Seagull Lake, Western Eyre Peninsula, South Australia: A Saline Lake to Benefit from Climate Change? Geomorphology, Invertebrates, Birds and the Future

正Seagull Lake is an unusual saline lake,having a marine spring connected to a large continental ecosystem.With climate change the balance between the two is likely to change.This lake originated about 6000 years ago as a     

Structure and age of the northern Leeuwin Complex,Western Australia: Constraints from field mapping and U–Pb isotopic analysis

Rocks in the northern Leeuwin Complex of southwestern Australia preserve evidence of having formed during the breakup of Rodinia and the subsequent amalgamation of Gondwana. Detailed field mapping, structural investigation and U–Pb isotopic zircon analysis, using the Sensitive High‐mass Resolution Ion Microprobe (SHRIMP), have revealed that: (i) protoliths of pink granite gneiss and grey granodiorite gneiss crystallised at ca 750 Ma, coeval with breakup of western Rodinia; (ii) granulite/upper amphibolite facies metamorphism occurred at 522 ± 5 Ma, in the Early Cambrian, ～100 million years later than previous estimates and of identical age to estimates of the final amalgamation of Gondwana; and (iii) three major phases of ductile deformation occurred during or after this metamorphism and represent a progressive strain evolution from subvertical shortening (D1) to subhorizontal east‐west (D2) then north‐northwest‐south‐southeast (D3) contraction.     

Oxidized and reduced mineral assemblages in greenstone belt rocks of the St. Ives gold camp, Western Australia: vectors to high-grade ore bodies in Archaean gold deposits?

Hydrothermal sulfide–oxide–gold mineral assemblages in gold deposits in the Archaean St. Ives gold camp in Western Australia indicate extremely variable redox conditions during hydrothermal alteration and gold mineralization in space and time. Reduced alteration assemblages (pyrrhotite–pyrite) occur in deposits in the southwest of the camp (e.g., Argo, Junction deposits) and moderately to strongly oxidized assemblages (magnetite–pyrite, hematite–pyrite) occur in deposits in the Central Corridor in the northeast (e.g., North Orchin, Revenge deposits). Reduced mineral assemblages flank the Central Corridor of oxidized deposits and, locally, cut across it along E–W trending faults. Oxidized mineral assemblages in the Central Corridor are focused on gravity lows which are interpreted to reflect abundant felsic porphyritic intrusions at about 1,000 m below present surface. Hydrothermal magnetite predates and is synchronous with early phases of gold-associated albite–carbonate–pyrite–biotite–chlorite hydrothermal alteration. Later-stage, gold-associated pyrite is in equilibrium with hematite. The spatial distribution and temporal sequence of iron sulfides and oxides with gold indicate the presence of at least two spatially restricted but broadly synchronous hydrothermal fluids with contrasting redox states. Sulfur isotope constraints support the argument that the different mineral assemblages reflect differences in redox conditions. The δ ³⁴S values for pyrite for the St. Ives gold camp range between −8.4‰ and +5.1‰ with the negative values occurring in oxidized magnetite-rich domains and slightly negative or positive values occurring in reduced, pyrrhotitic domains. Preliminary spatial and paragenetic analysis of the distribution of iron sulfides and oxides in the St. Ives camp suggests that gold grades are highest where the redox state of the hydrothermal alteration assemblages switches from relatively reduced pyrrhotite–pyrite to relatively oxidized magnetite–pyrite and hematite–pyrite both in space and time. Gold deposition is inferred to have occurred where fluids of contrasting redox state mixed.     

