Thermal equation of state of magnesite to 32 GPa and 2073 K

Pressure–volume–temperature relations have been measured to 32 GPa and 2073 K for natural magnesite (Mg_0.975Fe_0.015Mn_0.006Ca_0.004CO₃) using synchrotron X-ray diffraction with a multianvil apparatus at the SPring-8 facility. A least-squares fit of the room-temperature compression data to a third-order Birch–Murnaghan equation of state (EOS) yielded K₀ = 97.1 ± 0.5 GPa and K′ = 5.44 ± 0.07, with fixed V₀ = 279.55 ± 0.02 Å³. Further analysis of the high-temperature compression data yielded the temperature derivative of the bulk modulus (∂K_T/∂T)_P = −0.013 ± 0.001 GPa/K and zero-pressure thermal expansion α = a₀ + a₁T with a₀ = 4.03 (7) × 10⁻⁵ K⁻¹ and a₁ = 0.49 (10) × 10⁻⁸ K⁻². The Anderson–Grüneisen parameter is estimated to be δ_T = 3.3. The analysis of axial compressibility and thermal expansivity indicates that the c-axis is over three times more compressible (K_Tc = 47 ± 1 GPa) than the a-axis (K_Tc = 157 ± 1 GPa), whereas the thermal expansion of the c-axis (a₀ = 6.8 (2) × 10⁻⁵ K⁻¹ and a₁ = 2.2 (4) × 10⁻⁸ K⁻²) is greater than that of the a-axis (a₀ = 2.7 (4) × 10⁻⁵ K⁻¹ and a₁ = −0.2 (2) × 10⁻⁸ K⁻²). The present thermal EOS enables us to accurately calculate the density of magnesite to the deep mantle conditions. Decarbonation of a subducting oceanic crust containing 2 wt.% magnesite would result in a 0.6% density reduction at 30 GPa and 1273 K. Using the new EOS parameters we performed thermodynamic calculations for magnesite decarbonation reactions at pressures to 20 GPa. We also estimated stability of magnesite-bearing assemblages in the lower mantle.     

Polar mesosphere summer echoes (PMSE) studied at Bragg wavelengths of 2.8 m, 67 cm,and 16 cm

We present observations of radar volume reflectivities under conditions of polar mesosphere summer echoes (PMSE) at three frequencies, i.e., 53.5, 224, and 930 MHz corresponding to Bragg wavelengths of 2.8, 0.67, and 0.16 m. These measurements were made with the ALWIN radar in Andenes and the EISCAT VHF and UHF radars in Tromsø. Contributions to the signal at 930 MHz by incoherent scatter are used to estimate electron number densities and their gradient at PMSE altitudes, and spectral width measurements of Doppler spectra recorded at 224 MHz are used to estimate the turbulent energy dissipation rate. We further derive a theoretical expression for the radar volume reflectivity for the case of turbulent scatter aided by a large Schmidt number (i.e., the current standard theory of PMSE) and show that our observations quantitatively agree with this theory if Schmidt numbers between 2500 and 5000 are assumed. We then show that these Schmidt numbers correspond to ice particles with radii in the range 20–30 nm which should frequently occur in the polar summer mesopause region. In addition, we show that for the short period when PMSE was observed at UHF frequencies the volume reflectivity is proportional to a factor determined by the turbulent energy dissipation rate, electron number density, and the electron number density gradient in agreement with theory. We consider our findings as strong support that PMSE at all considered frequencies is indeed created by turbulent scatter in the presence of a large Schmidt number. We finally highlight that ultimate proof of this concept will require the direct measurement of ice particle sizes in a PMSE environment probed by radars covering frequencies between 50 MHz and 1 GHz.     

Evidence for a ∼ 200–100 ka meteorite impact in the Western Desert of Egypt

In this study, we present evidence, in the form of unusual silicate glasses, for a meteorite impact event ∼ 200–100 ka in the Dakhleh Oasis, Western Desert, Egypt. These glasses, known locally as Dakhleh Glass, were derived from the shock melting of a series of unconsolidated sediments underlain by interbedded carbonates, sandstones and phosphate-rich lithologies. Hypervelocity impact in to a volatile-rich target resulted in the production of impact glasses with CaO and Al₂O₃ contents of up to ∼ 25 and 18 wt.%, respectively. Other notable properties include the presence of globules of immiscible calcite and pyrrhotite melt phases, shattered quartz grains, and fragments of silicified plant matter. Dating of geoarchaeological artefacts associated with the Dakhleh Glass support preliminary ⁴⁰Ar/³⁹Ar data, indicating a ∼ 200–100 ka age for the impact event. Geoarchaeological evidence indicates that archaic Homo sapiens and early modern humans continually inhabited this region of the Western Desert during this period. While it is unclear at present whether the Dakhleh Glass was formed during a cratering event or a large aerial burst, the effect on the environment and inhabitants of Dakhleh would have been catastrophic.     

