Chemical evolution of the gas in C-type shocks in dark clouds

A magnetohydrodynamic model of a steady, transverse C-type shock in a dense molecular cloud is presented. A complete gas–grain chemical network is taken into account: the gas-phase chemistry, the adsorption of gas species on dust grains, various desorption mechanisms, the grain surface chemistry, the ion neutralization on dust grains, the sputtering of grain mantles. The population densities of energy levels of ions CI, CII and OI and molecules H₂, CO, H₂O are computed in parallel with the dynamical and chemical rate equations. The large velocity gradient approximation is used in the line radiative transfer calculations. The simulations consist of two steps: (i) modelling of the chemical and thermal evolution of a static molecular cloud and (ii) shock simulations. A comparison is made with the results of publicly available models of similar physical systems.The focus of the paper is on the chemical processing of gas material and ice mantles of dust grains by the shock. Sputtering of ice mantles takes place in the shock region close to the temperature peak of the neutral gas. At high shock speeds, molecules ejected from ice mantles are effectively destroyed in hot gas, and their survival time is low—of the order of dozens of years. After a passage of high-speed C-type shock, a zone of high abundance of atomic hydrogen appears in the cooling postshock gas that triggers formation of complex organic species such as methanol. It is shown that abundances of some complex organic molecules (COMs) in the postshock region can be much higher than in the preshock gas. These results are important for interpretation of observations of COMs in protostellar outflows.     

Life-bearing primordial planets in the solar vicinity

The space density of life-bearing primordial planets in the solar vicinity may amount to ～8.1×10⁴?pc^?3 giving total of ～10¹⁴ throughout the entire galactic disk. Initially dominated by H₂ these planets are stripped of their hydrogen mantles when the ambient radiation temperature exceeds 3?K as they fall from the galactic halo to the mid-plane of the galaxy. The zodiacal cloud in our solar system encounters a primordial planet once every 26 My (on our estimate) thus intercepting an average mass of 10³ tonnes of interplanetary dust on each occasion. If the dust included microbial material that originated on Earth and was scattered via impacts or cometary sublimation into the zodiacal cloud, this process offers a way by which evolved genes from Earth life could become dispersed through the galaxy.     

Synthesis and characterization of peptides after high-energy impact on the icy matrix: Preliminary step for further UV-induced formation

In the interstellar medium, the most probable source of organic molecules could be non-equilibrium processes driven by photons, cosmic rays, shock waves and solid bodies’ collisions. The dense cold phase of ISM host icy dust grains—important chemical catalyst during its life cycle. Such particles consist of mineral core composed by silicate or olivine admixed with metal sulfides and oxides, with the water-icy envelope containing organic molecules. Organic molecules in the ISM evolve and become later incorporated in solar system material (comets and meteorites).The formation of polypeptides from single amino acids was traced in simulation experiments representing the inner structure of icy dust grains. Experimental chamber was irradiated at subzero temperatures at the dosage of 2.54 kRad/min. Solid frozen solutions of Gly and Phe were taken as the experimental samples inserted into the metal tube kept at subzero temperatures in the presence of liquid nitrogen. Formation of di- and tri-peptides was demonstrated after applying mass-spectrometry and high performance liquid chromatography (HPLC) techniques.Having polypeptides within the icy matrix, dust grains with ice mantles are transported to warm, dense and active protostellar regions, where ultraviolet irradiation may become important and alter the grain composition. Furthermore UVC radiation may contribute to the formation of additional amounts of polypeptides, since short-wave photons are totally adsorbed by a thin outer layer. This presumption coincides with our previous investigations concerning UV impact on prebiotic formation of the main biological molecules. Combination of two irradiation types in different stages of interstellar flight could compensate the effects of low reagents concentration and temperature. Since the primordial Earth had no atmosphere, the natural carriers could get freely onto its surface and thus raise the concentration of organic molecules.     

Effects of shock processing on Serkowski polarization curves

This paper presents a semi-empirical model for variations of interstellar polarization curves based upon the Serkowski-Wilking law for optical and near-infrared wavebands. The model assumes that nonspherical dust grains producing interstellar polarization are core-mantle particles shaped like oblate spheroids. The physical picture is one in which large (a ₀ 0.1µm) particles in the dense cloud phase are deposited into the diffuse cloud medium and thereafter undergo mantle processing by galactic shocks and UV starlight. It is shown that polarization curves vary their widths mainly as a consequence of the nonthermal sputtering of mantles by low-velocity shocks. Mantle sputtering by shocks in low density clouds tends to broaden the curves, whereas mantle sputtering by shocks in denser clouds produce narrow curves. Hence, shock processing of grain mantles can explain the observed correlation between the width of polarization curves and the dust grain environment.     

