HE 1127–1304: the largest radio quasar

By considering the propagation of low-amplitude magnetohydrodynamic waves in partially ionized plasmas, it is shown that the ion-neutral drift (ambipolar diffusion) induced by the waves can have specific effects on the molecular chemistry of cold material. The chemistry occurring in gas swept by Alfvén waves is described and it is shown that this leads to spatial variations in the deuterium fractionation ratios of, for example, HCO⁺ and N₂H⁺, on spatial scales of a few hundredths of a parsec, depending upon the fractional ionization of the ambient medium. The possibility of detecting interstellar Alfvén waves by molecular spectroscopy and their effect of producing small-scale chemical abundance gradients in molecular clouds are briefly discussed.     

The interstellar magnetic field near the Galactic center

We review the current observational knowledge of the interstellar magnetic field within ∼150 pc ofthe Galactic center. We also discuss the various theoretical scenarios that have been put forward to explain the existing observations. Our critical overview leads to two important conclusions: (1) The interstellar magnetic field near the GC is approximately poloidal on average in the diffuse intercloud medium and approximately horizontal in dense interstellar clouds. (2) In the general intercloud medium, the field is relatively weak and probably close to equipartition with cosmic rays (B ∼ (6–20) μ G), but there exist a number of localized filaments where the field is much stronger (some filaments could possibly have B ≳ 1 mG). In dense interstellar clouds, the field is probably rather strong, with typical values ranging between a few 0.1 mG and a few mG (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Star formation in the LMC: Comparative CCD observations of young stellar populations in two giant molecular clouds

This work deals with a CCD imaging study at optical and near‐infrared wavelength oftwo giant molecular clouds (plus a control field) in the southern region of the Large Magellanic Cloud, one ofwhich shows multiple signs of star formation, whereas the other does not. The observational data from VLT FORS2 (R band) and NTT SOFI (Ks band) have been analyzed to derive luminosity functions and color‐magnitude diagrams. The young stellar content of these two giant molecular clouds is compared and confirmed to be different, in the sense that the apparently “starless” cloud has so far formed only low‐luminosity, low‐mass stars (fainter than m_Ks ∽ 16.5 mag, not seen by 2MASS), while the other cloud has formed both faint low‐mass and luminous high‐mass stars. The surface density excess oflow‐luminosity stars (∽2 per square arcmin) in the “starless” cloud with respect to the control field is about 20% whereas the excess is about a factor of 3 in the known star‐forming cloud. The difference may be explained theoretically by the gravo‐turbulent evolution of giant molecular clouds, one being younger and less centrally concentrated than the other (© 2009 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Limited diversity of the interstellar extinction law

We have applied the method of investigating extinction curves using statistically meaningful samples that was proposed by us 25 years ago. The extensive data sets of the ANS (Astronomical Netherlands Satellite) and 2MASS (Two Micron All Sky Survey) were used, together with UBV photometry to create average extinction curves for samples of OB stars. Our results demonstrate that in the vast majority of cases the extinction curves are very close to the mean galactic extinction curve. Only a few objects were found to be obviously discrepant from the average. The latter phenomenon may be related to nitrogen chemistry in translucent interstellar clouds (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The formation of molecular clouds

In a recent paper, Elmegreen has made a cogent case, from an observational point of view, that the lifetimes of molecular clouds are comparable to their dynamical time-scales. If so, this has important implications for the mechanisms by which molecular clouds form. In particular, we consider the hypothesis that molecular clouds may form not by in situ cooling of atomic gas, but rather by the agglomeration of the dense phase of the interstellar medium, much, if not most, of which is already in molecular form.     

Charge transfer reactions at interfaces between neutral gas and plasma: Dynamical effects and X‐ray emission

