Famennian Fusulinina (Foraminifera) from the Holy Cross Mountains (central Poland)

Calcareous foraminifers representing 9 species and 5 genera were investigated in two Famennian sections located in the south‐western part of the Holy Cross Mountains (HCM), central Poland. They constitute redeposited material that, together with crinoids and calcareous algae, comprise the dominant component of limestone turbidite beds intercalated with deep‐marine marly sediments. The calcareous material was redeposited from an unknown carbonate platform located probably to the south of the HCM area. The first appearance data of foraminifers, mainly from the quasiendothyrid group, correlated to the Standard Conodont Zonation, indicate a diachronous appearance of the same species in different parts of Europe due to a migration delay from the foraminiferal evolutionary centre located in the south‐eastern shelves of Laurussia in the neighbouring areas. As a result, the Moravian foraminiferal zonation, where index taxa appeared in similar stratigraphic intervals, was chosen as the most applicable to the stratigraphy in the central Polish area. The Quasiendothyra communis–Eonodosaria evlanensis Interzone, the Quasiendothyra communis–Quasiendothyra regularis Zone and Quasiendothyra kobeitusana–Quasiendothyra konensis Zone were distinguished, respectively, in the HCM sections. Copyright © 2012 John Wiley & Sons, Ltd.     

Site selectivity of the boring Rogerella isp. infesting Cardiaster granulosus (Goldfuss) (Echinoidea) in the type Maastrichtian (Upper Cretaceous,Belgium)

A burrowing spatangoid echinoid (heart urchin), Cardiaster granulosus (Goldfuss), from the type area of the Maastrichtian Stage (Upper Cretaceous) in Belgium, was infested only in the plates of the ambulacral petals by acrothoracian barnacle borings, Rogerella isp. This infestation was after the death and exhumation of the echinoid. The distribution of Rogerella may indicate the azimuth of current flow at the time of exhumation prior to final burial. Copyright © 2015 John Wiley & Sons, Ltd.     

Heterogeneous reduction of Tc(VII) by Fe(II) at the solid-water interface

Experiments were performed herein to investigate the rates and products of heterogeneous reduction of Tc(VII) by Fe(II) adsorbed to hematite and goethite, and by Fe(II) associated with a dithionite-citrate-bicarbonate (DCB) reduced natural phyllosilicate mixture [structural, ion-exchangeable, and edge-complexed Fe(II)] containing vermiculite, illite, and muscovite. The heterogeneous reduction of Tc(VII) by Fe(II) adsorbed to the Fe(III) oxides increased with increasing pH and was coincident with a second event of adsorption. The reaction was almost instantaneous above pH 7. In contrast, the reduction rates of Tc(VII) by DCB-reduced phyllosilicates were not sensitive to pH or to added that adsorbed to the clay. The reduction kinetics were orders of magnitude slower than observed for the Fe(III) oxides, and appeared to be controlled by structural Fe(II). The following affinity series for heterogeneous Tc(VII) reduction by Fe(II) was suggested by the experimental results: aqueous Fe(II) ∼ adsorbed Fe(II) in phyllosilicates [ion-exchangeable and some edge-complexed Fe(II)] ? structural Fe(II) in phyllosilicates ? Fe(II) adsorbed on Fe(III) oxides. Tc-EXAFS spectroscopy revealed that the reduction products were virtually identical on hematite and goethite that were comprised primarily of sorbed octahedral TcO₂ monomers and dimers with significant Fe(III) in the second coordination shell. The nature of heterogeneous Fe(III) resulting from the redox reaction was ambiguous as probed by Tc-EXAFS spectroscopy, although Mössbauer spectroscopy applied to an experiment with ⁵⁶Fe-goethite with adsorbed ⁵⁷Fe(II) implied that redox product Fe(III) was goethite-like. The Tc(IV) reduction product formed on the DCB-reduced phyllosilicates was different from the Fe(III) oxides, and was more similar to Tc(IV) oxyhydroxide in its second coordination shell. The heterogeneous reduction of Tc(VII) to less soluble forms by Fe(III) oxide-adsorbed Fe(II) and structural Fe(II) in phyllosilicates may be an important geochemical process that will proceed at very different rates and that will yield different surface species depending on subsurface pH and mineralogy.     

