annealing has led to widespread crystallization of their fine‐grained matrices, and accounts for the partial to complete destruction of presolar grains. In addition, presolar silicates in Adelaide show elevated Fe abundances and Fe‐rich rims indicative of infiltration of Fe into the grains from the surrounding matrix. This process probably also took place during annealing, most likely in the solar nebula, in a region with an enhanced dust‐to‐gas ratio. The most primitive meteorites, with the highest presolar grain abundances, appear to be those whose matrices contain abundant amorphous material that has escaped any significant thermal or aqueous alteration. 相似文献
4.
Toru YADA Christine FLOSS Frank J. STADERMANN Ernst ZINNER Tomoki NAKAMURA Takaaki NOGUCHI A. Scott LEA 《Meteoritics & planetary science》2008,43(8):1287-1298
Abstract— We report the discovery of presolar silicate, oxide (hibonite), and (possibly) SiC grains in four Antarctic micrometeorites (AMMs). The oxygen isotopic compositions of the eighteen presolar silicate (and one oxide) grains found are similar those observed previously in primitive meteorites and interplanetary dust particles, and indicate origins in oxygen‐rich red giant or asymptotic giant branch stars, or in supernovae. Four grains with anomalous C isotopic compositions were also detected. 12C/13C as well as Si ratios are similar to those of mainstream SiC grains; the N isotopic composition of one grain is also consistent with a mainstream SiC classification. Presolar silicate grains were found in three of the seven AMMs studied, and are heterogeneously distributed within these micrometeorites. Fourteen of the 18 presolar silicate grains and 3 of the 4 C‐anomalous grains were found within one AMM, T98G8. Presolar silicate‐bearing micrometeorites contain crystalline silicates that give sharp X‐ray diffractions and do not contain magnesiowüstite, which forms mainly through the decomposition of phyllosilicates and carbonates. The occurrence of this mineral in AMMs without presolar silicates suggests that secondary parent body processes probably determine the presence or absence of presolar silicates in Antarctic micrometeorites. 相似文献
5.
Pierre Haenecour Christine Floss Adrian J. Brearley Thomas J. Zega 《Meteoritics & planetary science》2020,55(6):1228-1256
Our detailed mineralogical, elemental, and isotopic study of the Miller Range (MIL) 07687 meteorite showed that, although this meteorite has affinities to CO chondrites, it also exhibits sufficient differences to warrant classification as an ungrouped carbonaceous chondrite. The most notable feature of MIL 07687 is the presence of two distinct matrix lithologies that result from highly localized aqueous alteration. One of these lithologies is Fe‐rich and exhibits evidence for interaction with water, including the presence of fibrous (dendritic) ferrihydrite. The other lithology, which is Fe‐poor, appears to represent relatively unaltered protolith material. MIL 07687 has presolar grain abundances consistent with those observed in other modestly altered carbonaceous chondrites: the overall abundance of O‐rich presolar grains is 137 ± 3 ppm and the overall abundance of SiC grains is 71 ± 11 ppm. However, there is a large difference in the observed O‐rich and SiC grain number densities between altered and unaltered areas, reflecting partial destruction of presolar grains (both O‐ and C‐rich grains) due to the aqueous alteration experienced by MIL 07687 under highly oxidizing conditions. Detailed coordinated NanoSIMS‐TEM analysis of a large hotspot composed of an isotopically normal core surrounded by a rim composed of 17O‐rich grains is consistent with either original condensation of the core and surrounding grains in the same parent AGB star, or with grain accretion in the ISM or solar nebula. 相似文献
6.