Progress towards the vindication of panspermia

Theories of panspermia are rapidly coming into vogue, with the possibility of the transfer of viable bacterial cells from one planetary abode to another being generally accepted as inevitable. The panspermia models of Hoyle and Wickramasinghe require the transfer of viable bacterial cells from interstellar dust to comets and back into interplanetary and interstellar space. In such a cycle a viable fraction of as little as 10^-18 at the inception of a newly formed comet/planet system suffices for cometary panspermia to dominate over competing processes for the origin and transfer of life. The well-attested survival attributes of microbes under extreme conditions, which have recently been discovered, gives credence to the panspermia hypothesis. The prediction of the theory that comets bring microbes onto the Earth at the present time is testable if aseptic collections of stratospheric air above the tropopause can be obtained. We describe a recent collection of this kind and report microbiological analysis that shows the existence of viable cells at 41 km, falling to Earth at the rate of a few tonnes per day over the entire globe. Some of these cells have been cultured in the laboratory and found to include microorganisms that are not too different from related species on the Earth. This is in fact what the Hoyle-Wickramasinghe theory predicts. The weight of evidence goes against the more conservative explanation that organisms are being lofted to the high atmosphere from the ground. This revised version was published online in July 2006 with corrections to the Cover Date.     

A propensity for n‐ω‐amino acids in thermally altered Antarctic meteorites

Abstract– Asteroids and their fragments have impacted the Earth for the last 4.5 Gyr. Carbonaceous meteorites are known to contain a wealth of indigenous organic molecules, including amino acids, which suggests that these meteorites could have been an important source of prebiotic organic material during the origins of life on Earth and possibly elsewhere. We report the detection of extraterrestrial amino acids in thermally altered type 3 CV and CO carbonaceous chondrites and ureilites recovered from Antarctica. The amino acid concentrations of the thirteen Antarctic meteorites ranged from 300 to 3200 parts‐per‐billion (ppb), generally much less abundant than in amino acid‐rich CI, CM, and CR carbonaceous chondrites that experienced much lower temperature aqueous alteration on their parent bodies. In contrast to low‐temperature aqueously altered meteorites that show complete structural diversity in amino acids formed predominantly by Strecker–cyanohydrin synthesis, the thermally altered meteorites studied here are dominated by small, straight‐chain, amine terminal (n‐ω‐amino) amino acids that are not consistent with Strecker formation. The carbon isotopic ratios of two extraterrestrial n‐ω‐amino acids measured in one of the CV chondrites (δ¹³C approximately ?25‰) are consistent with ¹³C‐depletions observed previously in hydrocarbons produced by Fischer‐Tropsch type reactions. The predominance of n‐ω‐amino acid isomers in thermally altered meteorites hints at cosmochemical mechanisms for the preferential formation and preservation of a small subset of the possible amino acids.     

星云中继假说: 星云中的原始生命和地球生命的起源

提出了关于地球生命起源的新模型---星云中继假说, 它是宇宙胚种论的修改版本. 在这个模型中, 作为宇宙``种子''的原始生命起源于太阳系的前身恒星系统中的生物化学过程, 并且在前身恒星死亡后充满整个原太阳星云. 地球生命的起源可以分为3个阶段: 太阳前身恒星的原始生命起源, 原太阳星云时期和太阳系形成与地球生命时期. 这个模型最主要的推论是原始生命(或其后裔)以及它们的化石存在于太阳系内各种天体之中.     