Origin of polyhalite deposits in the Zechstein (Upper Permian) Zdrada platform (northern Poland)

Polyhalite deposits in the Zechstein (Upper Permian) of northern Poland occur in the Lower Werra Anhydrite. In the Zdrada Sulphate Platform, the polyhalite appears to be a very early replacement of anhydrite. The replacement was caused by the halite-precipitating brines which contained potassium and magnesium ions. The formation of polyhalite was preceded by the syndepositional anhydritization of the original gypsum deposit which has often preserved its primary textures. This anhydritization on the platform and its slopes was a reaction of the precipitated gypsum in a hydrologically open evaporite basin, with brines of salt basins adjacent to the sulphate platform. These brines, when nearly saturated with respect to halite, and potassium and magnesium rich, reacted with anhydrite to precipitate polyhalite along the slopes of the Zdrada Platform. The oxygen and sulphur isotopic compositions of sulphate evaporites indicate that marine solutions were the only source of sulphate ions supplied to the Zechstein basin, and that anhydrite was transformed to polyhalite by reaction with marine brines more concentrated than those that precipitated precursor calcium sulphate minerals.     

Modeling the adsorption of Cd (II), Cu (II), Ni (II), Pb (II) and Zn (II) onto montmorillonite

The adsorption of five toxic metallic cations, Cd(II), Cu(II), Ni(II), Pb(II) and Zn(II), onto montmorillonite was investigated as a function of pH and ionic strength and a two-site surface complexation model was used to predict the adsorption data. The results showed that in the lower pH range, 3∼6 for Cd, Cu, Ni and Zn, and 3∼4.5 for Pb, the adsorption was greatly affected by ionic strength, while in the higher pH range, the adsorption was not. In the lower pH range, the metallic cations were mainly bound through the formation of outer-sphere surface on the permanently charged basal surface sites (≡X⁻), while in the higher pH range the adsorption occurred mainly on the variably charged edge sites (≡SOH) through the formation of inner-sphere surface complexes. Acid-base surface constants and metal binding constants for the two sites were optimized using FITEQL. The adsorption affinity of the five metallic cations to the permanently charged sites of montmorillonite was Pb > Cu > Ni ≈ Zn ≈ Cd, while that to the variable charged sites was Pb ? Cu > Zn > Cd > Ni.     

攀西裂谷内陆盆地自由热对流应力分析及盆地沉降

康滇地区裂谷作用已得到证实,但形成这种地堑地垒的格局有多种解释,以传统的地质力学分析为主。笔者借以热力学的自由热对流原理来加以论述：攀西巨厚的火山岩体在下覆异常地幔热作用下,发生自由热对流,引起热量散失,使地壳沉降与隆起不均衡,生成地堑地垒的格局。自由对流单元的侧向迁移,使盆地形成非对称性。     

Oxidative removal of Mn(II) from solution catalysed by the γ-FeOOH (lepidocrocite) surface

A laboratory study was undertaken to ascertain the role of surface catalysis in Mn(II) oxidative removal. γ-FeOOH, a ferric oxyhydroxide formed by O₂ oxidation of ferrous iron in solution, was studied in the following ways: surface charge characteristics by acid base titration, adsorption of Mn(II) and surface oxidation of Mn(II). A rate law was formulated to account for the effects of pH and the amount of surface on the surface oxidation rate of Mn(II). The presence of milli-molar levels of γ-FeOOH was shown to reduce significantly the half-life of Mn(II) in 0.7 M NaCl from hundreds of hours to hours. The numerical values of the surface rate constants for the γ-FeOOH and that reported for colloidal MnO₂ are comparable in order of magnitude.     