Jemma DAVIDSON Henner BUSEMANN Ian A. FRANCHI 《Meteoritics & planetary science》2012,47(11):1748-1771
Abstract– Interplanetary dust particles (IDPs) are the most primitive extraterrestrial material available for laboratory studies and may, being likely of cometary origin, sample or represent the unaltered starting material of the solar system. Here we compare IDPs from a “targeted” collection, acquired when the Earth passed through the dust stream of comet 26P/Grigg‐Skjellerup (GSC), with IDPs from nontargeted collections (i.e., of nonspecific origin). We examine both sets to further our understanding of abundances and character of their isotopically anomalous phases to constrain the nature of their parent bodies. We identified ten presolar silicates, two oxides, one SiC, and three isotopically anomalous C‐rich grains. One of seven non‐GSC IDPs contains a wealth of unaltered nebula material, including two presolar silicates, one oxide, and one SiC, as well as numerous δD and δ15N hotspots, demonstrating its very pristine character and suggesting a cometary origin. One of these presolar silicates is the most 17O‐rich discovered in an IDP and has been identified as a possible GEMS (glass with embedded metal and sulfides). Organic matter in an anhydrous GSC IDP is extremely disordered and, based on Raman spectral analyses, appears to be the most primitive IDP analyzed in this study, albeit only one presolar silicate was identified. No defining difference was seen between the GSC and non‐GSC IDPs studied here. However, the GSC collectors are expected to contain IDPs of nonspecific origin. One measure alone, such as presolar grain abundances, isotopic anomalies, or Raman spectroscopy cannot distinguish targeted cometary from unspecified IDPs, and therefore combined studies are required. Whilst targeted IDP populations as a whole may not show distinguishable parameters from unspecified populations (due to statistics, heterogeneity, sampling bias, mixing from other cometary sources), particular IDPs in a targeted collection may well indicate special properties and a fresh origin from a known source. 相似文献
7.
Christine FLOSS Frank J. STADERMANN Aaron F. MERTZ Thomas J. BERNATOWICZ 《Meteoritics & planetary science》2010,45(12):1889-1905
Abstract– An IDP nicknamed Andric, from a stratospheric dust collector targeted to collect dust from comet 55P/Tempel‐Tuttle, contains five distinct presolar silicate and/or oxide grains in 14 ultramicrotome slices analyzed, for an estimated abundance of approximately 700 ppm in this IDP. Three of the grains are 17O‐enriched and probably formed in low‐mass red giant or asymptotic giant branch (AGB) stars; the other two grains exhibit 18O enrichments and may have a supernova origin. Carbon and N isotopic analyses show that Andric also exhibits significant variations in its N isotopic composition, with numerous discrete 15N‐rich hotspots and more diffuse regions that are also isotopically anomalous. Three 15N‐rich hotspots also have statistically significant 13C enrichments. Auger elemental analysis shows that these isotopically anomalous areas consist largely of carbonaceous matter and that the anomalies may be hosted by a variety of components. In addition, there is evidence for dilution of the isotopically heavy components with an isotopically normal endmember; this may have occurred either as a result of extraterrestrial alteration or during atmospheric entry. Isotopically primitive IDPs such as Andric share many characteristics with primitive meteorites such as the CR chondrites, which also contain isotopically anomalous carbonaceous matter and abundant presolar silicate and oxide grains. Although comets are one likely source for the origin of primitive IDPs, the presence of similar characteristics in meteorites thought to come from the asteroid belt suggests that other origins are also possible. Indeed the distinction between cometary and asteroidal sources is somewhat blurred by recent observations of icy comet‐like planetesimals in the outer asteroid belt. 相似文献
8.
Adrian J. Brearley 《Meteoritics & planetary science》1993,28(4):590-595
Abstract— Rare, ultrafine-grained Ti oxides (Ti3O5 and the Magnéli phases, Ti5O9 and Ti8O15) have been identified by transmission electron microscopy in the CM2 carbonaceous chondrite, Bells and a carbonaceous chondrite matrix clast from the Nilpena polymict ureilite. In both meteorites the Ti oxides occur in the matrix as isolated grains and clusters of two or more grains. They are euhedral in shape and have grain sizes of 0.05–0.3 μm. Magnéli phases have been recently shown to be a common component in some interplanetary dust particles, but this is the first reported occurrence in a meteorite. The morphological properties and grain size of the Ti oxides are consistent with formation by vapor phase condensation either within the solar nebula or possibly in a presolar environment. 相似文献
9.