Relationships between magmatism,metamorphism and deformation in the Fraser Complex,Western Australia: Constraints from new SHRIMP U–Pb zircon geochronology

SHRIMP U–Pb zircon isotopic data have been obtained for four samples collected from granitoids and paragneisses in the Fraser Complex, a large composite metagabbroic body cropping out in the Mesoproterozoic Albany‐Fraser Orogen of Western Australia. The data are combined with the results of field mapping and petrographic analysis to revise a model for the geological evolution of the Fraser Complex. Three main phases of deformation are recognised in the Fraser Complex (D_1–3) associated with two metamorphic events (M_1–2), which involve four distinguishable episodes of recrystallisation. The first metamorphic event recognised (M_1a/D₁) reached granulite facies and is characterised by peak T ≥800°C and P = 600–700 MPa. A syn‐M_1a/D₁ charnockite has a U–Pb SHRIMP zircon age of 1301 ± 6 Ma, which also provides an estimate for the age of intrusion of Fraser Complex gabbroic rocks. Disequilibrium textures comprising randomly oriented minerals (M_1b), consistent with approximately isobaric cooling, formed in various lithologies in the interval between D₁ and D₂. Post‐D₁, pre‐D₂ granites intruded at 1293 ± 8 Ma and were foliated during the D₂ event, which culminated in the burial of the Fraser Complex to depths equivalent to 800–1000 MPa. Following burial, pyroxene granulites on the western boundary of the complex were pervasively retrogressed to garnet amphibolite (M_2a). An igneous crystallisation age of 1288 ± 12 Ma from a syn‐M_2a aplite dyke suggests that retrogression may have occurred only a few millions of years after the peak of granulite facies metamorphism. Exhumation to depths of less than ～400 MPa occurred within ～20–30 million years of the M_2a pressure peak. Associated deformation (D₃) is characterised by the development of mylonite and transitional greenschist/amphibolite facies disequilibrium textures (M_2b).     

In Situ Stresses in Borehole Blanche-1/South Australia Derived from Breakouts,Core Discing and Hydraulic Fracturing to 2 km Depth

The development of Hot-Dry Rock (HDR) geothermal energy in Australia with drillings to some kilometres depth yields an impetus for deep stress logging. For the Olympic Dam HDR-project, borehole Blanche-1 was drilled to almost 2 km depth and provided the possibility to estimate the in situ stresses within the granitic borehole section by the analysis of borehole breakouts and core discing, as well as by hydraulic fracturing combined with acoustic borehole televiewer logging for fracture orientation determination. Although the stress magnitudes derived by the different methods deviate significantly, they clearly indicate for the depth range between 800 and 1,740 m a compressional stress regime of S _v ≤ S _h < S _H and a consistent East–West orientation of maximum horizontal compression in agreement with existing stress data for Australia. The minor horizontal stress S _h derived from the hydraulic fracturing closure pressure values is about equal to the overburden stress and may be regarded as most reliable.     

Sedimentary processes,stratigraphic sequences and middens: the link between archaeology and geoheritage—a case study from the Quaternary of the Broome region,Western Australia

The cliffed and active dune coastal region of Broome provides an excellent record of Pleistocene and Holocene stratigraphy of desert environments interfacing with the Indian Ocean. The Mesozoic Broome Sandstone is the basal stratigraphic unit in the area and is overlain by Pleistocene red desert quartz sand (Mowanjum Sand). Modern coastal processes of waves, wind and tide have resulted in distinctive sedimentary bodies (stratigraphic units) clearly linked to the sedimentary environment. The Mowanjum Sand, reworked by coastal winds, generates the landward-ingressing orange quartzose Churchill Sand, or reworked by waves and abraded to white sand with the addition of carbonate grains that form the beaches (Cable Beach Sand) and with eolian action, coastal dunes or inland-ingressing white dunes (Shoonta Hill Sand). These sedimentary bodies and stratigraphic units form a template with which to locate and interpret archaeological middens and Indigenous occupation over the past 5000?years in a context of coastal occupation, coastal stability, mean sea-level changes, climate changes, and availability of marine food and freshwater. Shell middens and stone artefacts form definitive layers or horizons in relation to the stratigraphy, in places in situ, and elsewhere reworked as sheets and plumes; understanding their inter-relationships has enabled the unravelling of the archaeological history and relating Indigenous occupation to biofacies and lithofacies. The array of sedimentary, biofacies and stratigraphic units are of national geoheritage significance in their own right. The addition of archaeological deposits as stratigraphic units provides a link between geoheritage and archaeology, where the archaeological materials are viewed as part of the complex stratigraphic story, part of the coastal history, and part of the geoheritage story.     