Hydrothermally altered and (copper) mineralized porphyritic intrusions in the Serbo-Macedonian Massif (Greece)

Within the pre-alpidic consolidated Serbo-Macedonian Massif several paleogene hydrothermally altered porphyritic stocks have been found and investigated. The subvolcanic activity was ascertained to be confined to three main centers. Hydrothermal alterations within the stocks and as haloes in the surrounding country rock are widespread, the phyllic and the propylitic alteration facies being predominant, whereas the potassic facies seems to be lacking. Geochemical investigations in the Krousia Mountains and in the Eastern Chalkidiki traced in some of the altered stocks and alteration haloes a sulfide mineralization of porphyry copper type with pyrite, chalcopyrite, galena, sphalerite and some gold. The economic value of this metallogenic province is not yet fully established.     

The stress field near the sites of the Meckering (1968) and Calingiri (1970) earthquakes, Western Australia

A comparison of three methods of stress determination using overcoring tests, earthquake focal-mechanism solutions, and fault-displacement analysis, was carried out near the epicentres of the 1968 Meckering and the 1970 Calingiri earthquakes, Western Australia. Shallow overcoring measurements (3–10 m) were made at seven sites in competent granite, along a 200-km north—south traverse through the location of the Meckering earthquake. The in situ measurements indicate a high regional compressive stress, acting about N77°E. This compares with the direction of the P-axes from the Meckering and Calingiri earthquakes of N91°E and N102°E, respectively, and east-west orientation of major principal stress deduced from observations of surface faulting. The highest maximum principal stress, 23 MPa, was measured at the site farthest north from the Meckering epicentre (~ 90 km), and the lowest, 4 MPa, was measured near the epicentre. The magnitude of the stress increases with distance away from the epicentral area at about 0.2 kPa/m. The results were corrected for drilling water temperature, thermal rock stresses, and suction pore pressure. The total correction was less than 2 MPa at most sites.Estimates of shear stress release from the fault-scarp displacements for Meckering and Calingiri were of similar magnitude (~10 MPa) to the difference between observed shear stress at sites close to and sites remote from the Meckering earthquake.As a cause of the earthquake it is proposed that the fault plane is progressively weakened by alteration or weathering, and that a small long-term fluctuation of head of ground water was the trigger.The high stress at shallow depths, the growing evidence of east—west major principal stress in most of the Australian continent, and the existence of horizontal stress higher than gravity lithostatic stress may have a common explanation, in terms of the driving forces of plate tectonics. The Australian results do not agree with the north—south orientation suggested by crude plate-drift theories in which the major stress is in the direction of the drift, and do not appear to fit with orientations from other continents, in the Richardson et al. (1976) interacting plate model which assumes a velocity-dependent plate driving force. An analysis of driving forces at diverging plate boundaries was carried out and suggests no dominant force-velocity relationship, thus forces independent of plate velocity may control the stress orientation in the plate.     

Characterization of Chromophoric Dissolved Organic Matter (CDOM) in the Bohai Sea and the Yellow Sea Using Excitation-Emission Matrix Spectroscopy (EEMs) and Parallel Factor Analysis (PARAFAC)

Compositions and concentrations of chromophoric dissolved organic matter (CDOM) have been determined in the Bohai Sea (BS) and the Yellow Sea (YS) in the summer and autumn in 2013 by excitation and emission matrix spectroscopy (EEMs) and parallel factor analysis (PARAFAC). The PARAFAC model identified three humic-like components (C1, C2, and C3) and one protein-like component (C4). CDOM exhibited higher fluorescence intensities in the coastal areas in both the summer and autumn. However, its distribution patterns were different in the two seasons. Based on spatial and seasonal distributions of four components, as well as correlations with salinity, chlorophyll a (Chl-a), and apparent oxygen utilization (AOU), the following assignments were made. The C1, C2, and C3 components were mainly dominated by terrestrial inputs and influenced by the primary productivity of phytoplankton in the summer as well. C4 was assigned to terrestrial and autochthonous origins and most likely represented a biologically labile component. Terrestrial inputs were the dominant source of CDOM in the BS and YS. The humification index (HIX) and biological index (BIX) suggested that CDOM in the BS was more stable than that in the YS, which had an increase in autochthonous production, and in the summer, CDOM was less stable with a higher CDOM autochthonous production compared with that in the autumn.     