Charge‐transfer is the main process linking neutrals and charged particles in the interaction regions of neutral (or partly ionized) gas with a plasma. In this paper we illustrate the importance of charge‐transfer with respect to the dynamics and the structure of neutral gas‐plasma interfaces. We consider the following phenomena: (1) the heliospheric interface ‐ region where the solar wind plasma interacts with the partly‐ionized local interstellar medium (LISM) and (2) neutral interstellar clouds embedded in a hot, tenuous plasma such as the million degree gas that fills the so‐called “Local Bubble”. In (1), we discuss several effects in the outer heliosphere caused by charge exchange of interstellar neutral atoms and plasma protons. In (2) we describe the role of charge exchange in the formation of a transition region between the cloud and the surrounding plasma based on a two‐component model of the cloud‐plasma interaction. In the model the cloud consists of relatively cold and dense atomic hydrogen gas, surrounded by hot, low density, fully ionized plasma. We discuss the structure of the cloud‐plasma interface and the effect of charge exchange on the lifetime of interstellar clouds. Charge transfer between neutral atoms and minor ions in the plasma produces X‐ray emission. Assuming standard abundances of minor ions in the hot gas surrounding the cold interstellar cloud, we estimate the X‐ray emissivity consecutive to the charge transfer reactions. Our model shows that the charge‐transfer X‐ray emission from the neutral cloud‐plasma interface may be comparable to the diffuse thermal X‐ray emission from the million degree gas cavity itself (© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Observational Indicators of Formation Excitation of H2

Theoretical predictions by Farebrother et al. and Meijer et al. of rovibrational excitation probabilities in H₂ arising from formation by Eley-Rideal processes on a graphite surface are incorporated into a model of the chemistry and excitation of interstellar H₂. The model includes the usual radiative and collisional pumping of H₂ rotational and vibrational states, in addition to the formation processes. Predictions are made for HH₂ rovibrational emission line intensities for representative points in diffuse and in dark interstellar clouds. We find that – if all the interstellar HH₂ is formed by this Eley-Rideal process – then the consequences of formation pumping, as distinct from collisional and radiative pumping, should be clearly evident in both cases. In particular, we predict a clear spectral signature of this direct HH₂ formation process on graphite, distinct from radiative and collisional pumping; this signature should be evident in both diffuse and dark clouds; but the emissivity for dark clouds is predicted to be some 500 times greater than that in diffuse clouds in which the dense material may be embedded. An observational search for this signature in two dark cloud sources was made, but a preliminary analysis of the data did not yield a detection. The implications of and possible reasons for this preliminary conclusion are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.     

New models of interstellar gas–grain chemistry – III. Solid CO2

Solid CO₂ is observed to be an abundant interstellar ice component towards both quiescent clouds and active star-forming regions. Our recent models of gas–grain chemistry, appropriate for quiescent regions, severely underproduce solid CO₂ at the single assumed gas density and temperature. In this paper, we investigate the sensitivity of our model results to changes in these parameters. In addition, we examine how the nature of the grain surface affects the results and also consider the role of the key surface reaction between O and CO. We conclude that the observed high abundance of solid CO₂ can be reproduced at reasonable temperatures and densities by models with diffusive surface chemistry, provided that the diffusion of heavy species such as O occurs efficiently.     

A study of interstellar Na i D absorption lines towards the Lupus molecular clouds

Intermediate-resolution (60 000 R 120 000) observations of interstellar Na  i lines towards 29 stars in the general direction of the Lupus molecular clouds (330°≲ l ≲350°; 0°≲ b ≲25°) are presented. Previously published spectra towards an additional seven stars are also included. Based on the Hipparcos distances to these stars, and the minimum distance at which strong interstellar Na  i lines appear in the spectra, I obtain a distance of ~150±10 pc to the Lupus molecular complex. While in agreement with a number of other independent estimates, this result is at odds with the value of 100 pc recently obtained by Knude & Høg from a Hipparcos -based study of interstellar extinction. A possible explanation for this discrepancy is discussed, and it is concluded that the value of 150±10 pc obtained here is to be preferred. In addition, these observations have some other implications for the structure of the interstellar medium in this direction, and these are briefly considered.     

Gamma rays from molecular clouds

It is believed that the observed diffuse gamma-ray emission from the galactic plane is the result of interactions between cosmic rays and the interstellar gas. Such emission can be amplified if cosmic rays penetrate into dense molecular clouds. The propagation of cosmic rays inside a molecular cloud has been studied assuming an arbitrary energy and space dependent diffusion coefficient. If the diffusion coefficient inside the cloud is significantly smaller compared to the average one derived for the galactic disk, the observed gamma-ray spectrum appears harder than the cosmic ray spectrum, mainly due to the slower penetration of the low energy particles towards the core of the cloud. This may produce a great variety of gamma-ray spectra.     