Oxygen and hydrogen isotope geochemistry of thermal springs of the Western Cape, South Africa: Recharge at high altitude?

A number of thermal springs with temperature up to 64°C are found in the Western Cape Province of South Africa. The average δ¹³C value of gas (CO₂+CH₄) released at three springs is −22, which is consistent with an entirely biogenic origin for the C and supports previous investigations which showed that the springs are not associated with recent or nascent volcanic activity. Most springs issue from rocks of the Table Mountain Group, where faulted and highly jointed quartzites and sandstones of the Cape Fold Belt act as the main deep aquifer. The δD and δ¹⁸O values of the springs range from −46 to −18 and from −7.3 to −3.9, respectively. Although the thermal springs have isotope compositions that plot close to the local meteoric water line, their δD and δ¹⁸O values are significantly lower than ambient meteoric water or groundwater. It is, therefore, suggested that the recharge of most of the thermal springs is at a significantly higher altitude than the spring itself. The isotope ratios decrease wuth increasing distance from the west coast of South Africa, which is in part related to the continental effect. However, a negative correlation between the spring water temperature and the δ¹⁸O value in the thermal springs closest to the west coast indicates a progressive in increase in the average altitude of recharge away from the coast.     

Halogens and noble gases in sedimentary formation waters and Zn–Pb deposits: A case study from the Lennard Shelf,Australia

Halogen ratios (Br/Cl and I/Cl) and concentrations provide important information about how sedimentary formation waters acquire their salinity, but the possible influence of organic Br derived from sedimentary wall-rocks is rarely quantified. Here, it is demonstrated that Br/Cl versus I/Cl mixing diagrams can be used to deconvolve organic Br contributions; that organic matter has a limited range of Br/I ratios; and that organic Br is a more significant component in Zn–Pb deposit ore fluids than previously recognised. The significance of these findings is illustrated for the Lennard Shelf Zn–Pb deposits of Western Australia.Fluid inclusions related to Lennard Shelf Zn–Pb mineralisation have variable salinity and hydrocarbon contents. The halogen data from these fluid inclusions require mixing of three fluid end-members: (1) an evaporated seawater bittern brine (30 wt.% NaCl equiv.) with greater than seawater Br/Cl ratio; (2) a lower salinity pore fluid (?5 wt.% NaCl equiv.) with moderately elevated Br/Cl and I/Cl; and (3) fluids with Br/Cl ratios of ～5 times seawater and extremely elevated I/Cl ratios of ～11,500 times seawater. The first two fluids have ⁴⁰Ar/³⁶Ar of 300–400 and greater than air saturated water ³⁶Ar concentrations that are typical of fluid inclusions related to Zn–Pb mineralisation. The third ‘organic-rich’ fluid has the highest ⁴⁰Ar/³⁶Ar ratio of up to 1500 and a depleted ³⁶Ar concentration.Mineralisation is interpreted to have resulted from mixing of Zn-rich evaporitic brines and H₂S present in hydrocarbons. It is suggested that aqueous fluids acquired organic Br and I from hydrocarbons, and that hydrocarbons exsolving from the aqueous fluid removed noble gases from solution. Interaction of variably saline brines and hydrocarbons could account for the variable Br/Cl and I/Cl composition, and ³⁶Ar concentrations, recorded by Lennard Shelf fluid inclusions. The distinct ⁴⁰Ar/³⁶Ar signature of the fluid with the highest I/Cl ratio suggests the hydrocarbons and brines were sourced independently from different parts of the sedimentary basin. These data indicate the complementary nature of halogen and noble gas analysis and provide new constraints on important mixing processes during sediment-hosted Zn–Pb mineralisation.     