Report on the 2007 Recertification of the Certified Reference Materials GAS (Serpentinite) and OShBO (Alkaline Granite)

A report is presented on the recertification of two certified reference materials (CRMs) initially prepared and certified by the Central Geological Laboratory of Mongolia (CGL), namely serpentinite GAS and alkaline granite OShBO. Subsequent work done in collaboration with the International Association of Geoanalysts (IAG) followed the International Organisation for Standardisation (ISO) guidelines for certification (ISO Guide 35, 2006) more closely than had been possible originally. The certification protocol followed was that of the International Association of Geoanalysts (IAG). The recertification added to the number of elements that were certified for OShBO (from 21 to 30), but not for GAS (decreased from 15 to 12) because of the greater analytical difficulties posed by that sample matrix in meeting the more stringent metrological requirements for recertification. Further, the uncertainties for these values were established in accordance with the Guide to Measurement Uncertainty ; individual contributions of heterogeneity and bias are reported as appropriate for each of the certified constituents. Traceability of the certified values was demonstrated to the greatest possible extent, based on concurrent analyses of the matrix-matched existing CRMs, SW and GM, by all participating laboratories. The materials are now available from the CGL for use by laboratories in controlling data quality when analysing materials of similar matrices.     

Arsenite adsorption on galena (PbS) and sphalerite (ZnS)

Arsenite, As(III), sorption on galena (PbS) and sphalerite (ZnS) was investigated as a function of solution composition and characterized using X-ray absorption spectroscopy (XAS). Adsorption conformed to a Langmuir isotherm except at the highest surface loadings, and it was not strongly affected by changes in ionic strength. Arsenite sorbed appreciably only at pH > ∼5 for PbS and pH ∼4.5 for ZnS, behavior distinct from its adsorption on other substrates. Arsenite adsorption on PbS and ZnS resulted in the conversion from As-O to As-S coordination. Arsenite does not adsorb through ligand-exchange of surface hydroxyl or sulfhydryl groups. Rather, it forms a polynuclear arsenic sulfide complex on ZnS and PbS consistent with the As₃S₃(SH)₃ trimer postulated by Helz et al. (1995) for sulfidic solutions. This complex was unstable in the presence of oxidizing agents and synchrotron light—it quickly converted to As(V), which was largely retained by the surface. These data illustrate the complexity of As(III) adsorption to even simple sulfide minerals.     

Application of the long chain diol index (LDI) paleothermometer to the early Pleistocene (MIS 96)

Recently, a new organic geochemical paleothermometer based on the relative abundance of long chain alkyl 1,13- and 1,15-diols, the so-called long chain diol index (LDI), was proposed. Because of its novelty, the proxy has not been reported for sediments older than 43 ka. We therefore determined the LDI for 14 sediment samples from the early Pleistocene between 2.49 and 2.41 Ma, comprising Marine Isotope Stage (MIS) 98 to 95, and converted the values to sea surface temperature (SST) estimates to test whether the LDI could be applied or not to the early Quaternary. We show that the long chain diols can be preserved in marine sediments from the early Pleistocene, although at our study site this is limited to periods of increased biomarker accumulation (glacials). Although the results are based on a limited time interval and number of samples, the similarity between LDI-based SST and alkenone-based SST from the same samples suggests that the LDI proxy may have potential for studies covering the entire Quaternary.     