A Jupiter fragmented comet: Cause of the K/T boundary record

The extended period of mass extinctions around the K/T boundary correlating with extraterrestrial amino acids in the sediment record constitutes strong evidence of a cometary cause. The input of extraterrestrial matter over 10⁵ yr supports the hypothesis of a giant comet, fragmented into subcomets on close encounter with Jupiter, and subsequently perturbed into Earth-crossing orbits. Copious amounts of dust were emitted via this and possibly successive fragmenting encounters, and via normal cometary evaporation. The dynamics of dust from the disintegrating comet fragments favours retention in Earth-crossing orbits of the sub-micron fraction of organic composition. The shroud of dust accreted in the Earth's upper atmosphere varied with time and imposed climatic stresses that caused species extinctions over 10⁵ yr. While the iridium peak in the sediments coincides with the Chicxulub crater impactor, other iridium detail suggests that some of the impactor material was reinjected into space and in part re-accreted by Earth from the interplanetary orbits.     

The chemical evolution in a model of contracting cloud

The evolution of the different chemical species are followed in a model of contracting interstellar cloud. The central density increases from n = 10 cm^–3 diffuse initial cloud model to a dense cloud with central density number of n >- 10⁵ cm^–3 after a time of 1.2 × 10⁷ yr. A network of 622 reactions has been involved. The chemistry of the cloud is integrated simultaneously with the hydrodynamic equations of contraction.The results predict that the different molecular species increase in abundance as the contraction proceeds. The species which enhance significantly are CO, HCO, CS and NO. The fractional abundances of many of the other molecular species increase distinctly with contraction, e.g. CH, C₂H, CN, SO₂, CO₂, H₂O, C₂, NH₃, HCN, SO, OCS and SN. The transformation of the initial diffuse cloud model with small abundances of molecular species to a dense molecular cloud with enhancement of the different molecular species is confirmed. The results predict good agreements of our results with both the observations and other theoretical studies.     

Survival of organic phases in porous IDPs during atmospheric entry: A pulse‐heating study

Abstract— In this study, we have performed pulse‐heating experiments at different temperatures for three organic molecules (a polycyclic aromatic hydrocarbon [PAH], a ketone, and an amino acid) absorbed into microporous aluminum oxide (Al₂O₃) in order to imitate the heating of the organic molecules in interplanetary dust particles (IDPs) and micrometeorites (MMs) during atmospheric entry and to investigate their survival. We have shown that modest amounts (a few percent) of these organic molecules survive pulse‐heating at temperatures in the 700 to 900 °C range. This suggests that the porosity in IDPs and MMs, combined with a sublimable phase (organic material, water), produces an ablative cooling effect, which permits the survival of organic molecules that would otherwise be lost either by thermal degradation or evaporation during atmospheric entry.     

Possible potentially threatening co‐orbiting material of asteroid 2000EE104 identified through interplanetary magnetic field disturbances

Near‐Earth objects (NEOs) with diameters of <300 m are difficult to detect from the Earth with radar or optical telescopes unless and until they approach closely. If they are on collisional courses with the Earth, there is little that can be done to mitigate the considerable damage. Although destructive collisions in space are rare for 1 km diameter bodies and above, once hit by a sizeable impactor, such a NEO can develop a relatively dense cloud of co‐orbiting material in which destructive collisions are relatively frequent. The gas and nanoscale dust released in the destructive collisions can be detected remotely by downstream spacecraft equipped with magnetometers. In this paper, we use such magnetic disturbances to identify regions of near‐Earth space in which high densities of small objects are present. We find that asteroid (138175) 2000EE104 currently may have a cloud of potentially threatening co‐orbiting material. Due to the scattered co‐orbitals, there can be a finite impact probability whenever the Earth approaches the orbit of asteroid 2000EE104, regardless of the position of the asteroid itself.     

A Jupiter fragmented comet: Cause of the K/T boundary record

The extended period of mass extinctions around the K/T boundary correlating with extraterrestrial amino acids in the sediment record constitutes strong evidence of a cometary cause. The input of extraterrestrial matter over 10⁵ yr supports the hypothesis of a giant comet, fragmented into subcomets on close encounter with Jupiter, and subsequently perturbed into Earth-crossing orbits. Copious amounts of dust were emitted via this and possibly successive fragmenting encounters, and via normal cometary evaporation. The dynamics of dust from the disintegrating comet fragments favours retention in Earth-crossing orbits of the sub-micron fraction of organic composition. The shroud of dust accreted in the Earth's upper atmosphere varied with time and imposed climatic stresses that caused species extinctions over 10⁵ yr. While the iridium peak in the sediments coincides with the Chicxulub crater impactor, other iridium detail suggests that some of the impactor material was reinjected into space and in part re-accreted by Earth from the interplanetary orbits.School of Mathematics, University of Wales College of Cardiff.     