Thomas J. Zega Pierre Haenecour Christine Floss 《Meteoritics & planetary science》2020,55(6):1207-1227
We report on the isotopic, chemical, and structural properties of four O‐rich presolar grains identified in situ in the Adelaide ungrouped C2, LaPaZ Icefield (LAP) 031117 CO3.0, and Dominion Range (DOM) 08006 CO3.0 chondrites. All four grains have oxygen‐isotopic compositions consistent with origins in the circumstellar envelopes (CSE) of low‐mass O‐rich stars evolved along the red‐giant and asymptotic‐giant branch (RGB, AGB, respectively) of stellar evolution. Transmission electron microscope (TEM) analyses, enabled by focused‐ion‐beam scanning electron microscope extraction, show that the grain from Adelaide is a single‐crystal Mg‐Al spinel, and comparison with equilibrium thermodynamic predictions constrains its condensation to 1500 K assuming a total pressure ≤10?3 atm in its host CSE. In comparison, TEM analysis of two grains identified in the LAP 031117 chondrite exhibits different microstructures. Grain LAP‐81 is composed of olivine containing a Ca‐rich and a Ca‐poor domain, both of which show distinct orientations, suggesting changing thermodynamic conditions in the host CSE that cannot be precisely constrained. LAP‐104 contains a polycrystalline assemblage of ferromagnesian silicates similar to previous reports of nanocrystalline presolar Fe‐rich silicates that formed under nonequilibrium conditions. Lastly, TEM shows that the grain extracted from DOM 08006 is a polycrystalline assemblage of Cr‐bearing spinel. The grains occur in different orientations, likely reflecting mechanical assembly in their host CSE. The O‐isotopic and Cr‐rich compositions appear to point toward nonequilibrium condensation. The spinel is surrounded by an isotopically solar pyroxene lacking long‐range atomic order and could have served as a nucleation site for its condensation in the interstellar medium or the inner solar protoplanetary disk. 相似文献
10.
A study of presolar material in hydrated lithic clasts from metal-rich carbonaceous chondrites
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We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CBb3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high 15N-enrichments (~50‰ ≤ δ15N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between 15N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk 15N/14N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk 15N/14N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust. 相似文献
11.
Torsten Henkel Thomas Stephan Elmar K. Jessberger Peter Hoppe Roger Strebel Sachiko Amari Roy S. Lewis 《Meteoritics & planetary science》2007,42(7-8):1121-1134
Abstract— Thirteen presolar silicon carbide grains—three of supernova (SN) origin and ten of asymptotic giant branch (AGB) star origin—were examined with time‐of‐flight‐secondary ion mass spectrometry (TOF‐SIMS). The grains had been extracted from two different meteorites—Murchison and Tieschitz—using different acid residue methods. At high lateral resolution of ~300 nm, isotopic and elemental heterogeneities within the micrometer‐sized grains were detected. The trace elemental abundances, when displayed in two‐element correlation plots, of Li, Mg, K, and Ca show a clear distinction between the two different meteoritic sources. The different concentrations might be attributed to differences of the host meteorites and/or of extraction methods whereas the stellar source seems to be less decisive. In one SN grain with 26Mg‐enrichment from extinct 26Al, the acid treatment, as part of the grain separation procedure, affected the Mg/Al ratio in the outer rim and therefore the inferred initial 26Al/27Al ratio. A second SN grain exhibits a lateral heterogeneity in 26Al/27Al, which either is due to residual Al‐rich contamination on the grain surface or to the condensation chemistry in the SN ejecta. 相似文献
12.
Frank J. STADERMANN Christine FLOSS Maitrayee BOSE A. Scott LEA 《Meteoritics & planetary science》2009,44(7):1033-1049
Abstract— Presolar grains are small samples of stardust that can be found at low abundances in some of the most unaltered types of extraterrestrial materials. While earlier laboratory studies of stardust mainly focused on grain types that can be extracted from bulk meteorites by acid dissolution techniques, such as silicon carbide and graphite, recent analyses of presolar silicates rely on isotope imaging searches for locating these grains in situ. Since presolar silicates are generally less than a micrometer in diameter and represent at best only a few hundred ppm of their host materials (e.g., primitive meteorites or interplanetary dust particles), locating and studying these particles can be analytically challenging. Recently, we began using scanning Auger spectroscopy for the in situ elemental characterization of presolar silicate grains as a complement to NanoSIMS isotopic studies for obtaining spatially matched compositional data. Auger spectroscopy is a well‐established analytical technique for elemental characterizations in the material sciences, but has not been widely used in geological applications. We discuss the application of this technique to sub‐micrometer sized silicate grains and address practical issues such as sample preparation, measurement settings, spatial resolution, data processing, and elemental quantification. 相似文献
13.