Calibrating the Early Toarcian (Early Jurassic) with stratigraphic black holes (SBH)

Cyclostratigraphic analyses of Upper Pliensbachian and Lower Toarcian carbon-13 isotope (δ¹³C) data, together with radiometric dating, are used to calibrate biozones and magnetic chrons in the Astronomical Time Scale (ATS). In turn, the ATS is used to date sea-level and climate cycles in relation to the Early Toarcian carbon-isotope excursion (T-CIE) and the Karoo-Ferrar Large Igneous Provinces. The resulting chronology however is insufficiently accurate to determine if these global-scale events are causally related. In particular, cyclostratigraphic analyses typically underestimate the durations of biozones by failing to account for hiatuses in depositional discontinuities. To account for hiatuses this paper constructs a δ¹³C reference curve consisting of correlative segments from several localities and dates them with ammonite zones and subzones. By comparing the reference curve to those from numerous localities, four major discontinuity-prone intervals were identified and named ‘stratigraphic black holes’ (SBH). SBH 1 occurs in the Late Pliensbachian P. spinatum Zone. Early Toarcian SBH 2 occurs in a δ¹³C maximum interval in middle D. tenuicostatum Zone. The T-CIE is characterized by a decreasing δ¹³C trend (c. 0.4 myr falling limb) in D. semicelatum Subzone, a minimum δ¹³C interval (c. 0.4 myr valley) and an increasing δ¹³C trend (c. 0.4 myr rising limb) in the E. elegantulum Subzone. SBH 3 occurs at base T-CIE rising limb and SBH 4 near its top or above it in a c. 0.4 myr, post-T-CIE plateau in upper E. elegantulum Subzone. Comparisons to published floating chronologies resulted in an Early Toarcian timescale with ~1.0 myr for the D. tenuicostatum Zone, and ~1.6 myr for the H. serpentinum Zone. Initial volcanism in the Karoo Province correlates with the Pliensbachian/Toarcian boundary at ~183.6 Ma, while its second phase was coeval with the T-CIE. Volcanism in the Ferrar Province correlates with the T-CIE.     

The first record of dinosaurs in the Dalmatian part (Croatia) of the Adriatic-Dinaric carbonate platform (ADCP)

The first discovery of dinosaur footprints on the Dalmatian part of the Adriatic-Dinaric carbonate platform (ADCP) is reported. They constitute the geologically youngest record of footprints on the ADCP. The trackbearing layer was formed in the intertidal environment and represents the final stage of a shallowing-upward cycle. Just below it, a heavy dinoturbated limestone layer can be observed. Microfacies analysis, incorporating evidence from benthic foraminifera and algae, indicates a Late Turonian–Early Coniacian age. The overall morphology and size of the footprints points to sauropod dinosaurs; they represent the largest forms recorded so far on the ADCP. This hints at a prolonged sauropod presence on the platform and to its Late Cretaceous connection to the continent rather than isolation.     

Correlation of Plio-Pleistocene deposits of the Lower Rhine Basin (North-West Germany) and the Valle Ricca pits (Central Italy)

Biostratigraphic and palaeomagnetic research has been carried out on selected profiles in North-Western Germany and Central Italy in order to correlate Plio-Pleistocene sections.Around the Réunion subchronozone, vegetation in the Valle Ricca was dominated by a mountain forest type pointing to cool climatic conditions. In the Lower Rhine Basin vegetation had a slightly warmer character, but was also dominated strongly by a mountain type of forest vegetation, characteristic of cooler summers and higher precipitation than at present.Two warmer periods have been determined in the Central Italian profiles; the youngest around the Olduvai reversal, should correspond to the youngest Tiglian beds of the Lower Rhine Basin.Deposits older than the Réunion subzone have not been found in the Valle Ricca. In the Lower Rhine Basin, on the other hand, the Gauss-Matuyama boundary is located between the uppermost Pliocene, the Reuverian C and the Praetiglian.     