On the interstellar extinction law toward young stars

We have determined the atomic hydrogen column density N _HI toward all of the young stars from the Taurus-Auriga-Perseus star-forming complex for which the corresponding spectra are available in the Hubble Space Telescope archive (nine stars) by analyzing the Lyα line profile. We show that the stars studied, except DR Tau, lie not far from the edge of the gaseous cloud of the star-forming region closest to us or, more precisely, inside the outer H I shell of the cloud. This shell with a column density of N _HI ? 6 × 10²⁰ cm^?2 surrounds the molecular gas of the cloud composed of a diffuse component (the so-called diffuse screen) in which dense, compact TMC-1 cores are embedded. The properties of the dust grains toward the stars that lie at the front edge of the cloud most likely differ only slightly from those of the interstellar dust outside star-forming regions. This casts doubt on the validity of the hypothesis that the extinction curve toward young stars has an anomalously low amplitude of the 2175 Å bump—such an extinction curve is observed for the field stars HD 29647 and HD 283809 toward which the line of sight passes through the TMC-1 core.     

Unusual infrared fading of CH Cygni in 2006

Infrared observations of the unique symbiotic system CH Cyg in 2003–2006 are presented. Analysis of the observations has shown that a fairly dense dust structure (a cloud or a shell) appeared on the line of sight in August–November 2006. The dust grains in the new shell are similar in optical properties to graphite ones and their sizes are mostly within the range 0.14–0.16 μm. The dust shell is optically thick and its optical depth at 2.2 μm is τ(2.2) ≈ 0.97. The dust shell mass is M _d(06) ≈ 8 × 10⁻⁶ M _⊙ and the rate of matter flow into the shell has reached ∼2 × 10⁻⁵ M _⊙ yr⁻¹. Original Russian Text ? O.G. Taranova, V.I. Shenavrin, 2007, published in Pis’ma v Astronomicheskiĭ Zhurnal, 2007, Vol. 33, No. 8, pp. 598–603.     

The influence of grain mantles on the formation of hydrogen molecules on grain surfaces

The physical adsorption energy,E, of hydrogen molecules on various substrates at temperatures between 5 and 30 K and at the lowest practicable gas densities has been measured. Values ofE/k are for condensed CO 340 K, CO₂ 800 K, H₂O 850 K and for ‘dirty’ graphite 980 K and ‘dirty’ copper 800 K. From these measurements temperature ranges in which H atoms might combine on the surface to form H₂ molecules are estimated. Duley has discussed the formation and composition of condensed gas mantles on interstellar grains. The effects of such mantles in promoting and poisoning hydrogen molecule formation are discussed.     

The ORGANICS experiment on BIOPAN V: UV and space exposure of aromatic compounds

We studied the stability of aromatic compounds in low Earth orbit environment and describe the scientific results and successful flight of the ORGANICS experiment on-board the BIOPAN V space exposure facility. This experiment investigated the photo stability of large organic molecules in low Earth orbit. Thin films of selected organic molecules, such as polycyclic aromatic hydrocarbons (PAHs) and the fullerene C₆₀ were subjected to the low Earth orbit environment and the samples were monitored before and after flight. PAHs and fullerenes have been proposed as carriers for a number of astronomical absorption and emission features and are also identified in meteorites. Our experiment on BIOPAN V was exposed to a total fluence of 602.45 kJ m⁻² for photons in the range 170–280 nm. The experiment was also intended as a hardware test-flight for a long-term exposure experiment (Survival of organics in space) on the EXPOSE facility on the International Space Station (ISS). For the small fluence that was collected during the BIOPAN V experiment we found little evidence of photo-destruction. The results confirm that PAH molecules are very stable compounds in space. The small differences in destruction rates that are expected to arise among the PAH samples as a function of molecular size and structure will only show after the longer irradiation fluences that are expected in the exposure experiment on the ISS.     