A search for absorption of Mg and Ca compounds in molecular clouds towards Galactic continuum sources

Absorption lines of MgH and CaH N  = 1 − 0 transitions were searched for in foreground molecular clouds towards the continuum sources associated with Sgr B2 (M) and W49A (N). None of these lines was detected with our sensitivity level of ∼20 mK. Millimetric absorption lines of MgO, MgOH, CaO and CaOH were also searched for towards Sgr B2 (M) without success. The fractional abundances relative to molecular hydrogen are ≲ 1.0 × 10⁻¹¹ for MgH, ≲ 7.9 × 10⁻¹³ for MgO, ≲ 1.6 × 10⁻¹⁰ for MgOH, ≲ 1.6 × 10⁻⁹ for CaH, ≲ 2.0 × 10⁻¹² for CaO, and ≲ 2.5 × 10⁻¹⁰ for CaOH, respectively. The low abundances measured in absorption indicate that a significant fraction of interstellar magnesium and calcium cannot be tied up in their monohydrides, monoxides and monohydroxides. The low abundance of MgH also implies that grain-surface chemistry involving magnesium is not efficient and that magnesium is depleted on to grains to a factor of ≳ 10^2.5 in well-shielded molecular clouds.     

Hydrated sulphuric acid in dense molecular clouds

We consider sulphur depletion in dense molecular clouds, and suggest hydrated sulphuric acid, H₂SO₄ ·  n H₂O, as a component of interstellar dust in icy mantles. We discuss the formation of hydrated sulphuric acid in collapsing clouds and its instability in heated regions in terms of the existing hot core models and observations. We also show that some features of the infrared spectrum of hydrated sulphuric acid have correspondence in the observed spectra of young stellar objects.     

The search for the elusive Zeeman effect in HI

The paper describes the early endeavours by radioastronomers to detect the weak signature of the Zeeman effect in interstellar neutral hydrogen clouds in an effort to measure the Galactic magnetic field strength. The search is set in the context of the neutral hydrogen programme at Jodrell Bank. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The 2200 Å bump and the interstellar extinction curve

The 2200 Å bump is a major figure of interstellar extinction. However, extinction curves with no bump exist and are, with no exception, linear from the near‐infrared down to 2500 Å at least, often over all the visible‐UV spectrum. The duality linear versus bump‐like extinction curves can be used to re‐investigate the relationship between the bump and the continuum of interstellar extinction, and answer questions as why do we observe two different kinds of extinction (linear or with a bump) in interstellar clouds? How are they related? How does the existence of two different extinction laws fits with the requirement that extinction curves depend exclusively on the reddening E (B – V) and on a single additional parameter? What is this free parameter? It will be found that (1) interstellar dust models, which suppose the existence of three different types of particles, each contributing to the extinction in a specific wavelength range, fail to account for the observations; (2) the 2200 Å bump is very unlikely to be absorption by some yet unidentified molecule; (3) the true law of interstellar extinction must be linear from the visible to the far‐UV, and is the same for all directions including other galaxies (as the Magellanic Clouds). In extinction curves with a bump the excess of starlight (or the lack of extinction) observed at wavelengths less than λ = 4000 Å arises from a large contribution of light scattered by hydrogen on the line of sight. Although counter‐intuitive this contribution is predicted by theory. The free parameter of interstellar extinction is related to distances between the observer, the cloud on the line of sight, and the star behind it (the parameter is likely to be the ratio of the distances from the cloud to the star and to the observer). The continuum of the extinction curve and the bump contain no information on the chemical composition of interstellar clouds. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The chemistry of transient microstructure in the diffuse interstellar medium

Transient microstructure in the diffuse interstellar medium (ISM) has been observed towards Galactic and extragalactic sources for decades, usually in lines of atoms and ions, and, more recently, in molecular lines. Evidently, there is a molecular component to the transient microstructure. In this paper, we explore the chemistry that may arise in such microstructure. We use a photodissociation region (PDR) code to model the conditions of relatively high density, low temperature, very low visual extinction and very short elapsed time that are appropriate for these objects. We find that there is a well-defined region of parameter space where detectable abundances of molecular species might be found. The best matching models are those where the interstellar microstructure is young (<100 yr), small (∼100 au) and dense  (>10⁴ cm⁻³)  .     

New approaches to the modelling of surface chemistry on interstellar grains

In recent years, the need to replace rate equations for studying grain-surface chemistry in the modelling of interstellar clouds has become apparent. In this article, we discuss the three new replacement methods that have been suggested to date, and contrast their relative strengths and weaknesses. This revised version was published online in July 2006 with corrections to the Cover Date.     