从牙形刺动物群论依木干他乌组的时代

从牙形刺动物群论依木干他乌组的时代张师本，王成源（江汉石油管理局勘探开发研究院，湖北潜江，４３３１２４）（中国科学院南京地质古生物研究所，南京，２１０００８）关键词依木干他乌组，志留系，牙形刺，塔里木盆地，新疆依木干他乌组由地矿部１３大队（１９５６年...     

南泥湖——三道庄钼(钨)矿床中矽卡岩的形成过程及其与钼钨矿化的关系

通过野外地质、光学显微镜以及背散射(BSE)电子图像的观察,南泥湖—三道庄钼(钨)矿床中矽卡岩的形成过程为:第一期流体首先与靠近岩体的大理岩发生反应生成硅灰石、钙铁榴石、钙铝榴石、钙铁辉石和透辉石,当流体继续向外运移遇到灰岩时,直接将其交代形成透辉石矽卡岩或曲卷纹层状透辉石矽卡岩;第二期流体则沿裂隙向围岩中呈面型分布,叠加交代第一期矽卡岩化过程。据此,石榴子石和辉石可以划分为两个世代,第一世代石榴子石(Gro_(3-82)And_(15-96))呈斑点状,第一世代辉石(Di_(18-86)Hd_(13-70)Jo_(0-13))可与斑点状石榴子石共生,也可与斜长石(Ab_(55-70)An_(30-44))共生;第二世代石榴子石(Gro_(23-58)And_(37-74))呈面型分布,第二世代辉石(Di_(0-68)Hd_(28-84)Jo_(3-16))沿裂隙呈面型向围岩中展布。第一世代石榴子石和辉石在空间上分布范围较第二世代广。钼钨矿化在矽卡岩的最早阶段即已开始,贯穿整个矽卡岩的形成过程,引起钼钨沉淀的原因可能是具有较高钼钨含量的流体与围岩发生反应时引起的局部还原性环境。     

Reduction of uranium(VI) under sulfate-reducing conditions in the presence of Fe(III)-(hydr)oxides

Hexavalent uranium [U(VI)] dissolved in a modified lactate-C medium was treated under anoxic conditions with a mixture of an Fe(III)-(hydr)oxide mineral (hematite, goethite, or ferrihydrite) and quartz. The mass of Fe(III)-(hydr)oxide mineral was varied to give equivalent Fe(III)-mineral surface areas. After equilibration, the U(VI)-mineral suspensions were inoculated with sulfate-reducing bacteria, Desulfovibrio desulfuricans G20. Inoculation of the suspensions containing sulfate-limited medium yielded significant G20 growth, along with concomitant reduction of sulfate and U(VI) from solution. With lactate-limited medium, however, some of the uranium that had been removed from solution was resolubilized in the hematite treatments and, to a lesser extent, in the goethite treatments, once the lactate was depleted. No resolubilization was observed in the lactate-limited ferrihydrite treatment even after a prolonged incubation of 4 months. Uranium resolubilization was attributed to reoxidation of the uraninite by Fe(III) present in the (hydr)oxide phases. Analysis by U L₃-edge XANES spectroscopy of mineral specimens sampled at the end of the experiments yielded spectra similar to that of uraninite, but having distinct features, notably a much more intense and slightly broader white line consistent with precipitation of nanometer-sized particles. The XANES spectra thus provided strong evidence for SRB-promoted removal of U(VI) from solution by reductive precipitation of uraninite. Consequently, our results suggest that SRB mediate reduction of soluble U(VI) to an insoluble U(IV) oxide, so long as a suitable electron donor is available. Depletion of the electron donor may result in partial reoxidation of the U(IV) to soluble U(VI) species when the surfaces of crystalline Fe(III)-(hydr)oxides are incompletely reduced.