Tectonic controls on sediment provenance evolution in rift basins: Detrital zircon U–Pb and Hf isotope analysis from the Perth Basin,Western Australia

The role of tectonics in controlling temporal and spatial variations in sediment provenance during the evolution of extensional basins from initial rifting to continental breakup and passive margin development are not well established. We test the influence of tectonics in a rift basin that has experienced minimal uplift but significant extension throughout its history: the Perth Basin, Western Australia. We use published zircon U–Pb and Hf isotope data from basin inception through to continental drift and complement this with new data from samples deposited synchronously with the continental breakup of eastern Gondwana. Three primary source regions are inferred, namely the Archean Yilgarn Craton to the east, the Paleo- and Mesoproterozoic Albany–Fraser–Wilkes Orogen to the south and east, and the Mesoproterozoic and Ediacaran–Cambrian Pinjarra Orogen underlying the rift basin and comprising the dominant crustal components to the west and southwest. From mid-Paleozoic basin inception to Early Cretaceous breakup of eastern Gondwana, drainage in the Perth Basin was primarily north- to northwest-directed as evidenced by the dominant Mesoproterozoic detrital zircon cargo, paleodrainage patterns and paleocurrent directions. Thus, provenance was primarily parallel to the rift axis and perpendicular to the extension direction, particularly during periods of thermal subsidence. During episodes of mechanical extension, detrital zircon ages are polymodal and consistently dominated by Paleo- and Mesoproterozoic grains derived from the Albany–Fraser–Wilkes Orogen, but with significant Archean and Neoproterozoic inputs from the rift margins. It is inferred that during mechanical extension the rate of subsidence exceeded sediment supply, which generated basin-margin scarps and enhanced direct input from the rift shoulders. Detrital zircon spectra from temporally-equivalent samples at the rift margin and in the rift axis reveal that distinct sedimentary routing operated on the flanks. In summary, sediment provenance in the Perth Basin (and probably other rift basins) is tectonically controlled by: (1) extension direction, (2) episodes of mechanical extension (rift) or thermal subsidence (post-rift), and (3) proximity to rift axis or rift margin.     

A Holocene high-resolution record of aquatic productivity,seasonal anoxia and meromixis from varved sediments of Lake Łazduny,North-Eastern Poland: insight from a novel multi-proxy approach

Anthropogenic eutrophication and spreading anoxia in freshwater systems is a global concern. Little is known about anoxia in earlier historic times under weaker human impact, or under prehistoric natural conditions with different trophic, land cover and climatic regimes. We use a novel approach that combines high-resolution hyperspectral imaging with µ-XRF and HPLC-pigment data, which allows us to assess chloropigments (productivity) and bacteriopigments (anoxia) at seasonal subvarve-scale resolution. Our ~9700 cal a bp varved sediment record from NE Poland suggests that productivity increased stepwise from oligotrophic Early Holocene conditions (until ~9200 cal a bp ) to mesotrophic conditions in the Mid- and Late Holocene. Natural eutrophication was mainly a function of progressing landscape evolution with intense weathering under dense forest and warm-moist climatic conditions. Generally, anoxia increased with increasing productivity. Seasonal anoxia and some multi-decadal periods of meromixis were the common mixing patterns throughout the Holocene except for a period of persisting meromixis between ~5200 and 2000 cal a bp. Anthropogenic deforestation around 400 cal a bp resulted in substantially better lake oxygenation despite high productivity. In this small lake, aquatic productivity and lakeshore forest cover (wind shield) were more important factors controlling oxic/anoxic conditions than Holocene temperature variability.     

Compositional zoning of fluid inclusions in the Archaean Junction gold deposit,Western Australia: A process of fluid ‐ wall‐rock interaction?

