Control of Phosphate Concentration through Adsorption and Desorption Processes in Groundwater and Seawater Mixing at Sandy Beaches in Tokyo Bay, Japan

Field observation was conducted to monitor phosphate concentrations in groundwater and seawater mixing at two sandy beaches in Futtsu and Miura in Tokyo Bay, Japan. Dissolved phosphate concentrations were measured along transects from fresh groundwater aquifer to seawater adjacent the beaches. The concentrations were often high (up to 46 µM) in fresh groundwater samples (Cl^– < 0.2). Coastal seawater, on the other hand, exhibited low phosphate concentrations (1.5 µM or less). Along the transects, phosphate generally displayed non-conservative behavior during mixing of fresh and saline waters in the aquifer; concentrations as high as 100 µM were found around the upper limit of seawater intrusion (Cl^– = 2). Laboratory experiments were executed to identify the processes that control the phosphate behavior in the mixing processes. The results revealed that adsorption-desorption processes by the aquifer sand particles could significantly control the phosphate concentrations in the groundwater. Furthermore, the adsorption and/or desorption was found to be a function of salinity; the equilibrium concentration of dissolved phosphate in slurry of sand and water was the highest in freshwater and decreased considerably in saline water. The extreme concentration of phosphate may be caused by release from sand particles coinciding with the rapid change in salinity with tide.     

三门湾海域4、7月营养盐分布及其稀释效应

利用2005年4、7月三门湾海域26个站位的两次水化学要素调查资料,描述了表层盐度和营养盐平面分布特征,对营养盐和盐度进行相关分析,并探讨了24 h连续站的营养盐变化规律,结果表明:(1)表层硝酸盐、硅酸盐浓度基本呈东低西高分布,磷酸盐的分布规律不明显。(2)7月硝酸盐、磷酸盐平均浓度比4月低,而硅酸盐、亚硝酸盐平均浓度比4月高,氨平均浓度在4、7月无显著变化。(3)4、7月表、底层的硝酸盐、硅酸盐、亚硝酸盐浓度均为湾内高湾口低,且与盐度呈显著的负相关,表明在调查时间内受强潮汐作用的三门湾海域呈现出硝酸盐、硅酸盐的保守稀释效应,磷酸盐稀释效应则表现不明显。(4)7月25-26日连续站(29°06′33″N、121°39′03″E,三门湾中部猫头山嘴附近,水深为27-34 m)24 h盐度变化与潮汐变化几乎一致,硝酸盐、硅酸盐浓度与盐度变化呈显著负相关。硝酸盐、硅酸盐的浓度变化可以指示海水与淡水的稀释与混合效应。     

Spatial Patterns in Nutrient and In Vivo Fluorescence Distributions in the Marginal Ice Zone and the Seasonally Open Oceanic Zone in the Indian Sector of the Antarctic Ocean, in Austral Summer

Surface temperature, salinity, concentrations of silicate (Si) and nitrate + nitrite (N), and in vivo fluorescence (Fluor) were investigated in the marginal ice zone (MIZ) and the seasonally open oceanic zone (SOOZ) (32–40°E, 64–69°S) from February 23 to 28 1992. In the MIZ the mean Si and N were 67.8 ± 2.2 M and 32.5 ± 1.7 M, respectively. There was a trend that low N values coincided with high Fluor values. Observation conducted at one point (64°S, 38°E) revealed a diel variation pattern in Fluor. Applying this pattern of deviation from noon value, all Fluor data were normalized to value at local noon. In the MIZ a significant negative correlation was observed between the normalized Fluor and N but not Si. On the other hand, Si decreased continuously from south to north in the SOOZ and was negatively correlated with the normalized Fluor. Difference in Si concentration was about 30 M between the sea around 64°S and the MIZ, while the difference in N concentration was estimated as less than 10 M. If diatoms take up silicate and nitrogen at an approximate ratio of 1:1, additional nitrogenous nutrients other than nitrate and nitrite (e.g. ammonia, urea etc.) would be required. In this case, an f-ratio of lower than 33% is obtained. It is suggested that in the MIZ abundance of phytoplankton community dominated by non-diatom increases utilizing nitrate while in the SOOZ abundance of phytoplankton community dominated by diatoms increases consuming Si and regenerated nitrogen.     

Current and Turbidity Variations in the Western Part of Suo-Nada, the Seto Inland Sea, Japan: A Hypothesis on the Oxygen-Deficient Water Mass Formation

A hydrographic survey and a 25-hour stationary observation were carried out in the western part of Suo-Nada in the summer of 1998 to elucidate the formation mechanism of the oxygen-deficient water mass. A steep thermocline and halocline separated the upper layer water from the bottom water over the observational area except for near the Kanmon Strait. The bottom water, in comparison with the upper layer water, indicated lower temperature, higher salinity, lower dissolved oxygen, higher turbidity, and higher chlorophyll a. Turbidity in the upper layer water changed with semi-diurnal period while the bottom water turbidity showed a quarter-diurnal variation, though the M₂ tidal current prevailed in both waters. From the turbidity distribution and the current variation, it is revealed that the turbidity in the upper layer water is controlled by the advection due to the M₂ tidal current. On the other hand, the quarter-diurnal variation in the bottom water turbidity is caused by the resuspension of bottom sediments due to the M₂ tidal current. The steep thermocline and halocline were maintained throughout the observation period in spite of the rather strong tidal currents. This implies an active intrusion of the low temperature and high salinity water from the east to the bottom of Suo-Nada. Based on the observational results, a hypothesis on the oxygen-deficient water mass formation was proposed; the periodical turbidity variation in the bottom water quickly modifies the oxygen-rich water in the east to the oxygen-deficient bottom water in Suo-Nada in a course of circulation.