A study of presolar material in hydrated lithic clasts from metal-rich carbonaceous chondrites

We report on the investigation of presolar grain inventories of hydrated lithic clasts in three metal-rich carbonaceous chondrites from the CR clan, Acfer 182 (CH3), Isheyevo (CH3/CB_b3), and Lewis Cliff (LEW) 85332 (C3-un), as well as the carbon- and nitrogen-isotopic compositions of the fine-grained clast material. Eleven presolar silicate grains as well as nine presolar silicon carbide (SiC) grains were identified in the clasts. Presolar silicate abundances range from 4 to 22 parts per million (ppm), significantly lower than in pristine meteorites and interplanetary dust particles (IDP), and comparable to recent findings for CM2s and CR2 interchondrule matrix. SiC concentrations lie between 9 and 23 ppm, and are comparable to the values for CI, CM, and CR chondrites. The results of our investigation suggest similar alteration pathways for the clast material, the interchondrule matrix of the CR2 chondrites, and the fine-grained fraction of CM2 chondrites. Fine-grained matter of all three meteorites contains moderate to high ¹⁵N-enrichments (~50‰ ≤ δ¹⁵N ≤ ~1600‰) compared to the terrestrial value, indicating the presence of primitive organic material. We observed no correlation between ¹⁵N-enrichments and presolar dust concentrations in the clasts. This is in contrast to the findings from a suite of primitive IDPs, which display in several cases enhanced bulk ¹⁵N/¹⁴N ratios and high presolar grain abundances of several hundred or even thousand ppm. The bulk ¹⁵N/¹⁴N ratios of the clasts are comparable to the range for primitive IDPs, suggesting a nitrogen carrier less susceptible to destruction by aqueous alteration than silicate stardust.     

Amino acid survival in large cometary impacts

Abstract— A significant fraction of the Earth's prebiotic volatile inventory may have been delivered by asteroidal and cometary impacts during the period of heavy bombardment. The realization that comets are particularly rich in organic material seemed to strengthen this suggestion. Previous modeling studies, however, indicated that most organics would be entirely destroyed in large comet and asteroid impacts. The availability of new kinetic parameters for the thermal degradation of amino acids in the solid phase made it possible to readdress this question. We present the results of new high-resolution hydrocode simulations of asteroid and comet impact coupled with recent experimental data for amino acid pyrolysis in the solid phase. Differences due to impact velocity as well as projectile material have been investigated. Effects of angle of impacts were also addressed. The results suggest that some amino acids would survive the shock heating of large (kilometer-radius) cometary impacts. At the time of the origins of life on Earth, the steady-state oceanic concentration of certain amino acids (like aspartic and glutamic acid) delivered by comets could have equaled or substantially exceeded concentrations due to Miller-Urey synthesis in a CO₂-rich atmosphere. Furthermore, in the unlikely case of a grazing impact (impact angle ～5° from the horizontal), an amount of some amino acids comparable to that due to the background steady-state production or delivery would be delivered to the early Earth.     

The Contribution of Asteroid Dust to the Interplanetary Dust Cloud: The Impact of ULYSSES Results on the Understanding of Dust Production in the Asteroid Belt and of the Formation of the IRAS Dust Bands

Investigations of the zodiacal dust cloud give evidence for a significant contribution of asteroidal dust to the interplanetary dust cloud, a result which can now be compared to measurements of the ULYSSES dust detector during its passage of the asteroid belt. Especially we discuss the ULYSSES data with respect to the IRAS dust bands and consider geometric selection effects for the detector. From calculations of radiation pressure forces, we conclude that particles in the IRAS dust bands with massesm≥ 10⁻¹²g will stay in bound orbits after their release from asteroid fragmentation. This is already in the mass range (10⁻¹⁶–10⁻⁷g) of particles detectable with the dust detector onboard ULYSSES. The absence of these particles in the ULYSSES data cannot be explained exclusively in terms of their small detection probability. Thus we conclude that the size distribution of particles in the IRAS dust bands most probably cannot be continued to the submicrometer range. Concerning the global structure of the inner zodiacal cloud (i.e., about solar distancer< 3.5 AU) the ULYSSES data are not inconsistent with present models. Recent estimates of the total mass of the interplanetary cloud require a dust production rate of about 10¹⁴g/year of which a significant amount is assumed to result from the asteroids. Our estimate for the production of dust particles in an IRAS dust band, based on the assumption that the dust band results from a single destruction of an asteroid of 100 km size, yields a production rate of 10¹⁰g/year. Other models of the IRAS dust bands suggest production rates up to 10¹²g/year and also cannot provide a significant source of the dust cloud.