Entrainment of E. coli and Listeria monocytogenes from sediment in irrigation canal

E. coli and Listeria monocytogenes (or L. monocytogenes) are bacteria affecting fresh produce that is harmful for health of humans and animals. If these bacteria are present in surface waterbody (e.g., irrigation canals), they will impair irrigation water quality and threaten produce safety. This paper studied the resuspension of E. coli and Listeria from bed sediment into irrigation water through several sets of laboratory experiments in an open channel flume. We studied three types of sediments using several flow rates in different velocities and shear stress. Bacteria's concentration in water increases with the bed shear stress. Two empirical relations were derived to correlate the concentration of E. coli and L. monocytogenes with the dimensionless bed shear stress. The experimental data favorably verified the relationships for sandy loam, loamy sand, and loam. The results showed that both bacteria could entrain from sand more efficiently compared to other sediments (i.e., sandy loam or loam). These relationships can be applied to water quality models for simulating E. coli and L. monocytogenes transport in irrigation canals for better managing irrigation water quality.     

FeSi melting curve up to 70 GPa

The melting curve of iron monosilicide, FeSi, has been determined in a laser-heated diamond anvil cell from 6 up to 70 GPa by direct visual observation of the continuous laser-speckle motion in the liquid state. At 12 GPa and 1700 K, a discontinuous change in the slope of the melting curve indicates the first-order phase transition between the ?-FeSi (B20) and the CsCl-type FeSi structures (B2). During the phase transition the coordination number of both, Fe and Si atoms, increases from 7 to 8. Above this pressure, the melting curve rises steeply but shows significant flattening at higher pressures. A comparison with the melting curve of Fe shows that both curves cross at 32 ± 3 GPa, FeSi having higher melting temperatures (about 100 K) at high pressures.     

Up-scaling of SEBAL derived evapotranspiration maps from Landsat (30 m) to MODIS (250 m) scale

Remotely sensed imagery of the Earth’s surface via satellite sensors provides information to estimate the spatial distribution of evapotranspiration (ET). The spatial resolution of ET predictions depends on the sensor type and varies from the 30–60 m Landsat scale to the 250–1000 m MODIS scale. Therefore, for an accurate characterization of the regional distribution of ET, scaling transfer between images of different resolutions is important. Scaling transfer includes both up-scaling (aggregation) and down-scaling (disaggregation). In this paper, we address the up-scaling problem.The Surface Energy Balance Algorithm for Land (SEBAL) was used to derive ET maps from Landsat 7 Enhanced Thematic Mapper Plus (ETM+) and Moderate Resolution Imaging Spectroradiometer (MODIS) images. Landsat 7 bands have spatial resolutions of 30–60 m, while MODIS bands have resolutions of 250, 500 and 1000 m. Evaluations were conducted for both “output” and “input” up-scaling procedures, with aggregation accomplished by both simple averaging and nearest neighboring resampling techniques. Output up-scaling consisted of first applying SEBAL and then aggregating the output variable (daily ET). Input up-scaling consisted of aggregating 30 m Landsat pixels of the input variable (radiance) to obtain pixels at 60, 120, 250, 500 and 1000 m before SEBAL was applied. The objectives of this study were first to test the consistency of SEBAL algorithm for Landsat and MODIS satellite images and second to investigate the effect of the four different up-scaling processes on the spatial distribution of ET.We conclude that good agreement exists between SEBAL estimated ET maps directly derived from Landsat 7 and MODIS images. Among the four up-scaling methods the output simple averaging method produced aggregated data and aggregated differences with the most statistically and spatially predictable behavior. The input nearest neighbor method was the least predictable but was still acceptable. Overall, the daily ET maps over the Middle Rio Grande Basin aggregated from Landsat images were in good agreement with ET maps directly derived from MODIS images.     

Floral changes in calcareous nannofossils and their paleoceanographic significance in the equatorial Pacific Ocean during the last 500 000 years

Abstract   The late Quaternary calcareous nannofossil assemblages from Ocean Drilling Program Holes 807A and 846B, located in the western and eastern equatorial Pacific Ocean, respectively, were analyzed to clarify changes in surface-water conditions during the last 500 000 years. The uppermost Quaternary sediments in both holes contain abundant nannofossils, and their assemblages are characterized by high species diversity. The absolute abundances of coccoliths (specimens/g) and relative numbers of small reticulofenestrids decreased drastically in both holes between 0.3 and 0.2 Ma, whereas the relative abundance of warm-water species and Florisphaera profunda increased suddenly at this time. These data indicate that upwelling around the western and eastern equatorial Pacific regions weakened after 0.2 Ma, which was caused by a decrease in trade-wind strength.