Frans J. M. Rietmeijer Joseph A. Nuth Aurora Pun 《Meteoritics & planetary science》2013,48(10):1823-1840
This thermal annealing experiment at 1000 K for up to 167 h used a physical mixture of vapor phase‐condensed magnesiosilica grains and metallic iron nanograins to test the hypothesis that a mixture of magnesiosilica grains and an Fe‐source would lead to the formation of ferromagnesiosilica grains. This exploratory study found that coagulation and thermal annealing of amorphous magnesiosilica and metallic grains yielded ferromagnesiosilica grains with the Fe/(Fe + Mg) ratios in interplanetary dust particles. Furthermore, decomposition of brucite present in the condensed magnesiosilica grains was the source for water and the cause of different iron oxidation states, and the formation of amorphous Fe3+‐ferrosilica, amorphous Fe3+‐Mg, Fe‐silicates, and magnesioferrite during thermal annealing. Fayalite and ferrosilite that formed from silica/FeO melts reacted with forsterite and enstatite to form Mg, Fe‐silicates. The presence of iron in different oxidation states in extraterrestrial materials almost certainly requires active asteroid‐like parent bodies. If so, the possible presence of trivalent Fe compounds in comet P/Halley suggests that Halley‐type comets are a mixture of preserved presolar and processed solar nebula dust. The results from this thermal annealing experiment further suggest that the Fe‐silicates detected in the impact‐induced ejecta from comet 9P/Temple 1 might be of secondary origin and related to the impact experiment or to processing in a regolith. 相似文献
14.
Abstract— Scanning electron microscopy and secondary ion mass spectrometry of the unequilibrated CH chondrite Pecora Escarpment (PCA) 91467 revealed four carriers of isotopically heavy N: (1) aggregates of carbonaceous material and silicates, (2) iron‐nickel metal grains with fine Fe‐Cr sulfide inclusions, (3) Si‐rich Fe‐Ni metal associated with Fe‐sulfide and (4) hydrated areas in the matrix. N in carbon‐silicate aggregates is isotopically heavy (δ15N is as high as 2500%0), whereas the other elements are isotopically normal, suggesting interstellar origin of carbonaceous material in the aggregates. Based on isotopic and textural evidence, we suggest that the carriers (2) and (3) were formed by brief heating in the solar nebula, whereas the carrier (4) was formed in a parent‐body asteroid. The carbon‐silicate aggregates are likely to be related to interstellar graphite found in Murchison and may also be the source of heavy N in bencubbinites. 相似文献
15.
Sarah J. Day Stephen P. Thompson Aneurin Evans Julia E. Parker Leigh D. Connor Chiu C. Tang 《Meteoritics & planetary science》2013,48(8):1459-1471
The structural evolution of sol–gel‐produced amorphous Mg(x)Ca(1–x)SiO3 silicates is investigated. Mid‐IR Fourier transform infrared spectroscopy and synchrotron X‐ray diffraction are used to confirm the amorphous nature of the as‐prepared silicates, while subsequent in situ synchrotron X‐ray powder diffraction measurements are used to study the evolution of crystalline mineral phases as a function of annealing temperature. Multiple silicate phases, including diopside, enstatite, forsterite, and SiO2, are identified, while Rietveld (i.e., structure) refinement of the diffraction data is used to quantify phase change relationships. Investigated as possible analogs for the refractory dust grain materials likely to have been present in the early solar nebula, the likely relevance of these investigations to the observed silicate compositions of chondritic meteorites and cometary bodies and the processing of their precursor materials is discussed. 相似文献
16.