An ultra-high-resolution study of the interstellar medium towards Orion

We report ultra-high-resolution observations     of Na  i , Ca  ii , K  i , CH and CH⁺ for interstellar sightlines towards 12 bright stars in Orion. These data enable the detection of many more absorption components than previously recognized, providing a more accurate perspective on the absorbing medium. This is especially so for the line of sight to the Orion nebula, a region not previously studied at very high resolution. Model fits have been constructed for the absorption-line profiles, providing estimates for the column density, velocity dispersion and central velocity for each constituent velocity component. A comparison between the absorption occurring in sightlines with small angular separations has been used, along with comparisons with other studies, to estimate the line-of-sight velocity structures. Comparisons with earlier studies have also revealed temporal variability in the absorption-line profile of ζ Ori, highlighting the presence of small-scale spatial structure in the interstellar medium on scales of ≈10 au. Where absorption from both Na⁰ and K⁰ is observed for a particular cloud, a comparison of the velocity dispersions measured for each of these species provides rigorous limits on both the kinetic temperature and turbulent velocity prevailing in each cloud. Our results indicate the turbulent motions to be subsonic in each case.     abundance ratios are derived for individual clouds, providing an indication of their physical state.     

Thermal desorption of water ice in the interstellar medium

Water (H₂O) ice is an important solid constituent of many astrophysical environments. To comprehend the role of such ices in the chemistry and evolution of dense molecular clouds and comets, it is necessary to understand the freeze-out, potential surface reactivity and desorption mechanisms of such molecular systems. Consequently, there is a real need from within the astronomical modelling community for accurate empirical molecular data pertaining to these processes. Here we give the first results of a laboratory programme to provide such data. Measurements of the thermal desorption of H₂O ice, under interstellar conditions, are presented. For ice deposited under conditions that realistically mimic those in a dense molecular cloud, the thermal desorption of thin films (≪50 molecular layers) is found to occur with zeroth-order kinetics characterized by a surface binding energy, E _des, of 5773 ± 60 K, and a pre-exponential factor, A , of 10^30 ± 2 molecules cm⁻² s⁻¹. These results imply that, in the dense interstellar medium, thermal desorption of H₂O ice will occur at significantly higher temperatures than has previously been assumed.     

Dust-induced chemical differentiation in dense regions

Dust grains respond to the physical and chemical conditions of the interstellar region in which they are embedded. The interaction produces an extinction curve which depends on the local environment and on the past history of the dust grains. In this work we present a theoretical study of the effects of radial variations of dust extinction properties on gas-phase chemistry in spherical core–halo clouds. We use observational constraints on the variation range of the extinction curve, and we analyse if the degree of dust environmental processing could be reflected by chemical signatures in the gas-phase molecular concentrations. The results of this work show that significant variations in the photodestruction rates and in the thermal profile of the cloud might induce chemical patterns otherwise excluded in the standard dense-cloud chemistry. Some discrepancies between observations and theoretical provisions are discussed in the light of the present results.     

Lattice dynamical system modelling of molecular clouds

Because a comprehensive microscopic treatment of interstellar molecular clouds is out of reach, an alternative approach is proposed in which most of the crucial ingredients of the problem are considered, but at some 'minimal' level of modelling. This leads to the elaboration of a lattice dynamical system , i.e. a time-dependent, spatially extended, deterministic system of macroscopic cells coupled through radiative transfer. Each cell is characterized by a small set of variables and supports a caricatural chemistry possessing the essential dynamical features of more realistic reaction schemes.   This approach naturally precludes quantitative results, but allows heretofore unavailable insights into some of the basic mechanisms at play. We focus on the response of the transfer process and the chemistry to a frozen 'turbulent' velocity field. It is shown that the system settles generically into a state where the effective coupling between cells is neither local nor global, and for which no single length-scale exists.   The spectral lines reconstructed from the spatiotemporal evolution of our model may, depending on the velocity field, exhibit profiles ranging from Gaussian to bimodal with strong realization effects. In the bimodal case, the model intrinsically displays an energy cascade transport mechanism to the cells that cool most efficiently: the feedback of chemistry on radiative transfer cannot be neglected.   Finally, extensions of this work are discussed and future developments are outlined.