The Junction gold deposit, in Western Australia, is an orogenic gold deposit hosted by a differentiated, iron‐rich, tholeiitic dolerite sill. Petrographic, microthermometric and laser Raman microprobe analyses of fluid inclusions from the Junction deposit indicate that three different vein systems formed at three distinct periods of geological time, and host four fluid‐inclusion populations with a wide range of compositions in the H₂O–CO₂–CH₄–NaCl ± CaCl₂ system. Pre‐shearing, pre‐gold, molybdenite‐bearing quartz veins host fluid inclusions that are characterised by relatively consistent phase ratios comprising H₂O–CO₂–CH₄ ± halite. Microthermometry suggests that these veins precipitated when a highly saline, >340°C fluid mixed with a less saline ≥150°C fluid. The syn‐gold mineralisation event is hosted within the Junction shear zone and is associated with extensive quartz‐calcite ± albite ± chlorite ± pyrrhotite veining. Fluid‐inclusion analyses indicate that gold deposition occurred during the unmixing of a 400°C, moderately saline, H₂O–CO₂ ± CH₄ fluid at pressures between 70 MPa and 440 MPa. Post‐gold quartz‐calcite‐biotite‐pyrrhotite veins occupy normal fault sets that slightly offset the Junction shear zone. Fluid inclusions in these veins are predominantly vapour rich, with CO₂?CH₄. Homogenisation temperatures indicate that the post‐gold quartz veins precipitated from a 310 ± 30°C fluid. Finally, late secondary fluid inclusions show that a <200°C, highly saline, H₂O–CaCl₂–NaCl–bearing fluid percolated along microfractures late in the deposit's history, but did not form any notable vein type. Raman spectroscopy supports the microthermometric data and reveals that CH₄–bearing fluid inclusions occur in syn‐gold quartz grains found almost exclusively at the vein margin, whereas CO₂–bearing fluid inclusions occur in quartz grains that are found toward the centre of the veins. The zonation of CO₂:CH₄ ratios, with respect to the location of fluid inclusions within the syn‐gold quartz veins, suggest that the CH₄ did not travel as part of the auriferous fluid. Fluid unmixing and post‐entrapment alteration of the syn‐gold fluid inclusions are known to have occurred, but cannot adequately account for the relatively ordered zonation of CO₂:CH₄ ratios. Instead, the late introduction of a CH₄–rich fluid into the Junction shear zone appears more likely. Alternatively, the process of CO₂ reduction to CH₄ is a viable and plausible explanation that fits the available data. The CH₄–bearing fluid inclusions occur almost exclusively at the margin of the syn‐gold quartz veins within the zone of high‐grade gold mineralisation because this is where all the criteria needed to reduce CO₂ to CH₄ were satisfied in the Junction deposit.     

Understanding the Interactions between Climate Change, Landscape Evolution, Surface Processes and Tectonics in the Earth System: What Can the Studies of Chinese Deserts Contribute?

Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in deserts are, however, diverse and different over the globe with regard to their geomorphological nature, human activities and geological histories. In the last decades a great number of efforts have been put to the investigation of the initial timing of the occurrence of arid climate, e. g. in northwestern China. Silty sediments in the downwind directions have been used to deduce the histories of deserts. In general, there is a lack of knowledge about processes and landscapes in Chinese drylands between the initial Miocene silt sedimentation at desert margins and the late Quaternary multiple occurrences of wetter climate with assumed large lakes in many of the deserts in northern China. The geomorphological concept of three primary triggering factors, i.e., the sediment supply, sediment availability and transport capacity of wind, and additionally the underground geology need to be fully considered for a better understanding of the environmental histories of sand seas which should not be viewed as equivalent for deserts because sand seas cover between < 1% and ca. 45% of the desert areas in various continents dependent on a complex interaction between various processes of both exogenous and endogenous origins.