A. N. KROT A. MEIBOM M. I. PETAEV K. KEIL M. E. ZOLENSKY A. SAITO M. MUKAI K. OHSUMI 《Meteoritics & planetary science》2000,35(6):1249-1258
Abstract— The CH carbonaceous chondrites contain a population of ferrous (Fe/(Fe + Mg) ? 0.1‐0.4) silicate spherules (chondrules), about 15–30 μm in apparent diameter, composed of cryptocrystalline olivinepyroxene normative material, ±SiO2‐rich glass, and rounded‐to‐euhedral Fe, Ni metal grains. The silicate portions of the spherules are highly depleted in refractory lithophile elements (CaO, Al2O3, and TiO2 <0.04 wt%) and enriched in FeO, MnO, Cr2O3, and Na2O relative to the dominant, volatile‐poor, magnesian chondrules from CH chondrites. The Fe/(Fe + Mg) ratio in the silicate portions of the spherules is positively correlated with Fe concentration in metal grains, which suggests that this correlation is not due to oxidation, reduction, or both of iron (FeOsil ? Femet) during melting of metal‐silicate solid precursors. Rather, we suggest that this is a condensation signature of the precursors formed under oxidizing conditions. Each metal grain is compositionally uniform, but there are significant intergrain compositional variations: about 8–18 wt% Ni, <0.09 wt% Cr, and a sub‐solar Co/Ni ratio. The precursor materials of these spherules were thus characterized by extreme elemental fractionations, which have not been observed in chondritic materials before. Particularly striking is the fractionation of Ni and Co in the rounded‐to‐euhedral metal grains, which has resulted in a Co/Ni ratio significantly below solar. The liquidus temperatures of the euhedral Fe, Ni metal grains are lower than those of the coexisting ferrous silicates, and we infer that the former crystallized in supercooled silicate melts. The metal grains are compositionally metastable; they are not decomposed into taenite and kamacite, which suggests fast postcrystallization cooling at temperatures below 970 K and lack of subsequent prolonged thermal metamorphism at temperatures above 400–500 K. 相似文献
17.
Keiko NAKAMURA‐MESSENGER Lindsay P. KELLER Simon J. CLEMETT Scott MESSENGER Motoo ITO 《Meteoritics & planetary science》2011,46(7):1033-1051
Abstract– We have developed new sample preparation and analytical techniques tailored for entire aerogel tracks of Wild 2 sample analyses both on “carrot” and “bulbous” tracks. We have successfully ultramicrotomed an entire track along its axis while preserving its original shape. This innovation allowed us to examine the distribution of fragments along the entire track from the entrance hole all the way to the terminal particle. The crystalline silicates we measured have Mg‐rich compositions and O isotopic compositions in the range of meteoritic materials, implying that they originated in the inner solar system. The terminal particle of the carrot track is a 16O‐rich forsteritic grain that may have formed in a similar environment as Ca‐, Al‐rich inclusions and amoeboid olivine aggregates in primitive carbonaceous chondrites. The track also contains submicron‐sized diamond grains likely formed in the solar system. Complex aromatic hydrocarbons distributed along aerogel tracks and in terminal particles. These organics are likely cometary but affected by shock heating. 相似文献
18.
Shigeyuki WAKAKI Naoya SAKAMOTO Sachio KOBAYASHI Hisayoshi YURIMOTO 《Meteoritics & planetary science》2012,47(12):2070-2083
Abstract– High‐precision isotope imaging analyses of reversely zoned melilite crystals in the gehlenitic mantle of Type A CAI ON01 of the Allende carbonaceous chondrite reveal that there are four types of oxygen isotopic distributions within melilite single crystals: (1) uniform depletion of 16O (δ18O ≈ ?10‰), (2) uniform enrichment of 16O (δ18O ≈ ?40‰), (3) variations in isotopic composition from 16O‐poor core to 16O‐rich rim (δ18O ≈ ?10‰ to ?30‰, ?20‰ to ?45‰, and ?10‰ to ?35‰) with decreasing åkermanite content, and (4) 16O‐poor composition (δ18O ≥ ?10‰) along the crystal rim. Hibonite, spinel, and perovskite grains are 16O‐rich (δ18O ≈ ?45‰), and adjoin 16O‐poor melilites. Gas‐solid or gas‐melt isotope exchange in the nebula is inconsistent with both the distinct oxygen isotopic compositions among the minerals and the reverse zoning of melilite. Fluid‐rock interaction on the parent body resulted in 16O‐poor compositions of limited areas near holes, cracks, or secondary phases, such as anorthite or grossular. We conclude that reversely zoned melilites mostly preserve the primary oxygen isotopic composition of either 16O‐enriched or 16O‐depleted gas from which they were condensed. The correlation between oxygen isotopic composition and åkermanite content may indicate that oxygen isotopes of the solar nebula gas changed from 16O‐poor to 16O‐rich during melilite crystal growth. We suggest that the radial excursions of the inner edge of the protoplanetary disk gas simultaneously resulted in both the reverse zoning and oxygen isotopic variation of melilite, due to mixing of 16O‐poor disk gas and 16O‐rich coronal gas. Gas condensates aggregated to form the gehlenite mantle of the Type A CAI ON01. 相似文献
19.
Jemma Davidson Devin L. Schrader Conel M. O'D. Alexander Dante S. Lauretta Henner Busemann Ian A. Franchi Richard C. Greenwood Harold C. Connolly Jr. Kenneth J. Domanik Alexander Verchovsky 《Meteoritics & planetary science》2014,49(12):2133-2151
Here, we report the mineralogy, petrography, C‐N‐O‐stable isotope compositions, degree of disorder of organic matter, and abundances of presolar components of the chondrite Roberts Massif (RBT) 04133 using a coordinated, multitechnique approach. The results of this study are inconsistent with its initial classification as a Renazzo‐like carbonaceous chondrite, and strongly support RBT 04133 being a brecciated, reduced petrologic type >3.3 Vigarano‐like carbonaceous (CV) chondrite. RBT 04133 shows no evidence for aqueous alteration. However, it is mildly thermally altered (up to approximately 440 °C); which is apparent in its whole‐rock C and N isotopic compositions, the degree of disorder of C in insoluble organic matter, low presolar grain abundances, minor element compositions of Fe,Ni metal, chromite compositions and morphologies, and the presence of unequilibrated silicates. Sulfides within type I chondrules from RBT 04133 appear to be pre‐accretionary (i.e., did not form via aqueous alteration), providing further evidence that some sulfide minerals formed prior to accretion of the CV chondrite parent body. The thin section studied contains two reduced CV3 lithologies, one of which appears to be more thermally metamorphosed, indicating that RBT 04133, like several other CV chondrites, is a breccia and thus experienced impact processing. Linear foliation of chondrules was not observed implying that RBT 04133 did not experience high velocity impacts that could lead to extensive thermal metamorphism. Presolar silicates are still present in RBT 04133, although presolar SiC grain abundances are very low, indicating that the progressive destruction or modification of presolar SiC grains begins before presolar silicate grains are completely unidentifiable. 相似文献
20.
Abstract— Primary minerals in calcium‐aluminum‐rich inclusions (CAIs), Al‐rich and ferromagnesian chondrules in each chondrite group have δ18O values that typically range from ?50 to +5%0. Neglecting effects due to minor mass fractionations, the oxygen isotopic data for each chondrite group and for micrometeorites define lines on the three‐isotope plot with slopes of 1.01 ± 0.06 and intercepts of ?2 ± 1. This suggests that the same kind of nebular process produced the 16O variations among chondrules and CAIs in all groups. Chemical and isotopic properties of some CAIs and chondrules strongly suggest that they formed from solar nebula condensates. This is incompatible with the existing two‐component model for oxygen isotopes in which chondrules and CAIs were derived from heated and melted 16O‐rich presolar dust that exchanged oxygen with 16O‐poor nebular gas. Some FUN CAIs (inclusions with isotope anomalies due to fractionation and unknown nuclear effects) have chemical and isotopic compositions indicating they are evaporative residues of presolar material, which is incompatible with 16O fractionation during mass‐independent gas phase reactions in the solar nebula. There is only one plausible reason why solar nebula condensates and evaporative residues of presolar materials are both enriched in 16O. Condensation must have occurred in a nebular region where the oxygen was largely derived from evaporated 16O‐rich dust. A simple model suggests that dust was enriched (or gas was depleted) relative to cosmic proportions by factors of ~10 to >50 prior to condensation for most CAIs and factors of 1–5 for chondrule precursor material. We infer that dust‐gas fractionation prior to evaporation and condensation was more important in establishing the oxygen isotopic composition of CAIs and chondrules than any subsequent exchange with nebular gases. Dust‐gas fractionation may have occurred near the inner edge of the disk where nebular gases accreted into the protosun and Shu and colleagues suggest that CAIs formed. 相似文献